• Journal of Powder Materials
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• v.8 no.3
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• pp.201-206
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• 2001

$>LaMnO_3$$(La, Sr)MO_3$, and $(La, Sr)MO_3/YSZ$ gel films were deposited by spin-coating technique on scandium-doped zirconia (YSZ) substrate using the precursor solution prepared from $La(O-i-C_3H_7)_3$, $Co(CH_3COO)_2$or $Mn(O-i-C_3H_7)_2$,2-methoxyethanol, and polyethylene glycol. By heat-treating the gel films, the electrochemical cells, $(La, Sr)MnO_3{\mid}ScSZ{\mid}Pt$ were fabricated. The effect of polyethylene glycol on the microstructure evolution of $$LaCoO_3and $LaMnO_3$thin films was investigated, and NOx decomposition characteristics of the electrochemical cells were investigated at $500^{\circ}C$ to $600^{\circ}C$. By applying a direct current to the $(La, Sr)MnO_3{\mid}ScSZ{\mid}Pt$ electrochemical cell, good NOx conversion rate could be obtained relatively at low current value even if excess oxygen is included in the reaction gas mixture.

• Journal of Surface Science and Engineering
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• v.49 no.6
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• pp.567-574
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• 2016

We have analyzed chemical properties of polysiloxane and polysilazane films, respectively, as sealing materials for electrostatic chuck (ESC) and have investigated the possibility of polysilazane as an alternative sealant to polysiloxane. It has been revealed that Si-O with organic bonding ($Si-CH_3$) existed in polysiloxane films compared to only pure Si-O bonding in polysilazane films. The sealing property of polysilazane has been found outstanding even in a short time of application. In the polysiloxane films containing $H_2O$, pin holes have been found possibly due to $CO_2$ gas evolution, and low adhesion with Si substrate has been observed after heat stress test in connection with the existence of organic bonding. After acid resistance test in 0.5 vol.% HF, 68 wt.% $HNO_3$, and 37 wt.% HCl solution, polyilazane films have shown a longer survival times. Compared to the conventional polysiloxane sealant, polysilazane is expected as a new sealing material because of good thermal and chemical stability.

• Structural Engineering and Mechanics
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• v.62 no.2
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• pp.225-236
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• 2017

The purpose of this work is to predict ductile fracture of structural steel under extremely low cyclic loading experienced in earthquake. A cumulative damage model is proposed on the basis of an existing damage model originally aiming to predict fracture under monotonic loading. The cumulative damage model assumes that damage does not grow when stress triaxiality is below a threshold and fracture occurs when accumulated damage reach unit. The model was implemented in ABAQUS software. The cumulative damage model parameters for steel base metal, weld metal and heat affected zone were calibrated, respectively, through testing and finite element analyses of notched coupon specimens. The damage evolution law in the notched coupon specimens under different loads was compared. Finally, in order to examine the engineering applicability of the proposed model, the fracture performance of beam-column welded joints reported by previous researches was analyzed based on the cumulative damage model. The analysis results show that the cumulative damage model is able to successfully predict the cracking location, fracture process, the crack initiation life, and the total fatigue life of the joints.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2004.03a
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• pp.62-68
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• 2004

A comprehensive numerical analysis has been carried out for both non-reacting and reacting flows in a scramjet engine combustor with and without a cavity. The theoretical formulation treats the complete conservation equations of chemically reacting flows with finite-rate chemistry of hydrogen-air. Turbulence closure is achieved by means of a k-$\omega$ two-equation model. The governing equations are discretized using a MUSCL-type TVD scheme, and temporally integrated by a second-order accurate implicit scheme. Transverse injection of hydrogen is considered over a broad range of injection pressure. The corresponding equivalence ratio of the overall fuel/air mixture ranges from 0.167 to 0.50. The work features detailed resolution of the flow and flame dynamics in the combustor, which was not typically available in most of the previous studies. In particular, the oscillatory flow characteristics are captured at a scale sufficient to identify the .underlying physical mechanisms. Much of the flow unsteadiness is related not only to the cavity, but also to the intrinsic unsteadiness in the flow-field. The interactions between the unsteady flow and flame evolution may cause a large excursion of flow oscillation. The roles of the cavity, injection pressure, and heat release in determining the flow dynamics are examined systematically.

• Proceedings of the Korea Concrete Institute Conference
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• 2004.11a
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• pp.603-608
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• 2004

The paper analyzes a scheme of decontamination of radionuclides from concrete structures, in which rapid microwave heating is used to spall off a thin contaminated surface layer. The analysis is split in two parts: (1) The hygrothermal part of the problem, which consists in calculating the evolution of the temperature and pore pressure fields, and (2) the fracturing part, which consists in predicting the stresses, deformations and fracturing. The rate of the distributed source of heat due to microwaves in concrete is calculated on the basis of the standing wave normally incident to the concrete wall with averaging over both the time period and the wavelength because of the very short time period of microwaves compared to the period of temperature waves and the heterogeneity of concrete. The reinforcing bars parallel to the surface arc treated as a smeared steel layer. The microplane model M4 is used as the constitutive model for nonlinear deformation and distributed fracturing of concrete. The aim of this study is to determine the required microwave power and predict whether and when the contaminated surface layer of concrete spalls off. The effects of wall thickness, reinforcing bars, microwave frequencies and power are studied numerically. As a byproduct of this analysis, the mechanism of spalling of rapidly heated concrete is clarified.

