• 제목/요약/키워드: Graphites

검색결과 60건 처리시간 0.028초

石炭의 黑鉛性에 關한 硏究 (第1報) (Studies on the Electric Resistecna of Coals (1))

  • 오신섭;이석원
    • 대한화학회지
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    • 제5권1호
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    • pp.22-25
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    • 1961
  • The attempt to distinguish between graphite and domestic anthracite was means, especially electric resistance. The specific resistance values of various coals and graphites were determined by Wheaston Bridge equipped with more finely adjustable slide wire. The result of graphite was in the below of 0.08 ohm-cm and that of anthracite has $10^{-1}{\sim}10^1$ohm-cm range.

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Expanded Graphite Negative Electrode for Lithium-ion Batteries

  • Yoo, Hyun-D.;Ryu, Ji-Heon;Park, Seong-Ho;Park, Yu-Won;Ka, Bok-H.;Oh, Seung-M.
    • Journal of Electrochemical Science and Technology
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    • 제2권1호
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    • pp.45-50
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    • 2011
  • A series of expanded graphites is prepared from graphite oxide by changing the heat-treatment temperature, and their lithiation/de-lithiation mechanism and rate performance are examined. A featureless sloping profile is observed in their charge-discharge voltage and dilatometry profiles, which is contrasted by the stepwise plateau-like profiles observed with the pristine graphite. With an increase in the heat-treatment temperature from $250^{\circ}C$ to $850^{\circ}C$, the interlayer distance becomes smaller whereas the electric conductivity becomes larger, both of which are resulted from a removal of foreign atoms (mainly oxygen) from the interlayer gaps. The expanded graphite that is prepared by a heat-treatment at $450^{\circ}C$ delivers the best rate performance, which seems to be a trade-off between the $Li^+$ ion diffusivity that is affected by the interlayer distance and electrical conductivity.

팽창흑연/탄소섬유 혼합 보강 전도성 고분자 복합재료의 특성 평가 (Study on Mechanical and Electrical Properties of Expanded Graphite/Carbon fiber hybrid Conductive Polymer Composites)

  • 오경석;허성일;윤진철;한경섭
    • Composites Research
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    • 제20권6호
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    • pp.1-7
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    • 2007
  • 본 연구에서는 팽창흑연/탄소섬유 혼합 보강 전도성 고분자 복합재료를 2단계 성형 공법으로 제조하였으며, 탄소섬유의 첨가가 전도성 고분자 복합재료의 전기적, 기계적 특성에 미치는 영향을 고찰하였다. 전도성 충진재들은 고분자 수지와 기계적으로 혼합되었으며 이를 통하여 복합재료가 전기적 특성을 가지도록 하였다. 팽창흑연은 입자 간 접촉 면적이 넓기 때문에 복합재료 내 전도성 네트워킹의 형성에 매우 유리하지만, 팽창흑연과 고분자 수지만을 사용하여 상기 공정으로 복합재료를 제조할 경우 우수한 기계적 강도를 얻기가 어렵다. 따라서 이를 보완하기 위하여 탄소섬유를 복합재료에 첨가하였으며 전기적 기계적 물성을 바탕으로 탄소섬유의 혼합 비율을 최적화하였다. 굽힘 강도는 탄소섬유의 충친 비율이 증가할수록 섬유에 의한 강화 효과에 의하여 증가 하지만, 32wt.% 이상에서는 오히려 감소하였다. 이는 여분의 탄소섬유들이 공극을 발생시켜 응력집중이 발생하기 때문으로 판단된다. 전기 전도도는 탄소섬유의 비율이 증가할수록 전도성 공백이 발생하고 팽창흑연의 전도성 네트워킹이 저해되기 때문에 계속 감소한다.

구상흑연주철의 기계적 성질및 피로특성에 관한 연구 (A study on Mechanical and Fatigue Properties of Spheroidal Graphite Cast Iron)

  • 박노광;김창주;전의진
    • 한국기계연구소 소보
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    • 통권9호
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    • pp.83-93
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    • 1982
  • The influence of different heat treatment conditions on microstructure, mechanical and fatigue properties of Spheroidal Graphite cast Iron with 0.4-0.6% Mn was investigated. 1) Maximum tensile strength was arrived by tempering at about $450^{\circ}C$after quenching. Tempering at higher than $600^{\circ}C$ was changed martensitic structure to ferritic structure and secondary graphites were precipitated. 2) The relationship between matrix hardness and total hardness of the specimens are as following. [HB]$T$=0.7[HB] [HB]$M$+35 Maximum tensile strength was arrived at the total hardness of HB400-450. 3) Endurance ratio decreases with increasing total hardness, and fatigue limits can be presumed from as following. $\sigmaf$=$\sigmat$

