• Journal of Korean Society of Environmental Engineers
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• v.29 no.9
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• pp.1027-1034
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• 2007

This research was focused on the selective separation of $CO_2$ or $CH_4$ from mixture of these gases, by controlling the size of pore or pore gate. Pitch based activated carbon fibers(ACF) were used as adsorbents. The size of pore gate was controlled by the molecule having similar size to that of pore opening. After the adsorption of adsorbate on pore surface, planar molecules such as benzene and naphthalene covered the pore gate. The slow release of adsorbate from the pores covered by planar molecules makes apertures between planar molecules covering pore gate and this structure can be fixed by rapid pyrolysis. The control of pore gate using benzene as covering molecules could not accomplished due to the simultaneous volatilization of benzene and adsorbate$(CO_2)$ caused by similar temperatures of benzene volatilization and adsorbate desorption. Therefore we replaced benzene with naphthalene looking for the stability at a $CO_2$ desorption temperature. The naphthalene molecule was adsorbed on the ACF up to 15% of ACF weight and showed no desorption until $100^{\circ}C$, indicating that the molecule could be used as a good cover molecule. Naphthalene could cover almost all the pore gate, reducing BET surface area from 753 $m^2/g$ to 0.7 $m^2/g$. A mixed gas$(CO_2:CH_4=50:50)$ was adsorbed on the naphthalene treated OG-7A ACF. The amount of $CO_2$ adsorption increased with total pressure, whileas thai of $CH_4$ was not so much influenced on the pressure, indicating that $CO_2$ made more compounds on the ACF surface along with total pressure increase. The most $CO_2$ and the least $CH_4$ were adsorbed in the condition of 0.4 atm, resulting in the highly pure $CH_4$ left in ACF.

• Journal of Energy Engineering
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• v.16 no.2
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• pp.83-92
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• 2007

In view of stringent environment regulations to control the emission of green house gases and also depleting fossil fuel reserves, it is high quality desirable to develop alternative technologies to produce high quality fuels. To this end Biomass to Liquid (BTL) technology has received much attention in recent years. BTL process generally consists of gasification of biomass to produce bio-syngas, cleaning and control of $H_{2}/CO$ mole ratio of bio-syngas and Fischer-Tropsch synthesis & upgrading systems. Choren, Germany has first developed the commercial BTL process using unique gasification system i.e., Carbo-V. A new technology to remove tars and BTX has been developed by ECN in Netherlands employing a gasification system combined with OLGA technology. Several other countries including USA and Japan are showing great interest in BTL technology. Thus in view of our national energy security and also the environmental regulations, it is essential to develop alternative technologies like BTL in order to meet the increasing demand of energy though our insufficient biomass resources. In this paper we present an overview and development status of BTL-diesel technology.

• Journal of Korea Water Resources Association
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• v.42 no.12
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• pp.1029-1038
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• 2009

Recently, it is expected that small hydropower (SHP) could potentially provide sufficient amounts of alternative energy in Korea where there is an abundance of potential sites and where social efforts are being made to reduce the emissions of green house gases. In the past, the resources survey for SHP development has been carried out using onsite surveys and paper maps, which incurred a great deal of time and cost. Furthermore, the tools for decision making such as determining development priorities or evaluating feasibility have been considered only economic aspect and focused on the performance characteristics of power generation. However, as the concept of sustainable development has been being advanced in recent years, especially focused on human-social, environmental and ecological in addition to economical sector; the consideration of these multiple criteria has become essential for sustainable SHP development. This study aims to propose the spatial multi-criteria decision making (MCDM) methodology for determining priorities among a number of locations on the planning stage of SHP development using AHP and GIS. The proposed methodology is applied for determining development priorities among the SHP locations in Cho River basin and this study presents the detailed spatial information data and the results of development priorities. As a fundamental work, this study will be beneficial to the future activation of SHP development and will help the decision making in evaluating the feasibility of SHP development.

• Korean Journal of Construction Engineering and Management
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• v.15 no.1
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• pp.111-121
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• 2014

The Clean Development Mechanism (CDM) allows New & Renewable Energy projects to make additional income by selling CER's, which represent the amount of Green House Gases(GHG) that is reduced in the project. However, forward contracts used to hedge fluctuating market prices does not allow projects to sell CER's at a premium. As an alternate approach to maximize CER revenue, CER's are modeled as a 'real option', in which CER's are sold only above the desired sales price. Using the Binomial Option Pricing model, the resultant lattices are used to determine whether to sell, defer or abandon the option at individual nodes. Overlaying Pascal's Triangle on the lattices also enabled the calculation of the annual probabilities for deferring CER sales without incurring downside losses. Application to an actual Landfill Gas project showed increased overall NPV, and that CER sales could be deferred at a maximum of 2 years. The proposed framework allows transparency in the analysis and provides valuable and strategical information when making investment decisions related to CER sales of CDM projects.

