• Title/Summary/Keyword: Harmful gas

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Synthesis of functional ZnO nanoparticles and their photocatalytic properties

  • Nam, Sang-Hun;Kim, Myoung-Hwa;Lee, Sang-Duck;Kim, Min-Hee;Boo, Jin-Hyo
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.02a
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    • pp.54-54
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    • 2010
  • Zinc oxide is metal oxide semiconductor with the 3.37 eV bandgap energy. Zinc oxide is very attractive materials for many application fields. Zinc Oxide has many advantages such as high conductivity and good transmittance in visible region. Also it is cheaper than other semiconductor materials such as indium tin oxide (ITO). Therefore, ZnO is alternative material for ITO. ZnO is attracting attention for its application to transparent conductive oxide (TCO) films, surface acoustic wave (SAW), films bulk acoustic resonator (FBAR), piezoelectric materials, gas-sensing, solar cells and photocatalyst. In this study, we synthesized ZnO nanoparticles and defined their physical and chemical properties. Also we studied about the application of ZnO nanoparticles as a photocatalyst and try to find a enhancement photocatalytic activity of ZnO nanorticles.. We synthesized ZnO nanoparticles using spray-pyrolysis method and defined the physical and optical properties of ZnO nanoparticles in experiment I. When the ZnO are exposed to UV light, reduction and oxidation(REDOX) reaction will occur on the ZnO surface and generate ${O_2}^-$ and OH radicals. These powerful oxidizing agents are proven to be effective in decomposition of the harmful organic materials and convert them into $CO_2$ and $H_2O$. Therefore, we investigated that the photocatalytic activity was increased through the surface modification of synthesized ZnO nanoparticles. In experiment II, we studied on the stability of ZnO nanoparticles in water. It is well known that ZnO is unstable in water in comparison with $TiO_2$. $Zn(OH)_2$ was formed at the ZnO surface and ZnO become inactive as a photocatalyst when ZnO is present in the solution. Therefore, we prepared synthesized ZnO nanoparticles that were immersed in the water and dried in the oven. After that, we measured photocatalytic activities of prepared samples and find the cause of their photocatalytic activity changes.

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Physicochemical Characteristics of CDPF according to Ash a Cleaning agent (Ash 세정제에 따른 CDPF의 물리화학적 특성)

  • Seo, Choong-Kil
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.18 no.4
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    • pp.641-647
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    • 2017
  • In order to meet the stricter emission regulations, the proportion of after-treatments for vehicles and vessels has been increasing gradually. The objective of this study is to investigate the physicochemical properties according to ash cleaning agents of CDPF for Diesel Engines. Penetrating agents with strong penetration into ash and a surfactant component to mix water and oil were prepared properly. The cleaning characteristics of S1 sample were good. Washcoat loss rate of S1 sample was lower by about 2.2% because of less KOH component and lower Na2SiO3 content. Washcoat loss rate of S4 sample with an added KOH and Na2SiO3 components by penetration agents was increased by about 13%. In terms of less than about 13% of CDPF's washcoat loss rate, it was able to reduce the harmful gas components.

Design of Integrated Safery System for Sealed Places (밀폐된 공간을 위한 통합안전시스템의 설계)

  • Jeong, Min-Seung;Lee, Chang-Shin;Cho, Woo-Hyeon
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.23 no.1
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    • pp.97-102
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    • 2019
  • Disaster accidents at industrial sites have been increasing every year. In shipyards there are countless enclosed spaces causing issues like harmful-toxic gases stuck in those sealed areas. And due to such special and complicated structures of the working places with many layers of walls separating each other, there exist more issues of communication with workers trapped inside when accidents happen. Under this circumstance there must be a huge difficulty to evacuate or rescue the workers in case of any disaster. Therefore, in this paper, We would like to introduce the "integrated safety system" to more effectively deal with the problems and prevent such disasters in tough working environments. The suggested integrated safety system can prevent accidents in advance because it can control the data on the location of the workers in real time and the numerical values such as gas, oxygen, and carbon dioxide generated in the workplace in real time.

Dynamometer Test for the CVT System using Spring

  • Kwon, Young-Woong;Yang, Seung-Bok
    • International journal of advanced smart convergence
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    • v.11 no.3
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    • pp.222-228
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    • 2022
  • As a means to cope with the climate change crisis caused by global warming, automobile manufacturers continue to make efforts to use the driving energy of vehicles as electricity. As a result, parts industry such as battery, motor, and controller are attracting attention. China is often seen in large cities, with electric vehicles such as electric bicycles, electric motorcycles, and small electric vehicles popularized and commercialized, mainly in large cities. However, small electric vehicles are not popular in Korea, which is why the country's topography is high in hills. In order to drive the hilly domestic roads, power performance including vehicle climbing ability should be improved. In order to improve the power performance and the climbing capacity of small electric vehicles, the capacity of the motor should be increased. However, when the performance of the motor is improved, the weight of the motor becomes heavy and the price competitiveness is likely to decrease. In addition, in order to operate a high-performance motor, the power consumption of the battery is rapidly increased, so various problems must be solved. In order to commercialize a small electric vehicle for one or two people who do not emit harmful exhaust gas to the human body in a hilly domestic terrain, it is effective to have a separate transmission system. In this study, we were conducted dynamometer test to produce a continuously variable transmission(CVT) system prototype using a spring that can be applied to a small electric vehicle and to install a CVT system prototype manufactured in a small electric vehicle. The dynamometer test results showed that the maximum speed performance, acceleration performance, and climbing performance were improved.

