• Journal of the Korean Ceramic Society
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• v.55 no.6
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• pp.556-561
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• 2018

In this study, we performed a microwave sintering (MWS) of $Al_2O_3$ ceramic and $Al_2O_3$-based composites with nominal contents of graphene nanoplatelets (GPLs) of 0.2, 0.4, 0.6, and 0.8 vol%. The GPL dispersion in N-methyl pyrroleketone was optimized to deagglomerate the GPLs without damaging their structure. Dense composites were then obtained by MWS at $1500^{\circ}C$ for 30 min. The effects of different GPL contents on the phase compositions, microstructures, and mechanical properties of the composites were investigated. The microstructures of the composites became finer with the incorporation of the GPLs. The well-dispersed GPL fillers led to higher sintered densities in the composites. The optimal mechanical properties were achieved with 0.4 vol% GPLs. For this sample, the hardness, fracture toughness, and bending strength were $2000kgf/mm^2$, $6.19MPa{\cdot}m^{1/2}$, and 365.10 MPa, respectively. The addition of GPL could improve the microstructure of the $Al_2O_3$ ceramic and has potential to improve the fracture toughness of the ceramics.

• Steel and Composite Structures
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• v.51 no.4
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• pp.457-471
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• 2024

In this research, for the first time the instability boundaries for a spinning shaft reinforced with graphene nanoplatelets undergone the principle parametric resonance are determined and examined taking into account the gyroscopic effect. In this respect, the extracted equations of motion in our previous research (Ref. Asadi et al. (2023)) are implemented and efficiently upgraded. In the upgraded discretized equations the effect of the Rayleigh's damping and the varying spinning speed is included that leads to a different dynamical discretized governing equations. The previous research was about the free vibration analysis of spinning graphene-based shafts examined by an eigen-value problem analysis; while, in the current research an advanced mechanical analysis is addressed in details for the first time that is the dynamics instability of the aforementioned shaft subjected to the principal parametric resonance. The spinning speed of the shaft is considered to be varied harmonically as a function of time. Rayleigh's damping effect is applied to the governing equations in order to regard the energy loss of the system. Resorting to Bolotin's route, Floquet theory and β-Newmark method, the instability region and its accompanied boundaries are defined. Accordingly, the effects of the graphene nanoplatelet on the instability region are elucidated.

• Applied Chemistry for Engineering
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• v.30 no.3
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• pp.371-378
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• 2019

Graphene nanoplatelet (GnP)/reused phenolic foam (re-PF)/wood composite boards were fabricated with different GnP content as 5, 10 and 20 w/w% to investigate the effect of GnP on thermal- and flame retardant properties of wood-based composite boards. The thermal- and flame retardant properties of fabricated composite boards were investigated by thermogravimetric analysis (TGA) and limiting oxygen index (LOI), respectively. The thermal stability of the composite boards increased proportionally with respect to the amount of GnP, and the char yield of these boards increased up to 22% compared to that of the pure wood board. The LOI values of composite boards were about 4.8~7.8% higher than those of using pure wood boards. It was also confirmed that the flame retardant properties of composite boards were remarkably improved by the addition of re-PF and GnP. These results were because of the fact that the re-PF and GnP with a high thermal stability delayed the initial thermal degradation temperature of composite boards and made their char layers denser and thicker which led the overall combustion delay effect of the composite board. Especially, GnP as a carbon-based material, facilitated the char layer formation and increased remarkedly the char yield, which showed higher effect on flame retardant properties than those of the re-PF.

• Steel and Composite Structures
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• v.50 no.1
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• pp.63-75
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• 2024

In this paper, the modified couple stress theory (MCST) and first order shear deformation theory (FSDT) are employed to investigate the free vibration and bending analyses of a three-layered micro-shell sandwiched by piezoelectric layers subjected to an applied voltage and reinforced graphene nanoplatelets (GPLs) under external and internal pressure. The micro-shell is resting on an elastic foundation modeled as Pasternak model. The mixture's rule and Halpin-Tsai model are utilized to compute the effective mechanical properties. By applying Hamilton's principle, the motion equations and associated boundary conditions are derived. Static/ dynamic results are obtained using Navier's method. The results are validated with the previously published works. The numerical results are presented to study and discuss the influences of various parameters on the natural frequencies and deflection of the micro-shell, such as applied voltage, thickness of the piezoelectric layer to radius, length to radius ratio, volume fraction and various distribution pattern of the GPLs, thickness-to-length scale parameter, and foundation coefficients for the both external and internal pressure. The main novelty of this work is simultaneous effect of graphene nanoplatelets as reinforcement and piezoelectric layers on the bending and vibration characteristics of the sandwich micro shell.

• Steel and Composite Structures
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• v.37 no.1
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• pp.27-35
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• 2020

This study examines the wave propagation of the functionally graded polymer composite (FG-PC) nanoplates reinforced with graphene nanoplatelets (GNPs) resting on elastic foundations in the framework of the nonlocal strain gradient theory incorporating both stiffness hardening and softening mechanisms of nanostructures. To this end, the material properties are based on the Halpin-Tsai model, and the expressions for the classical and higher-order stresses and strains are consistently derived employing the second-order shear deformation theory. The equations of motion are then consistently derived using Hamilton's principle of variation. These governing equations are solved with the help of Trial function method. Extensive numerical discussions are conducted for wave propagation of the nanoplates and the influences of different parameters, such as the nonlocal parameter, strain gradient parameter, weight fraction of GNPs, uniform and non-uniform distributions of GNPs, elastic foundation parameters as well as wave number.

