• 한국재료학회지
• /
• 제23권10호
• /
• pp.543-549
• /
• 2013

The purpose of this paper was to investigate the effect of a high-energy milling (HEM) process on the particle morphology and the correlation between a thermal treatment and tetragonal/monoclinic nanostructured zirconia powders obtained by a precipitation process. To eliminate chloride residue ions from hydrous zirconia, a modified washing method was used. It was found that the used washing method was effective in removing the chloride from the precipitated gel. In order to investigate the effect of a pre-milling process on the particle morphology of the precipitate, dried $Zr(OH)_4$ was milled using a HEM machine with distilled water. The particle size of the $Zr(OH)_4$ powder exposed to HEM reduced to 100~150 nm, whereas that of fresh $Zr(OH)_4$ powder without a pre-milling process had a large and irregular size of 100 nm~1.5 ${\mu}m$. Additionally, modified heat treatment process was proposed to achieve nano-sized zirconia having a pure monoclinic phase. It was evident that two-step calcining process was effective in perfectly eliminating the tetragonal phase, having a small average particle of ~100 nm with good uniformity compared to the sample calcined by a single-step process, showing a large average particle size of ~300 nm with an irregular particle shape and a broad particle size distribution. The modified method is considered to be a promising process for nano-sized zirconia having a fully monoclinic phase.

• 대한환경공학회지
• /
• 제31권2호
• /
• pp.139-146
• /
• 2009

본 연구에서는 두부공장에서 발생된 폐수를 이용한 생물학적 수소생성 특성과 미생물의 군집 변화를 살펴보았다. 두부 폐수는 산 또는 알카리 조건에서 전처리 된 후 수소생성량을 비교 하였으며, 산처리와 열처리를 병행하여 전처리 하였을 때 가장 왕성한 수소생산을 보였으며, Gompartz 방정식을 이용한 수소가스 발생량($P_h$)은 약 661.01 mL이고 최대 수소 생성율($R_h$)은 12.21 mL/g dry wt biomass/hr 이였다. 16S rDNA의 PCR-DGGE 결과 대부분 군집은 Streptococcus sp. 미생물로 규명되었으며 수소생성에 기여도가 큰 미생물은 Streptococcus gallolyticus sub sp.으로 판단되었다.

• 콘크리트학회논문집
• /
• 제22권2호
• /
• pp.159-169
• /
• 2010

경량골재 사전흡수에 의한 콘크리트 내 수분이동 변화와 수축 저감 효과를 파악하기 위하여 일반콘크리트 및 경량콘크리트의 수분이동, 열전달, 변형률의 다중물리모델의 해석과 실험을 수행하였다. 그 결과 동일 물-결합재비일 경우 경량 콘크리트와 일반 콘크리트와의 습도 변화 비교는 모두 경량 콘크리트가 일반 콘크리트보다 초기재령, 장기 재령 모두에서 작은 습도 감소를 나타내어 경량 골재 사전흡수수에 의한 수분 공급이 효과적으로 이루어진 것으로 판단된다. 이에 따라 경량 콘크리트는 일반 콘크리트에 비해 수축변형률 크기 및 분포 모두 감소하였으며, 수축저감효과는 물-시멘트비 0.3에서는 초기재령에서, 물-시멘트비 0.5에서는 초기재령, 장기재령 모두에서 효과적인 것으로 나타났다. 수분이동 및 변형률 해석과 모형실험을 통해 일련된 연구에서 도출한 수분이동 특성값과 습도, 수축 관련식은 적합한 것으로 판단되며, 향후 경량콘크리트의 부등수축해석에 적절히 활용될 수 있을 것으로 생각된다.

