• Korean Journal of Materials Research
• /
• v.23 no.10
• /
• pp.543-549
• /
• 2013

The purpose of this paper was to investigate the effect of a high-energy milling (HEM) process on the particle morphology and the correlation between a thermal treatment and tetragonal/monoclinic nanostructured zirconia powders obtained by a precipitation process. To eliminate chloride residue ions from hydrous zirconia, a modified washing method was used. It was found that the used washing method was effective in removing the chloride from the precipitated gel. In order to investigate the effect of a pre-milling process on the particle morphology of the precipitate, dried $Zr(OH)_4$ was milled using a HEM machine with distilled water. The particle size of the $Zr(OH)_4$ powder exposed to HEM reduced to 100~150 nm, whereas that of fresh $Zr(OH)_4$ powder without a pre-milling process had a large and irregular size of 100 nm~1.5 ${\mu}m$. Additionally, modified heat treatment process was proposed to achieve nano-sized zirconia having a pure monoclinic phase. It was evident that two-step calcining process was effective in perfectly eliminating the tetragonal phase, having a small average particle of ~100 nm with good uniformity compared to the sample calcined by a single-step process, showing a large average particle size of ~300 nm with an irregular particle shape and a broad particle size distribution. The modified method is considered to be a promising process for nano-sized zirconia having a fully monoclinic phase.

• Journal of Korean Society of Environmental Engineers
• /
• v.31 no.2
• /
• pp.139-146
• /
• 2009

In this study, characteristics of biological hydrogen production and microbial distribution were investigated with the wastewater of Tofu manufacturing process. Comparison of hydrogen production was conducted with acid or base pre-treatment of the wastewater. Maximum hydrogen production was acquired with combination of heat and acid treatment. Hydrogen production ($P_h$) and maximum hydrogen production rate ($R_h$) was calculated 661.01 mL and 12.21 mL/g dry wt biomass/hr from the modified Gompartz equation. Most of microbial community was analyzed as Streptococcus sp. from PCR-DGGE experiment of 16S rDNA. It was concluded that most significant microorganism for hydrogen production was Streptococcus gallolyticus sub sp. in this experiment.

• Journal of the Korea Concrete Institute
• /
• v.22 no.2
• /
• pp.159-169
• /
• 2010

A multiphysics model analysis including moisture transport, heat transfer and solid mechanics and experiments on the normal and light weight concrete were carried out in order to study the effect of preabsorbed water in the light weight aggregates on the drying and shrinkage characteristics of concrete. Consequently, with fixed water-cement ratio, loss of water content of normal and light weight concrete were compared and the results showed that the lightweight concrete lost less moist than the normal concrete in early age and long term which was by moist supply effect. Accordingly, shrinkage strain size and distribution of lightweight concrete were decreased, and shrinkage reducing effect was efficient in early age with water cement ratio 0.3 and in both early age, and long term with water cement ratio 0.5. The comparison of analysis results and exaperimental results indicate that characteristic values of moisture transport and the relation humidity and shrinkage strain from this study are resonable for application for other differential shrinkage analysis in lightweight concrete.

• Journal of Environmental Science International
• /
• v.16 no.10
• /
• pp.1169-1177
• /
• 2007

The main objective of this research was to evaluate the effects of process variables which were forming ability, flow displacement, effective stress, effective strain, fluid vector and products defects on manufactured artificial lightweight aggregate made of both incinerated sewage sludge ash and clay by means of the numerical analysis of a rigid-plastic finite element method. CATIA (3D CAD program) was used for an extrusion metal mold design that was widely used in designing aircraft, automobile and metallic molds. A metal forming analysis program (ATES Co.) had a function of a rigid-plastic finite element method was used to analyze the program. The result of extrusion forming analysis indicated clearly that a shape retention of the manufactured artificial light-weight aggregate could be maintained by increasing the extrusion ratio (increasing compressive strength inside of extrusion die) and decreasing the die angle. The stress concentration of metal mold was increased by increasing an extrusion ratio, and it was higher in a junction of punch and materials, friction parts between a bottom of the punch and inside of a container, a place of die angle and a place of die of metal mold. Therefore, a heat treatment as well as a rounding treatment for stress distribution in the higher stress concentration regions were necessary to extend a lifetime of the metallic mold. A deformity of the products could have made from several factors which were a surface crack, a lack of the shape retention and a crack of inside of the products. Specially, the surface crack in the products was the most notably affected by the extrusion ratio.

• Journal of Electrochemical Science and Technology
• /
• v.1 no.1
• /
• pp.31-38
• /
• 2010

In this study, we have demonstrated the fine structure effect of PdCo electrocatalyst on oxygen reduction reaction activity with different alloy composition and heat-treatment time. In order to identify the intrinsic factors for the electrocatalytic activity, various X-ray analyses were used, including inductively coupled plasma-atomic emission spectrometer, transmission electron microscopy, X-ray diffractometer, and X-ray Absorption Spectroscopy technique. In particular, extended X-ray absorption fine structure was employed to extract the structural parameters required for understanding the atomic distribution and alloying extent, and to identify the corresponding simulated structures by using FEFF8 code and IFEFFIT software. The electrocatalytic activity of PdCo alloy nanoparticles for the oxygen reduction reaction was evaluated by using rotating disk electrode technique and correlated to the change in structural parameters. We have found that Pd-rich surface was formed on the Co core with increasing heating time over 5 hours. Such core shell structure of PdCo/C showed that a superior oxygen reduction reaction activity than pure Pd/C or alloy phase of PdCo/C electrocatalysts, because the adsorption energy of adsorbates was apparently reduced by lowering the dband center of the Pd skin due to a combination of the compressive strain effect and ligand effect.

• Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
• /
• v.14 no.4
• /
• pp.23-30
• /
• 2000

Cogeneration systems are seen as a significant innovation for dispersed energy generation since they are both environmentally friendly and has comparatively high degrees of efficiency. It is especially suited for the decentralized provision of electricity and heat. However, it causes operational problems such as voltage regulation, voltage variation, protection and safety. Especially, it is expected that the interconnection/disconnection operation of cogeneration system has an effect on distribution voltage regulation and variation. Recently, with the increased use of customer-owned computers and other sensitive electronic equipment, electric power quality has become an important concerns. Therefore, the voltage quality problems with cogeneration system should be investigated because the voltage quality is an important part of electrical power quality. In this paper, the momentary voltage dips associated with the interconnection/disconnection operation of cogeneration system are analyzed, including restraint solutions at the customer level. In addition, the unit capacity of cogeneration systems per feeder are evaluated from the view point of momentary voltage variations. The results of this paper are useful analysis data for interconnection standards/guidelines of cogeneration systems and dispersed generation (DG)

• Progress in Superconductivity and Cryogenics
• /
• v.16 no.1
• /
• pp.36-41
• /
• 2014

Since glass microsphere has high crush strength, low density and small particle size, it becomes alternative thermal insulation material for cryogenic systems, such as storage and transportation tank for cryogenic fluids. Although many experiments have been performed to verify the effective thermal conductivity of microsphere, prediction by calculation is still inaccurate due to the complicated geometries, including wide range of powder diameter distribution and different pore sizes. The accurate effective thermal conductivity model for microsphere is discussed in this paper. There are four mechanisms which contribute to the heat transfer of the evacuated powder: gaseous conduction ($k_g$), solid conduction ($k_s$), radiation ($k_r$) and thermal contact ($k_c$). Among these components, $k_g$ and $k_s$ were calculated by Zehner and Schlunder model (1970). Other component values for $k_c$ and $k_r$, which were obtained from experimental data under high vacuum conditions were added. In this research paper, the geometry of microsphere was simplified as a homogeneous solid sphere. The calculation results were compared with previous experimental data by R. Wawryk (1988), H. S. Kim (2010) and the experiment of this paper to show good agreement within error of 46%, 4.6% and 17 % for each result.

• Journal of the Computational Structural Engineering Institute of Korea
• /
• v.24 no.4
• /
• pp.429-438
• /
• 2011

In this paper, experiment of thermal conductivity among thermal properties for CCS insulation material was carried out under the condition ranged from room temperature to cryogenic temperature. CCS insulation system should be sustained under cryogenic temperature($-163^{\circ}C$), and lots of investigations will be conducted how to block the heat to insulation material. CCS components which consist of various materials are especially the main interests, and how the temperature of the entire CCS along the location is should be investigated through these studies. With the experimental thermal properties, the steady state thermal analysis of the entire cargo system was conducted. When the LNG leaked through the insulation system with external impact, temperature distribution and thermal safety of secondary barrier, especially plywood and hull structure, was observed.

• Transactions of the Korean Society of Machine Tool Engineers
• /
• v.17 no.2
• /
• pp.65-70
• /
• 2008

This study deals with the friction welding of SKH55 and SM45C; The friction time was variable conditions under the conditions of spindle revolution 2,000rpm, friction pressure of 190MPa, upset pressure of 270MPa and upset time of 2.0 seconds. Under these conditions, the microstructure of weld interface, tensile fracture surface and mechanical tests were studied, and so the results were as follows. 1. When the friction time is 1.0 seconds, the tensile strength of friction welds was 926MPa, which is around as much as 84% of the tensile strength of base metal(SKH55), the bending strength of friction welds was 1,542MPa, which is around as much as 80% of the bending strength of base metal(SKH55), the shear strength of friction welds was 519MPa, which is around as much as 70% of the shear strength of base metal(SKH55). 2 According to the hardness test, the hardness distribution of the weld interface was formed from 964Hv to 254Hv. HAZ(Heat Affected Zone) was formed from the weld interface to 1.5mm of SKH55 and 2mm of SM45C.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
• /
• v.20 no.7
• /
• pp.462-469
• /
• 2008

A regenerative evaporative cooler has been fabricated and tested for the evaluation of cooling performance. The regenerative evaporative cooler is a kind of indirect evaporative cooler comprised of multiple pairs of dry and wet channels. The air flowing through the dry channels is cooled without any change in the humidity and at the outlet of the dry channel a part of air is redirected to the wet channel where the evaporative cooling takes place. The regenerative evaporative cooler fabricated in this study consists of the multiple pairs of finned channels in counterflow arrangement. The fins and heat transfer plates were made of aluminum and brazed for good thermal connection. Thin porous layer coating was applied to the internal surface of the wet channel to improve surface wettability. The regenerative evaporative cooler was placed in a climate chamber and tested at various operation condition. The cooling performance is found greatly influenced by the evaporation water flow rate. To improve the cooling performance, the evaporation water flow rate needs to be minimized as far as the even distribution of the evaporation water is secured. At the inlet condition of $32^{\circ}C$ and 50%RH, the outlet temperature was measured at $22^{\circ}C$ which is well below the inlet wet-bulb temperature of $23.7^{\circ}C$.