• Title/Summary/Keyword: Green composites

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Microstructures Of Continuously Porous SiC-Si3N4 Composites Fabricated Using Waste SiC Sludge (폐 SiC 슬러지를 이용하여 제조한 연속다공질 SiC-Si3N4 복합체의 미세조직)

  • Gain Asit Kumar;Lee Hee-Jung;Jang Hee-Dong;Lee Byong-Taek
    • Korean Journal of Materials Research
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    • v.15 no.3
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    • pp.177-182
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    • 2005
  • Large amounts of the waste SiC sludge containing small amounts of Si and organic lubricant were produced during the wire cutting process of the single silicon crystal ingots. The waste SiC sludge was purified by the washing process and the purified SiC powders were used to fabricate continuously porous $SiC-Si_3N_4$ composites using a fibrous monolithic process, in which carbon, $6wt\%\;Y_2O_3-2\;wt\%\;A1_2O_3$ and ethylene vinyl acetate were added as a pore-forming agent, sintering additives, and binder, respectively. In the burning-out process, carbon was fully removed and continuously porous $SiC-Si_3N_4$ composites were successfully fabricated. The green bodies containing SiC, Si particles and sintering additives were nitrided at $1410^{\circ}C$ in a flowing $N_2+10\%\;H_2$ gas mixture. Continuously porous composites were combined with SiC, ${\alpha}Si_3N_4,\;\beta-Si_3N_4$ and a few $\%$ of Fe phases. The pore size of the 2nd and the 3rd passed $SiC-Si_3N_4$ composites was $260\;{\mu}m$ and $35\;{\mu}m$ in diameter, respectively.

Interfacial Evaluation of Flax and Hemp Fibers/Polypropylene Composites Using Micromechanical Test and Acoustic Emission (Micromechanical 시험법과 음향방출을 이용한 Flax 와 Hemp섬유 강화된 Polypropylene 복합재료의 계면 물성 평가)

  • Son, Tran-Quang;Hwang, Byung-Sun;Park, Joung-Man
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2005.04a
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    • pp.42-45
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    • 2005
  • Interfacial evaluation of various combinations of both Flax and Hemp fibers/polypropylene were performed by using micromechanical test and nondestructive acoustic emission (AE). It can be because interfacial adhesion between the natural fiber surface and matrix plays an important role in controlling the overall mechanical properties of polymer composite materials by transferring the stress from the matrix to the fiber. It is necessary to characterize the interphase and the level of adhesion to understand the performance of the composites properly. Microfailure mechanism of single Flax fiber bundles were investigated using the combination of single fiber tensile test and nondestructive acoustic emission. Microfailure modes of the different natural fiber/polypropylene systems were observed using optical microscope and determined indirectly by AE and their FFT analysis.

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A Study on the Mechanical, Thermal, Morphological, and Water Absorption Properties of Wood Plastic Composites (WPCs) Filled with Talc and Environmentally-Friendly Flame Retardants (친환경 난연제와 탈크를 첨가한 목재·플라스틱 복합재의 기계적, 열적, 형태학적 및 수분흡수 특성에 관한 연구)

  • Lee, Danbee;Kim, Birm-June
    • Journal of the Korea Furniture Society
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    • v.27 no.2
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    • pp.137-144
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    • 2016
  • Wood plastic composite (WPC) is a green composite made of wood flour and thermoplastics to provide better performance by removing the defects of both wood and plastics. However, relatively low thermal stability and poor fire resistance of wood and plastics included in WPC have been still issues in using WPC as a building material for interior applications. This study investigated the effect of environmentally-friendly flame retardants (EFFRs) on the mechanical, thermal, morphological, and water absorption properties of wood flour (WF)/talc/polypropylene (PP) composites in comparison with neat PP. The whole EFFRs-filled WF/talc/PP composites showed higher values in flexural strength, flexural modulus, and impact strength compared to neat PP. In thermal properties, aluminum hydroxide (AH)-filled composite showed a $36^{\circ}C$ reduction in maximum thermal decomposition temperature ($T_{max}$) compared to neat PP, but magnesium hydroxide (MH) played an important role in improving thermal stability of filled composite by showing the highest $T_{max}$. From this research, it can be said that MH has potentials in reinforcing PP-based WPCs with improvement of thermal stability.