• 한국신재생에너지학회:학술대회논문집
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• 2010.11a
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• pp.131.1-131.1
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• 2010

This study was conducted for engineering optimization for the gasification process which is the key factor for success of Taean IGCC gasification plant which has been driven forward under the government support in order to expand to supply new and renewable energy and diminish the burden of the responsibility for the reduction of the green house gas emission. The gasification process consists of coal milling and drying, pressurization and feeding, gasification, quenching and HP syngas cooling, slag removal system, dry flyash removal system, wet scrubbing system, and primary water treatment system. The configuration optimization is essential for the high efficiency and the cost saving. For this purpose, it was designed to have syngas cooler to recover the sensible heat as much as possible from the hot syngas produced from the gasifier which is the dry-feeding and entrained bed slagging type and also applied with the oxygen combustion and the first stage cylindrical upward gas flow. The pressure condition inside of the gasifier is around 40~45Mpg and the temperature condition is up to $1500{\sim}1700^{\circ}C$. It was designed for about 70% out of fly ash to be drained out throughout the quenching water in the bottom part of the gasifier as a type of molten slag flowing down on the membrane wall and finally become a byproduct over the slag removal system. The flyash removal system to capture solid particulates is applied with HPHT ceramic candle filter to stand up against the high pressure and temperature. When it comes to the residual tiny particles after the flyash removal system, wet scurbbing system is applied to finally clean up the solids. The washed-up syngas through the wet scrubber will keep around $130{\sim}135^{\circ}C$, 40~42Mpg and 250 ppmv of hydrochloric acid(HCl) and hydrofluoric acid(HF) at maximum and it is turned over to the gas treatment system for removing toxic gases out of the syngas to comply with the conditions requested from the gas turbine. The result of this study will be utilized to the detailed engineering, procurement and manufacturing of equipments, and construction for the Taean IGCC plant and furthermore it is the baseline technology applicable for the poly-generation such as coal gasification(SNG) and liquefaction(CTL) to reinforce national energy security and create new business models.

• Korean Journal of Soil Science and Fertilizer
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• v.41 no.6
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• pp.408-414
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• 2008

Importance of climate change and its impact on agriculture and environment has increased with the rise Green House Gases (GHGs) concentration in the atmosphere. To slow down the speed of climate change many efforts have been applied in industrial sectors to reduce GHGs emission and to enhance carbon storage. In agricultural sector, many researches have been performed on GHGs emission reduction, but few on the role of carbon sink. In this study, we investigated carbon balance and soil carbon storage in agricultural field in the barley-red pepper and barley-soybean cropping system. With the system for automatic measuring of carbon dioxide, net ecosystem production(NEP) was estimated to be $6.3ton\;CO_2\;ha-1$ for N-P-K chemical fertilizer treatment plot and $10.6ton\;CO_2\;ha^{-1}$ for N-P-K chemical fertilizer with swine manure treatment plot in the barley-soybean rotation cropping. In the barley-red pepper rotation cropping, it was $12.0ton\;CO_2\;ha^{-1}$ for N-P-K chemical fertilizer treatment plot and $13.2ton\;CO_2\;ha^{-1}$ for N-P-K chemical fertilizer with swine manure treatment plot. Soil carbon storage rate was estimated to be $0.7ton\;C\;ha^{-1}$ for the barley-soybean cropping system and $0.5ton\;C\;ha^{-1}$ for barley-pepper cropping system. In appeared that agricultural lands may contribute to the greenhouse effect as a potential carbon sink preserving carbon into soil.

• Journal of the Korea Organic Resources Recycling Association
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• v.28 no.1
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• pp.73-82
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• 2020

This study was conducted to investigate the differences in carbon storage capacity of soil between the conventional and the organic agricultural cultivation followed by the assessment of their economic values. An analysis of 107 samples in the organic and the conventional rice cultivation soils in six regions across South Korea showed that the five regions, Buyeo-II, Gimhae, Sancheong-I, II and Suncheon, had higher organic soil carbon contents than those of values observed on the conventional soils with the exception of the Buyeo-I areas. Based on the results from soil carbon contents, the carbon storage were estimated to be 36.1 megagram carbon (MgC) per ha in the organic paddy soils, while its conventional paddy soils were 29.4 MgC per ha. It showed that the organic paddy soils were 23 % greater than that of its conventional paddy soils. It was estimated that the carbon trading price for economic assessment was ￦758,100 per ha in the organic paddy soil and ￦617,400 per ha in the conventional paddy soil.

