• Title/Summary/Keyword: Hazardous component

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Effect of surfactant types in aqueous cleaning agents on their physical properties, cleaning ability and oil-water separation (수계세정제의 계면활성제 종류에 따른 물성, 세정성 및 유수분리 영향 연구)

  • Park, S. W.;Cha, A. J.;Kim, H. T.;Kim, H. S.;Bae, J. H.
    • Clean Technology
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    • v.9 no.1
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    • pp.9-21
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    • 2003
  • CFC-113 and 1,1,1-TCE which are ozone destruction substances are not used any more in the advanced countries because of Montreal protocol. MC and TCE are now used restrictively at small part of industrial fields in most of countries since they are known to be hazardous or carcinogenic materials. Thus, it is indispensible that the alternative cleaning agents which are environmental-friendly and safe, and show good cleaning ability should be developed or utilized for replacement of the halogenated cleaning agents. Aqueous cleaning agents are evaluated to be promising alternative ones among various alternatives in environmental and economical view point. This study has been carried out as a part of development program of aqueous cleaning agent. First of all, several types of surfactants which are the most important component in aqueous cleaning agents were chosen, and the physical properties, foaming ability, cleaning ability and oil-water separation efficiency of their aqueous solutions were measured and compared for selection of proper type of surfactant in aqueous cleaning agents.

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Comparative risk analysis for priority ranking of environmental problems in Seoul

  • Kim, Ye-Shin;Lee, Yong-Jin;Park, Hoa-Sung;Lim, Young-Wook;Shin, Dong-Chun
    • Proceedings of the Korea Society of Environmental Toocicology Conference
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    • 2003.10a
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    • pp.169-169
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    • 2003
  • In Korea, there is no CRA studies and has not well known CRA and not well established their methodologies. Therefore, objectives of this study is to establish the framework of CRA consisting of health risk, economic risk and perceived risk and the detail methodologies of three main component of estimating and comparing those risks for on the three environmental problems of air pollution, indoor air pollution and drinking water contamination which being subjective to the eight sub-problems of hazardous ai. pollutants (HAPs), regulated pollutants (representative as PM10) and Dioxins (PCDDS/ PCDFs) in air pollution, and indoor ai. pollutants (IAPs) and Radon in indoor air pollution, and drinking water pollutants (DWPs), disinfection-by- products(DBPs) and radionuclides in drinking water contamination in Seoul, Korea. And then, their problems set priorities by individual and integrated risk. As a results, ranking of health risk were the following order of indoor air pollution, air pollution and then drinking water contamination, in three environmental problems and of radon, PM10, IAPs, HAPs, DWPs, Dioxins, DBPs, and then radionuclides in eight sub-problems. And that of economic risk were the same order. In the contrary, ranking of perceived risk were the following order of air pollution, drinking water contamination, and then indoor air pollution, and of HAPs, Dioxins, radionuclides, PM10, DWPs, IAPs, Radon and then DBPs.

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Energetic Material Reduced Sensitivity RDX (에너지 물질 RDX의 둔감화)

  • Lee, Woojin;Kim, Younghan;Lee, Kibong;Koo, Kee Kahb;Lim, Ho Young
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2017.05a
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    • pp.482-488
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    • 2017
  • Recently, weapon system has been highly regarding IM ability. Explosive is positively necessary in weapon system and it is principle component that must be improved for IM as the most hazardous material. RDX is one of energetic materials used the most at present since 1930s. It is being applied a lot to most of explosive in warhead and artillery and rocket propellants in these latter days due to its low cost and high energetic characteristics. However, it has a disadvantage which is more sensitive than some insensitive explosive like NTO, DADNE recently developed. To overcome this, researches have been continued about insensitive RDX and we are performing the study as well. In this study, we developed to apply reduced sensitivity RDX to pilot scale and mass production and we could confirm a result by shock sensitivity test.

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Firing Test of Core Engine for Pre-cooled Turbojet Engine

  • Taguchi, Hideyuki;Sato, Tetsuya;Kobayashi, Hiroaiki;Kojima, Takayuki;Fukiba, Katsuyoshi;Masaki, Daisaku;Okai, Keiichi;Fujita, Kazuhisa;Hongoh, Motoyuki;Sawai, Shujiro
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2008.03a
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    • pp.115-121
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    • 2008
  • A core engine for pre-cooled turbojet engines is designed and its component performances are examined both by CFD analyses and experiments. The engine is designed for a flight demonstration of precooled turbojet engine cycle. The engine uses gas hydrogen as fuel. The external boundary including measurement devices is set within $23cm{\times}23cm$ of rectangular cross section, in order to install the engine downstream of the air intake. The rotation speed is 80000 rpm at design point. Mixed flow compressor is selected to attain high pressure ratio and small diameter by single stage. Reverse type main combustor is selected to reduce the engine diameter and the rotating shaft length. The temperature at main combustor is determined by the temperature limit of non-cooled turbine. High loading turbine is designed to attain high pressure ratio by single stage. The firing test of the core engine is conducted using components of small pre-cooled turbojet engine. Gas hydrogen is injected into the main burner and hot gas is generated to drive the turbine. Air flow rate of the compressor can be modulated by a variable geometry exhaust nozzle, which is connected downstream of the core engine. As a result, 75% rotation speed is attained without hazardous vibration and heat damage. Aerodynamic performances of both compressor and turbine are obtained and evaluated independently.

