• Title/Summary/Keyword: HAAs

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Ecotoxicological effects of ballast water effluent teated by an electrolytic method on marine environment

  • Kim, Tae Won;Kim, Keun-Yong;Shon, Myung-Baek;Kim, Young-Soo;Lee, Ji Hyun;Moon, Chang Ho;Son, Min Ho
    • Journal of Advanced Marine Engineering and Technology
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    • v.38 no.8
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    • pp.1010-1020
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    • 2014
  • Ballast water effluent treated by an electrolytic method contains reactive chlorine species and disinfection by-products (DBPs). In this study, we conducted whole effluent toxicity (WET) testing and ecological risk assessment (ERA) to investigate its ecotoxicological effects on marine environment. WET testing was carried out for three marine pelagic organisms, i.e., diatom Skeletonema costatum, rotifer Brachionus plicatilis and fish Paralichthys olivaceus. The biological toxicity test revealed that S. costatum was the only organism that showed apparent toxicity to the effluent; it showed no observed effect concentration (NOEC), lowest observable effect concentration (LOEC) and effect concentration of 50% (EC50) values of 12.5%, 25.0% and 83.3%, respectively, at brackish water condition. In contrast, it showed insignificant toxicity at seawater condition. B. plicatilis and P. olivaceus also showed no toxicities to the effluent at the both salinity conditions. Meanwhile, chemical analysis revealed that the ballast water effluent contained total residual oxidants (TROs) below $0.03{\mu}g/L$ and a total of 20 DBPs including bromate, volatile halogenated organic compounds (VOCs), halogenated acetonitriles (HANs), halogenated acetic acids (HAAs) and chloropicrin. Based on ERA, the 20 DBPs were not considered to have persistency, bioaccumulation and toxicity (PBT) properties. Except monobromoacetic acid, the ratio of predicted environmental concentration (PEC) to predicted no effect concentration (PNEC) of the other 19 DBPs did not exceed 1. Thus, our results of WET testing and ERA indicated that the ballast water effluent treated by electrolysis and subsequently neutralization was considered to have no adverse impacts on marine environment.

An Experimental Study on the Adaption of Announcement Based Evacuation Guidance System using Haas Effect in Large Space (대규모 공간에서 선행음 효과를 이용한 음성피난유도 시스템의 적용연구)

  • Baek, Eun-Sun;Baek, Geon-Jong;Shin, Hoon;Song, Min-Jeong;Kook, Chan
    • Fire Science and Engineering
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    • v.25 no.5
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    • pp.100-107
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    • 2011
  • In this study, a simulated situation in which the visions of the evacuees were blocked by the smoke, which is one of the most dangerous factors that cause casualties in case of an emergency, was conducted for the evaluation of the performance of an evacuation guidance system. For this purpose, the behavior and time taken by the experiment subjects in simulated evacuation test were measured and analyzed. When the evacuation guidance sound signals were given by 4 speakers at the same time, most of the subject were disoriented and took generally longer in getting to the pre-designated evac point. And, using only one speaker instead of two showed a better result in terms of the evacuation behavior or and orientation. Also, when there were two or more speakers used for the broadcasting of the guidance message, it turned out that using Hass effect, and placing the speakers closer, could result in higher awareness of the guidance message and maintenance of the orientation, while it also made the subjects took short to get to the evac point.

Educational Activities for Rural and Urban Students to Prevent Skin Cancer in Rio Grande do Sul, Brazil

