• Title/Summary/Keyword: Heating film

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Synthesis and Characterization of Aromatic Polyamideamide-imide and Polyamide-imide copolymers

  • Kim, Sang-Hern
    • Journal of the Korean Applied Science and Technology
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    • v.25 no.2
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    • pp.144-150
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    • 2008
  • The polyamide-amide-imide (PAAI) was synthesized by reacting 4,4'-diaminobenzanilide (DBA) with trimellitic anhydride chloride using a two-stage heating. The precursor of polyamide-acids was formed at first stage and followed by the formation of imide of PAAI. Two polyamide-imides (PAIs) were prepared from benzidine (BZ) or 4,4'-diaminodiphenylether (DPE) with trimellitic anhydride chloride. These three polymers had glass transition temperature in the temperature range of $240-250^{\circ}C$. X-ray data were obtained on thin film specimens cured at $250^{\circ}C$. There was a minimal kind of short-range order consisting of the most probable distances between neighboring chains. The average segmental spacing of short-range order decreased in the order of polymers obtained from 4,4'-diaminobenzanilide (DBA), polyamide-imide, and 4,4'-diaminodiphenylether (DPE). The imidization of three polyamide-imides was confirmed by $^{15}N$ MAS NMR and FT-IR spectroscopy. $^{15}N$ NMR spectrum of cured polyamide-imide showed imide $^{15}N$ peak, thereby providing an evidence for the imidization of three polyamide-imides.

Critical heat flux measurement experiment to improve safety of copper nano-particle coated heat exchanger (구리나노입자가 코팅된 열교환기의 안전성 향상을 위한 임계 열유속 측정실험)

  • Mo, Yong-Hyun;Kim, Nam-Jin;Jeon, Yong-Han;Lee, Deok-Soo
    • Journal of the Korea Safety Management & Science
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    • v.19 no.4
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    • pp.317-322
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    • 2017
  • When the heat flux on the heating surface following changing heat condition in the boiling heat transfer system exceeds critical heat flux, the critical heat flux phenomenon is going over to immediately the film boiling area and then it is occurred the physical destruction phenomenon of various heat transfer systems. In order to maximize the safe operation and performance of the heat transfer system, it is essential to improve the CHF(Critical Heat Flux) of the system. Therefore, we have analysis the effect of improving CHF and characteristics of heat transfer following the nanoparticle coating thickness. As the results, copper nanocoating time are increased to CHF, and in case of nano-coatings are increased spray-deposited coating times more than in the fure water; copper nanopowder is increased up to 6.40%. The boiling heat transfer coefficients of the pure water are increased up to 5.79% respectively. Also, the contact angle is decreased and surface roughness is increased when nano-coating time is increasingly going up.

Contamination Particle and Cracking Behavior of the Anodic Oxidation in Sulfuric Acid Containing Cerium Salt (세륨염을 첨가한 황산법 양극산화피막의 오염입자 및 열크랙 거동)

  • So, Jongho;Yun, Ju-Young;Shin, Jae-Soo
    • Journal of the Semiconductor & Display Technology
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    • v.17 no.4
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    • pp.11-15
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    • 2018
  • The parts of equipment for semiconductor are protected by anodic aluminum oxide film to prevent corrosion. This study investigated contamination particle and cracking behavior of anodic oxidation in sulfuric acid containing cerium salt. The insulating properties of the sample were evaluated by measuring the breakdown voltage. It was confirmed that the breakdown voltage was about 50% higher when the cerium salt was added, and that the breakdown voltage after the heat treatment was 55% and 35% higher at $300^{\circ}C$ and $400^{\circ}C$, respectively. After heating at $300^{\circ}C$ and $400^{\circ}C$, cracks were observed in non cerium and cerium 3mM, and more cracks occur at $400^{\circ}C$ than at $30^{\circ}C$. The amount of contamination particles generated in the plasma is about 45% less than that of non-cerium specimens.

