• 한국전기전자재료학회논문지
• /
• 제30권9호
• /
• pp.589-595
• /
• 2017

MOS-FET structured gas sensors were manufactured using MWCNTs for application as NOx gas sensors. As the gas sensors need to be heated to facilitate desorption of the gas molecules, heat dispersion plays a key role in boosting the degree of uniformity of molecular desorption. We report the desorption of gas molecules from the sensor at $150^{\circ}C$ for different sensor electrode gaps (30, 60, and $90{\mu}m$). The COMSOL analysis program was used to verify the process of heat dispersion. For heat analysis, structure of FET gas sensor modeling was proceeded. In addition, a property value of the material was used for two-dimensional modeling. To ascertain the degree of heat dispersion by FEM, the governing equations were presented as partial differential equations. The heat analysis revealed that although a large electrode gap is advantageous for effective gas adsorption, consideration of the heat dispersion gradient indicated that the optimal electrode gap for the sensor is $60{\mu}m$.

• 한국가스학회:학술대회논문집
• /
• 한국가스학회 2005년도 춘계학술대회 및 특별심포지움
• /
• pp.206-206
• /
• 2005

• 청정기술
• /
• 제27권4호
• /
• pp.359-366
• /
• 2021

할로이사이트(Al₂Si₂O₅(OH)₄·nH₂O)는 다층벽 나노 튜브 구조의 저단가 천연 점토 분말로, 상대적으로 우수한 비표면적으로 인해 수처리용 염료 흡착 소재로 연구되어왔다. 분말형 점토 소재는 수처리 시 응집으로 인한 관막음 현상을 억제하기 위해서 흡착 담체로의 사용이 검토되나, 강도 확보를 위한 높은 소성 온도 및 분말 대비 낮은 소재 활용률로 인해 흡착능 구현에 난점이 있다. 본 연구에서는 750 ℃에서 대기 소성에 따른 할로이사이트의 메틸렌블루(MB) 흡착능 유지율을 평가하였으며, 소재 활용율 향상을 위한 관형의 할로이사이트 담체를 제조하였다. 할로이사이트의 높은 열적 구조 안정성은 투과전자현미경 이미지를 통해 평가되었으며, 할로이사이트는 각각 22% (7.65 mg g^-1), 6% (11.7 mg g^-1)의 유지율을 보인 규조토 및 마그네솔^®XL 대비 우수한 MB 흡착능 유지율 및 흡착능(93%, 18.5 mg g^-1) 나타내었다. 또한, 성형 시 리그닌과의 복합화는 기존 소성체 대비 흡착능이 향상되었으며, 수소 분위기 하 소성 시 초기 MB 흡착을 촉진했다. 관형의 할로이사이트 담체는 접촉면적의 증가를 통해 막대형 담체 대비 빠른 초기 흡착량의 증가 및 우수한 질량 당 흡착능(7.36 mg g^-1)을 구현하였다.

• Carbon letters
• /
• 제13권4호
• /
• pp.236-242
• /
• 2012

Poly(vinylidene chloride) (PVDC)-derived nanoporous carbons were prepared by various activation methods: heat-treatment under an inert atmosphere, steam activation, and potassium hydroxide (KOH) activation at 873, 1073, and 1273 K. The pore structures of PVDC-derived nanoporous carbons were characterized by the $N_2$ adsorption technique at 77 K. Heat treatment in an inert atmosphere increased the specific surface area and micropore volume with elevating temperature, while the average micropore width near 0.65 nm was not significantly changed, reflecting the characteristic pore structure of ultramicroporous carbon. Steam activation for PVDC at 873 and 1073 K also yielded ultramicroporosity. On the other hand, the steam activated sample at 1273 K had a wider average micropore width of 1.48 nm, correlating with a supermicropore. The KOH activation increased the micropore volume with elevating temperature, which is accompanied by enlargement of the average micropore width from 0.67 to 1.12 nm. The average pore widths of KOH-activated samples were strongly governed by the activation temperature. We expect that these approaches can be utilized to simply control the porosity of PVDC-derived nanoporous carbons.

• 한국태양에너지학회 논문집
• /
• 제35권1호
• /
• pp.97-106
• /
• 2015

Gypsum board is easy to manufacture of a variety of forms and has stable mechanical properties and thermal properties. And gypsum boards are widely used to the walls and ceiling of the building as the interior building materials. The studies about technology of applying the various features in the gypsum board with additives are being actively investigated. Development methods for enhancing performance of the gypsum board using additives are largely divided into two categories. The first case is functional gypsum board that is to improve the moisture absorption and moisture-proof properties. Also studies of adsorption and decomposition of indoor air pollutants of the gypsum board using porous materials as an additive are being actively investigated. Another case is applying thermal storage materials which gives the heat storage performance to gypsum board. In this paper, we would like to introduce the various cases of gypsum board applied various additives.

• 한국염색가공학회지
• /
• 제15권5호
• /
• pp.316-320
• /
• 2003

In order to investigate the dyeing property of poly trimethylene terephthalate(PTT) fabric, the dyeing of PTT fabric was carried at under condition of different dyeing temperature by using several disperse dyes with different energy level. Particularly, this study discussed the PTT dyeing thermodynamically. Used disperse dyes were selected based on the their chemical structure and energy level. The obtained results were as followings; The dye adsorption of S type disperse dye such as C. I. Disperse Blue 79 increased with increasing dyeing temperature. In a exhaustion rate of PTT fabric with disperse dyes, C. I. Disperse Blue 56 showed higher values than that of C. I. Disperse Orange 29 and Blue 79. For the interpretation of thermodynamic dyeing behavior, the partition coefficient ( K ) and some several thermodynamic parameters such as standard affinity$(-\mu^\circ)$ and heat of dyeing$(\Delta{H}^\circ)$ calculated from the adsorption isotherm. From above results, as the energy level of disperse dye is small, the partition coefficient and standard affinity increased. But the heat of dyeing of PTT fabric with disperse dye showed high negative value in order of E type(C. I. Disperse Blue 56), SE type(C. I. Disperse Orange 29) and S type(C. I. Disperse 79).

