• Corrosion Science and Technology
• /
• v.4 no.6
• /
• pp.236-241
• /
• 2005

Hydrogen induced cracking (HIC) is one of the hydrogen degradation phenomena of linepipe steels caused by $H_2S$ gas in the crude oil or natural gas. However, NACE TM0284-96 standard HIC test method is hard to satisfy the steel requirements for sour service application since it uses more severe environmental conditions than actual conditions. Therefore, in order to use steels effectively, it is required to evaluate HIC resistance of steels in the practical range of environmental severity. In this study, HIC resistance of two high strength low alloy (HSLA) steels being used as line pipe steels was evaluated in various test solutions with different $H_2S$ pressures and pH values. The results showed that the key parameter affecting crack area ratio (CAR) is $H_2S$ partial pressure of test solution when the pH value of test solution is not over 4. Hydrogen diffusivity was not a constant value, but it was rather affected by the hydrogen ion concentration (pH value) in the solution.

• Proceedings of the Korean Society for Technology of Plasticity Conference
• /
• 2006.05a
• /
• pp.172-175
• /
• 2006

Effects of deformation at austenite non-recrystallization region and cooling rate on the microstructure and mechanical properties of low carbon (0.06 wt. %) high strength low alloy steels have been investigated. Average grain size decreased and polygonal ferrite transformation promoted with increasing deformation amount due to increase of ferrite nucleation site. As cooling rate increased, the major microstructure changed from polygonal ferrite to acicular ferrite and the fraction of M/A constituents gradually increased. Discontinuous yielding occurred in highly deformed specimen due to the formation of polygonal ferrite. However, small grain size of highly deformed specimen caused lower ductile-to-brittle transition temperature than slightly deformed specimen.

• Korean Journal of Materials Research
• /
• v.13 no.10
• /
• pp.683-690
• /
• 2003

The high strength low alloy(HSLA) steels microalloyed with Nb, Ti and V have been widely used as the automobile parts to decrease weight of vehicles. The effects of process conditions are investigated in the aspects of the precipitation behavior and the mechanical properties of HSLA steel microalloyed with Nb and Ti using TEM, SANS and mechanical testing. When Ti was added to a 0.07C-1.7Mn steel which was coiled at $500^{\circ}C$, the specimen revealed the property of higher tensile strength of 853.1 MPa and the stretch-flangeability of 60%. The stretch-flangeability was increased up to 97.8% for coiling temperature above $700^{\circ}C$. The precipitation hardening cannot be achieved in the 0.045C-1.65Mn steel which was the lower density of fine precipitates. However, the 0.07C-1.7Mn steels containing Nb and/or Ti which was coiled at X$/^{\circ}C$ have a high precipitates density of $2${\times}$10^{ 5}$/$\mu$㎥. The high strength of these steels was attributed to the precipitation hardening caused by a large volume froction of (Ti, Nb)C precipitates with a size below 5 nm in ferrite matrix.

• Journal of the Korean Society for Heat Treatment
• /
• v.14 no.5
• /
• pp.267-274
• /
• 2001

Microalloyed steels, which substituted by conventional quenched and tempered steels, have been used in a wide variety of structural and engineering application. The main driving force for preference of MA steels is a cost reduction which can be achieved by an omission of heat treatment. In this study, low carbon martensitic MA steels in 0.18C-0.30(0.60)Si-2.00(1.80)Mn-0.05S-1.5Cr-0.05(0.10)V-0.015Ti(wt%) were investigated to know the effects of cooling method on the mechanical properties and microstructures of Si, Mn, V added microalloyed steel at different reheating temperature. Microstructure of oil quenched steels which were comprised lath martensite, auto-tempered martensite and retained austenite, had more various structure than that of air cooled steel made of mainly bainite. Therefore, oil quenched steels, which had more various microstructure, had better strength-toughness balance compare to air cooled steels. In the impact test, fracture mode of oil quenched steels, which showed good mechanical properties, were dimple, but that of air cooled steels were cleavage.

