• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2019년도 춘계 학술논문 발표대회
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• pp.207-208
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• 2019

In this study, compressive strength was measured to evaluate the initial strength of cement mortar substituted with coal gasification slag containing desulfurized gypsum, and the reactivity of desulfurized gypsum was confirmed. In order to improve the reactivity, 2% gypsum mixed type and gypsum unfedged type specimens were fabricated and the influence of desulfurization gypsum on compressive strength of coal gasification slag and blast furnace slag fine powder replacement cement mortar was compared and confirmed. As a result of the experiment, it was confirmed that the initial compressive strength of the specimen containing the desulfurized gypsum was improved at the initial stage.

• 대한환경공학회지
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• 제28권4호
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• pp.438-446
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• 2006

팔당호 경안천 하류 정체수역에서 퇴적물 인 용출 저감을 위한 capping 소재를 개발하고자 실험실 규모의 batch test를 수행하였다. 조사지역 퇴적물 평균 입도는 7.7 ${\phi}$로 매우 세립하고, 유기탄소 함량은 2.4%로 매우 높게 나타났다. 최적의 capping 소재 선정을 위한 인 용출 실험을 위해 150 L 반응기 5개에 모래층, powder-gypsum($CaSO_4{\cdot}2H_2O$), granule-gypsum, 복합층(gypsum+sand)로 capping을 한 경우와 control을 45일간 비교 평가하였다. 모래로 capping할 경우, 퇴적물로부터 용출되는 인을 약 50% 차단 가능한 것으로 나타났다. 그러나 모래층 1 cm로는 $CH_4$ gas 발생으로 인한 퇴적물의 재부유와 유기물 분해에 의한 수층 용존산소 감소(3 mg/L 이하)를 초래하는 것으로 나타났다. 따라서 모래로 capping을 할 경우에는 모래층이 더 높아져야 할 것으로 판단된다. powder-Gypsum과 granule-Gypsum은 80% 이상의 인 용출 저감 효과를 보였으나 수층 ${SO_4}^{2-}$ 농도가 증가되어 상수원보호구역에 적용하기 어려운 것으로 나타났다. 따라서 ${SO_4}^{2-}$의 용해도를 감소시키기 위해 Fe-Gypsum, $SiO_2$-gypsum 소재를 개발하였다. powder-Gypsum은 물과 결합시 경화되어 퇴적물 층위에 공극이 전혀 없는 차단막을 만들기 때문에 gypsum 층에 crack이 생길 경우, $CH_4$ gas 발생으로 인한 인 용출이 한꺼번에 일어날 수 있다. 복합층(granule-Gypsum+sand(1 cm))으로 capping을 할 경우, 인 용출 차단 효과가 높을 뿐만 아니라, ${SO_4}^{2-}$ 농도 역시 powder-Gypsum, granule-Gypsum 보다 수층으로 용출이 적어 상수원보호구역에 적합한 것으로 나타났다. Gypsum으로 capping을 할 경우, 빠른 초기속성작용(early diagenesis)과 ${SO_4}^{2-}$ 농도가 퇴적물에 충분히 공급되어 SRB(sulfate reducing bacteria)의 활성이 높아져 methanogensis의 진행을 저하시킬 수 있는 것으로 나타났다.

• 펄프종이기술
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• 제45권3호
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• pp.20-26
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• 2013

We investigated practical methods of using recycled gypsum board paper in the paper industry. Gypsum board paper is used to produce construction gypsum board, and can be recycled through the recycling process of construction wastes. The experiments were carried out in two ways: One was the substitution of recycled gypsum board papers for KOCC, and the other was the use of recycled gypsum board paper powder. Recycled gypsum board paper was not disintegrated easily, but high temperature and the use of chemicals were able to improve their disintegration. The physical properties of handsheets made of the pulp of recycled gypsum board paper exhibited the same performance level as those made from KOCC except in the parameter of compressive strength. The powder of recycled gypsum board paper was manufactured using a grinder and handsheets were made with the powder and KOCC. The bulk was increased, but the strength properties were decreased by the addition of the powder.

• 한국건설순환자원학회논문집
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• 제5권4호
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• pp.106-113
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• 2010

본 연구에서는 고로슬래그 미분말 제조시 혼입되는 최적의 석고량을 도출하고, 분말도 및 제조환경에 관한 제반물성을 실험적으로 검토함으로서 고로슬래그 미분말의 품질향상 방안과 사용성 확대를 위한 기초자료로 활용하고자 하였다. 실험결과, 유동성은 석고첨가량이 높을수록 저하하는 경향이었고 천연석고와 석회 소성슬러지의 경우에는 첨가량 2.6%이상에서 KS 기준을 만족하지 못하였다. 압축강도는 인산석고, 탈황석고, 불산석고의 화학석고가 초기 강도가 높게 형성되었고 석회 소성슬러지와 석회석 미분말은 강도발현에 큰 영향이 없는 것으로 분석되었다. 분말도가 높아지면 유동성이 감소하고 압축강도는 증가하기 때문에 석고첨가량을 2.0%이하로 관리하는 것이 경제적일 것으로 판단된다. 저온에서는 불산석고, 고온에서는 탈황석고가 유동성 확보에 유리한 것으로 나타났고 동절기인 $10^{\circ}C$에서는 2.6%, 서중기인 $30^{\circ}C$에서는 2.0%이하로 사용하는 것을 적정 사용량으로 결정하였다.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2019년도 춘계 학술논문 발표대회
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• pp.17-18
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• 2019

In this study, the initial strength reduction of coal gasification slag fine powders was confirmed through previous studies when used in cement formulations. It is also confirmed that the blast furnace slag is mixed with cementitious coal blast furnace slag, which is similar to coal gasification slag, to incorporate gypsum in order to prevent initial strength deterioration. In order to analyze the reactivity of coal gasification slag by desulfurization gypsum, the formation of hydrates and their reactivity at early ages were confirmed by electron microscope. In order to confirm the reactivity, the gypsum samples were prepared with unincorporated type and 2% mixed type. Experimental results showed that 2% of the desulfurized gypsum specimens reacted more actively than the uninjured ones.

