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Functional Analysis of Electrode and Small Stack Operation in Solid Oxide Fuel Cell (고체산화물 연료전지의 전극과 스택운영의 기능적 분석)

  • Bae, Joong-Myeon;Kim, Ki-Hyun;Ji, Hyun-Jin;Kim, Jung-Hyun;Kang, In-Yong;Lim, Sung-Kwang;Yoo, Young-Sung
    • Journal of the Korean Ceramic Society
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    • v.43 no.12 s.295
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    • pp.812-822
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    • 2006
  • This study amis to investigate the functional analysis of anode and cathode materials in Anode supported Solid Oxide Fuel Cell. The concentration polarization of single cell was investigated with CFD (Computational Fluid Dynamics) method for the case of the different morphology by using four types of unit cell and discussed to reduce the concentration polarization. The concentration polarization at anode side effected the voltage loss in Anode supported Solid Oxide Fuel Cell and increased contact areas between fuel gas and anode side could reduce the concentration polarization. For intermediate temperature operation, Anode-supported single cells with thin electrolyte layer of YSZ (Yttria-Stabilized Zirconia) were fabricated and short stacks were built and evaluated. We also developed diesel and methane autothermal reforming (ATR) reactors in order to provide fuels to SOFC stacks. Influences of the $H_2O/C$ (steam to carbon ratio), $O_2/C$ (oxygen to carbon ratio) and GHSV (Gas Hourly Space Velocity) on performances of stacks have been investigated. Performance of the stack operated with a diesel reformer was lower than with using hydrogen as a fuel due to lower Nernst voltage and carbon formation at anode side. The stack operated with a natural gas reformer showed similar performances as with using hydrogen. Effects of various reformer parameters such as $H_2O/C$ and $O_2/C$ were carefully investigated. It is found that $O_2/C$ is a sensitive parameter to control stack performance.

Identification of the Volatile Components in Korean Ordinary Kochujang (한국재래식(韓國在來式) 고추장의 향기성분동정(香氣成分同定))

  • Ahn, Cheol-Woo;Kim, Jong-Kyu;Sung, Nack-Kie
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.16 no.3
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    • pp.27-34
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    • 1987
  • The present paper was attempted to obtain the basic date concerning a reasonable preparing method and optimum fermentation conditions of Kochujang (Red pepper paste). To establish the standard quality of Kochujang, the chemical compositions and the volatile components of Kochujang was discussed. The native Kochujang collected from 80 households contained 40.51% of moisture, 6.00% of salts, 3.25 % of crude fat, 10.30 % of crude ash, pH 4.79, 9.28ml of tillable acidity. 19.60% of reducing sugar, 179.51 mg/100g of amino nitrogen and 4.43% of total nitrogen. The volatiles of Kochujang were extracted by a steam-distillation under the reduced pressure and determined by gas chromatography-mass spectrometry (GC-MS). Total volatile components identified in the native Kochujang were 46 components, i. e., 30 components in neutral fraction, 8 components in phenolic fraction and 8 components in acidic fraction, respectively. But no components were detected basic fraction.

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The Study of KOGAS DME Process in Small and Medium Sized Gas Field Containing $CO_2$ ($CO_2$가 함유된 중소규모 가스전을 위한 KOGAS DME Process 연구)

  • Mo, Yong-Gi;Cho, Won-Jun;Song, Taek-Yong;Baek, Young-Soon
    • Journal of the Korean Institute of Gas
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    • v.14 no.4
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    • pp.51-55
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    • 2010
  • The global activities to reduce the $CO_2$ emission as a greenhouse gas have been various efforts. Under this circumstance, small and medium sized gas field containing $CO_2$ to develop as LNG is not economic feasibility. Particularly, for the separation of $CO_2$ in gas field, separation facilities should be installed to add. This is and increase in plant construction cost and separated $CO_2$ emission into the atmosphere is not the result of greenhouse gas reduction. When the uneconomic gas field apply the KOGAS DME process, the gas field containing $CO_2$ can be increase economic feasibility because of natural gas and $CO_2$ can be use to resource gas. The Tri-reformer produced syngas as H2 and CO in KOGAS DME process and the resource gases are natural gas, steam, oxygen and $CO_2$. The $CO_2$ is used as raw material gases from recover $CO_2$ in DME process. In this study, we investigated range of application of $CO_2$ in gas field.