Effect of fly ash and metakaolin on the properties of fiber-reinforced cementitious composites: A factorial design approach

  • Sonebi, Mohammed;Abdalqader, Ahmed;Fayyad, Tahreer;Amaziane, Sofiane;El-Khatib, Jamal
    • Computers and Concrete
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    • v.29 no.5
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    • pp.347-360
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    • 2022
  • Fiber-reinforced cementitious composites (FRCC) have emerged as a response to the calls for strong, ductile and sustainable concrete mixes. FRCC has shown outstanding mechanical properties and ductility where special fibres are used in the mixes to give it the strength and the ability to exhibit strain hardening. With the possibility of designing the FRCC mixes to include sustainable constituents and by-products materials such as fly ash, FRCC started to emerge as a green alternative as well. To be able to design mixes that achieve these conflicting properties in concrete, there is a need to understand the composition effect on FRCC and optimize these compositions. Therefore, this paper aims to investigate the influence of FRCC compositions on the properties of fresh and hardened of FRCC and then to optimize these mix compositions using factorial design approach. Three factors, water-to-binder ratio (w/b), mineral admixtures (total of fly ash and metakaolin by cement content (MAR)), and metakaolin content (MK), were investigated to determine their effects on the properties of fresh and hardened FRCC. The results show the importance of combining both FA and MK in obtaining a satisfactory fresh and mechanical properties of FRCC. Models were suggested to elucidate the role of the studied factors and a method for optimization was proposed.

Green Blends and Composites from Renewable Resources

  • Yu, L.;Petinakis, S.;Dean, K.;Bilyk, A.;Wu, D.
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.216-216
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    • 2006
  • A special group of polymers, those from renewable resources, has attracted an increasing amount of attention over the last two decades, due to two major reasons: environmental concerns and the limitations of our finite petroleum resources. Generally, polymers from renewable resources (PFRR) can be classified into three groups: (1) natural polymers, such as starch, protein and cellulose; (2) synthetic polymers from natural monomers, such as polylactic acid (PLA); and (3) polymers from microbial fermentation, such as polyhydroxybutyrate (PHB). Like many other petroleum based polymers, various properties of PFRR are also vastly improved through blending and composites formation.

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The Processing and Mechanical Performance of Cellulose Nanofiber-based Composites

  • Nakagaito, Antonio Norio;Takagi, Hitoshi;Pandey, Jitendra Kumar
    • International Journal of Ocean System Engineering
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    • v.1 no.4
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    • pp.180-184
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    • 2011
  • Nanocomposites based on cellulose nanofibers have been studied for a considerable time since its first introduction, however real applications seem to have hardly developed to these days. The high-strength of cellulose nanofibers suggests the potential to reinforce plastics to produce composites for semi-structural or even structural applications. This paper discusses some of the attempts to produce such high-strength nanocomposites and the main challenges that have to be overcome to bring them into commercial products.

Effect of Red Garlic-Composites on the Fecal Lipid Level and Hepatic Antioxidant Enzyme Activity in Rats Fed a High Fat-Cholesterol Diet (홍마늘 복합물이 고지방-콜레스테롤 식이성 흰쥐의 분변 지질 함량 및 간 조직의 항산화 효소 활성에 미치는 영향)

  • Lee, Soo-Jung;Kwon, Min-Hye;Kwon, Hyo-Jin;Shin, Jung-Hye;Kang, Min-Jung;Kim, Sung-Hee;Sung, Nak-Ju
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.42 no.1
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    • pp.17-25
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    • 2013
  • This study was performed to investigate the effects of the hot water extract of red garlic (RG) and RG-composites on fecal lipid levels and hepatic antioxidant enzyme activity in rats fed a high fat-cholesterol diet. Three different types of RG-composites prepared: RG and green tea (RGT), RG and dietary fiber (RGF), and RG, green tea, and dietary fiber (RGTF). Rats were divided into six groups: the control, the group fed a high fat-cholesterol diet (HFC), the RG-supplemented group (HRG), the RGT supplemented group (HRGT), the RGF supplemented group (HRGF), and the RGTF supplemented with HFC group (HRGTF). The antioxidant activity of these composites was tested, in vitro. The DPPH radical scavenging activity was higher RGT and RGTF than RG. ABTs radical scavenging activity of RGT was similar to RGTF. Their activities were significantly higher than RG. The reducing power was similar to their radical scavenging activities. Total lipid levels in the liver and triglyceride levels in the heart were lower in the groups fed RG-composites than the HRG group. Fecal total lipid level was higher in the HRGF and HRGTF groups than the HRG group after 4 weeks diet supplementation during 4 weeks. Lipid peroxide content was reduced to anywhere between 6.2% and 12.1% in the groups fed RG-composites, compared to the HFC group. Antioxidant activity was significantly higher in the groups fed RG-composites than the HFC group. Hepatic SOD activity was higher in the groups fed RG-composites than the HRG group. The HRGT group in catalase activity, and the HRGT and HRGTF groups in GSH-px activity were increased significantly compared to the HFC group. Hepatic UDPGT activity was increased significantly in the HRGT and HRGTF groups to the HFC group, as well. These results indicate that antioxidant activities of the RG-composites were related to the decrease of lipid levels by increasing the fecal excretion and enhancement of hepatic antioxidant enzyme activity in rats fed a high fat-cholesterol diet.