A Study on the Production of Supporting Ring Using Casting for Public Environmental Vehicles (대중적 환경차를 위한 주조를 이용한 서포트링 제작에 관한 연구)

  • Jeongick Lee
    • Journal of Advanced Technology Convergence
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    • v.2 no.3
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    • pp.17-24
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    • 2023
  • I am designing a research paper with the aim of studying hybrid vehicles. Hybrid vehicles, as the next-generation automobiles, feature a combination of internal combustion engines and battery engines, resulting in a revolutionary reduction in fuel consumption and harmful gas emissions compared to conventional vehicles. The electric motor in hybrid cars derives power from a high-voltage battery installed within the vehicle, which is recharged during vehicle motion. In contrast to traditional cars, which often experience energy losses due to idling caused by traffic congestion, hybrid systems optimize efficiency by skillfully managing the interplay between the internal combustion engine and the electric motor. This approach effectively addresses the inherent drawbacks of gasoline or diesel engines.Hybrid cars offer an array of benefits, including improved fuel efficiency, environmental friendliness, cost-effectiveness, and reduced noise emission. Consequently, they are progressively becoming a favored alternative among a growing number of individuals. This research endeavor has the potential to contribute towards curbing environmental pollution and dedicating efforts to future automotive research.

Effect of Varying Excessive Air Ratios on Nitrogen Oxides and Fuel Consumption Rate during Warm-up in a 2-L Hydrogen Direct Injection Spark Ignition Engine (2 L급 수소 직접분사 전기점화 엔진의 워밍업 시 공기과잉률에 따른 질소산화물 배출 및 연료 소모율에 대한 실험적 분석)

  • Jun Ha;Yongrae Kim;Cheolwoong Park;Young Choi;Jeongwoo Lee
    • Journal of the Korean Institute of Gas
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    • v.27 no.3
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    • pp.52-58
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    • 2023
  • With the increasing awareness of the importance of carbon neutrality in response to global climate change, the utilization of hydrogen as a carbon-free fuel source is also growing. Hydrogen is commonly used in fuel cells (FC), but it can also be utilized in internal combustion engines (ICE) that are based on combustion. Particularly, ICEs that already have established infrastructure for production and supply can greatly contribute to the expansion of hydrogen energy utilization when it becomes difficult to rely solely on fuel cells or expand their infrastructure. However, a disadvantage of utilizing hydrogen through combustion is the potential generation of nitrogen oxides (NOx), which are harmful emissions formed when nitrogen in the air reacts with oxygen at high temperatures. In particular, for the EURO-7 exhaust regulation, which includes cold start operation, efforts to reduce exhaust emissions during the warm-up process are required. Therefore, in this study, the characteristics of nitrogen oxides and fuel consumption were investigated during the warm-up process of cooling water from room temperature to 88℃ using a 2-liter direct injection spark ignition (SI) engine fueled with hydrogen. One advantage of hydrogen, compared to conventional fuels like gasoline, natural gas, and liquefied petroleum gas (LPG), is its wide flammable range, which allows for sparser control of the excessive air ratio. In this study, the excessive air ratio was varied as 1.6/1.8/2.0 during the warm-up process, and the results were analyzed. The experimental results show that as the excessive air ratio becomes sparser during warm-up, the emission of nitrogen oxides per unit time decreases, and the thermal efficiency relatively increases. However, as the time required to reach the final temperature becomes longer, the cumulative emissions and fuel consumption may worsen.

Synthesis and Luminescence Characteristics of SrGa2S4:Eu Green Phosphor for Light Emitting Diodes by Solid-State Method (고상법을 이용한 LED용 SrGa2S4:Eu 녹색 형광체의 합성 및 발광특성)

  • Kim, Jae-Myung;Kim, Kyung-Nam;Park, Joung-Kyu;Kim, Chang-Hae;Jang, Ho-Gyeom
    • Journal of the Korean Chemical Society
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    • v.48 no.4
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    • pp.371-378
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    • 2004
  • The $SrGa_2S_4:Eu^{2+}$ green emitting phosphor has been studied as a luminous device for CRT (Cathode Ray Tube) or FED (Field Emission Display) and EL (Electroluminescence). This phosphor, also, is under noticed for LED (Lighting Emitting Diode) phosphor, which makes use of excitation characteristics of long wavelength region. The $SrGa_2S_4:Eu^{2+}$ phosphor was prepared generally conventional synthesis method using flux. However, this method needs high heat-treated temperature, long reaction time, complex process and harmful $H_2S$or $CS_2$ gas. In this works, therefore, we have synthesized $SrGa_2S_4:Eu^{2+}$ using SrS, $Ga_2S_3$, and EuS as starting materials, and the mixture gas of 5% H2/95% N2 was used to avoid the $H_2S$or $CS_2$. We investigated the luminescence characteristic of $SrGa_2S_4:Eu^{2+}$ phosphor prepared in various synthesis conditions, performed post-treatment and sieving process for application to LED.

