• Title/Summary/Keyword: Grain-size

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High temperature oxidation behavior and surface modification of Ni-based superalloys (니켈기 초합금의 고온산화거동과 표면개질에 관한 연구)

  • Seol, Gyeong-Won
    • Korean Journal of Materials Research
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    • v.4 no.2
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    • pp.166-176
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    • 1994
  • Ni base superalloys are composed of solid sohltion hardening elements(Co, Cr. Mo. W and so on) and $\gamma '$ precipitation hardening elements(A1, Ti, Nb, Ta and so on). To Improve the mechanical properties and oxidation resistanre of superalloys, rare earth elements(%r, Hf, Y and so on) are added to the inner substrate, or are used as coating materials. Their pffects on the growth rate and adhes~on of oxide are changed according to the kinds of oxides such as $AI_2O_3$ and $Cr_2O_3$. The effect of yttrium on the oxidation rate, grain size of oxide, internal structure, and crack resistance was investigated for two kinds of Ni-base superalloys. One in AF'115 superalloy containing Hf and the other is MA6000 superalloy containing $Y_2O_3$. They werr owid~zed at high temperature after yttrium surface modification using ion coater. Yttrium coating on the AF115 and MA6000 superalloys results in a marked change in the growth of the inner oxide. For AF115 superalloy, the degree of gram boundary segregation of $Cr_2O_3$, and prefer en^ tial oxidation of Hf are decreased, and the shape of inner oxidation layer was changed from triangle to plate type. For MA6000 superalloy, $Cr_2O_3$ oxide scale was transformed as outer oxidation layer of CrZOI and inner oxidation layer of $Cr_2O_3$.

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Mineralogy and Geochemistry of Green-colored Cr-bearing Sericite from Hydrothermal Alteration Zone of the Narim Gold Deposit, Korea (나림 금광상의 열수변질대에서 산출되는 녹색크롬-견운모의 광물학적 및 지구화학적 특징)

  • Lee, Hyun Koo;Lee, Chan Hee
    • Economic and Environmental Geology
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    • v.30 no.4
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    • pp.279-289
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    • 1997
  • Dark to pale green-colored, Cr-bearing sericites from hydrothermal alteration zone of the Narim gold deposit were investigated mineralogically and geochemically. The alteration zone is composed mineralogically of quartz, carbonate minerals and green sericite with minor amounts of chlorite, barite and sulfide minerals (pyrite, sphalerite, galena). The zone is enriched in As (967 to 1520 ppm), Cu (31 to 289 ppm), Ni (1027 to 1205 ppm), Pb (0.20 to 1.24 wt.%) and Zn (1.03 to 1.07 wt. %) compared with fresh rocks such as granitic gneiss, porphyritic biotite granite and basic dyke. The Cr, probably the chromophore element, is highly enriched in the alteration zone (1140 to 1500 ppm), host granitic gneiss (1200 ppm) and porphyritic biotite granite (1200 ppm). Occurrence and grain size of sericite are diverse, but most of the Cr-bearing sericites (150 to $200{\mu}m$ long and 20 to $30{\mu}m$ wide) occur along the boundaries between ore veins and host rocks (especially basic dyke and granitic gneiss). X-ray diffraction data of the sericite show its monoclinic form with unit-cell parameters of $a=5.202{\AA}$, $b=8.994{\AA}$, $c=20.103{\AA}$, ${\beta}=95.746^{\circ}$ and $V=935.83{\AA}^3$, which are similar with the normal 2M1-type muscovite. Representative chemical formula of the sericite is ($K_{1.54}Ca_{0.03}Na_{0.01}$)($Al_{3.42}Mg_{0.38}Cr_{0.14}Fe_{0.06}V_{0.02}$)($Si_{6.69}Al_{1.31}$)$O_{20}(OH)_4$. The Cr content increases with decrease of the octahedral Al content, and ranges from 0.36 to 2.58 wt.%. DTA and TG curves of the sericite show endothermic peaks at $342^{\circ}$ to $510^{\circ}$, $716^{\circ}$ to $853^{\circ}$ and $1021^{\circ}C$, which are due to the expulsion of hydroxyl group. The total weight loss by heating is measured to be about 8.8 wt. %, especially at $730^{\circ}C$. Infrared absorption experiments of the sericite show broad absorption band due to the O-H bond stretching vibration near the $3625cm^{-1}$, coupled with the 825 and $750cm^{-1}$ doublet. The vibration bands related with the H-O-Al and Si-O-Al bonds occur at $1030cm^{-1}$ and 500 to $700cm^{-1}$, respectively. Based on paragonite content of the sericite, the formation temperature of the Narim gold deposit is calculated to be $220{\pm}10^{\circ}C$.