Epoxy Matrix with Adding Dopamine for Improving Mechanical Property and Interfacial Adhesion with Glass Fiber (도파민이 첨가된 에폭시 기지재의 기계적 물성 및 유리섬유 간 계면접착력 향상)

  • Shin, Pyeong-Su;Kim, Jong-Hyun;Baek, Yeong-Min;Park, Ha-Seung;Park, Joung-Man
    • Composites Research
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    • v.32 no.2
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    • pp.96-101
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    • 2019
  • Interfacial adhesion between fiber and resin are related to composites performance, so it is very important to evaluate them accurately. In this study, the interfacial properties of microdroplets under fatigue loading conditions were evaluated. The mechanical properties and interfacial adhesion of epoxy resin with dopamine were studied. Tensile specimens were prepared to evaluate mechanical properties and epoxy microdroplets specimens were used for the evaluation of interfacial adhesion. In addition, in the microdroplet fatigue test, the same diameter of the microdroplet was used and the experiment was performed under the same conditions. As a result, it was confirmed that mechanical and interfacial properties were improved when dopamine was applied to epoxy resin through tensile and microdroplet experiments. It is considered that dopamine improves the degree of curing of the epoxy resin and imparts hydroxyl groups to the epoxy resin to increase the mechanical properties and the interfacial adhesion between the glass fibers.

Flame Retardancy and Physical Properties of Ethylene Vinyl Acetate/Aluminum Trihydroxide Composites (에틸렌 비닐아세테이트/수산화알루미늄 복합재료의 난연 및 물리적 특성)

  • Lee, Minho;Yu, Dayeong;Kim, Yeongho;Lee, Sunghee;Kim, Jeong Ho;Lee, Young Chul
    • Polymer(Korea)
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    • v.39 no.3
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    • pp.433-440
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    • 2015
  • Aluminum trihydroxide (ATH) has been commonly employed as a flame retardant for ethylene vinyl acetate (EVA) copolymers. In the present work, ATH was obtained from a recycling process of multi-layer packaging film wastes. EVA/ATH composite samples were prepared using a two roll-mill and flame retardancy of EVA/ATH composites were examined using limiting oxygen index (LOI) and flame retardancy test (UL94). We observed excellent flame retardancy in case of adding 150 phr or more of recycled ATH to EVA. Particle size and specific surface area play crucial roles in LOI value and UL-94 classification of the EVA/ATH composites. Smaller particle size and higher specific surface area of ATH was found out to improve the flame retardancy. Regarding tensile properties, crosslinked EVA/ATH compounds which is practically used for electric cables had similar to or even better tensile property values than the ones without ATH.

Relations between Physical Parameters and Improvement of Mechanical Properties in Jute Fiber Green Composites by Maleic Anhydride Coupler (Jute fiber Green Composite의 커플링제에 의한 물리적 인자의 변화와 기계적 특성 향상)

  • Lee, Jung-H.;Byun, Joon-H.;Kim, Byung-S.;Park, Joung-M.;Hwang, Byung-S.
    • Composites Research
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    • v.20 no.1
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    • pp.23-31
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    • 2007
  • In order to improve the mechanical properties of jute fiber/polypropylene(PP) composites, the property change with the addition of a coupling agent, maleic anhydride polypropylene(MAPP) was examined experimentally. The maleated coupler acts as an intermediate to chemically connect the polar nature of the fiber and non-polar nature of the polyolefin polymer resin. Furthermore, the decrease in viscosity of the resin which results from the melting point reduction by the MAPP, leads to an increase of contact area with the fiber interface. We discussed the improvement of the PP composite blend of the maleated coupler with the 80mm jute long fiber mat in conjunction with the change of physical parameters in the thermoplastic resin. We confirmed the extent of contribution to the mechanical physical enhancement by using the following parameters: melting flow index(MI) and viscosity, contact angle, thickness of the composite, interfacial shear strength and morphology observation etc. Especially it was observed that the MI and viscosity, MAPP mixture had a very strong relationship with the tensile and flexural strength and modulus, and interfacial shear strength(IFSS).