  • Velasques, Kelle;Michels, Luana Roberta;Colome, Leticia Marques;Haas, Sandra Elisa
    • Asian Pacific Journal of Cancer Prevention
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    • v.17 no.3
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    • pp.1201-1207
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    • 2016
  • Background: Excessive exposure to the sun during childhood is strongly associated with the development of skin cancer in the future. The only way to prevent the development of skin cancer is to protect against ultraviolet radiation, which can be achieved through strategic awareness during childhood and adolescence. Objective. The aim of this work was to evaluate the impact of educational activities for rural and urban students to promote the use of sunscreens and prevent skin cancer. Materials and Methods: This study was carried out with students (9-12 years) of rural (n=70) and urban (n=70) schools in Rio Grande do Sul state, Brazil. The educational interventions were lectures and games. The impact of this strategy was evaluated through the application of a questionnaire before and after the interventions. Results: Before the intervention, it was found around 50% of rural and urban students were not aware of the damage caused by sun exposure, often exposing themselves to UV radiation without use sunscreen ( ~ 25 %) and at the most critical times of the day/year. After the lectures we observed an improvement in the behavior of the students with regard to sun exposure and knowledge about skin cancer. Conclusions: The results of this study emphasize the importance of prevention strategies for skin cancer and promoting the use of sunscreens based educational strategies. The interventions were of great value in relation to disseminating knowledge on the subject.

상수를 염소소독시 생성되는 염소 소독부산물(DBPs)의 생성능에 관한 연구

  • Jeong, Yong;Shin, Dong-Cheon;Lim, Young-Uk;Kim, Jun-Seong;Park, Yeon-Sin
    • Proceedings of the Korea Society of Environmental Toocicology Conference
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    • 1996.12a
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    • pp.75-75
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    • 1996
  • 최근 가장 관심이 집중되고 있는 음용수중의 미량오염물질로는 인위적으로 첨가되는 소독제(disi octant)로 인한 소독부산물(disinfection by-products: DBPs)을 들 수 있다. 1970년대부터 염소소독시 수중의 유기오염물길과 반응하여 발암성물질 과 돌연변이 물질이 다수 함유되어 있는 클로로포름(chloform)을 포함한 트리할로메탄(Trih리omethane: THMs)의 생성이 발견되었으며 이로 인한 건강상의 영향이 지속적으로 보고되고 있다. 염소소독시 780가지 이상의 화합물이 염소와 휴믹산(humic acids)과의 반응에 의해 생성되며, 이중 대부분이 할로겐 화합물로 알려져 있다. 염소 소독부산물로는 인체발암력을 지니고 있는 트리할로메탄(THMs) 이외에도 할로아세틱산(Haloaceticacids: HAAs), 할로아세토나이트릴(Haloacetbnitriles: HANs)등이 주 생성물질인 것으로 알려져 있으나 우러나라의 원수특성에 따른 소독부산물의 생성능 (Formation potential)에 대한 연구가 미흡한 실정이다. 본 연구에서는 우리나라 주요 4대강(한강, 대청호, 영산강, 낙동강)의 원수를 실험실내에서 염소처리하여 생성되는 소독부산물의 생성농과 pH, 체류시간 등의 조건에 따라 생성능을 조사하였다. 각 화합물은 추출 및 농축과정을 거친 후 GC/MSD를 사용하여 물질을 확인한 후 할로겐화합물에 민감한 GC/ECD를 사용하여 시료를 분석하였다. pH와 시간, 원수중의 유기물 함량이 소독부산물의 생성에 많은 영향을 미치는 것으로 나타났다. THMs은 알칼리에서, HAAs의 경우는 약산성에서 접촉시간이 증가할수록 높은 생성능을 보였고, HANs의 경우는 급속히 생성했다가 시간이 경과함에 따라 소멸하며 약산성에서 높은 생성능을 보임을 알 수 있었다, 강별로는 낙동강에서 THMs파 HANs의 생성능이 비교적 높았고, 영산강에서는 HAAs의 생성능이 높았다. 각 원수의 특성에 따른 생성능을 파악함으로써 생성능 저감방안을 마련하며, 소독 부산물질의 인체노출평가에 따른 위해성평가를 통해 관리기준을 설정해야 할 것이다.

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Changes of $\alpha$-Amylase Activity of Barley during Germination by the Red Light Irradiation (맥아제조시(麥芽製趙時) 적색광조사(赤色光照射)에 의한 $\alpha$-Amylase 활성변화(活性變化))

  • Kim, Jin-Ku;Kim, Soon-Dong;Kim, Kwang-Soo
    • Korean Journal of Food Science and Technology
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    • v.17 no.4
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    • pp.237-239
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    • 1985
  • The effects of red light on the $\alpha$-amylase activity of barley during germination was studied. The $\alpha$-amylase activity was highest at 5th day on germination, showing rapid increase from the 3rd-day of germination. The highest activity of $\alpha$-amylase was shown among the groups treated by red light at 100 Lux luminous intensity for 3 hours a day. The $\alpha$-amylase activity of barley during germination under the red light increased to 44% compared with that of barley during germination under the dark. The protein content was not increased by red light.

