• Title/Summary/Keyword: Green composites

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The Physical and Thermal Properties Analysis of the VOC Free Composites Comprised of Epoxy Resin, and Dicyandiamide (VOC Free Epoxy Resin/Dicyandiamide 경화물의 배합비 변화에 따른 물리적 특성 및 열적특성 분석)

  • Kim, Daeyeon;Kim, Soonchoen;Park, Young IL;Kim, Young Chul;Lim, Choong-Sun
    • Clean Technology
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    • v.21 no.1
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    • pp.76-82
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    • 2015
  • Volatile organic compounds (VOC) free adhesives have been interested by many scientists and engineers due to environmental regulations and the safety of industrial workers. In this work, a series of composites composed with bisphenol A epoxy resin used as solvent, dicyandiamide, and promoter were prepared to investigate the most appropriate molar ratio for steel-steel adhesion. The cured test specimen of each composite were measured with universal testing machine (UTM) to figure out mechanical properties such as tensile strength, Young’s modulus, and elongation. Furthermore, the lap shear strength of the specimen was tested with UTM while impact resistance was measured with Izod impact tester. The composite whose molar ratio of epoxy resin to curing agent is 1 : 0.9 (sample 3), showed better tensile strength, coefficient of elastic modulus, elongation, and impact strength than other composites did. The highest tanδ from dynamic mechanical analysis (DMA) was observed from sample 2 (epoxy resin: dicy = 1 : 0.7) while sample 3 showed slightly lower tanδ than that of 2. The morphology of the fracture surface of the cured composites from SEM showed that the number of subtle lines on the surface caused by impact increase as the contents of amine curing agent accrete. Furthermore, the viscosity change of sample 5 (epoxy resin: dicy = 1 : 1.3) was observed to confirm its storage stability.

Renewable and Sustainable Resource Derived Carbon Neutral Adhesive Materials (재생 및 지속사용 가능 자원 유래 탄소 중립형 접착소재)

  • Kim, Baekjin;Kim, Sangyong;Cho, Jin Ku;Lee, Sang-Hyeup;Kim, Hyun-Joong
    • Journal of Adhesion and Interface
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    • v.11 no.2
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    • pp.76-83
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    • 2010
  • The extensive use of fossil resources over the past century resulted in dwindling supply and surging price of oil and it is strongly suspected that irreversible global climate change might be due to carbon dioxide emitted from combustion of fossil carbons. With this regard, much attention is recently paid to renewable and sustainable resources as alternatives to petroleum. In this review, we considered a range of efforts to replace petroleum-derived chemicals, particularly adhesive materials with renewable and sustainable plant-based biomass feedstock.

Large amplitude free vibration analysis of laminated composite spherical shells embedded with piezoelectric layers

  • Singh, Vijay K.;Panda, Subrata K.
    • Smart Structures and Systems
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    • v.16 no.5
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    • pp.853-872
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    • 2015
  • Numerical analysis of large amplitude free vibration behaviour of laminated composite spherical shell panel embedded with the piezoelectric layer is presented in this article. For the investigation purpose, a general nonlinear mathematical model has been developed using higher order shear deformation mid-plane kinematics and Green-Lagrange nonlinearity. In addition, all the nonlinear higher order terms are included in the present mathematical model to achieve any general case. The nonlinear governing equation of freely vibrated shell panel is obtained using Hamilton's principle and discretised using isoparametric finite element steps. The desired nonlinear solutions are computed numerically through a direct iterative method. The validity of present nonlinear model has been checked by comparing the responses to those available published literature. In order to examine the efficacy and applicability of the present developed model, few numerical examples are solved for different geometrical parameters (fibre orientation, thickness ratio, aspect ratio, curvature ratio, support conditions and amplitude ratio) with and/or without piezo embedded layers and discussed in details.

A Study on the Si-SiC Composites Fabricated by Pressureless Powder Packing Forming Method (무가압 분말 충전 성형법에 의해 제조된 Si-SiC 복합체에 관한 연구)

  • 박정현;임은택;성재석;최헌진;이준석
    • Journal of the Korean Ceramic Society
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    • v.32 no.6
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    • pp.710-718
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    • 1995
  • The new forming method, Pressureless Powder Packing Forming Method was applied to the manufacturing of reaction sintered SiC. After the experiments of vibratory powder packing and binder infiltration, the abrasive SiC powder of which mean size is 45${\mu}{\textrm}{m}$ was selected to this forming method. Uniform green bodies with porosity of 45% and narrow pore size distribution could be formed by this new forming method. Also, complex or varied cross-sectional shapes could be easily manufactured through the silicone rubber mould used in this forming method. Maximum 15 wt% amorphous carbon was penetrated into green body by multi impregnation-carbonization cycles. And reaction-bonded SiC was manufactured by infiltration of SiC-carbon shaped bodies with liquid silicon.

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Behaviour of FRP composite columns: Review and analysis of the section forms

  • Rong, Chong;Shi, Qingxuan;Zhao, Hongchao
    • Advances in concrete construction
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    • v.9 no.2
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    • pp.125-137
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    • 2020
  • As confining materials for concrete, steel and fibre-reinforced polymer (FRP) composites have important applications in both the seismic retrofit of existing reinforced concrete columns and in the new construction of composite structures. We present a comprehensive review of the axial stress-strain behaviour of the FRP-confined concrete column. Next, the mechanical performance of the hybrid FRP-confined concrete-steel composite columns are comprehensively reviewed. Furthermore, the results of FRP-confined concrete column experiments and FRP-confined circular concrete-filled steel tube experiments are presented to study the interaction relationship between various material sections. Finally, the combinations of material sections are discussed. Based on these observations, recommendations regarding future research directions for composite columns are also outlined.