• 한국환경과학회지
• /
• 제16권10호
• /
• pp.1169-1177
• /
• 2007

The main objective of this research was to evaluate the effects of process variables which were forming ability, flow displacement, effective stress, effective strain, fluid vector and products defects on manufactured artificial lightweight aggregate made of both incinerated sewage sludge ash and clay by means of the numerical analysis of a rigid-plastic finite element method. CATIA (3D CAD program) was used for an extrusion metal mold design that was widely used in designing aircraft, automobile and metallic molds. A metal forming analysis program (ATES Co.) had a function of a rigid-plastic finite element method was used to analyze the program. The result of extrusion forming analysis indicated clearly that a shape retention of the manufactured artificial light-weight aggregate could be maintained by increasing the extrusion ratio (increasing compressive strength inside of extrusion die) and decreasing the die angle. The stress concentration of metal mold was increased by increasing an extrusion ratio, and it was higher in a junction of punch and materials, friction parts between a bottom of the punch and inside of a container, a place of die angle and a place of die of metal mold. Therefore, a heat treatment as well as a rounding treatment for stress distribution in the higher stress concentration regions were necessary to extend a lifetime of the metallic mold. A deformity of the products could have made from several factors which were a surface crack, a lack of the shape retention and a crack of inside of the products. Specially, the surface crack in the products was the most notably affected by the extrusion ratio.

• Journal of Electrochemical Science and Technology
• /
• 제1권1호
• /
• pp.31-38
• /
• 2010

In this study, we have demonstrated the fine structure effect of PdCo electrocatalyst on oxygen reduction reaction activity with different alloy composition and heat-treatment time. In order to identify the intrinsic factors for the electrocatalytic activity, various X-ray analyses were used, including inductively coupled plasma-atomic emission spectrometer, transmission electron microscopy, X-ray diffractometer, and X-ray Absorption Spectroscopy technique. In particular, extended X-ray absorption fine structure was employed to extract the structural parameters required for understanding the atomic distribution and alloying extent, and to identify the corresponding simulated structures by using FEFF8 code and IFEFFIT software. The electrocatalytic activity of PdCo alloy nanoparticles for the oxygen reduction reaction was evaluated by using rotating disk electrode technique and correlated to the change in structural parameters. We have found that Pd-rich surface was formed on the Co core with increasing heating time over 5 hours. Such core shell structure of PdCo/C showed that a superior oxygen reduction reaction activity than pure Pd/C or alloy phase of PdCo/C electrocatalysts, because the adsorption energy of adsorbates was apparently reduced by lowering the dband center of the Pd skin due to a combination of the compressive strain effect and ligand effect.

• 조명전기설비학회논문지
• /
• 제14권4호
• /
• pp.23-30
• /
• 2000

열병합발전 시스템은 환경 친화적인 동시에 상대적으로 고 효율의 에너지 시스템으로서 분산 방전설비의 혁신 기술중 하나이다, 아울러 열병합발전 시스템운 열과 전기의 분산공급에 적절한 발전 시스템이다. 그러나, 열병합발전 시스템의 계통 연계는 전압 소정, 전압변동, 보호협조, 안전등의 제반 연제문제를 수반한다. 특히, 이러한 연계문제 중 열병합발전 시스템의 배전계통 연계.분리 운전은 배전계통의 전압조정 및 변동에 영향을 미칠 것이 예상된다. 최근 수용가 소유의 컴퓨터 및 민감한 전자소자의 사용 증가로 인하여 전력품질온 중요한 고려사항이 되고 있다. 따라서 열병합발전 시스템과 관련한 전압품질은 반드시 분석되어야만 한다. 왜냐하면 전압품질은 전력 품질의 중요한 요소이기 때문이다. 본 논문에서는 열병합발전 시스템의 배전계통 연계 운전에 따른 순서전압변통 에 대하여 컴퓨터 시물레이션을 롱하여 분석하였고、 또한 이의 억제 대책을 제시하였다. 아울러 순시전압변동 측면에서 본 피더 당 열병합발전시스템의 단위 도입 용량을 평가하였다. 본 논문의 결과는 열병합발전 시스템 또는 분산형 전원의 계통 연계 표준. 가이드라인에 유용한 자료가 되리라 믿는다.

