• Title/Summary/Keyword: Heating and low temperature

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Analysis of Ammonium Carbamate Used as a NOx Reducing Agent for the SCR System of Marine Diesel Engines (선박용 디젤엔진 SCR 시스템에 NOx 환원제로 사용되는 암모늄 카바메이트의 물질 성분 분석 연구)

  • Kim, Hongsuk;Ryu, Younghyun
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.26 no.6
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    • pp.751-758
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    • 2020
  • SCR technology, which uses urea-water as a NOx reducing agent, has been widely used to reduce NOx in marine diesel engines. However, as an alternative NOx reducing agent, solid-phase ammonium carbamate has several advantages, such as low-temperature NOx reduction performance and NH3 storage capacity. This study presents a method for evaluating the purity of ammonium carbamate using EA, FTIR, and XRD to investigate the change in the material characteristics of ammonium carbamate when it is exposed to various temperature and pressure conditions. In this study, it was found that the purity of ammonium carbamate can be effectively evaluated via EA analysis. The FTIR analysis results confirmed that the properties of ammonium carbamate did not change even after repeated heating and cooling under thermal decomposition temperature conditions, which may be applied to the SCR system of marine diesel engines. Additionally, it was found that when ammonium carbamate was exposed to the atmosphere for a long time, it transformed into ammonium carbonate.

A Study on Development of Composite Ultrasonic Transducer Assembly with Drug Transfer Function (약물 이송기능을 갖는 복합구조 초음파 변환기 어셈블리 개발에 관한 연구)

  • Noh, Si-Cheol;Kim, Ju-Young;Yoo, Byeong-Cheol;Jung, Bong-Jae
    • Journal of the Korean Society of Radiology
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    • v.11 no.5
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    • pp.353-359
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    • 2017
  • The sonophoresis, a representative low-intensity ultrasonic therapy, is a technique for delivering the drugs into the epidermis, dermis and skin appendages by using physical vibration and heat effects of the ultrasonic waves. Sonophoresis could increases the delivering and absorption efficiency of the drugs usually consisting of hydrophilic molecules and macromolecules. In addition, it has the advantage of being effective in delivering drugs with relatively large molecular sizes such as insulin or lipid. In this study, we proposed a multi-structure ultrasonic transducer assembly with a large-size single piezoelectric element and a drug delivery function at the treatment site for efficient sonophoresis treatment. Futhermore, a transducer assembly structure capable of raising and maintaining the temperature of the treatment site was proposed and evaluated for effectiveness. The transducer assembly proposed in this study is expected to improve the efficiency of sonophoresis by providing a constant amount of drug, and assisting drug delivery through heating the treatment site.

Purification and Characterization of Polyphenol Oxidase from Burdock (Arctium lappa L.) (우엉(Arctium lappa L.) 뿌리 Polyphenol Oxidase의 부분정제 및 특성)

  • Lim, Jeong-Ho;Jeong, Moon-Cheol;Moon, Kwang-Deog
    • Food Science and Preservation
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    • v.12 no.5
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    • pp.489-495
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    • 2005
  • Polyphenol oxidase (PPO) from Burdock (Arctium lappa L.) was purified and characterized. Purification of polyphenol oxidase was achieved by ammonium sulfate precipitation, Phenyl-sepharose CL-4B hydrophobic chromatography and Sephadex G-100 gel filtration chromatography. The molecular mass of the purified PPO was estimated to be 30 kDa by SDS polyacrylamide gel electrophoresis. In a substrate specificity, maximum activity was achieved with chlorogenic acid, followed by catechol and catechin. Whereas, there was low activity with hydroquinic acid, resorcinol or tyrosine. The optimum pH and temperature for enzyme activity were 7.0 and 35$\circC$ with catechol, respectively. The enzyme was most stable at pH 7.0 while unstable at acidic and alkaline pH. The enzyme was stable when heated to 40$\circC$. But heating at 50$\circC$ for more than 30 min caused 50% loss of activity. Ascorbic acid, L-cystein and $Cu^{2+}$ inhibited the activity of pholyphenol oxidase.