Quality Stability of Products Containing Fermented Ginseng Berry Extracts (인삼열매 발효추출물을 함유한 제품의 품질안정성)

  • Kim, Seung Tae;Heo, Chang Hoe;Kim, Sung Hoon;Lee, Won Jong;Jang, Su Kil;Joo, Seong Soo
    • Journal of Food Hygiene and Safety
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    • v.34 no.5
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    • pp.473-479
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    • 2019
  • The purpose of this study was to investigate the storage stability of liquid stick packs containing concentrated and steam-dried ginseng berry. Storage stability of liquid stick packs was determined during storage at 10, 25 and $35^{\circ}C$ for 4 months. The pH was decreased from 4.81 to 3.81 after 4 months at $35^{\circ}C$ while the acidity and solubility were not changed during storage of 4 months. The DPPH radical scavenging activity was decreased during storage at $35^{\circ}C$ after 4 months. The Hunter L and yellowness (b) values decreased while the redness (a) was not changed during storage after 2 or 3 months. The total amount of six ginsenosides including Rg1, Rb1, F2, Rg3(S), Rg3(R), and Rg5 was not changed after storage of 4 months at 10 and $25^{\circ}C$. Neither bacteria nor coliforms were not detected during storage of 4 months. Considering quality parameters, significant changes were observed in color parameters L and b, while all others remained unchanged during 4 months stored at 10 and $25^{\circ}C$.

Effects of the Physicochemical Properties of Lignocellulosic Artificial Soil Containing Bacillus subtilis on the Growth of Lespedeza cyrtobotrya (Bacillus subtilis가 함유된 목질계 인공토양의 물리·화학적 특성이 참싸리 생육에 미치는 영향)

  • Kim, Ji-Su;Jung, Ji young;Ha, Si Young;Yang, Jae-Kyung
    • Journal of the Korean Wood Science and Technology
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    • v.47 no.4
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    • pp.393-407
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    • 2019
  • In this study, we prepared lignocellulosic artificial soil that contains Bacillus subtilis (peat moss/perlite/ steam-exploded oak wood/microbial culture = 3:1:3:3, w/w/w/w) for use in the restoration of damaged soil areas. The prepared lignocellulosic artificial soil was mixed with soil at ratios of 0%, 25%, 50%, 75%, and 100%. These mixed soils were then applied to fields, and the resultant physicochemical properties and their effects on the plant growth of Lespedeza cyrtobotrya were observed. The mixture of the prepared artificial soils (mixed at ratios of 25%-100%) with soil had a bulk densities of <$0.04g/cm^3$, porosities of >85%, pH values between 4.3 and 4.7, electrical conductivities of <0.5 dS/m, C/N ratios between 15.0 and 26.5, organic matter content between 23.6% and 43.2%, and bacterial densities between $157{\times}10^6$ and $624{\times}10^6CFU/g$. In addition, the prepared artificial soils mixed with soil at ratios of 25%-50% exhibited higher plant growth rates for L. cyrtobotrya compared with the control. Overall, we identified positive correlations between the plant growth of L. cyrtobotrya and soil bulk density, porosity, water-holding capacity, C/N ratio, organic matter, and bacterial densities.

Oxygen and Hydrogen Isotope Studies of the Hydrothermal Clay Deposits and Surrounded Rocks in the Haenam Area, Southwestern Part of the Korean Peninsula (한국 서남부, 해남지역의 열수 점토광상과 주변암에 대한 산소 및 수소동위원소 연구)

  • Kim, In Joon;Kusakabe, Minoru
    • Economic and Environmental Geology
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    • v.26 no.1
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    • pp.11-20
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    • 1993
  • In the present study, three representative hydrothermal clay deposits, named the Seongsan, Ogmaesan and Haenam deposits, were selected for oxygen and hydrogen isotope studies. Oxygen and hydrogen isotopic compositions of quartz, sericite, alunite and kaolin minerals from Seongsan, Ogmaesan, Haenam deposits and surrounded rocks of clay deposits have been measured. The ${\delta}^{18}O$ values of quartz, kaolin, sericite and alunite in the Seongsan mine are +8.4 to +11.1‰, +3.6 to 5.4‰, +4.8 to +5.8‰ and + 3.0 to +6.6‰, respectively. In the Ogmaesan mine, the ${\delta}^{18}O$ values of quartz, kaolin, sericite and alunite are +8.0 to +13.6‰, +2.8 to +6.7‰, +4.8 to +8.4‰ and +0.9 to +2.4‰, respectively. The ${\delta}^{18}O$ values of the Haenam mine range from +7.9 to +10.1‰ for quartz and from +4.5 to +6.5‰ for sericite. The ${\delta}^{18}O$ values of the whole-rocks range from + 3.0 to + 7.8‰ for the granitic rocks. The ${\delta}^{18}O$ values of the whole-rocks range from + 3.2 to + 10.7‰ for the volcanic rocks. The 8D values of kaolin, sericite and alunite in the Seongsan mine are -78 to -86‰, -71 to -90‰ and -43 to -77‰, respectively. In the Ogmaesan mine, the ${\delta}D$ values of kaolin, sericite and alunite are -73 to -80‰, -74 to -88‰ and -57 to -98‰, respectively. The ${\delta}D$ values of the Haenam mine range from -76 to -85‰ for sericite. The ${\delta}D$ values of the whole-rocks range from -77 to -105‰ for the granitic rocks. The ${\delta}D$ values of the wholerocks range from -76 to -100‰ for the volcanic rocks. The main result obtained oxygen and hydrogen isotope data can lead to the following interpretations on the origin of hydrothermal fluids in the clay deposits: Through the oxygen isotopic study, the formation temperature of the clay deposits was estimated from the coexisting minerals such as quartz-kaolin minerals and -sericite. Formation temperature of the acidic alteration zone is 165 to $280^{\circ}C$ in the Seongsan deposits, 175 to $250^{\circ}C$ in the Ogmaesan deposits and 250 to $350^{\circ}C$ in the Haenam deposits. Three clay deposits has been formed by magmatic water mixed with meteoric water. Furthermore, from this isotopic data, it is clarified that kaolin minerals and alunite are hypogene in origin, and has been formed by oxidation of hydrogen sulfide in the steam-heated environment, and that alunite has been produced in the spectacular solfataric alteration observed at the surface of some present-day hydrothermal systems. Oxidation of the $H_2S$ is thought to be generated when the vapor phase generated by boiling of the deep-seated water under the water table.

