• Korean Journal of Environmental Agriculture
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• v.22 no.3
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• pp.192-196
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• 2003

Objective of this study was to investigate the influences of harvest index and percolation water quality as irrigated the discharge waters from an industrial and a municipal wastewater treatment plants and seawater (1:5 seawater: tap water) as alternative water resources during tillering stage for drought stress. There were four different treatments such as the discharge water from an industrial (textile dyeing manufacture plant) wastewater treatment plant (DIWT), discharge water from the municipal wastewater treatment plant (DMWT), seawater (1:5) and groundwater as a control. For the initial chemical compositions of alternative waters, it appeared that higher concentrations of COD, $Mn^{2+}$, and $Ni^+$ in DIWT were observed than reused criteria of other country for irrigation, and concentrations of $EC_i$, Cl, and $SO_4$ in seawater were higher than that for irrigation. Harvest index was not significantly different between DIWT and DMWT with different irrigation periods in two soil types, but that of seawater (1:5) is decreased with irrigation periods in clay loam soil and not different between 10 days and 20 days of irrigation periods in sandy loam soil. For percolation water qualities, values of sodium adsorption ratio (SAR) are increased with prolonging the irrigation periods of seawater (1:5) and DIWT, but those of DMWT were almost constant through the cultivation periods regardless of the irrigation period in both soil types. EG of percolation waters is eventually increased with prolonging days after irrigation regardless of irrigation periods in both soil types. Therefore, it might be concluded that there was potentially safe to irrigate the discharge water from municipal wastewater treatment plant relative to harvest index, SAR and $EC_i$ values of the ground water through the rice cultivation period at tillering stage for drought period.

• Journal of the Korean Society of Groundwater Environment
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• v.7 no.3
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• pp.103-115
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• 2000

The formation of brown-colored precipitates is one of the serious problems frequently encountered in the development and supply of groundwater in Korea, because by it the water exceeds the drinking water standard in terms of color. taste. turbidity and dissolved iron concentration and of often results in scaling problem within the water supplying system. In groundwaters from the Pajoo area, brown precipitates are typically formed in a few hours after pumping-out. In this paper we examine the process of the brown precipitates' formation using the equilibrium thermodynamic and kinetic approaches, in order to understand the origin and geochemical pathway of the generation of turbidity in groundwater. The results of this study are used to suggest not only the proper pumping technique to minimize the formation of precipitates but also the optimal design of water treatment methods to improve the water quality. The bed-rock groundwater in the Pajoo area belongs to the Ca-$HCO_3$type that was evolved through water/rock (gneiss) interaction. Based on SEM-EDS and XRD analyses, the precipitates are identified as an amorphous, Fe-bearing oxides or hydroxides. By the use of multi-step filtration with pore sizes of 6, 4, 1, 0.45 and 0.2 $\mu\textrm{m}$, the precipitates mostly fall in the colloidal size (1 to 0.45 $\mu\textrm{m}$) but are concentrated (about 81%) in the range of 1 to 6 $\mu\textrm{m}$in teams of mass (weight) distribution. Large amounts of dissolved iron were possibly originated from dissolution of clinochlore in cataclasite which contains high amounts of Fe (up to 3 wt.%). The calculation of saturation index (using a computer code PHREEQC), as well as the examination of pH-Eh stability relations, also indicate that the final precipitates are Fe-oxy-hydroxide that is formed by the change of water chemistry (mainly, oxidation) due to the exposure to oxygen during the pumping-out of Fe(II)-bearing, reduced groundwater. After pumping-out, the groundwater shows the progressive decreases of pH, DO and alkalinity with elapsed time. However, turbidity increases and then decreases with time. The decrease of dissolved Fe concentration as a function of elapsed time after pumping-out is expressed as a regression equation Fe(II)=10.l exp(-0.0009t). The oxidation reaction due to the influx of free oxygen during the pumping and storage of groundwater results in the formation of brown precipitates, which is dependent on time, $Po_2$and pH. In order to obtain drinkable water quality, therefore, the precipitates should be removed by filtering after the stepwise storage and aeration in tanks with sufficient volume for sufficient time. Particle size distribution data also suggest that step-wise filtration would be cost-effective. To minimize the scaling within wells, the continued (if possible) pumping within the optimum pumping rate is recommended because this technique will be most effective for minimizing the mixing between deep Fe(II)-rich water and shallow $O_2$-rich water. The simultaneous pumping of shallow $O_2$-rich water in different wells is also recommended.