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Fault Detection Method for Multivariate Process using ICA (독립성분분석을 이용한 다변량 공정에서의 고장탐지 방법)

  • Jung, Seunghwan;Kim, Minseok;Lee, Hansoo;Kim, Jonggeun;Kim, Sungshin
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.24 no.2
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    • pp.192-197
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    • 2020
  • Multivariate processes, such as large scale power plants or chemical processes are operated in very hazardous environment, which can lead to significant human and material losses if a fault occurs. On-line monitoring technology, therefore, is essential to detect system faults. In this paper, the ICA-based fault detection method is conducted using three different multivariate process data. Fault detection procedure based on ICA is divided into off-line and on-line processes. The off-line process determines a threshold for fault detection by using the obtained dataset when the system is normal. And the on-line process computes statistics of query vectors measured in real-time. The fault is detected by comparing computed statistics and previously defined threshold. For comparison, the PCA-based fault detection method is also implemented in this paper. Experimental results show that the ICA-based fault detection method detects the system faults earlier and better than the PCA-based method.

Benzene Contents and Reliability of Material Safety Data Sheets for Paint Thinners sold in Busan, Ulsan, and Gyeongnam (부·울·경에서 판매되는 도료 희석제의 구성성분 함량과 물질안전보건자료의 신뢰성에 관한 연구)

  • Sungjun, Woo;Kwonchul, Ha
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.32 no.4
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    • pp.340-349
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    • 2022
  • Objectives: The importance of MSDS is emphasized for communicating hazardous information due to the increase in the types and usage of chemical substances. The purpose of this study is to assess the reliability of MSDS by collecting and examining paint thinners commercially available in South Korea. Methods: Twenty-five paint thinners were purchased at paint stores and the provision of MSDS was checked. Quantitative and qualitative analysis was performed on the chemical constituents of the thinners using GC-MSD and GC-FID. Reliability was evaluated by the MSDS collection rate for the paint thinners and calculating the rate of matching between laboratory analysis results and the contents and composition of chemical constituents given in the MSDS. Results: Unlike a study conducted in 2006, MSDS were provided for all 25 thinners. As a result of qualitative analysis using GC-MSD, 104 chemical substances were detected. The substances with the highest detection rate were identified in the order of toluene, butyl acetate, acetone, xylene, and ethyl benzene. A component matching rate of 41% was found by comparing the differences between the number of substances detected in laboratory testing and the number of substances listed in the MSDS. Benzene, a carcinogen not listed in the MSDS, was detected in two thinners produced by a small company. The detected benzene contents were 0.039 and 0.040%. When benzene is used, it should be strictly handled according to the Industrial Safety and Health Act. However, since it is not listed on the MSDS, it is judged that benzene was not being managed as a carcinogen in the workplaces where it is used. Conclusions: Since the reliability of MSDS, which play an important role in hazard communication, was evaluated to be low, it is necessary to systematically and continuously secure this reliability. In particular, carcinogens should be managed more strictly.

Seismic Retrofit Assessment of Different Bracing Systems

  • Sudipta Chakraborty;Md. Rajibul Islam;Dookie Kim;Jeong Young Lee
    • Architectural research
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    • v.25 no.1
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    • pp.1-9
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    • 2023
  • Structural ageing influences the structural performance in a negative way by reducing the seismic resilience of the structure which makes it a major concern around the world. Retrofitting is considered to be a pragmatic and feasible solution to address this issue. Numerous retrofitting techniques are devised by researchers over the years. The viability of using steel bracings as retrofitting component is evaluated on a G+30 storied building model designed according to ACI318-14 and ASCE 7-16. Four different types of steel bracing arrangements (V, Inverted V/ Chevron, Cross/ X, Diagonal) are assessed in the model developed in commercial nu-merical analysis software while considering both material and geometric nonlinearities. Reducing displacement and cost in the structures indicates that the design is safe and economical. Therefore, the purpose of this article is to find the best bracing system that causes minimum displacement, which indicates maximum lateral stiffness. To evaluate the seismic vulnerability of each system, incremental dynamic analysis was conducted to develop fragility curves, followed by the formation of collapse margin ratio (CMR) as stipulated in FEMA P695 and finally, a cost estimation was made for each system. The outcomes revealed that the effects of ge-ometric nonlinearity tend to evoke hazardous consequences if not considered in the structural design. Probabilistic seismic and economic probes indicated the superior performance of V braced frame system and its competency to be a germane technique for retrofitting.