• 대한전자공학회:학술대회논문집
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• 대한전자공학회 2001년도 The 6th International Symposium of East Asian Resources Recycling Technology
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• pp.432-436
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• 2001

In this study, calcium sulfate(gypsum) powder was obtained using waste sulfuric acid and stainless refinery sludge by- produced from chemical reagent and the iron industry, by the neutralization of waste sulfuric acid. As variables for the experiment the mole ratio of the H$_2$SO$_4$ : Ca(OH)$_2$, the pH, the reaction temperature and time, the amount of catalyst were used. The crystal shape and microstructure of obtained powder were observed by XRD and SEM, and the thermal property was investigated by DTA. As the NaCl is added 0~20wt% as a catalyst to the H$_2$SO$_4$ : Ca(OH)$_2$, system it can be found that the crystal shape goes through the processes as follows : gypsum dihydratlongrightarrowgypsum hemihydrate＋gypsum dihydratelongrightarrowgypsum hemihydrate. And gypsum hemihydrate is $\beta$-type as the result of DTA. As waste sulfuric acid and stainless refinery sludge were used, the pH of reacted solution (which was 0.8) was rapidly raised up to 8~9 by the addition of stainless sludge and gypsum dihydrate was produced as a by-product. Therefore, it was found that stainless refinery sludge is sufficiently applicable for the neutralization of waste sulfuric acid.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2009년도 춘계 학술논문 발표대회 학계
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• pp.77-80
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• 2009

The purpose of the study was to examine engineering characteristics due to fine particle cement and gypsum contents to improve early strength of concrete substituted blast furnace slag powder. The results were as follows. Above all, For fluidity, generally all mixtures had lower fluidity than Plain mixture and was not satisfied target scope, but for mixture substituted the gypsum showed a little increasing trend. For air content, generally all mixtures compared to Plain mixture had decreasing tendency. However, all mixtures were satisfied target scope. For compressive strength, long-term strength was better than early strength according to ternary blast furnace slag contents was increased. For complex mixture was better than individual use of gypsum and fine particle cement.

• Environmental Engineering Research
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• 제21권4호
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• pp.341-349
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• 2016

To improve the utilization rate of construction waste as mine backfilling materials, this paper investigated the feasibility of using recycled powder as mine paste backfilling cementitious material, and studied the pozzolanic activity of recycled construction waste powder. In this study, alkali-calcium-sulfur served as the activation principle and an orthogonal test plan was performed to analyze the impact of the early strength agent, quick lime, and gypsum on the pozzolanic activity of the recycled powder. Our results indicated that in descending order, early strength agent > quick lime > gypsum affected the strength of the backfilling paste with recycled powder as a cementitious material during early phases. The strength during late phases was affected by, in descending order, quick lime > gypsum > early strength agent. Using setting time and early compressive strength as an analysis index as well as an extreme difference analysis, it was found that the optimal ratio of recycled powder cementitious material for mine paste backfilling was recycled powder:quick lime:gypsum:early strength agent at 78%:10%:8%:4%. X-ray diffraction analysis and scanning electron microscope were used to show that the hydration products of recycled powder cementitious material at the initial stages were mainly CH and ettringite. As hydration time increased, more and more recycled powder was activated. It mainly became calcium silicate hydrate, calcium aluminate hydrate, etc. In summary, recycled powder exhibited potential pozzolanic activities. When activated, it could replace cementitious materials to be used in mine backfill.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2000년도 가을 학술발표회논문집(I)
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• pp.559-562
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• 2000

This study is about the compensation of early age strength on mortar and concrete admixed with blast-furnace slag powder. For study, we have used fine powder of gypsum and kiln dust from cement factory. According to the test results, we have obtained proper mixing ratio of slag powder, gypsum and kiln dust for the compensation of early age strength on mortar and concrete property.

• 한국건설순환자원학회논문집
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• 제7권4호
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• pp.128-135
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• 2012

ALC는 경량이며 단열 및 차열 등의 성능이 우수한 반면 낮은 강도로 인한 모서리부의 취성파괴가 발생하기 쉬우므로 운반 및 취급 시 상당한 주의를 요구한다. 본 연구에서는 ALC의 물리적 성능개선을 위해 메타카올린 및 실리카퓸 등의 혼화재나 규석 분말 및 석고의 혼입율을 조절하여 제조한 ALC의 성능을 평가하였다. 연구결과 메타카올린이나 규석 분말의 혼입율이 18%인 경우 강도의 개선이 현저하였다. 이와 같은 결과는 공극의 충전효과에 의한 것으로 강도는 개선되나 밀도가 증가하므로 밀도를 낮추면서 강도를 개선할 수 있는 배합이나 제조법에 대한 연구가 필요하다.