Development of Retort Packaging Material Using Cellulose Nano Fiber (셀룰로오스 나노 파이버를 적용한 레토르트 포장재 개발)

  • Lee, Jinhee;Choi, Jeongrak;Koo, Kang
    • Textile Coloration and Finishing
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    • v.33 no.1
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    • pp.40-47
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    • 2021
  • As modern society develops, it becomes very complex and diverse, and interests in the convenience of life and the natural environment are gradually increasing. Products used in our daily life are also changing according to the needs of consumers, and food packaging is one of them. In particular, retort packaging materials have been used for the purpose of long-term preservation of contents, but the appearance of products suitable for recent environmental issues has been somewhat delayed. Therefore, in order to develop eco-friendly and human-friendly products by replacing the metals used in the existing retort packaging materials, the possibility of substitution was examined using cellulose nanofibers, a natural material. As a result, it can be seen that all functions can be replaced according to the existing long-term storage characteristics for retort packaging films. In particular, not only oxygen permeability and water vapor permeability, which are one of the most important factors, but also heat resistance, which is heating durability, is evaluated as applicable to commercialization compared to products using metals currently in use.

Characteristics of $YBa_2Cu_3O_{7-x}$ Thin Films on $SrTiO_3$ substrate with surface modification by Au nanoparticles (STO기판에 금 나노입자가 분산된 YBCO 박막의 특성)

  • Oh, Se-Kweon;Jang, Gun-Eik;Tran, Hai Duc;Kang, Byoung-Won;Lee, Cho-Yeon;Hyun, Ok-Bae
    • Progress in Superconductivity and Cryogenics
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    • v.12 no.3
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    • pp.7-11
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    • 2010
  • For many large-scale applications of high-temperature superconducting materials, large critical current density($J_c$) in high applied magnetic fields are required. A number of methods have been reported to introduce artificial pinning centers(APCs) in $YBa_2Cu_3O_{7-\delta}$(YBCO) films for enhancement of their $J_c$. In this work, we investigated electric characteristic of YBCO films on $SrTiO_3$ (100) substrates whose surfaces were modified by the introduction of Au nanoparticles (AuNPs). Au nanoparticles were uniformly dispersed on STO substrates with one of typical solution techniques, self assembled monolayer. After heating the STO substrates with Au nanoparticles, the size of Au nanoparticles was around 29~32 nm in height and 41~49 nm in diameter. XRD diffraction patterns taken on the YBCO film with Au nanoparticles show the c-axis orientation. The measured $T_c$ of YBCO /AuNPs films was around 89K and the $J_c$ was 0.75 MA/$cm^2$ at 65 K and 1 T.

Laser-Induced Recrystallization of Perovskite Materials for High-Performance Flexible Light-Emitting Diode (고성능 유연 발광 다이오드 소자 구현을 위한 레이저 기반 페로브스카이트 소재의 재결정화)

  • Jae Chan Heo;Ji Eun Kim;Dong Gyu Lee;Yun Sik Hwang;Yu Mi Woo;Han Eol Lee;Jung Hwan Park
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.36 no.3
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    • pp.286-291
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    • 2023
  • Perovskite materials are promising candidates for next-generation optoelectronic devices owing to their outstanding external quantum efficiency, high color purity, and ability to tune the light emission wavelength. However, conventional thermal annealing processes caused the degradation of perovskite, resulting in poor optoelectronic properties and a short lifetime. Herein, we propose a laser-induced recrystallization of perovskite thin film to enhance its light-emitting properties. Laser-induced recrystallization process was performed using rapid and instantaneous laser heating, which successfully induced grain growth of the perovskite material. The laser processing conditions were thoroughly optimized based on theoretical calculations and various material analyses such as x-ray diffraction, scanning electron microscope, and photoluminescence spectroscopy.