• Water Engineering Research
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• v.5 no.2
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• pp.55-68
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• 2004

The GLEAMS (Groundwater Loading Effects of Agricultural Management System, version 3.0) water quality model was used to predict hydrology and water quality and to evaluate the effects of soil types from a cattle-grazed pasture field of Bermuda-Rye grass rotation with poultry litter application as a fertilizer in North Alabama. The model was applied and evaluated by using four years (1999-2002) of field-measured data to compare the simulated results for the 2.71- ha Summerford watershed. $R^2$ values between observed and simulated runoff, sediment yields, TN, and TP were 0.91, 0.86, 0.95, and 0.69, respectively. EI (Efficiency Index) of these parameters were 0.86, 0.67, 0.70, and 0.48, respectively. The statistical parameters indicated that GLEAMS provided a reasonable estimation of the runoff, sediment yield, and nutrient losses at the studied watershed. The soil infiltration rates were compared with the rainfall events. Only high intensity rainfall events generated runoff from the watershed. The measured and predicted infiltration rates were higher during dry soil conditions than wet soil conditions. The ratio of runoff to precipitation was ranging from 2.2% to 8.8% with average of 4.3%. This shows that the project site had high infiltration and evapotranspiration which generated the low runoff. The ratio of runoff to precipitation according to soil types by the GLEAMS model appeared that Sa (Sequatchie fine sandy loam) soil type was higher and Wc (Waynesboro fine sandy loam, severely eroded rolling phase) soil type relatively lower than the weighted average of the soil types in the watershed. The model under-predicted runoff, sediment yields, TN, and TP in Wb (Waynesboro fine sandy loam, eroded undulating phase) and Wc soil types. General tendency of the predicted data was similar for all soil types. The model predicted the highest runoff in Sa soil type by 105% of the weighted average and the lowest runoff in Wc soil type by 87% of the weighted average

• Korean Journal of Fisheries and Aquatic Sciences
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• v.46 no.5
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• pp.626-637
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• 2013

We measured the grain size, ignition loss (IL), chemical oxygen demand (COD), acid volatile sulfide (AVS) and trace metals (Al, Fe, Cu, Pb, Zn, Cd, Cr, Mn, Hg, and As) of intertidal surface sediment collected from 11 islands (62 stations) in the southern region of Jeollanam Province. The objective of this research was to evaluate the organic matter and trace metals contaminations of sediments from coastal island tidal flats. Surface sediment texture was characterized as follows: mud, sandy silt, muddy sand, and slightly gravelly sand facies. The finer sediments are mainly dominated in the northern part of each island. The concentrations of IL, COD, AVS and some trace metals (Al, Fe, Zn, Cr, Cu, and Hg) were higher in the northwestern part of Wan Island and the area between Gogeum and Sinji Islands, and were associated with relatively finer sediment, as compared to other locations. The concentrations of Mn, Pb, Cd, and As were higher in the northwestern and southeastern parts of Geoguem and Pyungil Islands, but were not correlated with mean grain size. Based on sediment quality guidelines (SQGs), the concentrations of trace metals were lower than the values of effect range low (ERL), used in United States, and threshold effects level (TEL), used in Korea, with exception of As. Similarly, the intertidal sediments were moderately contaminated with As, based on the the enrichment factor (EF) and the geoaccumulation index ($I_{geo}$). The high concentration of As in intertidal sediments from this study region may be due to the input of naturally or artificially contaminated submarine groundwater, contaminated waste from seaweed aquaculture operations and/or land-based seaweed processing facilities. Further studies are needed to identify the sources of As in this study region, and to determine the effects of As contamination on coastal ecosystem.

