• Title/Summary/Keyword: Hardened body

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Effect of Curing Temperature on Geopolymeric Polycondensation of Blast Furnace Slag (고로슬래그의 지오폴리머 축중합반응에 미치는 양생온도의 영향)

  • Jeon, Chang-Seob;Song, Tae-Woong
    • Journal of the Korean Ceramic Society
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    • v.48 no.6
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    • pp.610-616
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    • 2011
  • The effect of curing temperature on basic geopolymeric reactivity and hardening behaviour of blast furnace slag were investigated using the mixture of pulverized slag and several alkaline solutions of relatively high concentration. For the pastes prepared at several different temperatures between 20$^{\circ}C$ and 90$^{\circ}C$, setting time and heat of reaction were examined while mineralogical and morphological examinations were performed for the hardened paste after curing period at same temperature. The geopolymeric reaction of slag was revealed to be accelerated strongly according to the curing temperature regardless of the sort and concentration of the alkaline solution. The increase of concentration of the alkaline solution within 9M and the existence of silicic ion in the solution also promoted the reaction severely. The mineral component and their ratio of the hardened paste were revealed to be influenced by the chemical species and silicic ion contained in alkaline solution rather than by the curing temperature. The higher temperature and longer period of curing stage were effective for the sustained formation of geopolymer and succeed improvement of density and uniformity of morphology of the final hardened body.

Hydration of $C_4A_3\bar{S}$-Calciumsicate Clinker ($C_4A_3\bar{S}$-Calciumsicate계 크링커의 수화반응)

  • 이승주;최상흘
    • Journal of the Korean Ceramic Society
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    • v.19 no.1
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    • pp.51-57
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    • 1982
  • The clinckers were obtained when a raw mixture consisted of limestone, slags and gypsum was burned at 134$0^{\circ}C$ for 30 minutes, and 128$0^{\circ}C$ for 30 minutes adding $CaF_2$ as a flux. The principal compounds of these clinkers were $C_3S_2$, $\beta-C_2S$, $C_1A_3{\bar{S}}$. To investigate hydration behavior, cements were made and hydrated at constant humidity cabinet (W/C=0.5 20$\pm 1^{\circ}C$). X-ray diffractometer, SEM, and conduction calorimeter were employed to examine the hydration behavior. The hydrates were mainly C-S-H, ettringite, $Ca(OH)_2$. By the hydration of $C_3S$ and $C_4A_3\bar{S}$, the needle-like ettringite filling the inner vacant spaces of the hardened body might contribute to the rapid-hardening and high-strength phenomena. Furthermore, the hardened body became stronger due to the hydration of $C_2S$ at later period. The addition of granulated blastfurnace slags have a potential to be a blended cement.

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A Study on Silicon Nitride Based Ceramic Cutting Tool Materials

  • Park, Dong-Soo
    • Tribology and Lubricants
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    • v.11 no.5
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    • pp.78-86
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    • 1995
  • The silicon nitride based ceramic cutting tool materials have been fabricated by gas pressure sintering (GPS) or hot pressing (HP). Their mechanical properties were measured and the effect of the fabrication variables on the properties were examined. Also, effect of adding TiN or TiC particulates on the mechanical properties of the silicon nitride ceramics were investigated. Ceramic cutting tools (ISO 120408) were made of the sintered bodies. Cutting performance test were performed on either conventional or NC lathe. The workpieces were grey cast iron, hardened alloy steel (AISI 4140, HRc>60) and Ni-based superalloy (Inconel 718). The results showed that fabrication variables, namely, sintering temperature and time, exerted a strong influence on the microstincture and mechanical properties of the sintered body, which, however, did not make much difference in wear resistance of the tools. High hardness of the tool containing TiC particulates exhibited good cutting performance. Extensive crater wear was observed on both monolithic and TiN-containing silicon nitride tools after cutting the hardened alloy steel. Inconel 718 was extremely difficult to cut by the current cutting tools.

A Study on the Theoretical Relation between Flow Stress and Vickers Hardness (유동응력과 비커스경도의 이론적 관계 연구)

  • 이충호
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 1997.03a
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    • pp.69-72
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    • 1997
  • The indentation process in the Vickers hardness test is a kind of controlled local plastic deformation. Vickers hardness is defined as indenting force per unit area indented by a pyramid-shaped diamond at the hardness test. That is a measure of mechanical resistance against indentation of a rigid body into the deformable material. Therefore it is well known that Vickers hardness has a direct relation with the flow stress of the strain-hardened tmaterial. This relation is theoretically investigated and the result is given for use in practice.

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A Study on Hydration of Slag-Gypsum System (슬래그-석고계 수화반응에 대한 기초 연구)

  • 지정식;최상흘
    • Journal of the Korean Ceramic Society
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    • v.15 no.4
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    • pp.205-212
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    • 1978
  • The hydration reaction of the slag-gypsum system was studied by X-ray diffraction, differential thermal analysis, optical icroscopic observation, and measurement of heat liberation of hydration. 1. Domestic granulated slag was almost noncrystalized state, and its mineral compositions calculated were 46.53% of gehlenite, 28.14% of akermanite, and 19.04% of wollastonite. 2. The slag quenched with water at relatively high temperature had better reactivity. 3. The production of ettringite, CSH gel and AH3 gel were stimulated by effect of $Ca(OH)_2$, $Mg(OH)_2$ and calcined dolomite as activators, and the strength of hardened body would be developed by forming compacted microstructure.

