• 한국표면공학회지
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• 제36권1호
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• pp.48-58
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• 2003

This paper will present an overview of toxicity of hexavalent chromium as well as effort for its replacement by a wide spectrum of alternative materials and technologies. Cr-based materials such as trivalent electrodeposit will be one of strong candidates for hard chromium by surface modification of its surface hardness. Ni-base alloy deposits has proved its application in specific mold for glass. HVOF has been studied in aircraft and military sector. There are still under way of development for commercially available alternatives. To date, no single coating has been identified as universal process as comparable to conventional hard chromium electroplating.

• 한국분말야금학회:학술대회논문집
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• 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part 1
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• pp.47-48
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• 2006

Oridinal thermal spray process has developed into two ways, namely, temperature dominated represented by plasma spraying, and velocity dominated represented by HVOF. It is common for both that the particle materials sprayed are basically in melted or half melted condition. New process has developed recently, that is, Cold Spray and Aerosol Deposition. Particle's heating is limited in CS lower than half of the material's melting point. Moreover, exactly no heating is loaded in AD process. Through the investigation on common feature for these three spraying processes, potential of new material process - Particle Deposition, PD - is considered and proposed.

• 한국재료학회지
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• 제16권5호
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• pp.329-335
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• 2006

In order to improve thermal efficiency of the fossil fuel power plants, we need to develop advanced materials with superior durability in the ultra-super critical state, which requires surface modifications for superior surface properties. In this study, we coated the Incoloy 901 and 12-17Cr steels for turbine buckets and valves with nitriding, boriding, and $Cr_3C_2-NiCr$ HVOF(high velocity oxygen flow) method. Then the samples were heat treated at $650^{\circ}C$ for 100 hours in vacuum. We analyzed the evolution behaviors of nitrides such as $Fe_3N,\;Fe_4N$, and CrN and borides such as FeB and $Fe_2B$ with XRD and SEM/EDS by comparing hardnesses and compositions of the coated layers before and after the heat treatments.

• 대한용접접합학회:학술대회논문집
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• 대한용접접합학회 2004년도 춘계 학술발표대회 개요집
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• pp.316-318
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• 2004

In recent years, plastic waste has been recognized as a worldwide environmental issue. To solve the disposal problem of the plastic waste, alternative treatment such as the use of biodegradable plastic(polybutylene succinate: PBS) is indeed highly in demand due to its merit of PBS buried in soil decomposed into carbon dioxide and water. In the present study, for the production of further functional PBS with TiO$_2$ as photocatalyst, which shows the decomposition of detrimental organic compound and pollutant under ultraviolet irradiation, we attempted to prepare photocatalytic TiO$_2$ coatings on PBS substrate by HVOF and plasma spraying techniques under various conditions using three kinds of agglomerated powders (P200: 200nm, P30: 30nm, P7: 7nm). The microstructures of coatings were characterized with SEM and XRD analysis, and the photocatalytic efficiency of coatings was evaluated through the photo degradation of gaseous acetaldehyde. Therefore, such functional TiO$_2$-Plastic composite material is expected to considerably contribute to the reduction of aggravated environmental problem.

• 한국재료학회지
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• 제27권2호
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• pp.119-126
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• 2017

WC-CrC-Ni coatings were prepared by nine processes of the Taguchi program with three levels for the four spray parameters: spray distance, flow rates of hydrogen and oxygen, and powder feed rate. The optimal coating process (OCP) was oxygen flow rate of 38 FMR, hydrogen flow rate of 53 FMR, powder feed rate of 25 g/min, and spray distance of 7 inches. Hardness of 1150 Hv and porosity of 1.2 %, were obtained by OCP; these are better results compared with the highest 1033 Hv and the lowest 1.5 % porosity obtained by nine processes of the Taguchi program. Friction coefficient of the WC-CrC-Ni coating decreased from $0.36{\pm}0.07$ at $25^{\circ}C$ to $0.23{\pm}0.07$ at $450^{\circ}C$. These values were smaller than those of the EHC (electrolytic hard chrome) plating at both temperatures due to lubrication from the oxide debris. The wear trace and wear depth of the coating are smaller than those of the EHC at both temperatures. Pitting was not found in the WC-CrC-Ni coating sample, while it did appear in the EHC sample.

• 한국세라믹학회지
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• 제45권9호
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• pp.549-555
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• 2008

The thermal barrier coating must withstand erosion when subjected to flowing gas and should also maintain good stability and mechanical properties while it must also protect the turbine component from high temperature, hot corrosion, creep, and oxidation during operation. In this study we investigated the influence of subsurface layer, $Al_2O_3$ or NiCrCoAIY bond coat layer, on the indentation damage behavior of YSZ thermal barrier coating layers deposited by electron beam physical vapor deposition (EB-PVD). The bond coat is deposited using different process such as air plasma spray (APS) or spray of high velocity oxygen fuel (HVOF) and the thickness is varied. Hertzian indentation technique is used to induce micro damages on the coated layer. The stress-strain behaviors are characterized by results of the indentation tests.