• 한국수소및신에너지학회논문집
• /
• 제17권4호
• /
• pp.434-439
• /
• 2006

In this study, activated carbon(ACs) have been modified by nitric acid and heat-treatment. The surface and structure properties of ACs were determined by BET surface area, FT-IR pH and acid/base value. The changes in pore structure and surface properties of these modified ACs were correlated with natural gas adsorption which measured by volumetric apparatus at $0^{\circ}C$ and $25^{\circ}C$. The pore textural properties of activated carbon was also characterized by nitrogen adsorption at 77 K. Specific surface area and micropore volume of them were calculated by Langmuir equation and Horvath-Kawazoe method, and chemical properties of surface were measured by FT-IR and titration of acid and base solutions. Pore texture of activated carbons after treatments were not significantly changed. Total acidity increased and basicity of samples decreased. however the basicity increased with heat treatment. The methane adsorption of ACs become different depending on the acid/base value of samples.

• 설비공학논문집
• /
• 제17권12호
• /
• pp.1192-1203
• /
• 2005

A technical analysis was conducted to predict the development trend for heat pump system. The study was based on a submitted patent from 1983 to 2002 in Korea, U.S.A. and Japan. The total number of raw data from the registered database was 19,261 and the obtained data to be analyzed through the filtering process was 5,143. Technical development of compression type heat pump was more dominant than the other types, absorption, adsorption, and chemical heat pump. The patents for compression type made up over $80\%$ in each country, Most of patents were developed for the defrosting and controlling technology of the compression type heat pump system. Approximately $24\%\;and\;62\%$ of the patents about compression type heat pump were for defrosting and control technologies, respectively.

• 대한환경공학회지
• /
• 제31권11호
• /
• pp.1025-1032
• /
• 2009

본 연구에서는 세탁소에서 배출되는 휘발성유기화합물을 흡착처리하는 공정의 개발 가능성을 검토하였다. 휘발성 유기화합물을 흡착하는 재료로는 핏치계 활성탄소섬유를 선택하였고, 흡착제의 재생방법으로는 전기변동법을 사용하였다. 용제는 트리클로로에틸렌과 톨루엔을 대상으로 하였으며 활성탄소섬유와 용제의 종류에 따른 파과곡선과 흡착량을 비교 검토하였다. 흡착량을 증대시키기 위하여 다양한 방법으로 활성탄소섬유를 전처리하였다. 또한 흡착이 완료된 활성탄소섬유의 재생에 필요한 온도와 허용전압을 측정하였다. 그 결과 트리클로로에틸렌의 흡착에는 미세 기공이 잘 발달된 활성탄소섬유가 우수한 성능을 나타낸 반면 톨루엔의 경우에는 비표면적이 큰 흡착제가 우수한 성능을 보였다. 활성탄소섬유는 흡착제 무게의 41~54%에 해당하는 트리클로로에틸렌을 흡착하였으며 유입되는 휘발성유기화합물의 농도가 높아지면 완전흡착시간은 급격히 짧아지고 흡착량은 서서히 감소하여 낮은 농도의 휘발성유기화합물을 처리하는 것이 보다 유리한 것으로 나타났다. 활성탄소섬유 표면의 산소작용기를 조절한 결과, 진공열처리를 한 활성탄소섬유의 톨루엔 흡착성능이 가장 우수한 것으로 나타나, 톨루엔의 흡착은 빈자리 탄소(vacant carbon site)가 흡착점이라고 판단된다. 흡착된 용제는 $150^{\circ}C$에서 대부분 탈착되었다.

• 한국광물학회지
• /
• 제15권4호
• /
• pp.315-327
• /
• 2002

벤토나이트에 포함된 몬모릴로나이트의 층간에 Al산화물의 기둥(pillar)을 만든 Al-층간가교 점토를 합성하였다. 이 Al-층간가교점토에 대해 XRD, DTA, 화학분석 등을 실시하여 광물학적 특성을 검토하였으며, 그리고 이 가교점토에 대하여 Batch법의 흡착실험을 통하여 인산이온의 흡착성을 검토하였다. X-선 회절분석의 결과, Al-층간가교점토는 상온에서 층간격이 $18.03 \AA$으로 증가되어 나타났고, $550\AA$가열에서도 약 $17\AA$을 나타내어 열적 안정성이 크며, 글리세롤에 의한 층간격의 팽윤은 매우 미약한 것으로 나타났다. 열분석 결과, 이 점토에는 pillar부분에 관련된 물의 탈수에 의한 것으로 보이는 $270^{\circ}C$와 $420^{\circ}C$의 특징적인 흡열반응이 나타났다. Al-층간가교 점토의 인산 이온에 대한 흡착실험의 결과, 몬모릴로나이트는 거의 흡착능력을 보이지 않는데 비하여 월등히 우수한 인산이온($PO_{4}^{3－}$ /)성을 나타냈다. 시료 2 g에 용액 20 mL의 실험에서 300 mg/L 이하의 인산 농도에서는 거의 100%의 흡착효율을 나타냈다. 그리고 인산 이온에 흡착된 시료를 $500^{\circ}C$로 가열한 후 재차 흡착실험을 행한 결과, 역시 매우 높은 흡착효율을 나타냈다. 따라서 Al-층간가교 점토의 인산 이온 흡착에 대한 재활용의 가능성이 큰 것으로 나타났다