• 한국신재생에너지학회:학술대회논문집
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• 2005.11a
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• pp.554-557
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• 2005

The bipolar plate is a major component of the PEM fuel cell stack, which takes a large portion of stack cost. In this study, as alternative materials for bipolar plate of PEM fuel cells, graphite composites were fabricated by compression molding. Graphite particles mixed with epoxy resin were used as the main substance to provide electric conductivity. To achieve desired electric properties, specimens made with different mixing ratio, processing pressure and temperature were tested. To increase mechanical strength, one or two layer of woven carbon fabric were added to the original graphite and resin composite. Thus, the composite material is consisted of the three phases: graphite particles, epoxy resin, and carbon fabric. By increasing mixing ratio, fabricated pressure and process temperature, electric conductivity was improved. The results of tensile test showed that the tensile strength of two-phase graphite composite was about 5MPa, and that of three-phase composite was increased to 54MPa.

• Steel and Composite Structures
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• v.21 no.4
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• pp.849-862
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• 2016

This paper investigates the static buckling behaviours of Functionally Gradient Polymeric Material (FGPM) shells in the form of hemispherical segment. A new FGPM model based on experimental was considered to investigate the buckling problem of thin-walled spherical shells loaded by the external pressure. The spherical shells were formed by FGPM which was produced adding the two types of graphite powders into epoxy resin. The graphite powders were added to the epoxy resin as volume of 3, 6, 9, and 12%. Halpin-Tsai and Paul models were used to determine the elastic moduli of the parts of FGPM. The detailed static buckling analyses were performed by using finite element method. The influences of the types and volume of graphite powders on the buckling behaviour of the FGPM structures were investigated. The buckling loads of hemispherical FGPM shells based on Halpin-Tsai and Paul models were compared with those determined from the analytical solution of non-graphite condition existing for homogeneous material model. The comparisons between these material models showed that Paul model was overestimated. Besides, the critical buckling loads were predicted. The higher critical buckling loads were estimated for the PV60/65 graphite powder due to the compatible of the PV60/65 graphite powder with resin.

• Proceedings of the KSME Conference
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• 2001.11a
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• pp.596-602
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• 2001

Structures in current use are required of weight reduction and strength in many instances. This naturally necessitates frequent applications of composite materials in many areas. Elastic constants are one of key parameters in determining design guidelines for the specific applications of particular materials. In this research two vibratory techniques (acoustic resonance method and impulse technique)are utilized to evaluate elastic constants. Both techniques are suitable for the measurements of dynamic elastic constants. The Impulse technique provides a quick method for the measurement while the acoustic resonance method produces the values of elastic constants which agree better with theoretical values.

• Transactions of the Korean Society of Mechanical Engineers
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• v.13 no.4
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• pp.625-635
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• 1989

Mixed mode fracture problem is analyzed for the finite orthotropic plate where an inclined crack parallel to the fiber direction is centrally placed. Modified mapping collocation method with both uniform stress and uniform displacement boundary conditions is utilized to calculate stress intensity correction factors for glass/epoxy and graphite/epoxy composites. Computed results are presented for selected combinations of crack length to width ratio L/W and plate aspect ratio H/W with various fiber orientations.

• Proceedings of the Korean Society For Composite Materials Conference
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• 2001.05a
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• pp.46-49
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• 2001

In this paper. tile validity of work factor approach was investigated to determine compressive fracture toughness of unidirectional graphite/epoxy composites under hydrostatic pressure environment. The elastic work factor was determined under various pressures as a function of delamination length. It was found that elastic work factor was not affected by hydrostatic pressure.