Recent Progress in Air-Conditioning and Refrigeration Research : A Review of Papers Published in the Korean Journal of Air-Conditioning and Refrigeration Engineering in 2015 (설비공학회 분야의 최근 연구 동향 : 2015년 학회지 논문에 대한 종합적 고찰)

  • Lee, Dae-Young;Kim, Sa Ryang;Kim, Hyun-Jung;Kim, Dong-Seon;Park, Jun-Seok;Ihm, Pyeong Chan
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.28 no.6
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    • pp.256-268
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    • 2016
  • This article reviews the papers published in the Korean Journal of Air-Conditioning and Refrigeration Engineering during 2015. It is intended to understand the status of current research in the areas of heating, cooling, ventilation, sanitation, and indoor environments of buildings and plant facilities. Conclusions are as follows. (1) The research works on the thermal and fluid engineering were carried out in the areas of flow, heat and mass transfer, cooling and heating, and air-conditioning, the renewable energy system and the flow inside building rooms. Research issues dealing with air-conditioning machines and fire and exhausting smoke were reduced. CFD seems to be spreading to more research areas. (2) Research works on heat transfer area were carried out in the categories of heat transfer characteristics, pool boiling and condensing heat transfer and industrial heat exchangers. Researches on heat transfer characteristics included the economic analysis of GHG emission, micro channel heat exchanger, effect of rib angle on thermal performance, the airside performance of fin-and-tube heat exchangers, theoretical analysis of a rotary heat exchanger, heat exchanger in a cryogenic environment, the performance of a cross-flow-type, indirect evaporative cooler made of paper/plastic film. In the area of pool boiling and condensing, the bubble jet loop heat pipe was studied. In the area of industrial heat exchangers, researches were performed on fin-tube heat exchanger, KSTAR PFC and vacuum vessel at baking phase, the performance of small-sized dehumidification rotor, design of gas-injection port of an asymmetric scroll compressor, effect of slot discharge-angle change on exhaust efficiency of range hood system with air curtain. (3) In the field of refrigeration, various studies were carried in the categories of refrigeration cycle, alternative refrigeration/energy system, system control. In the refrigeration cycle category, a cold-climate heat pump system, $CO_2$ cascade systems, ejector cycles and a PCM-based continuous heating system were investigated. In the alternative refrigeration/energy system category, a polymer adsorption heat pump, an alcohol absorption heat pump and a desiccant-based hybrid refrigeration system were investigated. In the system control category, turbo-refrigerator capacity controls and an absorption chiller fault diagnostics were investigated. (4) In building mechanical system research fields, eighteen studies were reported for achieving effective design of the mechanical systems, and also for maximizing the energy efficiency of buildings. The topics of the studies included energy performance, HVAC system, ventilation, and renewable energies, piping in the buildings. Proposed designs, performance tests using numerical methods and experiments provide useful information and key data which can improve the energy efficiency of the buildings. (5) The field of architectural environment was mostly focused on indoor environment and building energy. The main researches of indoor environment were related to the user and location awareness technology applied dimming lighting control system, the lighting performance evaluation for light-shelves, the improvement evaluation of air quality through analysis of ventilation efficiency and the evaluation of airtightness of sliding and LS window systems. The subjects of building energy were worked on the energy saving estimation of existing buildings, the developing model to predict heating energy usage in domestic city area and the performance evaluation of cooling applied with economizer control. The studies were also performed related to the experimental measurement of weight variation and thermal conductivity in polyurethane foam, the development of flame spread prevention system for sandwich panels, the utilization of heat from waste-incineration facility in large-scale horticultural facilities.

Thermally Stimulated Current Analysis of (Ba, Sr)TiO$_3$ Capacitor ((Ba, Sr)TiO$_3$ 커패시터의 Thermally Stimulated Current분석)