• 한국초전도ㆍ저온공학회논문지
• /
• 제16권1호
• /
• pp.36-41
• /
• 2014

Since glass microsphere has high crush strength, low density and small particle size, it becomes alternative thermal insulation material for cryogenic systems, such as storage and transportation tank for cryogenic fluids. Although many experiments have been performed to verify the effective thermal conductivity of microsphere, prediction by calculation is still inaccurate due to the complicated geometries, including wide range of powder diameter distribution and different pore sizes. The accurate effective thermal conductivity model for microsphere is discussed in this paper. There are four mechanisms which contribute to the heat transfer of the evacuated powder: gaseous conduction ($k_g$), solid conduction ($k_s$), radiation ($k_r$) and thermal contact ($k_c$). Among these components, $k_g$ and $k_s$ were calculated by Zehner and Schlunder model (1970). Other component values for $k_c$ and $k_r$, which were obtained from experimental data under high vacuum conditions were added. In this research paper, the geometry of microsphere was simplified as a homogeneous solid sphere. The calculation results were compared with previous experimental data by R. Wawryk (1988), H. S. Kim (2010) and the experiment of this paper to show good agreement within error of 46%, 4.6% and 17 % for each result.

• 한국전산구조공학회논문집
• /
• 제24권4호
• /
• pp.429-438
• /
• 2011

본 논문에서는 Membrane형 LNG선의 구성 요소를 대상으로 단열창의 열적 분포를 알아보기 위해 극저온 상태에서부터 온도 별로 각 소재의 열적 물성치인 열전도도(thermal conductivity)를 실험을 통해서 알아보았다. 극저온 상태인 $-163^{\circ}C$의 온도상태로 유지되어야 하는 LNG선 화물탱크는 단열재료로 하여금 열을 차단하기 위해 많은 연구가 되어야 하는데 특히 여러 재료로 구성되어 있는 단열 화물창(CCS: Cargo containment system)은 열적 물성치가 온도에 따라 각각 어떠한 값을 가지는 것이 주요 관심대상이고, 이를 통해 전체 LNG 단열 화물창이 어떤 열적 분포를 가지는 것에 대한 연구가 필요하다. 실험을 통해 얻은 물성치를 가지고 전체 화물창의 온도분포를 정적 열해석을 통해 알아보았다. 또한 외부의 충격에 의해 LNG가 누수되었을때 2차 방벽 특히 hull 부분에서는 누수량에 대해서 어떠한 온도분포와 열적 안전성에 대해서 알아보았다.

• 한국공작기계학회논문집
• /
• 제17권2호
• /
• pp.65-70
• /
• 2008

This study deals with the friction welding of SKH55 and SM45C; The friction time was variable conditions under the conditions of spindle revolution 2,000rpm, friction pressure of 190MPa, upset pressure of 270MPa and upset time of 2.0 seconds. Under these conditions, the microstructure of weld interface, tensile fracture surface and mechanical tests were studied, and so the results were as follows. 1. When the friction time is 1.0 seconds, the tensile strength of friction welds was 926MPa, which is around as much as 84% of the tensile strength of base metal(SKH55), the bending strength of friction welds was 1,542MPa, which is around as much as 80% of the bending strength of base metal(SKH55), the shear strength of friction welds was 519MPa, which is around as much as 70% of the shear strength of base metal(SKH55). 2 According to the hardness test, the hardness distribution of the weld interface was formed from 964Hv to 254Hv. HAZ(Heat Affected Zone) was formed from the weld interface to 1.5mm of SKH55 and 2mm of SM45C.

• 설비공학논문집
• /
• 제20권7호
• /
• pp.462-469
• /
• 2008

A regenerative evaporative cooler has been fabricated and tested for the evaluation of cooling performance. The regenerative evaporative cooler is a kind of indirect evaporative cooler comprised of multiple pairs of dry and wet channels. The air flowing through the dry channels is cooled without any change in the humidity and at the outlet of the dry channel a part of air is redirected to the wet channel where the evaporative cooling takes place. The regenerative evaporative cooler fabricated in this study consists of the multiple pairs of finned channels in counterflow arrangement. The fins and heat transfer plates were made of aluminum and brazed for good thermal connection. Thin porous layer coating was applied to the internal surface of the wet channel to improve surface wettability. The regenerative evaporative cooler was placed in a climate chamber and tested at various operation condition. The cooling performance is found greatly influenced by the evaporation water flow rate. To improve the cooling performance, the evaporation water flow rate needs to be minimized as far as the even distribution of the evaporation water is secured. At the inlet condition of $32^{\circ}C$ and 50%RH, the outlet temperature was measured at $22^{\circ}C$ which is well below the inlet wet-bulb temperature of $23.7^{\circ}C$.