A Study on the Properties of AlN Films Deposited with Nitrogen Ion Beam Assisted RF Magnetron Sputtering (질소이온 빔 보조 마그네트론 스퍼터로 증착 된 AlN 박막의 물성연구)

  • Heo, Sung-Bo;Lee, Hak-Min;Jeong, Chul-Woo;Choi, Dae-Han;Lee, Byung-Hoon;Kim, Min-Gyu;You, Yong-Zoo;Kim, Daeil
    • Journal of the Korean Society for Heat Treatment
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    • v.24 no.2
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    • pp.77-81
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    • 2011
  • Aluminum nitride (AlN) thin films were prepared by using nitrogen ion beam assisted reactive radio frequency (RF) magnetron sputtering on the glass substrates without intentional substrate heating. After deposition, the effect of nitrogen ion beam energy on the structural and optical properties of AlN films were investigated by x-ray diffraction (XRD), atomic force microscope (AFM) and UV-Vis. spectrophotometer, respectively. AlN films deposited with $N^+$ ion irradiation at 100 eV show the higher (002) peak intensity in XRD pattern than other films. It means that $N^+$ ion energy of 100 eV is the favorable condition for low temperature crystallization. AFM images also show that surface average roughness is increased from 1.5 to 9.6 nm with $N^+$ ion energy in this study. In an optical observation, AlN films which deposited by $N^+$ ion beam energy of 100 eV show the higher transmittance than that of the films prepared with the other $N^+$ ion beam conditions.

Optimum Pumping Rates of Ground-Water Heat Pump System Using Groundwater or Bank Infilterated Water (강변여과수와 천부 지하수를 이용하는 지하수 열펌프시스템의 적정유량)

  • Hahn, Jeong-Sang;Han, Hyuk-Sang;Hahn, Chan;Jeon, Jae-Soo;Kim, Hyong-Soo
    • Economic and Environmental Geology
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    • v.40 no.6
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    • pp.833-841
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    • 2007
  • The groundwater heat pump system(GWHP) is one of the most efficient ground source heat pump system(GSHP) which uses low grade and shallow geothermal energy for cooling and heating purpose. The GWHP system shall be designed properly based on peak block load performance and optimum pumping rate of groundwater comparable to ground coupled heat pump system(GCHP). The optimum pumping rate depends on groundwater temperature at a specific site, size of plate heat exchanger, and total head loss occurred by whole system comprising pumps and pipings. The required optimum flow rates of the system per RT are ranged from 3.8 to 9.8lpm being less than the typical building loop flow of 9.5 to 11.4lpm.

Control of Size and Morphology of Particles Using CO2 Laser in a Flame (화염증 CO2 Laser를 이용한 입자의 크기 및 형상 제어)

  • Lee, Donggeun;Lee, Seonjae;Choi, Mansoo
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.23 no.11
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    • pp.1379-1389
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    • 1999
  • A new technique for control of size and shape of flame-made particles is Introduced. The characteristic sintering time can be controlled Independently of collision time by heating the particles with irradiation of laser because the sintering time strongly depends on temperature. A coflow oxy-hydrogen diffusion flame burner was used for $SiCl_4$ conversion to silica particle. Nanometer sized aggregates irradiated by a high power CW $CO_2$ laser beam were rapidly heated up to high temperatures and then were sintered to approach volume-equivalent spheres. The sphere collides much slower than the aggregate, which results in reduction of sizes of particles maintaining spherical shape. Light scattering of Ar ion laser and TEM observation using a local sampling device were used to confirm the above effects. When the $CO_2$ laser was irradiated at low position from the burner surface, particle generation due to gas absorption of laser beam occurred and thus scattering intensity increased with $CO_2$ laser power. At high irradiation position, scattering intensity decreased with $CO_2$ laser power and TEM image showed a clear mark of evaporation and recondensation of particles for high $CO_2$ laser power. When the laser was irradiated between the above two positions where small aggregates exist, average size of spherical particles obviously decreased to 58% of those without $CO_2$ laser irradiation with the spherical shape. Even for increased carrier gas flow rate by a factor of three, TEM photograph also revealed considerable reduction of particle size.

Surface Discharge Characteristics of Phenolic Resin Treated by Heat and Its Structure Analysis (열처리된 페놀수지 표면에서의 방전 특성과 구조분석)

  • Shong, Kil-Mok;Roh, Young-Su;Kwak, Hee-Ro
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.20 no.8
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    • pp.71-79
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    • 2006
  • For clearing the cause of firing due to the tacking on the surface of phenolic resin, this paper describes the analysis through a couple of methods ; FT-IR; DTA; photograph analysis, etc. Phenolic resin has been widely employed as a case of low voltage appliances. In the experiment it was confirmed that its surface was carbonized and graphitized by the external fire. In the FT-IR test a graphite specimen thermally treated at $150[^{\circ}C]$ showed the 2 different IR absorption peaks at $1,730[cm^{-1}]\;and\;1,680[cm^{-1}]$. In normal phenolic resin, the exothermic peak appeared at $450[^{\circ}C]$, while in graphite specimen, it appeared at $610[^{\circ}C]$ in DTA test. From the results, the electrical fire causes could be cleared and it is expected to protect the human life and property from the electrical fire by using the important data.

