• Title/Summary/Keyword: Graphite plate

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Manufacture and Evaluation of Small Size PEMFC Stack Using Carbon Composite Bipolar Plate (탄소복합소재 분리판을 이용한 소형 고분자전해질 연료전지 스택 제작 및 성능분석)

  • Han, C.;Choi, M.;Lee, J.J.;Lee, J.Y.;Kim, I.T.;An, J.C.;Shim, J.;Lee, H.K.
    • Journal of the Korean Electrochemical Society
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    • v.13 no.2
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    • pp.81-88
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    • 2010
  • Small size polymer electrolyte membrane fuel cell (PEMFC) stacks were prepared using carbon composite and graphite bipolar plates and their performances were evaluated on reactant gas and operating time. In comparison to single cell and stack, it was identified that home-made bipolar plate was well-designed to maximize stack performance as high as that of single cell. During long-term operation, the performances of stacks using two different kinds of bipolar plates were compared. The decrease of performance in both stacks was accelerated with increasing load current. It was observed from stack test that the stack performance using carbon composite bipolar plate was very similar to that using graphite bipolar plate.

Thermal Strain and Temperature Measurements of Structures by Using Fiber-Optic Sensors (광섬유 센서를 이용한 구조물의 열변형 및 온도 측정)

  • 강동훈;강현규;류치영;홍창선;김천곤
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2000.04a
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    • pp.184-189
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    • 2000
  • Two types of fiber-optic sensors, EFPI(extrinsic Fabry-Perot interferometer) and FBG(fiber Bragg grating), have been investigated for measurement of thermal strain and temperature. The EFPI sensor is only for measurement of thermal strain and the FBG sensor is for simultaneous measurement of thermal strain and temperature. FBG temperature sensor was developed to measure strain-independent temperature. This sensor configuration consists of a single-fiber Bragg grating and capillary tube which makes it isolated from external strain. This sensor can then be used to compensate for the temperature cross sensitivity of a FBG strain sensor. These sensors are demonstrated by embedding them into a graphite/epoxy composite plate and by attaching them on aluminum rod and unsymmetric graphitelepoxy composite plate. All the tests were conducted in a thermal chamber with the temperature range $20-100^{\circ}C$. Results of strain measurements by fiber-optic sensors are compared with that from conventional resistive foil gauge attached on the surface.

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Actuating Characteristics of a Piezoceramic fiber Composite Actuator (압전섬유 복합재 엑츄에이터의 거동 특성)

  • Koo, Kun-Hyung;Kim, Cheol
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2001.10a
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    • pp.53-56
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    • 2001
  • Piezoelectric Fiber Composites with Interdigitated Electrodes (PFCIDE) were previously introduced as an alternative to monolithic wafers with conventional electrodes for applications of structural actuation. This paper is an investigation into the performance improvement of piezoelectric fiber composite actuators by changing the matrix material and actuator shape. This paper presents a modified micro-electromechanical model and numerical analyses of piezoelectric fiber/piezopolymer matrix composite actuator with interdigitated electrodes (PFPMIDE). Numerical analyses show that the shape of the graphite/epoxy composite plate with the PFPMIDE may be controlled by judicious choice of voltages, piezoelectric fiber angles, and elastic tailoring of the composite plate.

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A Study on the Vacuum Casting of Poly-Si Wafer (다결정 Si 기판의 진공주조법에 관한 연구)

  • Lee, Geun-Hee;Lee, Zin-Hyoung
    • Journal of Korea Foundry Society
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    • v.20 no.3
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    • pp.188-196
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    • 2000
  • A vacuum casting was proposed as a new fabrication method of Si wafer for solar cell substrate. It was tried to fabricate a Si plate with good properties and to reduce the production cost by direct vacuum casting. By $5{\sim}10$ cmHg of pressure difference Si plate with $50{\times}46{\times}1.5\;mm^3$ was fabricated. For the preventing of the reaction between graphite mold and Si melt, BN powder coating or BN insert were used. The Si wafer was poly crystalline with 100 ${\mu}m{\sim}1$ mm order of grain size. And there were some twins and dislocations in the grains.

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Development of Cermet Cutting Tool by Powder Injection Molding

  • Chung, Seong-Taek;Kwon, Young-Sam
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09a
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    • pp.493-494
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    • 2006
  • Chip breaker of cutting tool is an important feature to enhance cutting performance. Powder injection molding process was used to produce a triangular-shape cermet grooving insert which has three chip breakers. Attrition milled cermet powders were mixed with wax-based binder system in continuous twin screw extruder. Three-plate injection mold with slide cores was used to produce injection-molded parts. After molding, solvent and thermal debinding was carried out. Sintering was conducted in a batch furnace with a graphite heater. The sintered parts satisfy the requirements of dimensional tolerances and material properties.

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Commercializing Technology Development of Bipolar Plates for Polymer Electrolyte Membrane Fuel Cell (고분자연료전지용 분리판 상용화 기술개발)

  • Kim, Jeong-Heon
    • Transactions of the Korean hydrogen and new energy society
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    • v.22 no.3
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    • pp.409-414
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    • 2011
  • To promote the industry of PEMFC, the commercialization of its parts especially bipolar plate is needed. The bipolar plate is one of key parts for PEMFC, which occupies cost portion of 5~8% in the system. To replace the bipolar plate of machined graphite highly costly, the stamped thin matal or the molded carbon composite has been developed. According to the merits and demerits of each material and its forming process, the stamped metallic plate has been considered to the bipolar plate of PEMFC for automotive, and on the other hand, the molded composite plate has been considered to one for building applications. Hankook Tire Co., Ltd. has developed the carbon composite material and the manufacturing process for the bipolar plates. The developed bipolar plates were proved to be fully applicable to PEMFC of building applications in characteristics and performance, and so government strategic project to develop the mass-production technology for bipolar plates was started and is being conducted by the company. Through the government project for obtaining both the commercialization technology and production capacity for the bipolar plates, the price and the performance of domestic PEMFCs are expected to become competitive in international market.

