• Proceedings of the Materials Research Society of Korea Conference
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• 2011.05a
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• pp.11.2-11.2
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• 2011

Polymer based organic photovoltaics have attracted a great deal of attention due to the potential cost-effectiveness of light-weight and flexible solar cells. However, most BHJ polymer solar cells are not thermally stable as subsequent exposure to heat drives further development of the morphology towards a state of macrophase separation in the micrometer scale. Here we would like to show three different approaches for developing new electroactive polymers to improve the thermal stability of the BHJ solar cells, which is a critical problem for the commercialization of these solar cells. For one of the examples, we report a new series of functionalized polythiophene (PT-x) copolymers for use in solution processed organic photovoltaics (OPVs). PT-x copolymers were synthesized from two different monomers, where the ratio of the monomers was carefully controlled to achieve a UV photo-crosslinkable layer while leaving the ${\pi}-{\pi}$ stacking feature of conjugated polymers unchanged. The crosslinking stabilizes PT-x/PCBM blend morphology preventing the macro phase separation between two components, which lead to OPVs with remarkably enhanced thermal stability. The drastic improvement in thermal stabilities is further characterized by microscopy as well as grazing incidence X-ray scattering (GIXS). In the second part of talk, we will discuss the use of block copolymers as active materials for WOLEDs in which phosphorescent emitter isolation can be achieved. We have exploited the use of triarylamine (TPA) oxadiazole (OXA) diblock copolymers (TPA-b-OXA), which have been used as host materials due to their high triplet energy and charge-transport properties enabling a balance of holes and electrons. Organization of phosphorescent domains in TPA-b-OXA block copolymers is demonstrated to yield dual emission for white electroluminescence. Our approach minimizes energy transfer between two colored species by site isolation through morphology control, allowing higher loading concentration of red emitters with improved device performance. Furthermore, by varying the molecular weight of TPA-b-OXA and the ratio of blue to red emitters, we have investigated the effect of domain spacing on the electroluminescence spectrum and device performance.

• Journal of Korea Water Resources Association
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• v.44 no.9
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• pp.741-751
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• 2011

In this study, a methodology was devised to overcome that difficulty for thermal stratification modeling using EFDC. For the increase of reproductability for thermal stratification analysis, the effect of parameter such as distribution of solar radiation, depth of active bed temperature layer, heat transfer coefficients were analyzed. The simulation period was from June to December in 2005 and statistical index is used to analyze the model results. The results showed that distribution of solar radiation is zero and depth of active bed temperature layer is 10 m are suitable for simulation of thermal stratification in Yongdam Dam reservoir. This study results can be used for guideline to analyze the thermal stratification of large dam reservoir in Korea.

• The KSFM Journal of Fluid Machinery
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• v.17 no.3
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• pp.19-24
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• 2014

Development of long-term mobile energy sources for mobile robots or small-sized unmanned vehicles are actively increasing. The micro gas turbine generator (MTG) is a good candidate for this purpose because it has both of high energy density and high power density, and 500W class MTG is under development. The designed MTG can be divided into 2 main parts. One part consists of motor/ generator and compressor, and the other one consists of combustor, recuperator and turbine. 500W class MTG is designed to operate at ultra-high speed of 400,000 rpm in high turbine temperature over $700^{\circ}C$ to improve the efficiency. Because the magnetism of NdFeB permanent magnet for the motor/generator could be degraded if the temperature is over $150-200^{\circ}C$, MTG needs the thermal insulation to block the heat transfer from combustor/turbine side to motor/generator side. Moreover, the motor/generator is allocated to get the cooling effect from the rapid air flow by the compressor. This study presents the experimental results to verify whether the thermal insulator and air flow are effective enough to keep the motor/generator part in the low temperature less than $100^{\circ}C$. From the motoring test by using the high temperature test rig, it was confirmed that the motor/generator part could maintain the temperature less than $50^{\circ}C$ under the condition of 1.0 bar compressed air.

• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.48 no.2
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• pp.99-108
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• 2020

In the field of aircraft icing prediction, surface roughness has been considered as critical factor because it enhances convective heat transfer and changes local collection efficiency. For this significance, experimental studies have been conducted to acquire the quantitative data of the formation process. Meanwhile, these experiments was conducted under low-speed condition due to the measurement difficulties. However, it has not been investigated that how the flow characteristic of low-speed will effects to the surface roughness. Therefore, the present study conducted experiment under low-speed icing condition, and analyzed the relation between surface roughness characteristics and icing condition. As an analysis method, the dominant parameters used in the previous high-speed experiments are employed, and roughness characteristics are compared. The size of roughness element was consistent with the previous known tendency, but not the smooth zone width.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.14 no.5
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• pp.1115-1128
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• 1994