THE NITROUS OXIDE CONCENTRATION IN BREATHING ZONE ACCORDING TO SCAVENGING METHODS DURING DEEP SEDATION OF PEDIATRIC DENTAL PATIENTS (소아치과 환자의 깊은 진정시 호기가스 제거 방법에 따른 호흡대역에서 Nitrous Oxide 농도 변화)

  • Lee, Chung-Won;Yoon, Hyung-Bae
    • Journal of the korean academy of Pediatric Dentistry
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    • v.30 no.1
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    • pp.124-131
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    • 2003
  • The concentration of nitrous oxide in dental environment has increased especially in pediatric department. In pediatric department frequently met the behavior disordered patients who need the deep sedation. As the deeply sedated patients could not respond well to verbal command, the amount of mouth breathing would be increased especially with mouth prop which backward transposition of mandible. Inhalation of low concentration of nitrous oxide for a long duration has caused various side effects such as spontaneous abortion and inhibition of methionine synthetase activity which is harmful to DNA synthesis. For evaluation of factors of mouth breathing during deep sedation. The author measured the concentration of nitrous oxide in breathing zone by the change of the scavenging methods. One is drain the gas through the tail part of reservoir bag of Jackson Ree's system naturally. Another is scavenge from tail portion of reservoir bag with negative pressure. Last one is scavenge from nasal mask with negative pressure. The nitrous oxide concentration in breathing zone was the lowest in nasal part drainage but high above the recommended concentration of NIOSH. The order of nitrous concentration in breathing zone was: natural drainage, tail part with negative pressure, nasal part with negative pressure. This would reflect the order of resistance of nasal airway and showed the amount of mouth breathing. From the above experiment, the resistance of nasal airway by the increment of gas flow in corrugating tube and reservoir bag would be one of the causative factors of mouth breathing in deeply sedated patients.

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Simultaneous Reduction of CH4 and NOx of NGOC/LNT Catalysts for CNG buses (CNG 버스용 NGOC/LNT 촉매의 CH4와 NOx의 동시 저감)

  • Seo, Choong-Kil
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.19 no.6
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    • pp.167-175
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    • 2018
  • Natural gas is a clean fuel that discharges almost no air-contaminating substances. This study examined the simultaneous reduction of $CH_4$ and NOx of NGOC/LNT catalysts for CNG buses related to the improvement of the $de-CH_4/NOx$ performance, focusing mainly on identifying the additive catalysts, loading of the washcoat, stirring time, and types of substrates. The 3wt. % Ni-loaded NGOC generally exhibited superior $CH_4$ reduction performance through $CH_4$ conversion, because Ni is an alkaline, toxic oxide, and exerts a reducing effect on $CH_4$. A excessively small loading resulted in insufficient adsorption capacity of harmful gases, whereasa too high loading of washcoat caused clogging of the substrate cells. In addition, with the economic feasibility of catalysts considered, the appropriate amount of catalyst washcoat loading was estimated to be 124g/L. The NOx conversion rate of the NGOC/LNT catalysts stirred from $200^{\circ}C$ to $550^{\circ}C$ for 5 hours showed 10-15% better performance than the NGOC/LNT catalysts mixed for 2 hours over the entire temperature range. The NGOC/LNT catalysts exhibitedapproximately 20% higher $de-CH_4$ performance on the ceramic substrates than on the metal substrates.

Improvement of the performance and emission in a four-stroke diesel engine using fuel additive (4행정 디젤엔진에 연료첨가제 사용에 따른 성능 및 배기배출물 개선에 관한 연구)

  • Ryu, Younghyun;Lee, Youngseo;Nam, Jeonggil
    • Journal of Advanced Marine Engineering and Technology
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    • v.40 no.9
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    • pp.762-767
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    • 2016
  • High thermal efficiency and the ability to use various types of fuel are a few of the many advantages of diesel engines. However, a major disadvantage is that their exhaust emissions are more harmful to humans and the environment than that of conventional engine. Consequently, the provisions of the international emissions standards for diesel engine equipped passenger cars, commercial vehicles, and ships have become more stringent. These standards include the EU Euro 6, the IMO MEPC Tier 3, and the US EPA Tier 4. Ryu et al. published a study that applied fuel additives to two-stroke diesel engines. In this study, a four-stroke diesel engine using diesel oil for a generator is utilized as the test subject, and an experiment is performed to verify whether fuel additive can be used to improve performance and exhaust emissions. In addition, this experimental study presents research results for the application of fuel additives in both two-stroke and four-stroke diesel engines. The experimental results were compared and analyzed by placing an oil-soluble calcium-based organometallic compound in diesel oil. The results confirmed that the addition of fuel additive improved the performance (fuel consumption rate, exhaust gas temperature) and exhaust emissions (NOx, CO) of the diesel engine.