Development of Bipolar Plate Stack Type Microbial Fuel Cells

  • Shin, Seung-Hun;Choi, Young-jin;Na, Sun-Hee;Jung, Seun-ho;Kim, Sung-hyun
    • Bulletin of the Korean Chemical Society
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    • v.27 no.2
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    • pp.281-285
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    • 2006
  • Microbial fuel cells (MFC) stacked with bipolar plates have been constructed and their performance was tested. In this design, single fuel cell unit was connected in series by bipolar plates where an anode and a cathode were made in one graphite block. Two types of bipolar plate stacked MFCs were constructed. Both utilized the same glucose oxidation reaction catalyzed by Gram negative bacteria, Proteus vulgaris as a biocatalyst in an anodic compartment, but two different cathodic reactions were employed: One with ferricyanide reduction and the other with oxygen reduction reactions. In both cases, the total voltage was the mathematical sum of individual fuel cells and no degradation in performance was found. Electricity from these MFCs was stored in a supercapacitor to drive external loads such as a motor and electric bulb.

A Study on the Performance of the Polymer Electrolyte Membrane Fuel Cell Using the Metal Bipolar Plates (금속분리판을 이용한 고분자전해질 연료전지의 성능에 관한 연구)

  • Jeon, U.-S.;Cho, E.A.;Ha, H.-Y.;Hong, S.-A.;Oh, I.-H.
    • Transactions of the Korean hydrogen and new energy society
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    • v.13 no.4
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    • pp.313-320
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    • 2002
  • The characteristics of the AISI bipolar plates have been investigated to replace the expensive graphite bipolar plates. It was found from the contact resistance evaluation of graphites, composites, and AISI that the contact resistance of AISI was the lowest, but it could approach to that of composites at higher compression forces. The single cell operation using the AISI bipolar plates revealed that the lower performance of the AISI single cell compared to the graphite one was due to not only the higher contact resistance but the flooding effect caused by high wettability of AISI. The performance of the AISI single cell could be improved if the channels were modified appropriately. The large size AISI single cell was operated to investigated the size effect on the performance.

Development of surface treatment materials for improving durability of metallic bipolar plates in PEMFC (연료전지용 금속분리판 내구성 향상을 위한 표면처리기술 개발)

  • Kim, Myong-Hwan;Goo, Young-Mo;Yoo, Seung-Eul
    • 한국신재생에너지학회:학술대회논문집
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    • 2008.05a
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    • pp.41-44
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    • 2008
  • 본 연구에서는 고분자 전해질 연료전지용 금속분리판의 전기화학적 부식을 방지하기 위한 금속 첨가 DLC(Diamond-like-carbon) 표면처리 방법을 개발하였으며, stainless steel 304를 모재로 하여 텅스텐 첨가 DLC, 티타늄 첨가 DLC, 몰리브덴 첨가 DLC 금속분리판을 제작하였다. 제작된 금속분리판을 이용하여 내구성 평가,전기화학적 부식 특성, 성능평가 및 접촉저항 특성 등을 평가하였다. 전기화학적 부식특성의 경우 각각의 분리판에 대해 6.69, 1.2, 1.0 ${\mu}A/cm^2$로 모재인 STS 304의 25 ${\mu}A/cm^2$의 부식전류밀도에 비해 우수한 부식특성을 보였다. 또한 초기 성능에서 몰리브덴 첨가 DLC 분리판의 경우 300 mA/$cm^2$에서 0.757 V로 측정되었으며, 이는 graphite 분리판 측정 결과인 0.758 V와 유사한 성능을 보였다. 또한 내구성 평가에서 초기 성능 대비 성능 감소율이 10% 감소하는데 소요된 시간은 graphite 분리판의 경우 2,000시간으로 나타났으며, 몰리브덴 첨가 DLC 분리판의 경우 1,700시간으로 측정되었다. 1,500시간 까지의 성능 감소율은 grphite,텅스텐 첨가DLC,티타늄 첨가DLC, 몰리브덴 첨가 DLC 분리판 순으로 각각에 대해 37.7, 60.3, 92.8, 45.7 ${\mu}V$/hr로 나타났다.

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Humidification Optimization in Silicon-based Miniaturized Fuel Cell (실리콘으로 제작된 소형 연료 전지에서 가습 조건의 최적화)

  • Kwon, Oh-Joong;Won, Ho-Youn;Kim, Jae-Jeong
    • Journal of the Korean Electrochemical Society
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    • v.10 no.2
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    • pp.104-109
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    • 2007
  • Single fuel cell was fabricated with a MEA (membrane electrode assembly) that had a $4cm^2$ active area and with silicon bipolar plates those were introduced to miniaturize the fuel cell by replacing heavy weight graphite plates. Optimum humidification condition for the single cell was selected based on performance results obtained varying humidifier temperature at a fixed feed rate of hydrogen and oxygen. Furthermore, to study the effect of humidification condition on the performance of a fuel cell stack, the fuel cell stack consisting of two MEAs and silicon bipolar plates was studied, then problems and characteristics of silicon-based fuel cell stack were examined.