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Thermal, Tribological, and Removal Rate Characteristics of Pad Conditioning in Copper CMP

  • Lee, Hyo-Sang;DeNardis, Darren;Philipossian, Ara;Seike, Yoshiyuki;Takaoka, Mineo;Miyachi, Keiji;Furukawa, Shoichi;Terada, Akio;Zhuang, Yun;Borucki, Len
    • Transactions on Electrical and Electronic Materials
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    • v.8 no.2
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    • pp.67-72
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    • 2007
  • High Pressure Micro Jet (HPMJ) pad conditioning system was investigated as an alternative to diamond disc conditioning in copper CMP. A series of comparative 50-wafer marathon runs were conducted at constant wafer pressure and sliding velocity using Rohm & Haas IC1000 and Asahi-Kasei EMD Corporation (UNIPAD) concentrically grooved pads under ex-situ diamond conditioning or HPMJ conditioning. SEM images indicated that fibrous surface was restored using UNIPAD pads under both diamond and HPMJ conditioning. With IC1000 pads, asperities on the surface were significantly collapsed. This was believed to be due to differences in pad wear rates for the two conditioning methods. COF and removal rate were stable from wafer to wafer using both diamond and HPMJ conditioning when UNIPAD pads were used. Also, HPMJ conditioning showed higher COF and removal rate when compared to diamond conditioning for UNIPAD. On the other hand, COF and removal rates for IC1000 pads decreased significantly under HPMJ conditioning. Regardless of pad conditioning method adopted and the type of pad used, linear correlation was observed between temperature and COF, and removal rate and COF.

An Analysis of Trainers' Perspectives within an Ecological Framework: Factors that Influence Mine Safety Training Processes

  • Haas, Emily J.;Hoebbel, Cassandra L.;Rost, Kristen A.
    • Safety and Health at Work
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    • v.5 no.3
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    • pp.118-124
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    • 2014
  • Background: Satisfactory completion of mine safety training is a prerequisite for being hired and for continued employment in the coal industry. Although training includes content to develop skills in a variety of mineworker competencies, research and recommendations continue to specify that specific limitations in the self-escape portion of training still exist and that mineworkers need to be better prepared to respond to emergencies that could occur in their mine. Ecological models are often used to inform the development of health promotion programs but have not been widely applied to occupational health and safety training programs. Methods: Nine mine safety trainers participated in in-depth semi-structured interviews. A theoretical analysis of the interviews was completed via an ecological lens. Each level of the social ecological model was used to examine factors that could be addressed both during and after mine safety training. Results: The analysis suggests that problems surrounding communication and collaboration, leadership development, and responsibility and accountability at different levels within the mining industry contribute to deficiencies in mineworkers' mastery and maintenance of skills. Conclusion: This study offers a new technique to identify limitations in safety training systems and processes. The analysis suggests that training should be developed and disseminated with consideration of various levels-individual, interpersonal, organizational, and community-to promote skills. If factors identified within and between levels are addressed, it may be easier to sustain mineworker competencies that are established during safety training.

Chemical Mechanical Planarization of Cu Hybrid Structure by Controlling Surfactant (계면활성제 함량 조절을 통한 구리 하이브리드 구조물의 화학 기계적 평탄화)

