• Journal of Korean Society for Atmospheric Environment
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• v.18 no.4
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• pp.285-295
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• 2002

In this study, several types of gravimetric methods (such as high, medium, low, and ultra low volume sampling methods) were applied to determine suspended particulate matter concentrations in both ambient and indoor environments. Comparative evaluations were undertaken with SPM data obtained using a variety of samplers (TSP, PM10, and PM4.0) at different sampling flow rates. Correlation coefficients between TSP and PM10 concentrations measured at different flow rates fell in the range of 0.73∼0.94 (n=40). In addition, correlation coefficients for PM concentrations measured by different TSP samplers were in the range of 0.90∼0.95 (n=36 or n=38), while 0.77∼0.91 (n=38) for PM10 samplers. Correlation analysis was also conducted on indoor monitoring data that were measured using ultra-low-volume samplers at both different or identical flow rates. The correlation coefficients were in the range of 0.98∼0.99 (n=38) between TSP and TSP and 0.92∼0.94 (n=38) between TSP and PM10. The mean ratio for high volume PM10 to TSP concentration that was monitored at identical flow rates in the ambient air appeared to be 0.72. The mean ratios of PM10 to TSP and PM4.0 to TSP observed with identical flow rates at indoor environments were 0.47 and 0.40. The results of this study may provide empirical information concerning the compatability of aerosol data obtained by gravimetric sampling methods at different flow rates.

• Journal of Environmental Impact Assessment
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• v.19 no.4
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• pp.431-441
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• 2010

In this study, inter-comparison for PM-2.5 was undertaken. The PM-2.5 mass concentrations using the gravimetric and beta-attenuation methods were compared during the winter in 2007. Two different types of conventional filter-based measurements (Cyclone type and Impactor type) were also collocated and the measurement data was compared with each other. As a result, continuous PM-2.5 data using beta attenuation method show a comparable mass concentration with gravimetric measurement when the inlet of beta-gauge sampler is heated. The results also showed that the cyclone type shows a little high PM-2.5 concentration than Impactor type. In all the sampling cases, the correlations between measurement methods are high. Subsequently, this study suggests that highly correlated relationship between PM-2.5 measurement instruments can be obtained through the inter-comparison results based on filterb-ased gravimetric method and more intensive measurement and theoretical studies are needed in order to clarify the measurement errors for different sampler types.

• Proceedings of the Korea Air Pollution Research Association Conference
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• 2002.11a
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• pp.276-277
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• 2002

One of drawbacks of the inertial impactor measurement is the required long sampling time (Keskinen et al., 1992). In a gravimetric method, an impaction substrate must be weighed and placed on the corresponding collection plate before being assembled. After sampling, the inertial impactor is disassembled and the collection plate is weighted again. The sampling time depends on the sampled particle mass because the collected particle mass must be sufficiently high to be measured by a sensitive microbalance. (omitted)

• Journal of Environmental Science International
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• v.14 no.1
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• pp.91-96
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• 2005

Several samplers using gravimetric methods such as high-volume air sampler, MiniVol portable sampler, personal environmental monitor(PEM) and cyclone were applied to determine the concentrations of fine particles in atmospheric condition. Comparative evaluation between high-volume air sampler and Minivol portable sampler for $PM_{10}$, and between Minivol portable sampler and PEM was undertaken from June, 2003 to January 2004. Simultaneously, meteorological conditions such as wind speed, wind direction, relative humidity and temperature was measured to check the factors affecting the concentrations of fine particles. In addition, particle concen­trations by cyclone with an aerodynamic diameter of $4{\mu}m$ were measured. Correlation coefficient between high­volume air sampler and portable air sampler for $PM_{10}$ was 0.79 (p<0.001). However, the mean concentration for $PM_{10}$ by high-volume air sampler was significantly higher than that by Minivol portable sampler (p=0.018). Correlation coefficient between Minivol portable sampler and PEM for $PM_{2.5}$ as 0.74 (p<0.001), and the measured mean concentrations for $PM_{2.5}$ did not show significant difference. Difference of the measured con­centrations of fine particle might be explained by wind speed and humidity among meteorological conditions. Particle concentration differences by measurement samplers were proportional to the wind speed, but inversely proportional to the relative humidity, though it was not a significant correlation.