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Preparation of zirconia coated graphite powders

  • Kim, J.H.;Lee, K.G.;Lee, S.K.
    • 한국결정성장학회:학술대회논문집
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    • 한국결정성장학회 1997년도 Proceedings of the 12th KACG Technical Meeting and the 4th Korea-Japan EMGS (Electronic Materials Growth Symposium)
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    • pp.45-48
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    • 1997
  • ZrO$_2$ coated flake graphite powders were prepared by the controlled hydrolysis of zirconium oxichloride. The stirring process plays an important role in the coating process. There are two types of coated ZrO$_2$ particles: (a)primary particles with few nm size were obtained by the direct formation of the shell by precipitation of the surface of the graphite and (b) Secondary particles of ZrO$_2$ with ∼0.1$\mu\textrm{m}$ size were obtained by the independent formation of primary particles ZrO$_2$ and subsequent heterocoagulation at the graphites surface.

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低質炭의 利用硏究 (第一報) 無燃固體燃料의 燃燒速度의 測定) (Studies on the Utilization of Low Quality Coals (1) Determination of combustion velocity of smokeless solid fuels)

  • 오신섭;김정혁
    • 대한화학회지
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    • 제4권1호
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    • pp.78-80
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    • 1957
  • Up to now, only superficial studies on the combustion velocity of smokeless fuels have been reported, while it should be a basical factor on the utilization of low quality coals and some other smokeless solid fuels. It was, therefore, difficult to choose raw material coals in manufacturing gaseous fuels. With the intent to solve above problem, we have determined combustion velocity of domestic anthracites, graphites, coalites of lignite and cokes from Japanese bituminous coal. The results show that the cokes from Japanese bituminous coal which has been used as raw material in the manufacturing gaseous fuels such as water gas, or producer gas in Korea can be replaced by some sources of domestic anthracite or coalite of lignite.

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저 열팽창 주철의 진동감쇠능에 미치는 흑연 및 탄화물의 영향 (Effects of Graphites and Carbides on the Specific Damping Capacity of Low Thermal Expansion Cast Irons)

  • 문병문;홍준표
    • 한국주조공학회지
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    • 제17권1호
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    • pp.51-57
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    • 1997
  • Effects of the amount of flake type graphite, morphology and (V,Mo)carbides on the specific damping capacity of austenitic low thermal expansion cast irons were investigated. Specific damping capacity(SDC) of low thermal expansion cast irons increased with the increased amount of graphite. Specific damping capacity of low thermal expansion cast iron decreased with the increased Young's modulus. In the case of V and Mo addition, SDC decreased with the increased amount of carbides. Specific damping capacity increased about 2% by the movement of magenetic domains which appeared in ferromagnetic materials.

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$CO_2$ 레이저 분산빔에 의한 표면경화가 구상흑연주철의 피로특성에 미치는 영향 (Effects of surface hardening by using $CO_2$ laser defocussed beam on the fatigue resistance of ductile irons)

  • 박근웅;한유희;이상윤
    • 한국레이저가공학회지
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    • 제2권2호
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    • pp.42-51
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    • 1999
  • This study has been performed to investigate into some effects of the output power and traverse speed of laser beam on the microstructures, hardness and fatigue resistance of the ductile iron surface-hardened by $CO_2$ laser defocussed beam. Optical micrographs have shown that with increasing the output power and decreasing the traverse speed, the martensite was coarsened and some retained austenite were appeared in ductile iron. The microstructures of hardening zone were composed of bull's eye and some nodular graphite dissolved structures by the effect of self quenching. Fatigue fracture characteristics of ductile iron have appeared in the high stress and low stress ranges. The fracture initiated at nodular graphites in the surface hardened layer due to the stress concentration caused by a notch effect. The interior graphite nodules were broken away or popped out during crack propagation. Fatigue test has shown that values of fatigue strength considerably increased with increasing output power at a given traverse speed.

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주철의 가스질화침탄처리 (A Study on the Gaseous Nitrocarburising of Cast Irons)

  • 김영희;윤희재
    • 열처리공학회지
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    • 제16권2호
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    • pp.71-77
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    • 2003
  • We investigate the phase formation in the compound layer of cast irons during the gaseous nitrocarburising of four different cast irons, that contain different types of graphites in the shape and size. We examine the change in the surface roughness with the nitrocarburising time. The observation of cross-sectional microstructure and X-ray diffraction analysis indicate that the compound layer consists of single ${\varepsilon}-Fe_{2-3}(N,C)$ phase and that its thickness increases in a parabolic manner with the treatment time. The surface roughness parameters, Rz and Ra increase with increasing treatment time. In other words, the roughness parameters increase as the thickness of compound layer increases. The parameters also depend on the shape and size of graphite in the individual cast irons.