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Distribution of Sedimentation Environments and Benthic Macro-fauna Communities in Habitats and Non-habitats of Zostera marina on the Yeongheung-do Tidal Flats, West Coast of Korea (한국의 서해안 영흥도 조간대의 거머리말(Zostera marina) 서식지와 비서식지에서 퇴적환경과 대형저서동물군집의 분포)

  • Bae, Jong Il;Shin, Hyen Chul;Hwang, Sung Il;Lee, Jeng Ho
    • Korean Journal of Environmental Biology
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    • v.36 no.2
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    • pp.107-116
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    • 2018
  • In this study, the distribution of sedimentary environment and benthic macro-fauna in habitats and non-habitats of Zostera marina were investigated. The purpose of this study was to obtain basic data about the sedimentary environment and benthic macro-fauna in the habitats and non-habitats of Z. marina. Sand was dominant within habitat environments, whereas the non-habitats were predominantly composed of silt. As a result, the habitats of Z. marina have a different grain size and organic matter content compared to the non-habitats. These differences in the sedimentary environment were expected to influence the species composition of benthic animals. Benthic communities in the habitats of Z. marina showed a higher density and a greater number of species than in the non-habitats. As a result of an ecological index evaluation, the species diversity index (H') was $3.44{\pm}0.10$ for the habitat; the non-habitat was analyzed as $2.34{\pm}0.35$. It was also found that the stability of community in the habitats was higher than that in the non-habitats. The cluster analysis also clearly showed that habitats and non-habitats of Z. marina have distinct characteristics.

Effect of Cd Concentration on Characteristics of CdS Thin Films Prepared by Chemical Bath Deposition (화학용액증착법에 의하여 증착된 CdS 박막의 특성에 대한 Cd 농도의 영향)

  • Jung, SungHee;Chung, CheeWon
    • Applied Chemistry for Engineering
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    • v.23 no.4
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    • pp.377-382
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    • 2012
  • CdS thin films have been widely used as a buffer layer of CIGS semiconductor solar cells to reduce the lattice mismatch between transparent electrode and absorber layer. In order to prepare the CdS films with high transparency and low resistivity, they were deposited by varying Cd concentration with the constant S concentration in the solution using chemical bath deposition method. They were analyzed in terms of structural, optical and electrical properties of CdS films according to the $[S^{2-}]/[Cd^{2+}]$ ratio. In the case of Cd concentration higher than S concectration, CdS thin films were formed mainly by cluster- by-cluster formation due to the homogeneous reaction between Cd and S in the solution. Therefore the grain size increased and the transmittance decreased. On the other hand, in the case of Cd concentration lower than S concentration, CdS films were formed by heterogeneous reaction on the substrate rather than in the solution. The CdS films have the grains with the uniform circular shape of a few hundreds ${\AA}$. As the Cd concentration increased in the solution, the $[S^{2-}]/[Cd^{2+}]$ ratio decreased and the resistivity decreased by the increase in the carrier concentration due to the formation S vacancy by the excess Cd.

Numerical Experiments of Dynamic Wave Pressure Acting on the Immersed Tunnel on Seabed Foundation (해저지반 상부에 설치된 침매터널에 작용하는 동수압에 관한 수치실험)

  • Hur Dong Soo;Kim Chang Hoon;Yeom Gyeong Seon;Kim Do Sam
    • Journal of Korean Society of Coastal and Ocean Engineers
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    • v.17 no.4
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    • pp.294-306
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    • 2005
  • Most immersed tunnels investigated have been investigated based on the engineer's experience with design and construction. From engineering point of view, it is very important to understand the wave interaction with the seabed and immersed tunnel, since the stability of an immersed tunnel depends largely on the behavior of the seabed foundation. In this study, for the first stage research to find out the mechanism of the wave interaction with the seabed and immersed tunnel, the benchmarking method called as direct numerical simulation (DNS) was employed to analyze comprehensively the wave-induced pore water pressures, vorticity and flows in seabed or inside rubble stone around the immersed tunnel. The immersed tunnel is modeled based on Busan-Geoje fixed link project in Korea, which is now on the stage of planning. Moreover, the nonlinear water wave interaction with an immersed tunnel/its seabed foundation was thoroughly examined with regard to the stabilities of the immersed tunnel subjected to various water wave conditions, median grain size and so forth.