• Carbon letters
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• v.24
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• pp.41-46
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• 2017

The microstructure, flexural properties, electrical conductivity, thermal conductivity and electromagnetic interference (EMI) shielding effectiveness (SE) of epoxy composites filled with multi-walled carbon nanotubes (CNTs), exfoliated graphite nanoplatelets (xGnPs) and CNT-xGnP hybrid filler were investigated. The EMI SE of the CNT-xGnP hybrid composite was higher than 25 dB at 100 MHz while that of the xGnP based composite was almost zero. The flexural modulus of the CNT-xGnP based epoxy composite continuously increased to 3.32 GPa with combined filler content up to 10 wt% while that of the CNT based epoxy composites slightly decreased to 1.96 GPa at 4 wt% CNT, and dropped to 1.57 GPa at 5 wt% loading, which is lower than that of epoxy. The CNT and CNT-xGnP samples had the same EMI SE at the same surface resistivity, because samples with the same surface conductivity have the same amount of the charge carriers.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.22 no.3
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• pp.540-544
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• 1998

Compliance calibration method is frequently used to determine $G_IC$ from the DCB composite specimen. However, the method requires at least 4 to 5 fracture test (loading-unloading) records. In this study, $G_IC$ of unidirectional graphite/epoxy DCB composites was determined from the elastic work factor approach which uses a single fracture test record. In order to inspect the validity of the elastic work factor approach, $G_IC$ determined from the elastic work factor approach was compared to that of determined from the compliance calibration method. It was shown that $G_IC$ determined from the elastic work factor approach was comparable to that determined from the compliance calibration method. That is, the elastic work factor approach can be used to determine $G_IC$ of unidirectional graphite/epoxy DCB specimen from a single fracture record.

• 한국신재생에너지학회:학술대회논문집
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• 2010.06a
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• pp.144.2-144.2
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• 2010

Bipolar plate는 고분자 전해질 연료전지(PEMFC)에서 핵심 부품 중의 하나이고, 전해질 막이나 촉매 등에 비해서는 상대적으로 쉽게 접근할 수 있기 때문에 많은 연구가 수행되고 있다. Bipolar plate를 제조하는 기술은 크게 금속을 프레스 가공하는 방법, graphite 판을 직접 밀링하는 방법 및 고분자/카본계의 press molding 법 등 3가지로 분류되며, 본 연구에서는 3번째 방법에 의해서 bipolar plate를 대량 생산하는 방법에 대해 연구하였다. 고분자 매트릭스는 에폭시계 수지를 사용하였고, 카본계 재료는 graphite 분말과 carbon nanotube를 사용하였다. 이들 재료들을 일정한 비율로 혼합한 후 differential scanning calorimetry(DSC)를 사용하여 열분석 하였고, 그 결과를 Kissinger equation에 대입하여 경화반응 속도론을 연구하였다. 또한, 경화된 에폭시/탄소 복합재료의 전기전도도, 유리전이온도, 표면에너지 특성 등을 분석하였다.

• Journal of the Korean Society for Precision Engineering
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• v.25 no.9
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• pp.103-108
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• 2008

In-plane shear tests were performed to investigate the shear property change of FRP by plasma modification. Graphite/epoxy prepreg was used as a test material and plasma source was a microwave (2.4GHz) type. Plasma was induced by oxygen gas and its flow rate was kept $4{\sim}5$sccm with low vacuum state of $10^{-3}$ Torr. Prepreg was stacked unidirectionally ($[0^0]_8$) after plasma modification. Wettability was determined by measuring a contact angle. The results showed that the contact angle was decreased from $86^0$ to $45^0$ after plasma modification. Shear strength was also improved by ${\sim}10%$. SEM examination was made on the fracture surface and functional group produced by the plasma modification was investigated by XPS.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.20 no.8
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• pp.2431-2435
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• 1996

In order to determine the effects of hydrostatic pressure on the mechanical behavior of graphite fiber reinforced composites, the modulus, fracture stress(maximum stress), and fracture strain of graphite/epoxy composites have been determined as a function of pressure. Composite specimens used in this study were 90-deg unidirectional and had a 60% fiber volume fraction. Compressive tests under five different pressure levels were conducted. The result showed the modulus measured from as initial slope of stress-strain curve increased bilinearly with pressure with a break at 200 MPa. It was also found that fracture stress and fracture strain increased in a linear fashion with pressure.