• Journal of Korean Society for Atmospheric Environment
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• v.14 no.1
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• pp.1-10
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• 1998

Relationships between TSP and PM10 concentrations were evaluated using their respective data sets collected from Taegu and Kyeungsan areas during the period of December 1993 to November 1994. The collection of data was made using the gravimetric and $\beta$-ray absorption ($\beta$-MPM) methods for 7 days of every month from three urban sites in Taegu and one suburban site in Kyeungsan. Correlation coefficients between TSP and PM10 concentrations for these four sampling sites were found in the range of 0.85 $\sim$ 0.96. Correlation analysis was also conducted for $\beta$-PM concentration data that were measured only from the residential and commercial sites. The correlation coefficients between TSP and $\beta$-PM concentrations were 0.9 in the residential site and 0.8 in the commercial site. By contrast, the correlation coefficients between PM10 $\beta$-PM concentrations were almost identical for both the residential and commercial sites with a value of 0.88. The mean ratio for PM10 to TSP concentrations for all sites was appeared to be 0.68. The analysis of seasonal trends in PM10/TSP ratios showed that the contribution of PM10 to TSP concentrations was more significant during winter (0.70 $\sim$ 0.75) than during summer (0.61 $\sim$ 0.68). The results of this study may provide empirical informations on the compatability of aerosol data measured by different sampling methods.

• Journal of the Korean Institute of Gas
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• v.19 no.1
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• pp.12-17
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• 2015

The core of the CNG fueling station is the compressor and most of CNG compressors in Korea require lubrication. Lubrication oil of CNG compressor that can be transferred into the pressure regulators and the engines of fueling system can cause a negative effect on NGV(Nature Gas Vehicle) performance during refueling due to oil Carry-over. In order to avoid the problem, it is necessary to enhance the quality of the compressed natural gas by measuring quantitatively the amount of the transferred oil. In this research, a sampling device and sampling tube were developed, which can be used with a gravimetric method of detection to measure CNG oil Carry-over. In addition, CNG samples were taken at 6 pre-selected CNG fueling stations and analysed for their trace oil Carry-over. The measured total oil Carry-over ranged from 2.569 to 6.509 ppm. This test measurements were compared with those of previous studies to verify the results.

• Journal of Korean Society of Occupational and Environmental Hygiene
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• v.16 no.2
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• pp.91-100
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• 2006

The purpose of this study was to validate alternative method by using non-carcinogenic, and less toxic solvents than NIOSH analytical method 5524 for measuring the airborne MWFs in workplaces. In laboratory tests, the ETM solvents(mixture of same volume for ethyl ether, toluene, and ethanol) were selected. The alternative method of analyzing MWFs, referred to as the ETM solvent extraction method, showed 0.04 mg/sample as LOD, and 0.15 mg/sample as LOQ. The analytical precision (pooled CV, coefficient of variation) of the ETM solvent extraction method for analyzing the straight, soluble, semisynthetic, and synthetic metalworking fluid was 1.5%, 2.0%, 2.6%, 1.6%, respectively, which was similar to the precision (2.6%) of NIOSH analytical method (NIOSH 0500) for total dust. The analytical accuracy by recovery test, spiked mass calculated as extractable mass, was almost 100%. As the result of storage stability test, metalworking fluid samples should be stored in refrigerated condition, and be analyzed in two weeks after sampling. The 95% confidence limit of the estimated total standard error for the ETM solvent extraction method for analyzing the straight, soluble, semisynthetic, and synthetic metalworking fluid was ${\pm}12.6%$, ${\pm}12.5%$, ${\pm}14.0%$, and ${\pm}13.6%$, respectively, which satisfied the OSHA sampling and analytical criteria.

• Journal of Environmental Impact Assessment
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• v.19 no.4
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• pp.421-429
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• 2010