Timing of the Hydrothermal Alteration Associated with the Fault Activities along the Ulsan Fault Bone, Southeast Korea (울산단층대의 단층활동에 수반된 열수변질작용시기)

  • 조규환;다카기히데오;이와무라아키라;아와지도타;장태우;손승완;이타야테츠마루;오카다도시노리
    • Economic and Environmental Geology
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    • v.34 no.6
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    • pp.583-593
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    • 2001
  • Clay minerals are common component of fault gouge and have been used to determine the fault activity age using K-Ar dating technique. We carried out XRD and K-Ar analyses of the mica clay minerals from the fault gouge along the Ulsan Fault Zone, southeastern Korea to estimate the timing of the major fault activity. Mica clay minerals for four grain size fractions of 5-2 Um, 2-1 $\mu$m, 1-0.35$\mu$m, and 0.35-0.05 $\mu$m were separated from the gouge samples in the three locations by the hydraulic elutriation and contrifugal separator. Fault gouges are composed of smectite, mica clay minerals, kaolinite, chlorite, quartz, and feldspar. The illite crystallinity of mica clay minerals is the highest in the finest grained fraction with lM polytype, indicating that the aulhigenic mica clay minerals have been concentrated in the fraction. K-Ar ages give some variation from 46 to 35 Ma (330-2), 45 to 39 Ma (16Ww), and 32 to 15 Ma (102Ws) and are the youngest in the finest grained fraction. These results suggest that the hydrothermal alteration associated with the major fault activities along the Ulsan fault Zone took place twice at 39-35 Ma and 15 Ma.

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Comparison of Physicochemical, Microbial and Antioxidant Properties in Domestic and Imported Wheat Kernels for Bread Making (제빵용 우리밀과 수입밀 원맥의 이화학, 미생물, 항산화 특성 비교)

  • Kwak, Han Sub;Kim, Mi Jeong;Heo, JeongAe;Kim, Min Jung;Shim, Jaewon;Kim, Oui-Woung;Kim, Hoon;Kim, Sang Sook
    • The Korean Journal of Food And Nutrition
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    • v.31 no.1
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    • pp.17-23
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    • 2018
  • The objective of this study was to compare physicochemical, microbial, and antioxidant properties of domestic and imported wheat kernels for bread making. Two domestic (JK1, 2) and three imported (ND, DNS, and CWRS) kernels were compared. Domestic kernels had higher moisture contents, and lower ash and protein contents (p<0.05). In grain characteristics, JK1 had 13.62% of damaged kernels, which was the highest among the samples (p<0.05). JK2 was similar to imported kernels in the ratio of sound kernels, foreign materials, and damaged kernels. Kernel size of JK1, 2 was larger than the imported kernels; therefore, kernels area and perimeter were higher by the image analyzer. Domestic kernels hid lower total aerobic counts the imported kernels (p<0.05). Domestic kernels and DNS had no yeast, while NS and CWRS had yeast in kernels. DNS (3.08 mg gallic acid equivalent (GAE)/g) had the highest total polyphenol content (TPC), followed by JK1 (2.81 mg GAE/g). JK2 had the lowest amount of TPC as 2.26 mg GAE/g. Total flavonoid content (TFC) was the highest in DNS as 0.44 mg catechin equivalent (CE)/g and JK2 was the lowest as 0.12 mg CE/g. Domestic wheat kernels had lower protein content and lightness than the imported wheat kernels so that flour from domestic wheat kernels may have lower quality for baking.