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Comparison of γ-aminobutyric acid and isoflavone aglycone contents, to radical scavenging activities of high-protein soybean sprouting by lactic acid fermentation with Lactobacillus brevis (발아 고단백 콩의 Lactobacillus brevis 젖산발효에 의한 가바와 이소플라본 함량 및 라디칼 소거활성의 비교)

  • Hwang, Chung Eun;Haque, Md. Azizul;Lee, Jin Hwan;Joo, Ok Soo;Kim, Su Cheol;Lee, Hee Yul;Um, Bong Sik;Park, Kyung Sook;Cho, Kye Man
    • Food Science and Preservation
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    • v.25 no.1
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    • pp.7-18
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    • 2018
  • In this study, soy-powder yogurt (SPY) with enhanced levels of ${\gamma}$-aminobutyric acid (GABA) and isoflavone aglycone was produced from sprouting high-protein soybeans (HPSs). The fermented steam-HPS sprouts (0 to 4 cm) were fermented (72 h) with Lactobacillus brevis, and the total free amino acids (FAAs) of the formed mixtures were determined to be 79.53, 489.93, 877.55, 780.53, and 979.97 mg/100 mL in the fermented HPS (FHPS), and the fermented steam-HPS with 0 cm (FSHPS-0), 1 cm (FSHPS-1), 2 cm (FSHPS-2), and 4 cm sprouting lengths (FSHPS-4), respectively. The levels of glutamic acid (GA) and GABA were observed to be the highest, 100.31 and 101.60 mg/100 mL, respectively, in the unfermented HPS (UFSHPS-1, 1 cm) and FSHPS-1 sprouts, respectively. Moreover, the total contents of the isoflavone glycoside form decreased proportionally to the increasing total levels of isoflavone aglycones after fermentation in FSHPS-0, FSHPS-1, FSHPS-2, and FSHPS-4. The levels of isoflavone aglycones were detected as 350.34, 289.15, 361.61, 445.05, and $491.25{\mu}g/g$ in FHPS, FSHPS-0, FSHPS-1, FSHPS-2, and FSHPS-4, respectively. While FSHPS-1 exhibited the highest DPPH (63.28%) and ABTS (73.28%) radical scavenging activities, FSHPS-4 contained the highest isoflavone aglycone ratio (81.63%). All in all, the FSHPS-1 mixture prepared in this study exhibited high GABA content and functional prosperity, thereby making it suitable for potential applications in the soy-dairy industry.

Promotion effects of steam-dried Betula platyphylla extract on hair regrowth (자작나무 증포 추출물의 발모 촉진 효과)

  • Ahn, Jeong Won;Jang, Su Kil;Jo, Bo Ram;Kim, Hyun Soo;Jeoung, Eui Young;Hillary, Kithenya;Yoo, Yeong Min;Joo, Seong Soo
    • Korean Journal of Food Science and Technology
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    • v.54 no.1
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    • pp.43-51
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    • 2022
  • Regulation of the hair follicle cycle in association with dermal papilla cells is one of the most interesting targets for promoting hair regrowth. In this study, we examined whether steam-dried Betula platyphylla extracts (BPE) promote hair growth by upregulating in vitro and in vivo responses of dermal papilla cells. The data showed that BPE3 contained high amounts of phenolic compounds with higher antioxidant effects and increased hair growth-related genes, including fibroblast growth factor7 and Wnt7b, in dermal papilla cells. Notably, BPE3 effectively enhanced the formation of hair follicles by increasing FGF7, Wnt7b, and vascular endothelial growth factor in C57BL/6N dorsal skins. Additionally, BPE3 significantly decreased the expression of inflammatory repertoires, inducible nitric oxide synthase, interleukin-6, and cyclooxygenase 2. Several small molecules, such as betulin and unsaturated fatty acids, support the pharmacological activity of BPE3. In conclusion, BPE3 effectively promoted hair growth by activating dermal papilla cells and enhancing hair follicle cycles by attenuating the inflammatory environment in the scalp.