Manufacturing of W-Cu and Mo-Cu Sheet by Tape Casting Method (Tape Casting법을 이용한 W-Cu, Mo-Cu 박판소재 제조)

  • Park, Chi-Wan;Jang, Gun-Eik;Kim, Tae-Hyoung;Woo, Yong-Won
    • Journal of the Korean Society for Heat Treatment
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    • v.17 no.5
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    • pp.293-298
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    • 2004
  • For the application of heat sink device, the green sheets of powder of W-XCu and Mo-XCu composites were fabricated by tape casting technique. The mixing ratio of powder and binder was 6:4. The green sheet was shrinked up to 10~20% after sintering and the maximum relative density was above 95%. Thermal conductivity and Thermal expansion systematically increased with increasing Cu contents. The maximum thermal conductivity of W-20wt.%Cu was about 206[W/mK].

Studies on the Application and Characteristics of IR for Footwear (IR 고무의 특성(特性) 및 고무화류(靴類)에 활용(活用)하는데 관(關)한 연구(硏究))

  • Kwak, Byung-Kil
    • Elastomers and Composites
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    • v.9 no.1
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    • pp.5-13
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    • 1974
  • The characteristics of IR and IR blended elastomers, for footwear by means of blending with NR and SBR, have been studied. The results obtained were as follows: 1. The mastication of IR was almost not required, where as NR and SBR are necessary. Therefore mixing time was much reduced because of speedy filler feeding. 2. Disadvantage of low Mooney viscosity was covered by blending with NR and SBR, and by loading filler. Superior flow property in comparison to other polymers was worthy and valuable in providing formulas for mould flow, 3. The elongation property of green stocks and vulcanizates was shown smooth surface for extruded and calendered stocks, and facilitated fabrication processes. 4. Because of slow vulcanization, IR is required to control vulcanization time by adding proper accelerators. This property, in turn, made possible to improve the storing stability of green stocks by controlling scorch time.

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Analysis for Measuring the Thermal Diffusivity of Multilayered Composites in Flash Method (다층복합재료의 열확산계수를 섬광법으로 측정하기 위한 해석)

  • Lee, K. S.
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.7 no.4
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    • pp.477-482
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    • 1983
  • 섬광법의 응용범위를 증대하기 위하여 시편 저, 후면에서 복사와 대류 열손실이 있고, 전면에 임 의 열원이 가해지는 3층 복합재료의 열확산 방정식을 Green 함수를 도입하여 해석하였다. 본 해 석결과는 고체 재료를 1층 재료로 표면처리를 실시한 얇은 층 또는 코오팅 재료를 2층재료로, 용 기내에 들어있는 액체나 기체를 3층 재료로 하여 저온으로부터 고온에 이르기까지 광범위한 온 도에 걸쳐 열확산 계수를 구하는데 응용될 수 있다.

Fabrication of Glass-Ceramic Composites by Selective Laser Sintering of Alumina-Glass Powder Blends (알루미나와 글래스 분말의 선택적 레이저 소결에 의한 글래스-세라믹 복합재료의 제조)

  • Lee, In-Seop
    • Korean Journal of Materials Research
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    • v.8 no.7
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    • pp.628-633
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    • 1998
  • 단사정 HBO2 분막을 무기접착제로 이용하여 선택적 레이저 소결 기술을 적용시켜 알루미나-글래스 복합재료를 제조하였다. 만들어진 green SLS 시험편을 여러 온도에서 열처리하여 글래스-세라믹 복합재료를 얻었다. 글래스의 양이 많을수록 복합재료는 높은 밀도와 높은 굽힘강도를 보여주었다. 열처리 온도 $900^{\circ}C$에서 복합재료는 최대 밀도와 최대 강도를 나타낸다. 이것은 글래스의 낮은 점도로 인한 좋은 유동성 때문에 글래스의 재분배가 이루어졌기에 가능하다고 생각되어진다. 그리고 기공이 많은 열처리한 SLS 시험편에 콜로이드 실리카를 주입시켜 치밀화시켰다.

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The Improvement of Interlaminar Shear Strength for Low Density 2-D Carbon/Carbon Composites by Additives (첨가제에 의한 저밀도 2-D 탄소/탄소 복합재의 층간전단강도 개선)

  • 손종석;정구훈;주혁종
    • Polymer(Korea)
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    • v.24 no.6
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    • pp.845-853
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    • 2000
  • The optimum cure cycle and carbonization condition were selected by the DSC and TGA analysis and green bodies were prepared by the method of hot press molding and then carbonized up to 140$0^{\circ}C$. Additives such as graphite powder, carbon black, milled carbon fiber and carbon fiber mat, which were considered to be effective in improving the interlaminar shear strength, were also added to check their effects on the density and porosity of products. Then, their relations with mechanical properties such as ILSS and flexural strength were investigated. The composites added 9 vol% of graphite powder showed the greatest values of ILSS and flexural strength. Otherwise, in case of adding carbon black, the composites showed the slight improvement of ILSS at its contents of 3 vol% but the flexural strength was decreased. When milled carbon fiber and carbon fiber mat were added, the lack of resin and the heat shrinkage during the carbonization caused the delamination, resulting in decreasing the density, ILSS and flexural strength.

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