• Biotechnology and Bioprocess Engineering:BBE
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• v.10 no.6
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• pp.482-493
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• 2005

Biomass is originally photosynthesized from inorgainic compounds such as $CO_2$, minerals, water and solar energy. Recent studies have shown that anaerobic bacteria have the ability to convert recalcitrant biomass such as cellullosic or chitinoic materials to useful compounds. The biomass containing agricultural waste, unutilized wood and other garbage is expected to utilize as feed, food and fuel by microbial degradation and other metabolic functions. In this study we isolated several anaerobic, cellulolytic and chitinolytic bacteria from rumen fluid, compost and soil to study their related enzymes and genes. The anaerobic and cellulolytic bacteria, Clostridium thermocellum, Clostridium stercorarium, and Clostridium josui, were isolated from compost and the chitinolytic Clostridium paraputrificum from beach soil and Ruminococcus albus was isolated from cow rumen. After isolation, novel cellulase and xylanase genes from these anaerobes were cloned and expressed in Escherichia coli. The properties of the cloned enzymes showed that some of them were the components of the enzyme (cellulase) complex, i.e., cellulosome, which is known to form complexes by binding cohesin domains on the cellulase integrating protein (Cip: or core protein) and dockerin domains on the enzymes. Several dockerin and cohesin polypeptides were independently produced by E. coli and their binding properties were specified with BIAcore by measuring surface plasmon resonance. Three pairs of cohesin-dockerin with differing binding specificities were selected. Two of their genes encoding their respective cohesin polypeptides were combined to one gene and expressed in E. coli as a chimeric core protein, on which two dockerin-dehydrogenase chimeras, the dockerin-formaldehyde dehydrogenase and the dockerin-NADH dehydrogenase are planning to bind for catalyzing $CO_2$ reduction to formic acid by feeding NADH. This reaction may represent a novel strategy for the reduction of the green house gases. Enzymes from the anaerobes were also expressed in tobacco and rice plants. The activity of a xylanase from C. stercorarium was detected in leaves, stems, and rice grain under the control of CaMV35S promoter. The digestibility of transgenic rice leaves in goat rumen was slightly accelerated. C. paraputrificum was found to solubilize shrimp shells and chitin to generate hydrogen gas. Hydrogen productivity (1.7 mol $H_2/mol$ glucos) of the organism was improved up to 1.8 times by additional expression of the own hydrogenase gene in C. paraputrficum using a modified vector of Clostridiu, perfringens. The hydrygen producing microflora from soil, garbage and dried pelletted garbage, known as refuse derived fuel(RDF), were also found to be effective in converting biomass waste to hydrogen gas.

• Journal of Korean Society for Geospatial Information Science
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• v.20 no.1
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• pp.53-63
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• 2012

As a result of the economical loss caused by unusual climate changes resulting from emission of excessive green house gases such as carbon dioxide which is expected to account for 5~20% of the world GDP by 2100, researching technologies regarding the reduction of carbon dioxide emission is being favored worldwide as a part of the high value-added industry. As one of the Annex II countries of Kyoto Protocol of 1997 that should keep the average $CO_2$ emission rate of 5% by 2013, South Korea is also dedicated to the researches and industries of $CO_2$ emission reduction. In this study, Application of LiDAR data & KOMPSAT-2 satellite image for calculated forest Biomass. Raw LiDAR data's tree numbers and tree-high with field survey data resulted in 90% similarity of objects and an average of 0.3m difference in tree-high. Calculating the forest biomass through forest type information categorized as KOMPSAT-2 image and LiDAR data's tree-high data of tree enabled the estimation of $CO_2$ absorption and forest biomass of forest type, The similarity between the field survey average of 90% or higher were analyzed.

• Korean Journal of Microbiology
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• v.52 no.3
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• pp.365-374
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• 2016

In high-latitude regions, temperature has risen ($0.6^{\circ}C$ per decade) and this leads to the increase in microbial degradability against soil organic carbon (SOC). Furthermore, the decomposed SOC is converted into green-house gases ($CO_2$ and $CH_4$) and their release could further increase the rate of climate change. Thus, understanding the microbial diversity and their functions linked with SOC degradation in soil-thawing model is necessary. In this study, we divided tundra soil from Council, Alaska into two depth regions (30-40 cm and 50-60 cm of depth, designated as SPF and PF, respectively) and incubated that for 108 days at $0^{\circ}C$. A total of 111,804 reads were obtained through a pyrosequencing-based metagenomic study during the microcosm experiments, and 574-1,128 of bacterial operational taxonomic units (OTUs) and 30-57 of archaeal OTUs were observed. Taxonomic analysis showed that the distribution of bacterial taxa was significantly different between two samples. In detail, the relative abundance of phyla Actinobacteria and Firmicutes largely increased in SPF and PF soil, respectively, while phyla Crenarchaeota was increased in both soil samples. Weight measurement and gel permeation chromatography of the SOC extracts demonstrated that polymerization of humic acids, main component of SOC, occurred during the microcosm experiments. Taken together our results indicate that these bacterial and archaeal phyla could play a key function in SOC degradation and utilization in cold tundra soil.