• Advances in concrete construction
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• v.15 no.2
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• pp.97-114
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• 2023

The nonlocal strain gradient theory for the static bending analysis of graphene nanoplatelets (GPLs) reinforced the nanoplate is developed in this paper. The nanoplatelet is exposed to thermo-mechanical loads and is also supposed to stand on an elastic foundation. For computing impressive composite material characteristics, the Halpin-Tsai model is selected for various sectors. The various distributions are propounded including UD, FG-O, and FG-X. The represented equations are acquired based on the virtual work and sinusoidal shear and normal deformation theory (SSNDT). Navier's solution as the analytical method is applied to solve these equations. Furthermore, the effects of GPL weight fraction, temperature parameters, distribution pattern and parameters of the foundation are presented and discussed.

• Proceedings of the Korean Vacuum Society Conference
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• 2012.08a
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• pp.79-79
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• 2012

A high temperature and a low temperature plasma process technologies were developed and demonstrated for synthesis, hybrid formation, surface treatment and CVD engineering of nano powder. RF thermal plasma is used for synthesis of spherical nano particles in a diameter ranged from 10 nm to 100 nm. A variety of nano particules such as Si, Ni, has been synthesized. The diameter of the nano-particles can be controlled by RF plasma power, pressure, gas flow rate and raw material feed rate. A modified RF thermal plasma also produces nano hybrid materials with graphene. Hemispherical nano-materials such as Ag, Ni, Si, SiO2, Al2O3, size ranged from 30 to 100 nm, has been grown on graphene nanoplatelet surface. The coverage ranged from 0.1 to 0.7 has been achieved uniformly over the graphene surface. Low temperature AC plasma is developed for surface modification of nano-powder. In order to have a three dimensional and lengthy plasma treatment, a spiral type of reactor has been developed. A similar plasma reactor has been modfied for nano plasma CVD process. The reactor can be heated with halogen lamp.

• Steel and Composite Structures
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• v.36 no.6
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• pp.689-702
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• 2020

The current study deals with the size-dependent free vibration analysis of graphene nanoplatelets (GNPs) reinforced polymer nanocomposite plates resting on Pasternak elastic foundation containing different boundary conditions. Based on a four variable refined shear deformation plate theory, which considers shear deformation effect, in conjunction with the Eringen nonlocal elasticity theory, which contains size-dependency inside nanostructures, the equations of motion are established through Hamilton's principle. Moreover, the effective material properties are estimated via the Halpin-Tsai model as well as the rule of mixture. Galerkin's mathematical formulation is utilized to solve the equations of motion for the vibrational problem with different boundary conditions. Parametrical examples demonstrate the influences of nonlocal parameter, total number of layers, weight fraction and geometry of GNPs, elastic foundation parameter, and boundary conditions on the frequency characteristic of the GNPs reinforced nanoplates in detail.

• Proceedings of the Korean Vacuum Society Conference
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• 2014.02a
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• pp.433.2-433.2
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• 2014

그래핀(graphene)은 탄소나노튜브(CNTs)에 비해 가격 경쟁력이 있고 우수한 광투과성과 전기 및 열 전도성을 갖고 있어 반도체 소재, 방열 소재, 접점 소재 등에 적용 가능성이 높은 재료로 주목받고 있다. 특히 모바일 디바이스의 소형화, 고집적화 등의 이슈로 인해 그래핀 소재의 방열 소재 적용을 위해 다양한 연구가 진행되고 있다. 한편 산화 구리 나노선(CuO Nanowire)은 전기 및 열전도도가 우수하고 1차원 나노 구조는 부피대비 큰 표면적, 종횡비가 커서 뛰어난 열전도 구조로서 방열 소재로 응용되기 좋은 조건을 갖고 있다. 본 연구에서는 2차원 구조의 그래핀 나노플레이트(Graphene Nanoplatelet)와 1차원 구조의 CuO NW를 하이브리드화를 통해 열전도도 향상를 개선시키고자 하였다. 소재 합성은 GNP에 Cu 무전해 도금을 진행한 후 열산화 방식을 적용하여 CuO NW를 직접 성장시키는 방식으로 진행하였다. 합성된 GNP-CuONWs 다차원 나노구조체의 열전도도 측정은 에폭시에 분산시켜 레이져 플레쉬법을 이용하였다. 미세 구조 관찰 결과, CuO NW 성장 거동은 열처리 온도 및 시간 그리고 O2 가스의 순환 환경이 주요인자로 작용하는 것을 확인하였다. 열전도도 향상은 다차원 구조의 특성으로 인해 면접촉과 선접촉이 동시에 이루어졌기 때문인 것으로 분석되었으며, 이러한 CuO NWs morphology와 열전도도 향상과의 상관 관계에 대해 논의할 것이다.

• Composites Research
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• v.33 no.6
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• pp.321-328
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• 2020

Recently, development of nanocomposite materials for applying in various fields has been actively underway. Of the two-dimensional nanomaterials, graphene nanoplatelets (GnPs) are highly utilized because of their excellent properties, but a problem of strong aggregations is occurred when GnPs are fabricated with polymer nanocomposites, so there is a growing demand for research on the methods of dispersion. In this review paper, the research on GnP nanocomposites with improved properties through various dispersion methods of GnPs. The welldispersed GnP nanocomposites will be applied in more diverse fields in the future.