• Economic and Environmental Geology
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• v.40 no.1 s.182
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• pp.129-140
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• 2007

CFC(CFC-12, CFC-11 and CFC-113) analytical system for air and water was constructed using a customized purge and trap extraction device and a gas chromatograph with an electron capture detector. Sampling methods of air and water for CFCs were also established. The analytical system was experimentally optimized to result in reproducibilities of triplicates less than 2% for current air samples and less than 5% for groundwater samples with CFC-12 concentration of 160 to 180 pg/kg, and verified with respect to the CFC system in USGS, which showed analytical results were in agreement within 10%. CFCs in air were monitored at three sites over 19-month period in the central part of South Korea, and the result indicates no significant local sources of CFCs in those areas. For groundwater in Jeju Island, CFCs were measured over a year with a two-month interval. The time-series data showed seasonal fluctuations which could be interpreted by the effect of recharge pulse derived from large amount of rainfall during monsoon period with a few month delay, which indicates high permeability of basaltic rocks in Jeju Island.

• Journal of the Korean Chemical Society
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• v.36 no.5
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• pp.727-737
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• 1992

The water chemical characteristics and age dating of springwater in Cheju island had been investigated. C_1, C_4, C_7, C_9 springwaters were not affected by seawater intrusion by TDS and electrical conductivity, relationship of Cl and tritium, Cl and HCO_3 ratio, and total hardness and pseudo hardness. In this case only C_7 springwater was evaluated tasty and healthy mineral springwater by Hahimoto's Mineral Balance Index. On the basis of the mean tritium content of rainfalls and springwater, the average residence time of it, were calculated. Considering the hydrogeologic and hydrochemical condition, completely mixed model seems to be very fit. It was obtained the result that C_9 group springwater (C_{10}, C_{12}, C_{14}) was 1.2 months, C_7 springwater was 5.6 months, and deep groundwater C_{17} was 4 years.

• Economic and Environmental Geology
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• v.11 no.3
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• pp.99-108
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• 1978

The Gum-Ho river basin is one of the densely populated area having more than 35% of the total population and it was also well irrigated since earlier days in the Nackdong river basin. Most of the easily developed source of surface water are fully utilized, and at this moment the basin is at the stage that no more :surface water can be made available under the present rapid development of economic condition. Since surface water supplies from the basin have become more difficult to obtain, the ground water resources must be thoroughly investigated and utilized greatly hereafter. In economic ground of the basin what part could ground water play? In what quantities and, for what uses could it be put? The answer to these questions can be relatively simple;the ground water resources in the basin can be put at almost any desired use and almost anywhere in the basin The area of the basin is at about $2088km^2$ in the middle part of Nackdong river basin and it is located along the Seoul-Pusan express highway. The mean annual rainfall is about 974.7mm, most of which falls from June to September during the monsoon. Accumulated is appeared approximately after every 8 year's accumlated dry period with the duration of 5 years. The water bearing formation in the basin include unconsolidated alluvial deposits in Age of Quaternary, saprolite derived from weathered crystalline rocks, Gyongsang sedimentary formations of the period from late Jurassic to Cretaceouse, and igneouse rocks ranging of the Age from Mesozoic to Cenozoic. The most productive ground water reservoir in the basin is calcareous shale and sandstones of Gyongsang system, which occupies about 66% of the total area. The results of aquifer test on Gyongsang sedimentary formation show that average pumping capacity of a well drilled into the formation with drilling diameter and average depth of $8{\frac{1}{2}}$ inch and 136m is $738m^3/day$ and also average specific capacity of those well is estimated $77.8m^3/D/M$. Total amount of the ground water reserved in the basin is approximately estimated at 37 billion metric tons, being equivalent 18 years total precipitations, among which 7 billion metric tons of portable ground water can be easily utilized in depth of 200 meters.