The reliability of the measurement of ambient trace species is an important issue, especially, in background area such as Gosan in Jeju Island. In a previous episodic study, it was suggested that the PM10 measurement result by the gravimetric method(GMM) was not in agreement with the result by the ${\beta}$-ray absorption method(BAM). In this study, a systematic comparison was carried out for the data between 2001 and 2008 at Gosan(GMM and BAM) and Jeju city (BAM) which is near to Gosan. It was found that at Gosan the PM10 concentration by BAM was higher than GMM and the correlation between them was low. The BAM results at Gosan and Jeju city showed similar trend implying the discrepancy at Gosan was not caused by instrumental problem of the BAM at Gosan. Based on the previous studies two probable reasons for the discrepancy are identified; (1) negative measurement error by the evaporation of volatile ambient species at the filter in GMM such as nitrate and ammonium and (2) positive error by the absorption of water vapor during measurement in BAM. There was no heater at the inlet of BAM at Gosan during the sampling period. Based on the size-segregated measurement data, it was identified that the evaporation error was minor, if any. The relationship between the two methods did not vary with the ambient relative humidity. Thus, at present, it is not clear why the discrepancy had been occurring and when using the PM10 data at Gosan, one should be aware the possible errors.

• Journal of Korean Society for Atmospheric Environment
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• v.33 no.3
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• pp.277-288
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• 2017

Previous studies of health effects of $PM_{2.5}$ performed spatial monitoring campaigns to assess spatial variability of $PM_{2.5}$ across people's residences. Highly reliable portable and cost-effective samplers will be useful for such campaigns. This study aimed to investigate applicability of the Deployable Particulate Impact Sampler(DPIS), one of the compact impact samplers, to spatial monitoring campaigns of $PM_{2.5}$ in Seoul, Korea. The investigation focused on the consistency of $PM_{2.5}$ concentrations measured by DPISs compared to those by the Low-volume Cyclone sampler (LCS). LCS has operated at a fixed site in the Seoul National University Yeongeon campus, Seoul, Korea since 2003 and provided qualified $PM_{2.5}$ data. $PM_{2.5}$ sampling of DPISs was carried out at the same site from November 17, 2015 through February 3, 2016. $PM_{2.5}$ concentrations were quantified by the gravimetric method. Using a duplicated DPIS, we confirmed the reliability of DPIS by computing relative precision and mean square error-based R squared value ($R^2$). Relative precision was one minus the difference of measurements between two samplers relative to the sum. For accuracy, we compared $PM_{2.5}$ concentrations from four DPISs (DPIS_Tg, DPIS_To, DPIS_Qg, and DPIS_Qo) to those of LCS. Four samplers included two types of collection filters(Teflon, T; quartz, Q) and impaction discs(glass fiber filter, g; pre-oiled porous plastic disc, o). We assessed accuracy using accuracy value which is one minus the difference between DPIS and LCS $PM_{2.5}$ relative to LCS $PM_{2.5}$ in addition to $R^2$. DPIS showed high reliability (average precision=97.28%, $R^2=0.98$). Accuracy was generally high for all DPISs (average accuracy=83.78~88.88%, $R^2=0.89{\sim}0.93$) except for DPIS_Qg (77.35~78.35%, 0.82~0.84). Our results of high accuracy of DPIS compared to LCS suggested that DPIS will help the assessment of people's individual exposure to $PM_{2.5}$ in extensive spatial monitoring campaigns.

• Journal of Korean Society of Occupational and Environmental Hygiene
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• v.11 no.1
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• pp.42-47
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• 2001

The purpose of this study was to investigate for filtration efficiency of several dust masks, comparing with filtration efficiency certified by KOSHA(Korea Occupational Safety & Health Agency), and to require of the right use of protective respirators. Using a welding fume generator and chamber, several dust masks, which were widely used in the workplaces in korea, were tested for their filtering efficiency for stainless steel arc welding fume. The filtration efficiency testing system consisted of a welding fume generator, a chamber and a filtration unit. The filtration unit was made of a mask which was inserted into the sampling cassette and another sampling cassette, which contained mixed cellulose ester filter paper. These two cassettes were connected with tubing. Stainless steel arc welding fume generator was delivered into an chamber. The welding fume in the chamber was passed into the filtration unit with flow rate of 30 liter/min. The welding fume filtration efficiency was evaluated by gravimetric measurement. Metal concentrations in the welding fume before and after filtration were measured with inductive coupling plasma analyzer. Following results were obtained: Filtration efficiency of welding fume for common hygienic mask was 63.82% and the average efficiencies for A, B, C, D, E, F and G masks were 94.62%, 96.58%, 83.20%, 82.76%, 77.25%, 86.55% and 93.22%, respectively. Our results indicate that dust masks used widely in the welding workplaces in korea are not proper for protecting worker's health and then the use of fume mask should be required.