• 한국재료학회지
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• 제25권9호
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• pp.442-449
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• 2015

The effects of coating parameters were investigated in wear resistance coatings of Diamalloy-406 on Inconel 718 to obtain an optimum coating condition by high velocity oxy-fuel spraying. The coating parameters, the flow rates of source gases (hydrogen and oxygen), the powder feed rate, and the spray distance, were designed by the Taguchi method. The optimal conditions were determined: oxygen flow rate 34 FRM, hydrogen flow rate 57 FRM, powder feed rate 35 g/min, and spray distance 7 inch. Friction coefficients of the coating and the substrate decreased with an increasing sliding surface temperature from $25^{\circ}C$ to $450^{\circ}C$. The friction coefficient of Diamalloy-4006 coating decreased as the sliding surface temperature increased from $0.43{\pm}0.01$ at $25^{\circ}C$ to $0.29{\pm}0.01$ at $450^{\circ}C$. The wear trace and wear depth of the coating were smaller than the substrate at all temperatures tested. The relationship between spray parameters and wear resistance was discussed extensively, based on the measured roughness, hardness, and porosity in each coating.

• 한국표면공학회:학술대회논문집
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• 한국표면공학회 2011년도 춘계학술대회 및 Fine pattern PCB 표면 처리 기술 워크샵
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• pp.80-80
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• 2011

세계 기후 변화와 불안정한 유가 변화에 대응하고 국내산업의 저탄소 녹색성장을 위해 신재생에너지 개발이 활발하게 이루어지고 있다. 해양에너지 중에서 조류발전은 대규모 댐을 건설할 필요가 없어 비용이 적게 소요되고 특히 날씨 변화나 계절에 관계가 없고, 발전량이 예측 가능하므로 신뢰성 있는 에너지원으로 적용이 가능하다. 조류발전기 블레이드에 폴리머계 복합재료와 스테인리스강이 대부분인데, 이 재료는 특정 회사에서만 제작 가능하며, 충격에 약하고, 균열전파 속도가 빠르며, 대단히 고가이며, 수입에 의존하고 있는 실정이다. 이러한 조류발전에 사용되는 블레이드는 가혹한 부식, 캐비테이션 그리고 침식환경에 노출되어 있어 내구성이 우수한 제품개발이 대단히 중요하며, 조류발전 블레이드를 동합금으로 제작시, 내식성이 뛰어나며 구리의 특성상 해양생물 서식을 방지할 수 있고, 내캐비테이션 특성, 내구성, 가공성 및 유지보수가 용이한 장점이 있다. 이러한 동합금에 WC-27NiCr와 WC-10Co4Cr를 초고속 화염용사(HVOF)를 이용하여 코팅층의 캐비테이션 특성 및 전기화학적 거동을 연구하였다. 본 연구에서는 조류발전용 블레이드의 재료로 사용하려는 동합금에 WC-27NiCr와 WC-10Co4Cr이 용사코팅된 시험편을 사용하였다. 다채널 부식시험기인 WonA-tech WMPG-1000을 이용하여, 자연전위를 측정하였으며, 분극실험은 자체 제작한 홀더를 사용하여 $0.3318cm^2$를 노출 시켜 실험하였다. 기준전극은 은/염화은 전극을, 대극은 백금 전극을 사용하였다. 양분극과 음분극 실험을 통해 개로전위에서의 부식거동을 확인하였고, 정전위 실험도 실시하였다. 실험 종료 후 3D현미경 및 전자주사현미경(SEM)을 사용하여 코팅층 표면의 손상거동을 관찰하였다. 캐비테이션 실험은 ASTM-G32 규정에 의거하여 압전효과를 용한 진동발생 장치(RB 111-CE)를 사용하였다. 수조는 전기화학적 부식의 영향을 고려하여 아크릴로 제작하였고, 시험편은 실험장비에 맞게 파인커팅머신을 이용하여 $20mm{\times}20mm$로 절단하여 사용하였으며 혼과 대향하도록 하여 1mm 간격을 두어 실험하였다. 실험 실시 전, 미소전자저울을 사용하여 무게감소량을 측정하였으며 표면관찰을 통하여 캐비테이션 거동을 관찰하였다.

• 한국표면공학회:학술대회논문집
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• 한국표면공학회 2008년도 추계학술대회 초록집
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• pp.11-12
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• 2008

Micron-sized Co-alloy T800 powder was coated on Inconel718 (IN718) using high velocity oxygen fuel (HVOF) thermal spraying by the optimal coating process (OCP) determined from the best surface hardness of 16 coatings prepared by Taguchi program. The surface hardness improved 140-160 % from 399 Hv of IN718 to 560-630 Hv by the coating. Porosity of the coating was 1.0-2.7 %, strongly depending on spray parameters. Both friction coefficients (FC) and wear traces (WT) of the coating were smaller than those of IN718 substrate at both $25^{\circ}C$ and $538^{\circ}C$. FC and WT of IN718 and coating decreased with increasing the surface temperature. Tensile bond strength (TBS) and fracture location (FL) of Ti64/T800 were 8,770 psi and near middle of T800 coating respectively. TBS and FL of Ti64/NiCr/T800 were 8,740 psi and near middle of T800 coating respectively. This showed that cohesion of T800 coating was 8,740-8,770 psi, and adhesion of T800 on Ti64 and NiCr was stronger than the cohesion of T800.

• 한국분말재료학회지
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• 제29권3호
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• pp.240-246
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• 2022

Novel Ni- and Fe-based alloys are developed to impart improved mechanical properties and corrosion resistance. The designed alloys are manufactured as a powder and deposited on a steel substrate using a high-velocity oxygen-fuel process. The coating layer demonstrates good corrosion resistance, and the thus-formed passive film is beneficial because of the Cr contained in the alloy system. Furthermore, during low-temperature heat treatment, factors that deteriorate the properties and which may arise during high-temperature heat treatment, are avoided. For the heattreated coating layers, the hardness increases by up to 32% and the corrosion resistance improves. The influence of the heat treatment is investigated through various methods and is considered to enhance the mechanical properties and corrosion resistance of the coating layer.