• Economic and Environmental Geology
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• v.34 no.5
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• pp.471-483
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• 2001

The pH values of the mine and surface water from the Tohyun mine creek were higher compared with those of groundwater, and 2nd round samples in same sites were even alkaline. The stream and mine waters belong to the characteristics of (Ca+Mg)-(SO$_4$) and (Ca+Mg)-(HCO$_3$) types, and groundwaters have to the (Ca+Mg+Na+K)-(HCO$_3$+SO$_4$) type. As the 2nd samples. concentrations of mostly anions are increasing compared with the forder samples. However, the mostly cation concentrations are decreasing. The hydrogeochemistry indicate that water quality is different chemical characteristics and evolution trends. The range of $\delta$D and $\delta$$^{18}$ valutes (relative to SMOW) in the waters are shown in -62.2 to -70.1$\textperthousand$, and -8.1 to -9.4$\textperthousand$. The values are plowed parallel to $\delta$D=8$\delta$$^{18}$ O+ (6$\pm$4). The d values of groundwater show 2.4, which is lower than the surface (5.2) and mine (7.6) waters. Strontium concentra titans range from 0.025 to 11.844 mg/$\ell$ in all kinds of water samples, but the groundwater has the highest contents The $^{87}$ Sr/$^{86}$ Sr ratios (0.7115 to 0.7129) show more lightened to the groundwater. The $\delta$$^{18}$ O value, Ca and Sr contents are decreased with $^{87}$ Sr/$^{86}$ Sr increasing, because it is support to the altitude effects of the sampling sites rather than a water-rock interaction of environmental isotope. Using computer code of WATEQ4F, saturation indices of albite, Quartz, gibssite and gypsum are calculated to be soluble. The calcite and dolomite show super saturation state, however, clay mineral species are plotted boundary between undersaturation and supersaturation. In the Tohyun mine creek, reaction materials with ore wastes arid precipitation have influence upon increasing EC and TDS of the waters independent of pH. The SO$_4$ concentrations in the mine water is 181.845 mg/$\ell$. This is abruptly increase in surface water and then detected 249.727 mg/$\ell$ in the groundwater. As a results of the calculated sulfate mineral solubilities, the sulfate ions became saturation states an above 150 mg/$\ell$ concentrations.

• Journal of Soil and Groundwater Environment
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• v.10 no.5
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• pp.25-36
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• 2005

Several metalliferous and coal mines, including Myungjin, Seojin and Okdong located at the upper watershed of Okdong stream, were abandoned or closed since 1988 due to the mining industry promotion policy. Thus these disposed an enormous amount of mining wastes without a proper treatment facilities, resulting in water pollution in the downstream areas. Acid mine drainage (AMD) and waste water effluents from the closed coal mines were very strongly acidic showing pH ranges of 2.7 to 4.5 and had a high level of Total Dissolved Solids (TDS) showing the ranges of 1,030 to 1,947 mg/L. Also heavy metal concentrations in these samples such as Fe, Cu, Cd and anion such as sulfate were very high. Concentrations of water soluble heavy metals in the Okdong streams were in the orders of Fe>Al>Mn>Zn>Cu>Pb>Cd, indicating Fe from the AMD and waste water effluents contributed greatly to the quality of water and soil in the lower watershed of Okdong stream. Copper concentrations in the effluents from the tile drainage of mine tailings dams were highest during the raining season. Water Pollution Index (WPI) of the surface water at the upper stream of Okdong river where AMD of the abandoned coal mines was flowed into main stream were in the ranges of 16.3 to 47.1. On the other hand, those at the mid stream where effluents from tailings dams and coal mines flowed into main stream were in the WPI ranges of 10.6 to 19.5. However, those at the lower stream were ranged from 10.6 to 14.9. These results indicated that mining wastes such as AMD and effluents from the closed mines were the major source to water pollution at the Okdong stream areas.