• Geosciences Journal
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• v.22 no.6
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• pp.1001-1013
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• 2018

A new type of uranium occurrence in Korea was identified in pegmatitic and hydrothermally altered granite in the Daejeon area. The U-bearing parts typically include muscovite, pink-feldspar and sericite as alteration minerals. In this study, the geochemical characteristics and alteration age of the granitic rocks were examined to provide evidence for hydrothermally-enriched uranium. The K-Ar ages of muscovite coexisting with U-bearing minerals were determined as 123 and 128 Ma. The U-bearing rocks have relatively low ($CaO+Na_2O$), high $K_2O$ contents, and high alteration index values by major element geochemistry. The trace element geochemistry shows that the uraniferous rocks have significantly low Th/U ratios and strongly differentiated features. The rare earth element patterns indicate that the uraniferous rocks have a low total REE and LREE contents with depletion of Eu. Considering the geochemical variation of the granitic rock major, trace and rare earth elements, it can be concluded that uranium enrichment in pegmatites and altered granite should be genetically related to post-magmatic hydrothermal alteration of K-metasomatism after emplacement of the two-mica granite. This is the first report for geochemical characteristics of Mesozoic granite-related U-occurrences in South Korea. This study will help further research for uranium deposits with similarities in geological setting, mineralogy and age data between South China and Korea, and can also be expected to help solve the source problems related to high uranium concentrations in some groundwater occurring in the granitic terrane.

• Journal of the Korean Chemical Society
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• v.40 no.2
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• pp.101-108
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• 1996

The chemical characteristics and age dating of the thermal springwater developed recently in Chullabukdo were investigated. The temperature range of the thermal springwater was found 27∼29$^{\circ}C$, indicating a low temperature thermal springwater. The concentration of $F^-$ ion in the springwater was found relatively high in the range of 2∼3 ppm, but $NO_3^-$ ion was nearly not detected. The concentration range of $SO_4^{2-}$ ion was 0.02∼23 ppm, among which $SO_4^{2-}$ content of $Y_3$ was found very high compared to that of other springwater, since this site is known as a sulfur spring. $HCO_3^-$ ion content was found 2∼5 times higher than that of groundwater. $Y_1,\;Y_3,\;Y_5,\;Y_2,\;Y_4,\;and\;Y_8$, were classified as $HCO_3^-$ type, $Y_6$ as $CI^-$type, and $Y_7$, as no domonant type by classification diagram for anion and cation facies. From the results of age dating on the basis of the mean tritium level of precipitation and thermal springs, $Y_1$ was identified as the oldest thermal spring (-89 years) and $Y_7$ was identified as -89 years and $Y_7$ was -1 year using dispersive model. The results calculated by two models agreed well each other.

• Journal of the Korean Society of Groundwater Environment
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• v.1 no.2
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• pp.100-104
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• 1994

The rock matrix diffusion provides a retarding mechanism for sorbing and especially non-sorbing radionuclides. It has to be verified not only theoretically and experimentally but also from natural phenomena, before the mechanism can be incorporated fully into transport codes. The natural analogue studies, such as the concentration variation of radionuclides in profiles perpendicular to fluid-conducting fractures and to intrusive contact zones, have been believed to provide a validation. In thermal alteration zones of Naeduckri granite intruded by a pegmatite, large alkali and alkaline earth elements such as K, Rb, Sr, and Ba were moderately migrated during thermal alteration. Li, V. and Nb were also migrated about 9cm in width from the contact between the granite and the pegmatite. The concentration variation of these elements in thermally altered zones seems to be resulted from the local migration due to the re-equilibration among the elements released from the breakdown of primary minerals in the granite. Most of these natural analogue studies simply show only the concentration variation of elements without detailed informations on the diffusion time and other important data fir interpreting the behaviour of radionuclides, because of the absence of appropriate minerals for age data. Despite this problem, natural analogue studies will be needed for transport models of radionuclides in safety assessment.