• 한국전자현미경학회:학술대회논문집
• /
• 1999.05a
• /
• pp.62-63
• /
• 1999

• Journal of Welding and Joining
• /
• v.13 no.2
• /
• pp.122-131
• /
• 1995

The effects of cooling rate on the microstructures, precipitation of Cu-cluster, .epsilon.-Cu and impact toughness of high strength low alloy(HSLA) steel were studied using hardness tester, impact tester, DSC(differential scanning calorimetry), AES(auger electron spectroscopy) and TEM(transmission electron microscopy). Not only the Cu-precipitates but also the segregation of Cu, As, Sb, P, S, N, Sn along grain boundary were not observed at the specimens heat treated from 800.deg. C to 300.deg. C with the cooling time of 12-125 sec. The Cu-cluster, .epsilon.-Cu are formed by introducing ageing after cooling and the effect of precipitates on hardening increase after cooling was the same in all cooling rate. The peak hardness was obtained at an ageing of 500.deg. C in all cooling conditions. The impact energy become higher as the cooling time increases. This fact can be explained to be due to the tempering effect applied on the cooling stage since the present alloy has a relatively high Ms temperature and the local high concentration of the retained austenite.

• Journal of Welding and Joining
• /
• v.8 no.2
• /
• pp.70-79
• /
• 1990

Stainless clad steels were made through hot rolling process. Backing plates employed in this study were HSLA steel and mild steel. The shear bond strength increased with an increase of the soaking temperature and time. It was also found that the shear bond strength increased with an increase of the reduction ratio. The threshold deformation was observed to be 20% and 10% respectively when the soaking conditions of 15 min. at 900.deg. C and 30 min. at 1000.deg. C were applied. Either the rolling or the transverse direction did not give any significant difference in the shear bond strength. Stainless steel-HSLA steel was superior to stainless steel-mild steel in the same range of magnitude. Because the above experimental results were in contrary to the existing mechanisms, the new model was proposed to describe the bonding mechanism and the void formation.

• Journal of Korea Foundry Society
• /
• v.30 no.4
• /
• pp.151-156
• /
• 2010

The high-strength low-alloy (HSLA) steels have low carbon contents (0.05~0.25% C) in order to produce adequate formability and weldability, and they have manganese contents up to 1.7%. Small quantities of silicon, chromium, nickel, copper, aluminum, molybdenum are used in various combinations. The results contained in this paper can provide the valuable information on the development of $-40^{\circ}C$ low temperature HSLA. Furthermore, the present experimental data will provide important database for casting steel materials of the offshore structure.

• Corrosion Science and Technology
• /
• v.9 no.2
• /
• pp.67-73
• /
• 2010

Niobium microalloying is effective in hot-rolled and cold-rolled steels by providing a fine-grained microstructure resulting in increased strength. To optimize the strengthening effect, alloy design and hot-rolling conditions have to be adapted. As a key issue the dissolution and precipitation characteristics of Nb are discussed in particular with regard to the run-out table conditions. It is then considered how the hot-rolled microstructure and the solute state of Nb interact with the hot-dip galvanizing cycle. The adjusted conditions allow controlling the morphology and distribution of phases in the cold-rolled annealed material. Additional precipitation hardening can be achieved as well. The derived options can be readily applied to produce conventional HSLA and IF high strength steels as well as to modern multiphase steels. It will be explained how important application properties such as strength, elongation, bendability, weldability and delayed cracking resistance can be influenced in a controlled and favorable way. Examples of practical relevance and experience are given.

• Journal of Powder Materials
• /
• v.28 no.4
• /
• pp.317-324
• /
• 2021

High-strength low-alloy (HSLA) steels show excellent toughness when trace amounts of transition elements are added. In steels, prior austenite grain size (PAGS), which is often determined by the number of added elements, is a critical factor in determining the mechanical properties of the material. In this study, we used two etching methods to measure and compare the PAGS of specimens with bainitic HSLA steels having different Nb contents These two methods were nital etching and picric acid etching. Both methods confirmed that the sample with high Nb content exhibited smaller PAGS than its low Nb counterpart because of Nb's ability to hinder austenite recrystallization at high temperatures. Although both etching approaches are beneficial to PAGS estimation, the picric acid etching method has the advantage of enabling observation of the interface containing Nb precipitate. By contrast, the nital etching method has the advantage of a very short etching time (5 s) in determining the PAGS, with the picric acid etching method being considerably longer (5 h).