A Study on the Selectively Block Barrier for Prevent the Spread of TPH and Phenol in the Ground (지중 내 TPH, Phenol의 확산방지를 위한 선택적 차수재 제조에 관한 연구)

  • HoJin Lim;WooRi Cho;SeungJin Oh;SuHee Kim;JaiYoung Lee
    • Journal of the Korean Geosynthetics Society
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    • v.23 no.1
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    • pp.1-7
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    • 2024
  • In this study, a selecvively block barrier was developed to prevent the spread of contaminants (TPH, Phenol) in the ground only when contamination occurs. The materials were used Jumunjin sand, bentonite, polyolefin elastomer and spill hound marine. First, the properties and environmental hazards characteristics of materials were analyzed for evaluated their usability. Then, the possibility of use as a barrier material was confirmed by analyzing the water permeability characteristics that change after 24 hours of contact with contaminants. As a result of the analysis, the pH of each component was similar to the general groundwater pH range. In addition, the toxicity characteristics and the possibility of dissolution of hazardous substances, it was determined that there was no environmental hazard as the content was below the regulation value. Lastly, when comparing the permeability coefficient before and after contact with the contaminant, the permeability coefficient of approximately α × 10-3cm/sec before contact was reduced to α × 10-6cm/sec after contact with the contaminant.

Development of Source Profiles and Estimation of Source Contribution for Hazardous Air Pollutants by the Principal Component Analysis in Indoor Air

  • Kim, Yoon-Shin;Hong, Seoung-Cheol;Lee, Cheol-Min;Kim, Jong-Cheol;Jeon, Hyung-Jin;Song, Kyoung-Min;Roh, Young-Man
    • Proceedings of the Korean Environmental Health Society Conference
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    • 2005.06a
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    • pp.254-258
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    • 2005
  • The purpose of this study is to characterize the indoor-outdoor relationship of airborne pollutants and recognize probable sources in inside and outside individual apartments in Seoul metropolitan. Simultaneous air monitoring in inside and outside of the 16 Korean Apartments classified into 2groups: less than 1 year old and more than 4 years old from October, 2004 to February, 2005were sampled f3r airborne pollutants(volatile organic compounds, formaldehyde, respiratory particles, carbon dioxide and bacteria) using the Korean Indoor Air Quality Official Method. The concentrations of $CO_2$, TVOCs, HCHO, bacteria and PM10 in the less than 1 year old apartments were determined to be $773.6{\pm}422.3ppm$, $4,393.8{\pm}2,758.2{\mu}g/m^3$, $98.0{\pm}56.4{\mu}g/m^3$, $254.0{\pm}186.3CFU/m^3$ and $31.7{\pm}14.8{\mu}g/m^3$, respectively, Also, the concentrations of those in the more than 4 years old apartments were determined to be $798.9{\pm}266.5ppm$, $792.7{\pm}398.3{\mu}g/m^3$, $70.0{\pm}30.7{\mu}g/m^3$, $245.6{\pm}122.0CFU/m^3$, $49.7f28.7{\pm}g/m^3$, respectively. The average ratios of the indoor and outdoor concentrations of $CO_2$, TVOCs, HCHO, bacteria and PM10 were 2.2, 3.6, 3.1, 3.9 and 1.4, respectively. These results of this analysis is suggested that $CO_2$, TVOCs, HCHO, bacteria and PM10 in indoor air are both emitted from source within the apartment environment and partly come from outdoor air. With the above considerations in mind, it is suggested that the research for source contribution of indoor air pollutants should be expanded and the detailed interpretation of the results on these needed further study(using principal component analysis(PCA).

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Quality Characteristics of the Vaporized Liquid of Water-boiled Pine Needle (솔잎 열수 증류액의 품질특성)

  • Lee, Hyo-Jin;Cui, Cheng-Bi;Choi, Hyung-Taek;Kim, Soo-Hyun;Ham, Young-An;Lee, Deuk-Sik;Ham, Seung-Shi
    • Food Science and Preservation
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    • v.12 no.2
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    • pp.107-111
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    • 2005
  • We investigated the quality of vaporized liquid of water-boiled pine needle in the aspects of drinking conformity and aroma characteristics. As a result, there was no hazardous component in the assessment for 45 types of ingredients. Especially, inorganic components such as arsenic (As), lead (Pb), mercury (Hg), and cadmium (Cd) which are harmful to human body were not detected. Additionally, we observed that other ingredients were present within the standard level suitable for drinking. The total 34 volatile components of the vaporized liquid of water-boiled pine needle were identified by dynamic head-space method. Fenchol, bomeol $\beta-fenchyl$ alcohol and bomyl acetate were the major volatiles and composed of 6.7, 13.1, 26.6 and $16.2\%$ of total volatiles, respectively. In addition, the alcohols and aldehydes were the prominent ingredients of which the contents showed comparatively high.