• The Journal of the Petrological Society of Korea
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• v.14 no.3 s.41
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• pp.127-140
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• 2005

The Samyuri area of Jeoksang-myeon, Muju-gun at the Middle Yeongnam Massif consists of granitic gneiss, porphyroblastic gneiss and leucocratic gneiss, which correspond to Precambrian Wonnam Series. Here we discuss a geochemical implication of the data based on major element composition, trace element, rare earth element (REE), Sm-Nd and Rb-Sr isotope systematics of the boring cores in the granite gneiss area. The boring cores are granitic gneiss (including biotite gneiss) and amphibolite. The major and trace element compositions of granitic gneiss and amphibolite suggest that the protolith belongs to TTG (Tonalite-Trondhjemite-Granodiorite) and tholeiitic series, respectively. Chondrte-normalized REE patterns vary in LREE, HREE and Eu anomalies. The granitic gneiss and amphibolite have Sm-Nd whole rock age of $2,026{\pm}230(2{\sigma})$ Ma with an initial Nd isotopic ratio of $0.50979{\pm}0.00028(2{\sigma})$ (initial ${\epsilon}_{Nd}=-4.4$), which suggests that the source material was derived from old crustal material. Particularly, this initial ${\epsilon}$ Nd value belongs to the range of the geochemical evolution of Archean basement in North-China Craton, and also corresponds to the initial Nd isotope evolution line by Lee et al. (2005). In addition, chondrite-normalized REE pattern and initial Nd value of amphibolite are very similar to those of juvenile magma in crustal formation process.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2006.04a
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• pp.76-81
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• 2006

창녕군 증산리 지역은 신규 취수원 확보 일환으로 강변여과 방식 취수 가능성이 한국수자원공사에 의해서 평가되고 있는 지역이다. 강변여과 방식 취수의 타당성 평가를 위해 현장 지질조사, 시추조사, 전기 비저항 탐사 및 고해상도 탄성파 탐사를 수행하였다. 또한 대상 연구지역에서의 개략적 취수 가능량 산정을 위해 모델링 평가가 수행되었으며, 개별 정호에 대한 양수량 산정을 위해 시험 정호를 설치하였다. 현장 시추 조사와 시료에 대한 입도 분석 결과, 연구 지역의 충적층 두께는 35m 전후이며, 주 대수층 구간은 지표하 $25{\sim}35m$인 것으로 추정되었다. 또한 주 대수층 구간의 수리전도도는 $10^{-2}cm/sec$ 이상으로 주로 모래섞인 자갈층으로 구성되어있는 것으로 평가되었다. 또한 전기비저항 조사 결과는 부분적으로 매우 낮은 비저항 분포 지층을 보여주고 있으며, 이는 주로 실트 및 점토로 된 지층이 부분적으로 퇴적되어 있음을 지시하며, 고해상도 탄성파 탐사 결과는 전반적으로 지하수위는 지표하부 5m 전후에 분포하고, 충적층의 하부 경계는 35 내지 45m인 것으로 해석되었다. 지하수 모델링을 통해, 취수 목표량인 180,000톤/일은 주대수층까지의 지하수위 강하 없이 확보 가능할 것으로 평가되었다. 또한 개별 정호의 산출 특성을 평가하기 위해 시험 정호를 설치하여, 실제 2,700톤/일 예비 양수 시험을 수행하였다. 예비 양수 시험 결과, 양수정에서의 수위 강하는 개략 10m, 양수정관측정에서는 약 0.3m의 수위강하만이 관찰되었으며, 양수 영향권이 수 십 m를 넘지 않을 것으로 판단되었다.서의 S97과 JBR의 세포감염 억제율은 3.85%와 3.63%로 나타났다. $textsc{k}$-casein, CU는 로타바이러스 S97과 JBR에 대해 농도 2000UM에서 97%이상의 억제효과를 나타냈으며, sialic acid는 억제효과가 거의 없었다. K-casein, GMP는 송아지뿐만 아니라 유아의 로타바이러스에 의한 설사를 억제할 수 있을 것으로 기대된다.을 향상하기 위해서는 이러한 부위에 대한 미생물 오염을 낮출 수 있는 세심한 현장 품질관리가 필요하다.en and adolescents, analysed by country, age group and gender. The paper discusses the places young consumers can turn to in trying to fulfil their growing consumer needs. It also examines how much money is at their disposal. It then concludes by considering the influence of "financial socialization" on how young people deal with money.nsumption visions based on the various perspectives, consumers are influenced in the apparel buying decision-making. Many subjects reported experiencing positive affect when imagining positive outcomes of produc