The condition of temperature gradients in asphaltic concrete (Ascon) pavement have been analyzed based on the data collected from 5 major sites in Korea. From this. considering heat transfer by insolation flux and air temperature within pavement slab. temperature variation on the surface of pavement was computed and numerical model using the theory of thermal conductivity was applied to estimate the temperature gradients in depth. To investigate the present condition of asphalt generally used in Korea. the asphalt property tests were applicated on 5 different AP-3 (AC 85~100), and AP-5 (AC 60~70) asphalts classified by penetration index. Uniaxial compression test and indirect tensile test were also carried out for varying temperature conditions to analyze the effect of temperature on the deformation characteristics of Ascon pavement by calculating the variation of static elastic modulus and layer coefficients.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.40 no.5
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• pp.329-337
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• 2016

As a turbulence-enhancing device, a mixing vane, which is installed at a spacer grid of the fuel assembly, plays an important role in improving convective heat transfer by generating either swirl flow in the subchannels or cross flow between the fuel rod gaps. Therefore, both the geometric configuration and the arrangement pattern of a mixing vane are important factors in determining the performance of a mixing vane. In this study, in order to examine the flow-distribution features inside a $5{\times}5$ fuel assembly with split-type mixing vanes, which was used in the benchmark calculation of the OECD/NEA, we conduct simulations using the commercial computational fluid dynamics software, ANSYS CFX R.14. We compare the predicted results with measured data obtained from the MATiS-H (Measurement and Analysis of Turbulent Mixing in Subchannels-Horizontal) test facility. In addition, we discuss the effect of the split-type mixing vanes on the flow pattern inside the fuel assembly.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.34 no.8
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• pp.1083-1089
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• 2010

Shape memory alloys (SMAs) are smart materials. The unique characteristics of SMAs enable the production of large force and displacement. Hence, SMAs can be used in many applications such as in actuators and active structural acoustic controllers; the SMAs can also be used for dynamic tuning and shape control. A SMA torque tube actuator consisting of SMA tubes and superelastic springs is proposed, and the behaviors of the actuator are investigated. From the results of heat transfer analysis, it is proved that the SMA torque tube actuator with both resistive heating of SMA itself and a separate conventional heating rod in the tube core has good performance. The behavior of an actuator system was analyzed by performing a contact analysis, and the twisting motion was noticed when checking the actuation. 3D SMA nonlinear constitutive equations were formulated numerically and implemented by performing a nonlinear analysis by using Abaqus UMAT.

• Journal of the Korean Society of Manufacturing Process Engineers
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• v.13 no.2
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• pp.124-130
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• 2014

In a mass manufacturing system of optical fibers, the sufficient cooling of glass fibers freshly drawn from a draw furnace is essential, asinadequately cooled glass fibers can lead to poor resin coating on the fiber surface and possibly fiber breakage during the process. In order to improve fiber cooling at a high drawing speed, it is common to use a helium injection into a glass fiber cooling unit in spite of the high cost of the helium supply. The present numerical analysis carried out three-dimensional thermo-fluid computations of the cooling gas flow and heat transfer on moving glass fiber to determine the cooling performance of glass fiber cooling depending on the method of helium injection. The results showed that afront injection of helium is most effective compared to a uniform or rear injection for reducing air entrainment into the unit and thus cooling the glass fibers at a high fiber drawing speed. However, above a certain amount of injected helium, there was no more increase of the cooling effect regardless of the helium injection method.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.36 no.5
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• pp.523-531
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• 2012

The performance simulation of a desiccant rotor, which is a core component of a desiccant cooling system, was conducted on the basis of a theoretical solution of the heat and mass transfer process in the rotor. The simulation model was validated by comparing simulation results with experimental data; reasonable agreement was observed. The effect of the rotation speed on the performance of the desiccant rotor was investigated for various operation conditions: temperature (50 to $70^{\circ}C$), humidity ratio (0.01 to 0.02 kg/kg DA), and flow rate of regeneration air. The optimum rotation speed was determined from the maximum moisture removal capacity (MRC) of the desiccant rotor, and it was found to vary with the operation conditions. Further, the correlation for the optimum rotation speed was determined by regression analysis.

• Applied Chemistry for Engineering
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• v.27 no.3
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• pp.335-341
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• 2016

In this study, impurity effects on diffusive-convection flow fields by physical vapor transport under terrestrial and microgravity conditions were numerically analyzed for the mixture of $Hg_2Cl_2-I_2$ system. The numerical analysis provides the essence of diffusive-convection flow as well as heat and mass transfer in the vapor phase during the physical vapor transport through velocity vector flow fields, streamlines, temperature, and concentration profiles. The total molar fluxes at the crystal regions were found to be much more sensitive to both the gravitational acceleration and the partial pressure of component $I_2$ as an impurity. Our results showed that the solutal effect tended to stabilize the diffusive-convection flow with increasing the partial pressure of component $I_2$. Under microgravity conditions below $10^{-3}g_0$, the flow fields showed a one-dimensional parabolic flow structure indicating a diffusion-dominant mode. In other words, at the gravitational levels less than $10^{-3}g_0$, the effects of convection would be negligible.