• Bulletin of the Korean Chemical Society
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• v.14 no.6
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• pp.740-743
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• 1993

By considering both electron-electron and electron-lattice interactions, the effect of charge transfer on the bond structure and electronic states of $C_{60}$ is studied without configuration limitation. The results show that the electron-electron interaction does not eliminate the layer structure of the bond distortion and the self-trapping of transferred electrons. For charged ${C_{60}}^{2-}$, there exist two localized electronic states, which possess laminar wave functions, and four nonequivalent groups of carbon atoms, which induce a fine-structure in the NMR spectrum line.

• Bulletin of the Korean Chemical Society
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• v.15 no.9
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• pp.774-776
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• 1994

Ab initio studies of simple model systems for the carboxypeptidase A active site indicate that penta-and hexa-coordinate Zn(II) complexes have comparable structural stabilities. These facile coordination structures can be responsible for the catalytic role. Although the hexa-coordinate Zn(II) complex is more stable in enthalpy than the penta-coordinate Zn(II) complex, the entropy effect makes the latter as stable as or slightly more stable in free energy than the former.

• Bulletin of the Korean Chemical Society
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• v.15 no.5
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• pp.399-404
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• 1994

The non-Newtonian viscosities (the specific or intrinsic viscosities) of poly(L-proline) (PLP, $M_v$=19,000 and 32,000) in various mixed-solvent systems like water-propanol and acetic acid-propanol of varying compositions were measured during the reverse mutarotation (Form II ${\rightarrow}$Form I) by the application of external pressure (up to 4.5 psi). The non-Newtonian viscosity effect was found to be larger in acetic acid-propanol system than in water-propanol system and to somewhat decrease during the reverse mutarotation at a given solvent system. The non-Newtonian viscosity behavior of PLP in aqueous salt ($CaCl_2$) solution was also studied, from which it was found that the degree of the non-Newtonian effect decreased with increasing salt concentration, and increased with increasing PLP molecular weight. These findings could be explained in terms of conformational changes of PLP in solution (like the helix-helix or helix-coil transition) involved.

• Bulletin of the Korean Chemical Society
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• v.14 no.4
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• pp.457-461
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• 1993

Bioconcentration factors (BCF) in fish of organic nonelectrolytes are well correlated by a linear solvation energy relationship (LSER) of the form : log BCF= -0.95 + 4.74 $V_I/100 - 4.39{\beta} + 0.88{\alpha}$ where $V_I$ is the intrinsic solute molecular volume and ${\beta}$ and ${\alpha}$ are the solvatochromic parameters that measure hydrogen bond acceptor basicity and donor acidity of the compound. The LSER model can not only correlate the property with an accuracy comparable to molecular connectivity model but also provide a quantitative informationon on the nature and relative strength of solute-target system interactions affecting the property of interest. Such an information can hardly be obtained from molecular connectivity model.

• Bulletin of the Korean Chemical Society
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• v.12 no.6
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• pp.618-625
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• 1991

A general expression adopting a nonmultipole expansion method is derived for pseudocontact contribution to the NMR chemical shift arising from the electron orbital angular momentum and electron spin dipolar-nuclear spin angular momentum interaction of $3d^9$ system in a strong crystal field of tetragonally distorted tetrahedral symmetry. From this expression all the multipolar term are determined and the exact solution of ${\Delta}$B/B(ppm) is compared with the multipolar term. The $1/R^5$ term in the multipolar terms contributes dominantly to the NMR chemical shift but the other terms are certainly significant except that of the <111> axis. In addition, an analysis of the temperature dependence of the NMR chemical shift further illustrates that considerable care must be taken in interpeting NMR results in paramagnetic system.

• International Journal of Naval Architecture and Ocean Engineering
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• v.1 no.1
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• pp.50-56
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• 2009

The hydrodynamic effect of appendages for high-speed passenger vessels, such as Ro-Pax, Ro-Ro and cruiser vessels, is very severe and, therefore, it is essential to carry out the design of appendages for high-speed passenger vessels from the preliminary design stage to the final detail design stage through a full survey of the reference vessels together with sufficient technical investigation. Otherwise, many problems would be caused by mismatches between the appendages and the hull form. This paper investigates the design characteristics of some appendages, such as the side thruster, the shaft-strut, and the stern wedge, based on the design experience accumulated at Samsung, on CFD, and on model test results for high-speed passenger vessels. Further to this investigation, some practical and valuable design guidelines for such appendages are suggested.

• The Transactions of the Korean Institute of Power Electronics
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• v.26 no.5
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• pp.349-356
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• 2021

Permanent magnet synchronous motors are mainly used in the traction of electric vehicle and home application products including air-conditioners and refrigerators. For sensorless control without rotor position sensors, I-F control is applied for initial starting at low speeds, and mode is changed to sensorless control when the rotor speed is sufficiently accelerated for estimating rotor position. When the mode is changed to the sensorless control from the open-loop starting, the initial integral value of the speed controller should be considered by load condition; otherwise, the transition to sensorless control may fail. The sensorless transfer algorithm of PM synchronous motor based on load condition for smooth transition is proposed. The performance of the proposed sensorless transfer algorithm was verified by experiments.

• Journal of Environmental Science International
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• v.28 no.8
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• pp.709-712
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• 2019

The effect of insect feed powder on the growth performance and economic evaluation of ducks was investigated. One hundred and twenty-old Pekin ducks were randomly assigned to two dietary treatments (0% and 1% Hermetia illucens powder) with three replicates of 20 birds each for 14-42 d. No significant (p>0.05) difference in growth performance between the control and 1% H. illucens powder was observed, except the feed conversion ratio (p<0.05), for the experimental period. The treatments with 1% H. illucens powder improved the economic indicators in comparison with the controls. Therefore, a diet supplemented with 1% H. illucens powder could significantly improve the feed conversion ratios and increase the economic indicators.

• Journal of Environmental Science International
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• v.28 no.1
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• pp.159-162
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• 2019

This study aimed to evaluate the effects of dietary microbial-fermented molasses on egg production and egg quality in laying hens.In total, 90 Hy-line Brown laying hens were divided into two treatment groups (control and 1% microbial-fermented molasses)with three replicates of 15 birds each. During the experimental period, supplementation of hen diets with 1% microbial-fermented molassesdid not influence egg weight, hen-day egg production, egg mass, and feed conversion ratio (p > 0.05), except for feed intake. Regarding egg quality, diets containing 1% microbial-fermented molasses significantly affected eggshell thickness, Haugh unit, and albumen height (p < 0.05). However, there were no remarkable differences between control and 1% microbial-fermented molasses in eggshell color and egg yolk color (p > 0.05). These results indicate that supplementing 1% microbial-fermented molasses to the diet of laying hens improved egg quality parameters such as eggshell thickness, Haugh unit, and albumen height rather than egg production.

• Journal of Chest Surgery
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• v.51 no.6
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• pp.423-426
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• 2018

This study determined the feasibility of the cuff technique for small-caliber vascular grafts in a rat model. A graft was implanted with the cuff technique or suture technique in a 1-cm segment of the abdominal aorta in 12 rats. The mean aortic clamp time was 29 minutes with the cuff technique and 44 minutes with the suture technique; the cuff technique was significantly shorter. Abdominal angiography at 1 week after implantation showed no significant stenosis in 9 rats, focal stenosis of the mid-portion of the graft in 1 rat with each technique, and total occlusion of the graft in 1 rat with the suture technique. We have successfully used the cuff technique for anastomosis for small-caliber vascular grafts in an animal model.