• Journal of the Korean Society of Groundwater Environment
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• v.7 no.3
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• pp.116-124
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• 2000

Geochemical and isotopic analyses were carried out to investigate hydrochemical characteristics, source of carbon species in the carbonated waters in South Korea. Most Korean carbonated waters from different geologic settings are characterized by a Ca-HCO$_3$type with a relatively low pH range from 5.3 to 6.3 (avg. 6.0). The concentrations of cations and anions in the carbonate waters are in the order of Ca$^{2＋}$>Na$^{＋}$>Mg$^{2＋}$>Si$^{4＋}$>Fe$^{2＋}$>K$^{＋}$ and HCO$_3$$^{－}$>SO$_4$$^{2－}$>Cl$^{－}$, respectively. The HCO$_3$$^{－}$ ion is more enriched in the carbonated water from the sedimentary rock and granitic rock of Mesozoic age in the Gyungsang basin(GII) and the Precambrian metamorphic rock and Jurassic granitic rocks of the Gyunggj massif in the Gangwon province(GⅠ) than those of the meta-sedimentary rock and granite in the Ogcheon zone(GⅢ). Based on the oxygen and hydrogen isotopic data, the carbonated waters are derived from the meteoric water, showing apparent latitude and altitude effects. The $delta$$^{13}$C values of carbon species in the carbonated water are in between -6.23 and 0.0 $textperthousand$, suggesting inorganic source of carbon originated from the carbonate mineral and carbonate rock in the aquifer.

• Economic and Environmental Geology
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• v.45 no.1
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• pp.31-40
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• 2012

This paper examined the characteristics of ductile and brittle structural elements with detailed mapping by lithofacies classification to clarify the relationship between the geological structure and the geochemical high-grade uranium anormal zone and to provide the basic information on the flow of groundwater in the eastern area of Shinbo mine, Jinan-gun, Jeollabuk-do, Korea. It indicates that this area is mainly composed of Precambrian quartzite, metapelite, metapsammite, which show a zonal distribution of mainly ENE-WSW trend, and age unknown pegmatite and Cretaceous porphyry which intrude them. But the Cretaceous Jinan Group which unconformably covers them, contrary to assumption, could not be observed. The main ductile deformation structures of Precambrian metasedimentary rocks were formed at least through three phases of deformation [ENE striking regional foliation (D1) -> ENE or EW striking crenulation foliation (D2) -> WNW or EW trending open, tight, kink folds (D3)]. The predominant orientation of S1 regional foliation strikes ENE and dips south, being similar to the zonal distribution of Precambrian metasedimentary rocks. Most predominant orientation of high-angled brittle fracture (dip angle ${\geq}45^{\circ}$) [ENE (frequency: 24.3%) > NS (23.9%) > (N)NW (18.8%) > WNW (16.9%) > NE (16.1%) fracture sets in descending frequency order], which is closely related to the flow of groundwater, strikes ENE and dips south. It also agrees with the zonal distribution of metasedimentary rocks and the predominant orientation of S1 regional foliation. The next one strikes NS and dips east or west. Considering the controlling factor of the geochemical uranium anormal zone in the Shinbo mine and its eastern areas from the above structural data. the uranium source rock in these areas might be pegmatite and the geochemical uranium anormal zone in the Sinbo mine area could be formed by an secondary enrichment through the flow of pegmatite aquifer's groundwater into the Sinbo mine area like the previous research's result.