• Membrane Journal
• /
• v.22 no.6
• /
• pp.435-440
• /
• 2012

In this study, nanoporous HKUST-1 membranes were synthesized by solvothermal method. It is very difficult to prepare uniform and crack-free HKUST-1 layer on macroporous alumina support by in-situ solvothermal method. In this study, continuous and crack-free HKUST-1 membranes could be obtained by spraying solvothermal precursor solution on the heated alumina support, followed by solvothermal synthesis. HKUST-1 membranes were characterized by XRD, FE-SEM and single gas permeation experiments.

• Korean Journal of Chemical Engineering
• /
• v.36 no.6
• /
• pp.975-980
• /
• 2019

Infrared (IR) spectroscopy is a powerful technique for observing organic molecules, as it combines sensitive vibrational excitations with a non-destructive probe. However, gaseous volatile compounds in the air are challenging to detect, as they are not easy to immobilize in a sensing device and give enough signal by themselves. In this study, we fabricated a thin nanocrystalline metal-organic framework (nMOF) film on a surface plasmon resonance (SPR) substrate to enhance the IR vibration signal of the gaseous volatile compounds captured within the nMOF pores. Specifically, we synthesized nanocrystalline HKUST-1 (nHKUST-1) particles of ca. 80 nm diameter and used a colloidal dispersion of these particles to fabricate nHKUST-1 films by a spin-coating process. After finding that benzene was readily adsorbed onto nHKUST-1, an nHKUST-1 film deposited on a plasmonic Au substrate was successfully applied to the IR detection of gaseous benzene in air using surface-enhanced IR spectroscopy.

• Asian Pacific Journal of Cancer Prevention
• /
• v.14 no.6
• /
• pp.3729-3734
• /
• 2013

The aim of this study was to evaluate expression of COX-1 in renal cell carcinoma (RCC) and its prognostic value. mRNA of COX-1 was detected in 42 paired RCC and adjacent normal tissues with quantitative realtime polymerase chain reaction (qRT-PCR). Expression of COX-1 was also evaluated in 196 RCC sections and 91 adjacent normal tissues with immunohistochemistry. Statistical analysis was performed to assess COX-1 expression in RCC and its prognostic significance. The results of qRT-PCR showed mRNA levels of COX-1 in RCC tissues to be significantly higher than that in adjacent normal tissues (p < 0.001). Immunohistochemical assays also revealed COX-1 to be overexpressed in RCC tissues (p < 0.001). Statistical analysis demonstrated high expression of COX-1 was correlated with tumour size (p = 0.002), pathological stage (p = 0.003), TNM stage (p = 0.003, 0.007, 0.027, respectively), and tumour recurrence (p < 0.001). Survival analysis indicated patients with high expression of COX-1 had shorter survival time (p < 0.001), and COX-1 was an independent predictor. This is the first study to reveal overexpression of COX-1 in RRC and point to use as a prognostic marker in affected patients.

• Wind and Structures
• /
• v.12 no.5
• /
• pp.413-424
• /
• 2009

A series of wind tunnel free-decay sectional model dynamic tests were conducted to examine the effects of torsional-to-vertical natural frequency ratio of 2DOF bridge dynamic systems on the aerodynamic and dynamic properties of bridge decks. The natural frequency ratios tested were around 2.2:1 and 1.2:1 respectively, with the fundamental vertical natural frequency of the system held constant for all the tests. Three 2.9 m long twin-deck bridge sectional models, with a zero, 16% (intermediate gap) and 35% (large gap) gap-to-width ratio, respectively, were tested to determine whether the effects of frequency ratio are dependent on bridge deck cross-section shapes. The results of wind tunnel tests suggest that for the model with a zero gap-width, a model to approximate a thin flat plate, the flutter derivatives, and consequently the aerodynamic forces, are relatively independent of the torsional-to-vertical frequency ratio for a relatively large range of reduced wind velocities, while for the models with an intermediate gap-width (around 16%) and a large gap-width (around 35%), some of the flutter derivatives, and therefore the aerodynamic forces, are evidently dependent on the frequency ratio for most of the tested reduced velocities. A comparison of the modal damping ratios also suggests that the torsional damping ratio is much more sensitive to the frequency ratio, especially for the two models with nonzero gap (16% and 35% gap-width). The test results clearly show that the effects of the frequency ratio on the flutter derivatives and the aerodynamic forces were dependent on the aerodynamic cross-section shape of the bridge deck.

• Korean Journal of Optics and Photonics
• /
• v.29 no.6
• /
• pp.268-274
• /
• 2018

In this study we suggest a humidity-sensitive color sensor using a one-dimensional photonic crystal and Hong Kong University of Science and Technology-1 (HKUST-1), which is a metal-organic framework (MOF) substance. One-dimensional photonic crystals have a photonic band gap, due to a periodic refractive-index change, and block and reflect light components in a specific wavelength band. The refractive index of HKUST-1 differs in dry and humid environments. Herein we designed a sensor using the presence of the photonic band gap, with FDTD simulation. As a result of optical analysis, the color conversion of the reflected light was superior to the color conversion of the transmitted light. When the center wavelength of the photonic band gap was 550 nm, the maximum peak value of the wet environment increased by a factor of about 9.5 compared to the dry environment, and the color conversion from achromatic to green was excellent as a sensor. The results of this study suggest the application of MOF materials to moisture sensors, and the nanostructure design of MOF materials will expand the applications to industrial devices.