• Computers and Concrete
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• v.11 no.4
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• pp.271-289
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• 2013

In this research, a developed microstructural model of cement particles was presented to describe the cement hydration procedure. To simplify the hydration process, the whole hydration was analyzed in a series of sub-steps. In each step, the hydration degree, as well as the microstructural size of the hydration cell, was calculated as a function of the radius of the unreacted cement particles. With the consideration of the water consumption and the reduction of the interfacial area between water and hydration products, the micro-level expressions of the cement hydration kinetics were established. Then the heat released and temperature history of the concrete was carried out with the hydration degree obtained from each sub-steps. The equivalent age method based on the Arrhenius law was introduced in this research. Based on the equivalent age method, a maturity model was applied to describe the evolution of the mechanical properties of the material during the hydration process. The finite element program ANSYS was used to analyze the temperature field in concrete structures. Then thermal stress field was calculated using the elasticity modulus obtained from code formulate. And the risk of thermal cracking was estimated by the comparison of thermal stress and concrete tensile strength.

• Transactions of Materials Processing
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• v.23 no.3
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• pp.164-170
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• 2014

To predict the deformation and fracture during tube expansion using the finite element (FE) method, a material model is considered that incorporates the damage evolution due to the deformation. In the current study, a Rice-Tracey model was used as the damage model with inclusion of the hydrostatic stress term. Since OFHC Cu is not significantly affected by strain rate, a Hollomon flow stress model was used. The material parameters in each model were obtained by using an optimization method. The objective function was defined as the difference between the experimental measurements and FE simulation results. The parameters were determined by minimizing the objective function. To verify the validity of the FE modeling, cross-verification was conducted through a tube expansion test. The simulation results show reasonable agreement with the experiments. The design for a minimum diameter of expansion tube using the FE modeling was verified by a simplified tube expansion test and simulation results.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.21 no.10
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• pp.1254-1261
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• 1997

Pulse boiling, the unsteady periodic boiling phenomenon appearing in the evaporator of thermosyphons was investigated by many researchers. In the present study investigations were conducted to examine the evolution of flow patterns at the evaporator, and changes in thermodynamic state that each of liquid pool and vapor experiences through 1 cycle of pulse boiling process. For wall and liquid pool the degree of superheat for the onset of nucleation was examined. It revealed that the degree of superheat increased with the increase of pulse period, reaching to 16.5 deg.C and 23 deg.C for liquid pool and evaporator wall respectively at .tau.=80 sec. The data on flow patterns obtained through series of operation tests were plotted in the coordinates of heat flux and vapor pressure to get a regime map. Further this map could be used to figure out the conditions of pulse boiling for a thermosyphon.

• Journal of Microbiology and Biotechnology
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• v.29 no.3
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• pp.419-428
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• 2019

Phytases are enzymes that can hydrolyze phytate and its salts into inositol and phosphoric acid, and have been utilized to increase the availability of nutrients in animal feed and mitigate environmental pollution. However, the enzymes' low thermostability has limited their application during the feed palletization process. In this study, a combination of B-value calculation and protein surface engineering was applied to rationally evolve the heat stability of Escherichia coli phytase. After systematic alignment and mining for homologs of the original phytase from the histidine acid phosphatase family, the two models 1DKL and 1DKQ were chosen and used to identify the B-values and spatial distribution of key amino acid residues. Consequently, thirteen potential amino acid mutation sites were obtained and categorized into six domains to construct mutant libraries. After five rounds of iterative mutation screening, the thermophilic phytase mutant P56214 was finally yielded. Compared with the wild-type, the residual enzyme activity of the mutant increased from 20% to 75% after incubation at $90^{\circ}C$ for 5 min. Compared with traditional methods, the rational engineering approach used in this study reduces the screening workload and provides a reference for future applications of phytases as green catalysts.

• Applied Chemistry for Engineering
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• v.22 no.4
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• pp.423-428
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• 2011

Hydration characteristics of cement containing zeolite mined at Daepo in Gyeongbuk province were studied for use as a mineral admixture. The cement paste containing zeolite was characterized by the measurement of heat evolution, XRD, EDS, nitrogen adsorption and mercury intrusion porosimetry. The cement paste containing zeolite exhibited tendencies toward acceleration of paste setting and promotion of cement hydration with the increase of zeolite content. The flow of mortar containing zeolite strongly reduced with increase of zeolite content. Compressive strength of the mortar containing zeolite increased very rapidly at an early age in comparison with plain mortar. These results would be related to aluminum species escaped from zeolite particles during the alkali dealumination of zeolite by the hydration process of cement.