The Study on Fabrication of LAS System Ceramics for Thermal Shock Resistance from Silicate Minerals: (I) Preparation of Eucryptite Powders with Sillimanite Group, Kaolin Group Minerals (실리케이트 광물을 이용한 내열충격성 LAS계 세라믹스의 제조에 관한 연구: (I) Sillimanite와 Kaolin족 광물을 이용한 Eucryptite 분말합성)

  • 박한수;조경식;문종수
    • Journal of the Korean Ceramic Society
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    • v.31 no.5
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    • pp.572-580
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    • 1994
  • With low thermal expansion coefficients, eucryptite (Li2O.Al2O3.2SiO2) and spodumene (Li2O.Al2O3.4SiO2) in LAS ceramic system show good thermal shock resistance. In this study, sillimanite or kaolin group silicate minerals and Li2CO3 were used as starting materials, and if necessary SiO2 or Al2O3 were added for making stoichiometrically formed specimens. By this process, eucryptite powders were synthesized and characterized. The powder mixtures of lithiumcabonate and silicate minerals calcined at 80$0^{\circ}C$ for 2 hrs were made into powder compacts. $\beta$-Eucryptite single phase was formed via intermediate phases of Li2SiO3 and LiAlO2 et al, by heating at 110$0^{\circ}C$ or 120$0^{\circ}C$ for 10 hrs from those powder compacts. When using the sillimanite group minerals, Virginia kyanite or andalusite was reacted to form eucryptite at 120$0^{\circ}C$and CMK International kyanite were completed at 110$0^{\circ}C$. When kaolin group minerals were used, it was found that the synthesizing temperature (100$0^{\circ}C$) of $\beta$-eucryptite from the mixture of New Zealand white kaolin was lower than that from Hadong pink kaolin (110$0^{\circ}C$). The Microstructure of systhesized powder showed the irregular lump shape such as densed crystallines.

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Characteristic Analysis of Al Films Grown on Plastic Substrates and Glass Substrates (고분자 플라스틱 기판과 유리 기판위에 증착한 알류미늄 박막 특성 분석)

  • Lee, Myoung-Jae;Kwak, Sung-Kwan;Kim, Dong-Sik;Kim, Jang-Kwon
    • Journal of the Institute of Electronics Engineers of Korea TE
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    • v.39 no.2
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    • pp.6-10
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    • 2002
  • Al films (1000~4000${\AA}$)were deposited on glass and polymer(polyethersulfine) plastic substrates by DC-magnetron sputtering for plastic-based flat-panel displays. A stepped heating process was used both to improve the electrical characteristics and to diminish the thermal expansion of the polymer substrates. Following this procedure, we could succeed in sputtering Al films without any cracking or shrinkage of the polymer substrates. The treatment temperatures and deposited process of Al films were under 200$^{\circ}C$. Also, this low temperature fabrication process allows the application of plastic substrates. Scanning Electrom Microscopy, Atomic Force Microscopy, X-ray Dffractometry, and electrical measurements such as resistivity measurements were performed to investigate the properties of deposited the Al films and their reliability. 

The Development of Infrared Thermal Imaging Safety Diagnosis System Using Pearson's Correlation Coefficient (피어슨 상관계수를 이용한 적외선 열화상 안전 진단 시스템 개발)

  • Jung, Jong-Moon;Park, Sung-Hun;Lee, Yong-Sik;Gim, Jae-Hyeon
    • Journal of the Korean Solar Energy Society
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    • v.39 no.6
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    • pp.55-65
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    • 2019
  • With the rapid development of the national industry, the importance of electrical safety was recognized because of a lot of new electrical equipment are installing and the electrical accidents have been occurring annually. Today, the electrical equipments is inspect by using the portable Infrared thermal imaging camera. but the most negative element of using the camera is inspected for only state of heating, the reliable diagnosis is depended with inspector's knowledge, and real-time monitoring is impossible. This paper present the infrared thermal imaging safety diagnosis system. This system is able to monitor in real time, predict the state of fault, and diagnose the state with analysis of thermal and power data. The system consists of a main processor, an infrared camera module, the power data acquisition board, and a server. The diagnostic algorithm is based on a mathematical model designed by analyzing the Pearson's Correlation Coefficient between temperature and power data. To test the prediction algorithm, the simulations were performed by damaging the terminals or cables on the switchboard to generate a large amount of heat. Utilizing these simulations, the developed prediction algorithm was verified.