• The Journal of Korean Institute of Communications and Information Sciences
• /
• v.30 no.2C
• /
• pp.1-9
• /
• 2005

Code is a set of words. If, for any pair of words in the code, one is not prefix of another, the code is called "Prefix(-Free) Code". The prefix coding problem is, given n, to find an optimal code with the minimum-sum of lengths of n words. As a special case of this, we present a method to find, given language L in some specific classes of regular languages, an optimal code among prefix codes in L. We also show how the structure of optimal codes varies as n grows, using trees.

• Membrane Journal
• /
• v.31 no.1
• /
• pp.35-51
• /
• 2021

Advancements in thin-film nanocomposite (TFN) membrane technology for nanofiltration is crucial for removing pollutants from natural resources. In recent years, various metal-organic framework (MOF) modifications have been tested to overcome the drawbacks that are inevitable with conventional thin-film composite (TFC) and TFN membranes. In general, MIL-101(Cr), UiO-66, ZIF-8, and HKUST-1 [Cu3(BCT2)] are MOFs that were proven to exhibit excellent membrane performance in terms of solvent permeability and solute rejection; their respective studies are reviewed in this article. Other novelties, such as the simultaneous use of different MOFs and unique MOF layering techniques (e.g., dip-coating, spray pre-disposition, Langmuir-Schaefer film, etc.) are also discussed as they present alternate solutions for membrane enhancement and/or preparation convenience. Not only are these MOF-modified TFN membranes frequently shown to improve separation performance from their respective TFC and TFN membranes, but many reports also explain their potential for a cost-effective and environmentally friendly process. In this review the thin film nanocomposite nanofiltration membrane is discussed.

• Proceedings of the KAIS Fall Conference
• /
• 2011.12a
• /
• pp.200-203
• /
• 2011

A copper-based metal organic framework (MOF) named Cu-BTC, also known as HKUST-1, was synthesized by using a solvothermal method at various synthesis temperature, time and pressure. The obtained samples were characterized with Powder X-ray diffraction (XRD) for phase structure, scanning electron microscopy (SEM) for crystal structure, and nitrogen adsorption-desorption for pore textural structure. The Cu-BTC sample was also studied for $CO_2$ adsorption. The analysis results displayed that the sample synthesized at the condition of temperature: $120^{\circ}C$, synthesis time: 12 hours, pressure: 1 bar exhibited a good crystal structure with uniform size of octahedral particles. The BET data revealed a high surface area of 1741.7 $m^2g^{-1}$ and a pore volume of 0.7137 $cm^3g^{-1}$and exhibiteda maximum $CO_2$ adsorption capacity of 170 mg/g of the sorbent at $25^{\circ}C$.

• Proceedings of the KAIS Fall Conference
• /
• 2011.05a
• /
• pp.147-150
• /
• 2011

A copper-based metal organic framework (MOF) named Cu-BTC, also known as HKUST-1, was successfully synthesized by using a solvothermal method. The properties of the Cu-BTC sample were characterized with Powder X-ray diffraction (XRD) for phase structure, Thermogravimetric analysis (TGA) for thermal stability, Scanning electron microscopy (SEM) for crystal structure, and Nitrogen adsorption-desorption for pore textural structure. The analysis results displayed that the Cu-BTC sample exhibited a good crystal structure with uniform size of octahedral particles. The BET data revealed a high surface area of $1457 \;m^2g^{-1}$ and a pore volume of $0.60\; cm^3g^{-1}$. The Cu-BTCs ample was also studied for $CO_2$ adsorption and exhibited a maximum $CO_2$ adsorption capacity of 170 mg/g of the sorbent (3.8 mol/kg) at $25^{\circ}C$.

• Ocean Science Journal
• /
• v.42 no.4
• /
• pp.199-209
• /
• 2007

Empirical band-ratio algorithms and artificial neural network techniques to retrieve sea surface chlorophyll concentrations were evaluated in the Bohai Sea of China by using an extensive field observation data set. Bohai Sea represents an example of optically complex case II waters with high concentrations of colored dissolved organic mattei (CDOM). The data set includes coincident measurements of radiometric quantities and chlorophyll a concentration (Chl), which were taken on 8 cruises between 2003 and 2005, The data covers a range of variability in Chl in surface waters from 0.3 to 6.5 mg $m^{-3}$. The comparison results showed that these empirical algorithms developed for case I and case II waters can not be applied directly to the Bohai Sea of china, because of significant biases. For example, the mean normalized bias (MNB) for OC4V4 product was 1.85 and the root mean square (RMS) error is 2.26.