  • Jang, Soocheon;An, Joonho;Park, Jaehong;Jeong, Haedo
    • Korean Journal of Materials Research
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    • v.22 no.11
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    • pp.587-590
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    • 2012
  • Recently, the demand for the miniaturization of package substrates has been increasing. Technical innovation has occurred to move package substrate manufacturing steps into CMP applications. Electroplated copper filled trenches on the substrate need to be planarized for multi-level wires of less than $10{\mu}m$. This paper introduces a chemical mechanical planarization (CMP) process as a new package substrate manufacturing step. The purpose of this study is to investigate the effect of surfactant on the dishing and erosion of Cu patterns with the lines and spaces of around $10/10{\mu}m$ used for advanced package substrates. The use of a conventional Cu slurry without surfactant led to problems, including severe erosion of $0.58{\mu}m$ in Cu patterns smaller than $4/6{\mu}m$ and deep dishing of $4.2{\mu}m$ in Cu patterns larger than $14/16{\mu}m$. However, experimental results showed that the friction force during Cu CMP changed to lower value, and that dishing and erosion became smaller simultaneously as the surfactant concentration became higher. Finally, it was possible to realize more globally planarized Cu patterns with erosion ranges of $0.22{\mu}m$ to $0.35{\mu}m$ and dishing ranges of $0.37{\mu}m$ to $0.69{\mu}m$ by using 3 wt% concentration of surfactant.

Gate-Controlled Spin-Orbit Interaction Parameter in a GaSb Two-Dimensional Hole gas Structure

  • Park, Youn Ho;Koo, Hyun Cheol;Shin, Sang-Hoon;Song, Jin Dong;Kim, Hyung-Jun;Chang, Joonyeon;Han, Suk Hee;Choi, Heon-Jin
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.02a
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    • pp.382-383
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    • 2013
  • Gate-controlled spin-orbit interaction parameter is a key factor for developing spin-Field Effect Transistor (Spin-FET) in a quantum well structure because the strength of the spin-orbit interaction parameter decides the spin precession angle [1]. Many researches show the control of spin-orbit interaction parameter in n-type quantum channels, however, for the complementary logic device p-type quantum channel should be also necessary. We have calculated the spin-orbit interaction parameter and the effective mass using the Shubnikov-de Haas (SdH) oscillation measurement in a GaSb two-dimensional hole gas (2DHG) structure as shown in Fig 1. The inset illustrates the device geometry. The spin-orbit interaction parameter of $1.71{\times}10^{11}$ eVm and effective mass of 0.98 $m^0$ are obtained at T=1.8 K, respectively. Fig. 2 shows the gate dependence of the spin-orbit interaction parameter and the hole concentration at 1.8 K, which indicates the spin-orbit interaction parameter increases with the carrier concentration in p-type channel. On the order hand, opposite gate dependence was found in n-type channel [1,2]. Therefore, the combined device of p- and n-type channel spin transistor would be a good candidate for the complimentary logic device.

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Assessment of Disinfection By-Products in Drinking Water in Korea (음용수 중 소독부산물 발생현황에 관한 연구)

  • Shin, Dong-Chun;Chung, Yong;Choi, Yoon-Ho;kim, Jun-Sung;Park, Yeon-Sin;Kum, Hee-Jung;Jeon, Hee-Kyoung
    • Environmental Analysis Health and Toxicology
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    • v.16 no.1
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    • pp.1-8
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    • 2001
  • The main purpose of applying the chlorination process during water treatment is for disinfection. Research results, however, indicate that disinfection by-products including trihalomethanes, haloacetic acids, haloacetonitriles, haloketones, and chloropicrin can be produced by chlorination process. Some of these disinfection by-products are known to be potential human carcinogens. This three-year project is designed to establish a standard analysis procedure for disinfection by-products in drinking water and investigate the distribution and sources of specific disinfection by-products. The occurrence level of DBPs in drinking water was below 50$\mu\textrm{g}$/L in most cases. THMs in plant effluent accounted for 48% of all DBPs measured, whereas HAAs accounted for 24%, HANs 14%, haloketones 5%, chloral hydrate 7%, and chloropicrin 2%. Chloroform was found to be the major THMs compound (71%), followed by bromodichloromethane (21%), dibro-mochloromethane (7%), and bromoform (3%), The concentration of DBPs formed in distribution systems increased from those detected in plant effluent. Results would play an important role in exposure assessment as a part of the risk assessment process, and would give basic information for establishment of disinfection by-products reduction and management procedures.

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