Comprehensive comparison of the primary and secondary metabolites and antioxidant activity of Polygoni multiflori Radix by processing methods (가공 방법에 따른 하수오의 영양성분 및 항산화 활성의 종합적인 비교)

  • Hee Yul Lee;Chung Eun Hwang;Kyung Pan Hwa;Du Yong Cho;Jea Gack Jung;Min Ju Kim;Jong Bin Jeong;Mu Yeun Jang;Kye Man Cho
    • Journal of Applied Biological Chemistry
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    • v.65 no.4
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    • pp.287-298
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    • 2022
  • This study investigated the changes in the physiochemical property, phytochemical content, nutritional content and antioxidant activity of Polygoni multiflori Radix by steam, aging, and fermentation. After processing Polygoni multiflori Radix (PMR), pH slightly decreased, while acidity increased (pH 5.70→4.78, acidity 0.23→0.29%). The reducing sugar content increased after aging and fermentation from 1.19 mg/g (PMR) to 1.40 (fermented PMR, FPMR), 1.30 (red PMR, RPMR), 1.53 (fermented red PMR, FRPMR), 1.99 (black PMR, BPMR), and 2.33 mg/g (fermented black PMR, FBPMR). Total phenolic content was highest in PMR (6.05 mg/g) and total flavonoids and maillard product were increased after aging and fermentation of PMR, and were the highest in BPMR (1.60 mg/g) and FBPMR (2.76 O.D.), respectively. The major phytochemical was 2,3,5,4'-tetrahydroxystilbene-2-0-α-glucoside, which were highest in PMR (64.9 mg/g) with 46.47 mg/g at FPMR, 33.94 mg/g at RPMR, 48.76 mg/g at FRPMR, 36.68 mg/g at BPMR and 34.35 mg/g at FBPMR. The main fatty acids and free amino acids were detected as palmitic acid (C16:0) and proline, respectively. Generally, 2,2-diphenyl-1-picrylhydrazyl and 2,2'-azino-bis (3-ethylbenzothiazoline-6-sulfonic acid) diammonium salt radical scavenging activities and FRAP reducing powers were shown high in PMR (39.06%, 98.32%, and 2.61 O.D. in extracts concentration 1.0 mg/mL), then were decreased after aging and fermentation.

A Study on thinner's Physicochemical property and its effect on genital organ of rat (시너(thinner)의 물리화학적 특성과 랫트의 생식기에 미치는 영향 연구)

  • Kim, Hyeon-Yeong;Lee, Sung-Bae;Han, Jeong-Hee;Kim, Tae-Gyun;Lee, Jung-Suk;Kang, Min-Gu;Lee, Chae-Kwan
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.18 no.3
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    • pp.224-238
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    • 2008
  • The aim of this study is to confirm the physicochemical property and hazard of thinner (012), which is a diluent of enamel paint used for floor coating for waterproofing and oil painting for the outer wall. The literatures of physicochemical property and hazard of thinner were surveyed and its physicochemical property were evaluated. And then, the inhalation toxicity of thinner affecting the central nervous system and reproductive organs in rats were examined by subchronic (6 h./day. 5 days/ week for 13 weeks) inhalation test. 1) According to the 13-week subchronic inhalation test, there were no significant changes in clinical test and body weight. However, a significant evidence of toxicity was observed in the hematological test and organ weight such as heart, kidney, liver and brain (p<0.01) in the 200 ppm and 1,000 ppm exposure groups in a dose response manner. In the histopathology analysis, there were no significant evidence of toxicity. Therefore, thinner was not classified as an organ targeted toxic agent. In case of Harmfulness, it could be classified as a chronic toxic agent 3($500 ppm/4hr, rat). 2) The reproductive toxicity such as extension of the period of estrous cycle, reduction of serum estradiol concentration and increase of frequency of the abnormal sperm was observed in the 1,000 ppm exposed animals. 3) The result of the physicochemical property of the test material showed that the specific gravity was 0.793, boiling point $155.8^{\circ}C$, steam pressure 2.1 kPa, ignition point $34.5^{\circ}C$, and spontaneous ignition point $280^{\circ}C$. The endothermic and exothermic values were 371.4 J/g and 159.1 J/g. respectively. The explosion limit was 214 mg/l. These data showed that thinner could be classified as an explosion agent level 1.2 and ignitive liquid agent 3 ($23-60^{\circ}C$) according to the notification No. 2008-1 of the Labor Ministry, "Classifying Standard of Chemical Materials."