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Effect of Carbon on the Micro Structure and Hardness of Internally Hardened Ductile Cast Iron Roll (내부 경화형 구상흑연주철 롤 동체와 넥의 미세조직과 경도에 미치는 탄소 영향)

  • Sang-Mook Lee;Ki-Hang Shin;Byung-Chul Choi;Ki-Woo Nam
    • Journal of the Korean Society of Industry Convergence
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    • v.26 no.1
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    • pp.79-86
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    • 2023
  • This study was investigated the effect of carbon on the micro-structure and hardness of ductile cast iron roll with internal curing capacity. Spheroidal graphite existed at roll body with rapid cooling, but granular graphite existed at roll neck with slow cooling. The volume fraction of graphite increased at roll body with rapid cooling, That of roll neck with slow cooling decreased, but graphite size increased. The volume fraction of cementite decreased, but volume fraction increased. The cementite size was larger at roll neck than roll body. The hardness was decreased at roll body and roll neck due to volume fraction of cementite. The hardness of roll body was higher than roll neck.

An improved Maxwell creep model for salt rock

  • Wang, Jun-Bao;Liu, Xin-Rong;Song, Zhan-Ping;Shao, Zhu-Shan
    • Geomechanics and Engineering
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    • v.9 no.4
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    • pp.499-511
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    • 2015
  • The creep property of salt rock significantly influences the long-term stability of the salt rock underground storage. Triaxial creep tests were performed to investigate the creep behavior of salt rock. The test results indicate that the creep of salt rock has a nonlinear characteristic, which is related to stress level and creep time. The higher the stress level, the longer the creep time, the more obvious the nonlinear characteristic will be. The elastic modulus of salt rock decreases with the prolonged creep time, which shows that the creep damage is produced for the gradual expansion of internal cracks, defects, etc., causing degradation of mechanical properties; meanwhile, the creep rate of salt rock also decreases with the prolonged creep time in the primary creep stage, which indicates that the mechanical properties of salt rock are hardened and strengthened. That is to say, damage and hardening exist simultaneously during the creep of salt rock. Both the damage effect and the hardening effect are considered, an improved Maxwell creep model is proposed by connecting an elastic body softened over time with a viscosity body hardened over time in series, and the creep equation of which is deduced. Creep test data of salt rock are used to evaluate the reasonability and applicability of the improved Maxwell model. The fitting curves are in excellent agreement with the creep test data, and compared with the classical Burgers model, the improved Maxwell model is able to precisely predict the long-term creep deformation of salt rock, illustrating our model can perfectly describe the creep property of salt rock.

Analysis of Hydrogen-tightness on the Metal Sealing of a Fuel Pipe for FCEV according to Material Change of the Fitting Body (체결부 재료에 따른 FCEV 연료파이프 메탈 씰링부의 기밀성 분석)

  • Lee, J.M.;Han, E.S.;Chon, M.S.;Lee, H.W.
    • Transactions of Materials Processing
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    • v.28 no.5
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    • pp.266-274
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    • 2019
  • Metal sealing is used to connecting the parts between valves and fuel pipes for a FCEV which utilizes hydrogen gas of 700 bar. Instead of general carbon steel, stainless steel is the primary material used to manufacture fuel pipes due to hydrogen embrittlement. The shape of deformation between metals is an important factor on the air-tightness of the metal to metal contact. Since the stainless steel pipe is hardened using the plastic forming during the tip shaping stage, this work hardening could have an effect on the deformed shape and characteristics of contact surfaces in fastening of pipes. In this paper, the deformation history of the pipe model was considered in order to analyze the hydrogen-tightness on the metal sealing part. The contact distance and the forward displacement for fastening were compared using experimental results and the simulation results. The simulation of the effect of material change on the fitting body demonstrated that the hardness or the strength of the formed tip of the pipe was designed to a proper valued level since the characteristics of the contact surface was exhibited better when the strength of the pipe was lower than that of the fitting body.

Shrinkage Strain Property of the Magnesium Oxide Matrix According to Magnesium Chloride Addition Ratio (염화마그네슘 첨가율에 따른 산화마그네슘 경화체의 길이변화 특성)

  • Jung, Byeong-Yeol;Lee, Sang-Soo;Song, Ha-Young
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2013.11a
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    • pp.150-151
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    • 2013
  • Recently, the internal space organization of the building changes to the frame construction and flat slab construction in the wall type structure. And the use of light weight panel changing the internal joint use easily is increased. Therefore, in this research, the length change characteristic that the magnesium chloride addition rate reaches to the magnesium curing body tries to be studied. It could confirm according to the length change specific result that the magnesium chloride amount of addition reaches to the magnesium oxide curing body to expand. And the thing described below was the large-scale expansion the magnesium oxide addition rate 60%. And it showed up as 50, 40, 30, 20, and order of 10s (%). It could look at to form the hydrate of the SEM picture result needle-shaped of the Hardened.

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