Characteristics of Concrete Polymer Composite Using Atomizing Reduction Steel Slag as an Aggregate (II) (Use of Polystyrene as a Shrinkage Reducing Agent) (아토마이징 제강 환원슬래그를 골재로 사용한 폴리머 콘크리트 복합재료의 특성(II) (폴리스티렌 수축저감재 사용))

  • Hwang, Eui-Hwan;Kim, Jin-Man
    • Applied Chemistry for Engineering
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    • v.25 no.4
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    • pp.380-385
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    • 2014
  • Spherical atomizing reduction steel slag was prepared by atomizing technology using reduction steel slag (ladle furnace slag, LFS) generated from steel industry. In order to develop the mass-recycling technology of atomizing reduction steel slag, polymer concrete composite was prepared using spherical atomizing reduction steel slag instead of fine aggregate (river sand) and coarse aggregate (crushed aggregate), depending on the grain size. Different polymer concrete specimens were prepared with the various proportions of polymer binder and replacement ratios of atomizing reduction steel slag in order to investigate the characteristics of polymer concrete composite. Results showed that compressive strengths of polymer concrete specimens decreased with the increase of replacement ratios of atomizing reduction steel slag, but flexural strengths of the specimens showed a maximum strength at the 50% of replacement ratios of atomizing reduction steel slag. It was concluded that addition ratio of polymer binder, which affect greatly on the prime cost of production of polymer concrete, could be reduced by maximum 18.2 vol% because the workability of the polymer concrete was remarkably improved by using the atomizing reduction steel slag. However, further study is required because the mechanical strength of the specimen using atomizing reduction steel slag was greatly reduced in hot water resistance test.

Study on Stable Use of Stainless EAF Oxidizing Slag as Fine Aggregate of Concrete (스테인리스 전기로 산화슬래그의 콘크리트용 잔골재 활용방안 검토)

  • Cho, Bong-Suk
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.18 no.3
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    • pp.133-142
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    • 2014
  • Recently, more focus is shift to imbalances in aggregate market supply and demand and an exhaustion of natural resources. In this situation, Electric arc furnace oxidizing slag (EAF Slag) has high application possibility as aggregate for concrete due to similar property with general aggregate. In this study, We've got the plan to assure the chemical stability of EAF Slag, and then experimentally tested the mechanical performance and durability for the fine aggregate used EAF Slag. On this test result, we suggest the application plan. At the result of this study, it shows that EAF slag would reduce the surface defect such as pop-out due to natural aging for the fixed hour and adjustment the grain size of EAF Slag. And mechanical performance and durability according to the replacement rate of concrete service, were revealed more than equal or equal compare to general aggregate. Hereafter, quality control must precede not to impede the beauty of concrete surface as assure the safety for aging and processing. And, to establish the environmental resource recycling system for by-products of steel, it should be made development of various application and guideline of quality control for the EAF slag aggregate. Moreover, it must be constantly studied all kind of engineering performance and durability for related to this study.

Shear Strength Characteristics of Weathered Granite Soil below the Freezing Point (동결온도 조건에서의 화강풍화토 전단강도 특성에 관한 연구)

  • Lee, Joonyong;Choi, Changho
    • Journal of the Korean GEO-environmental Society
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    • v.14 no.7
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    • pp.19-29
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    • 2013
  • Analysis via classical soil mechanics theory is either ineffective or inappropriate for fully describing stress distribution or failure conditions in cold regions, since mechanical properties of soils in cold regions are different from those reported in the classical soil mechanics theory. Therefore, collecting and analyzing technical data, and systematic and specialized research for cold regions are required for design and construction of the structure in cold regions. Freezing and thawing repeat in active layer of permafrost region, and a loading condition affecting the structure changes. Therefore, the reliable analysis of mechanical properties of frozen soils according to various conditions is prerequisite for design and construction of the structure in cold regions, since mechanical properties of frozen soils are sensitive to temperature condition, water content, grain size, relative density, and loading rate. In this research, the direct shear apparatus which operates at 30 degrees below zero and large-scaled low temperature chamber are used for evaluating shear strength characteristics of frozen soils. Weathered granite soil is used to analyzed the shear strength characteristics with varying freezing temperature condition, vertical confining pressure, relative density, and water content. This research shows that the shear strength of weathered granite soil is sensitively affected by various conditions such as freezing temperature conditions, normal stresses, relative densities, and water contents.