• Journal of Soil and Groundwater Environment
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• v.8 no.4
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• pp.68-73
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• 2003

This study performed from 2002 October to 2003 April. The samples were taken at 66 sites, divided into the 6 sections functionally in the southern part of Seoul such as Yangchon-gu, Kangseo-gu, Kuro-gu, Yeongdengpo-gu, Kwanak-gu, Dongjak-gu, Seocho-gu, Kangnam-gu, Songpa-gu, and Kangdong-gu. The result of research showed that each property soil was pH 4.7∼9.5, Cd; 0.391 mg/kg (0.011∼l.081 mg/kg). Cu; 12.35 mg/kg (0.061∼73.62 mg/kg), Pb; 13.04 mg/kg (N.D.∼61.85 mg/kg), Hg; 0.0866 mg/kg (N.D.∼1.353 mg/kg), F; 206.8 mg/kg(47.1∼561.1mg/kg). The minimum and maximum of the concentration with functional soils were Cd; 0.632 mg/kg for multi-purposed soil,0.079 mg/kg for schools, Cu; 21.35 mg/kg for roadside, 2.159 mg/kg for schools, Pb; 24.70 mg/kg for roadside, 1.030 mg/kg for schools, Hg; 0.1780 mg/kg for multi purposed, 0.0087 mg/kg for schools. Especially F was the high concentration at the hills. Also the concentration of Cd, Cu, Pb, Hg and F at school Zone was detected such as low. area of schools area was detected the low concentrations as the items of Cd, Cu, Pb, Hg, and F. The average concentrations of metals and fluorine in the survey area were below the Preliminary Standard of the Soil Preservation Acts in Korea. To evaluate the soil quality of these area showed as a good qualified results. The results of SQPI (Soil Quality Pollution Index the qualified results as much as 86.4%.

• Korean Journal of Environment and Ecology
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• v.29 no.6
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• pp.917-922
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• 2015

This study was carried out to investigate solutes concentration change with respect to discharge change in coniferous forest experiment watershed in Gyeonggi-do, Korea. From 2005 to 2008. Precipitation, discharge, solutes has been analyzed from 23 precipitation events. The results showed that low API induced low discharge. $NH_4{^+}$, $K^+$, and $Ca^{2+}$ were indicated by clockwise and $Cl^-$ and $NO_3{^-}$ were represented by counterclockwise hysteresis loop. ${SO_4}^{2-}$, $Na^+$, $Mg^{2+}$ showed no hysteresis loop pattern. $Cl^-$, $Na^+$, $NH_4{^+}$ was relatively constant due to groundwater during precipitation, $NO_3{^-}$ was increased due to soil water compared to early precipitation. $Cl^-$, ${SO_4}^{2-}$, $Na^+$, $Mg^{2+}$, $Ca^{2+}$ was diluted with respect to increased discharge and $NO_3{^-}$ was diluted in early precipitation and then increased in the end. $NO_3{^-}$ and $Ca^{2+}$ eluviated in early precipitation. This characteristics was presumed by the effect of API, discharge and ground water.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2001.04a
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• pp.98-103
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• 2001

In order to understand the characteristics of leachate at the Seokdae municipal waste landfill in the Pusan city, the correlation between leachate pollution loading and volume of gas production. concentration of gas and subsidence of ground, the characteristical methos, geochemical analyses and laboratory column tests using samples of gases, leachate and surface soil of Seokdae waste landfill area. Through the analysis of water balance, leachate flow rate and pollution loading were estimated. Geistatistical analysis of four gas components ( $O_2$, C $H_4$, $H_2$S and CO) shows the possibility of ground subsidence around the group of a site with high concentration of gas. From geochemical analyses of leachate, EC and Total-Alkalinity of ground subsidence around the group of a site with high concentration of gas. From geochemical analysis of leachate, Ec and Total-Alkalinity were increased, and Cl, Cr, Mn, Cu, Zn, Cd and Pb were decreassed comparing to the part, and the type of water quality was Na-HC $O_3$ in trilinear diagram. It shows that biodecomposition of municipal wastes continues actively. From the analysis of water balance, the total leachate flow rate is about 465.11㎥/day and pure pollution loading of Cl, Mn and Fe are estimated to 223.8kg/day, 0.2kg/day, 0.3kg/day, respectively. The laboratory column test of residual soil and landfill soil shows 0.206cm and 0.019cm for linear velocity(equation omitted), 0.234 $\textrm{cm}^2$/min and 0.018$\textrm{cm}^2$/min for diffusion coefficient ( $D_{ι}$), and 1.136cm and 0.095cm longitudinal dispersion index ($\alpha$$_{ι}$), respective]y. It demonstrates that the delay time of contamination for residual soil is shorter than that of landfill soil.