  • Kim, Yong-Ju;Cha, Seon-Yong;Lee, Hui-Cheol;Lee, Gi-Seon;Seo, Gwang-Seok
    • Journal of the Institute of Electronics Engineers of Korea SD
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    • v.38 no.5
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    • pp.329-337
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    • 2001
  • It has been known that the leakage current in the low field region consists of the dielectric relaxation current and intrinsic leakage current, which cause the charge loss in dynamic random access memory (DRAM) storage capacitor using (Ba,Sr)TiO$_{3}$ (BST) thin film. Especially, the dielectric relaxation current should be seriously considered since its magnitude is much larger than that of the intrinsic leakage current in giga-bit DRAM operation voltage (~IY). In this study, thermally stimulated current (TSC) measurement was at first applied to investigate the activation energy of traps and relative evaluation of the density of traps according to process change. And, through comparing TSC to early methods of I-V or I-t measurement and analyzing, we identify the origin of the dielectric relaxation current and investigate the reliability of TSC measurement. First, the polarization condition such as electric field, time, temperature and heating rate was investigated for reliable TSC measurement. From the TSC measurement, the energy level of traps in the BST thin film has been investigated and evaluated to be 0.20($\pm$0.01) eV and 0.45($\pm$0.02) eV. Based on the TSC measurement results before and after rapid thermal annealing (RTA) process, oxygen vacancy is concluded to be the origin of the traps. TSC characteristics with thermal annealing in the MIM BST capacitor have shown the same trends with the current-voltage (I-V) and current-time (I-t) characteristics. This means that the TSC measurement is one of the effective methods to characterize the traps in the BST thin film.

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Electrical Properties of Sputtered Gallium-doped Zinc Oxide Films Deposited Using Ne, Ar, or Kr Gas (Ne, Ar, Kr 가스를 사용하여 제작한 스퍼터 Gallium 도프 ZnO 박막의 전기적 특성)

  • Song, Pung-Keun;Ryu, Bong-Ki;Kim, Kwang-Ho
    • Journal of the Korean Ceramic Society
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    • v.39 no.10
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    • pp.935-942
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    • 2002
  • Gallium-doped ZnO (GZO) films were deposited on soda-lime glass substrate without heating using Ne, Ar, or Kr gas. Electrical properties of GZO films deposited at various total gas pressures were investigated for the film positions corresponding to the erosion region (region B) and outside the erosion region (region A) of the target. Region B showed high resistivity, which was attributed to the decrease in carrier density and Hall mobility, compared to region A. GZO films deposited using Ne gas showed the degradation in resistivity and crystallinity, whereas, GZO films deposited using Kr gas showed the improvement in resistivity and crystallinity. This degradation in film properties could be attributed to the film damage caused by the bombardment of high-energy particles. Especially, the energies of recoiled neutral atoms ($Ne^0,\;Ar^0,\;Kr^0$) calculated by Monte Carlo simulation corresponded to experimental results.

Effect of Planting Density on Growth and Quality in Hydroponics of Sedum sarmentosum (돌나물 수경재배에서 재식밀도에 따른 생육 및 품질 특성)

  • Lee, Seung-Yeob;Kim, Hyo-Jin;Bae, Jong-Hyang
    • Horticultural Science & Technology
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    • v.28 no.4
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    • pp.580-584
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    • 2010
  • The effect of planting densities on the growth of $Sedum$ $samentosum$ (4 collections) was investigated using nutrient film technique (NFT) with Yamazaki' lettuce nutrient solution (1982) from September 5th to October 24th in non-heating plastic film house. At 40 days, the plant height of 4 collections showed the range of 15.0-18.9 cm, and mean plant height was high the order of $10{\times}10$, $2.5{\times}2.5$, and $5{\times}5cm$. The growth of 'Pohang' and 'Wando' collections was better compared to that of 'Gunsan' and 'Wanju' collections. Number of node, stem diameter, and fresh and dry weight per plant were decreased in higher planting density. Despite the lower fresh weight per plant obtained, the fresh yield per $m^2$ was significantly increased in higher planting density. The mean fresh yield was $14.9kg{\cdot}m^{-2}$ in $2.5{\times}2.5cm$, and 'Pohang' collection showed the highest fresh yield ($17.6kg{\cdot}m^{-2}$). The first optimized harvesting time base on plant height was 30-40 days after NFT culture during autumn season. In eating quality, compression force of stem and bitterness of shoot were decreased in higher planting density. However, the heavy labor demanding high density cutting needs to be improved for hydroponic culture of $S.$ $samentosum$.