• Title/Summary/Keyword: Grain structure

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무전해 은도금층과 전기도금층의 형성에 관한 연구 (A Study on he Electroless Deposits and Electrodeposits)

  • 임종주;민병승;정원섭;김인곤
    • 한국표면공학회지
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    • 제33권4호
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    • pp.273-280
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    • 2000
  • Silver was deposited on glass by electroless plating and electroplating. Surface properties were investigated using the AFM. Crystal structure of deposit layers was confirmed by TEM and XRD. Electroplating is performed by DC plating and pulse plating, respectively. This study resulted in followings, first, deposit of electroless plating showed fine grain and was similar to the amorphous structure. Second, electrodeposit on the electroless layer was revealed following results ; (1) more uniform layer and finer grains were obtained with increasing frequency (2) more isotropic structure was obtained with increasing frequency (3) finer grains at 25% duty cycle was obtained (4) grain size and roughness of the silver deposit was decreased with increasing frequency.

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지리산 주변 산지하천의 step-pool 구조 특성 (Characteristics of step-pool structure in the mountain streams around Mt. Jiri)

  • 김기흥;정혜련
    • 한국수자원학회논문집
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    • 제51권4호
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    • pp.313-322
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    • 2018
  • Step의 높이는 하상재료 입경의 크기와 거의 같은 상관관계가 있으며, 하도경사에 따라 증가하고, 하도 폭과 step 파장은 거의 같은 크기로서 하도경사가 증가하면 step 파장은 감소하는 것으로 분석되었다. 하도 폭과 step 폭은 뚜렷한 상관관계가 있으며, 하도 폭의 증가에 따라 step 폭도 증가하는 것으로 분석되었다. 또한, step 파장은 하도 폭에 의하여 규모가 정해지고, step 높이는 step을 형성하는 암석의 크기에 의해 지배되기 때문에 step-pool의 종단면의 하상구조는 하도경사에 따라 변화하는 것으로 판단된다. Pool의 규모는 하도 폭, 입경 및 하도경사와 상관성이 큰 것을 확인하였다. 따라서 하천의 step-pool 구조 특성은 다양한 인자들의 영향을 받지만 대표적으로 입경, 하도 폭 및 하도경사로서 설명할 수 있는 것으로 분석되었다.

Environmental and Socioeconomic Determinants of Grain Virtual Water Trade: An Empirical Analysis using Decomposition and Decoupling Model

  • Golden Odey;Bashir Adelodun;Seulgi Lee;Kyung Sook Choi
    • 한국수자원학회:학술대회논문집
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    • 한국수자원학회 2023년도 학술발표회
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    • pp.394-394
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    • 2023
  • The world's sustainable growth is being severely hampered by the inefficient use of water resources. Despite the widely acknowledged importance of trade in global and regional water and food security, societal reliance on local production as well as international trade remains inadequately assessed. Therefore, using South Korea as a case study, this study fills in this research gap by applying the virtual water concept, the logarithmic mean divisia index (LMDI) method, and the Tapio decoupling model. The virtual water concept was used to estimate South Korea's net virtual water trade for major grain crops from 1992 to 2017. Then, the LMDI method was utilized to assess the driving factors causing changes in net virtual water trade. Lastly, the Tapio decoupling model was used to investigate the decoupling relationships between economic growth and the driving factors of net virtual water trade. Results showed that South Korea remains a net importer of virtual water flows with respect to grain crops, with an average import of 16,559.24 million m3 over the study period. In addition, the change in net virtual water trade could be attributed to water intensity effect, product structure effect, economic effect, and population effect. However, water intensity and economic effects were the major decisive factors for decrease and increase in net virtual water trade respectively, while the population and product structure effects had minor positive influences on the net virtual water trade. Furthermore, water intensity and economic growth showed a strong decoupling in most periods, while the decoupling state between product structure and economic growth was observed as expansive negative decoupling. Likewise, population size and economic growth showed a weak decoupling in most periods. The results reveal South Korea's status as it concerns the virtual water trade of grain crops, thus providing valuable insights into the sustainability of trade activities for the management of local water resources.

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AZ31 합금의 온간 부풀림 성형시 결정립 변화에 관한 연구 (Grain Evolution during Bulge Blow forming of AZ31 Alloy)

  • 백성규;이영선;이정환;권용남
    • 한국소성가공학회:학술대회논문집
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    • 한국소성가공학회 2008년도 추계학술대회 논문집
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    • pp.452-455
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    • 2008
  • In the present study, blow forming characteristics of commercially roiled AZ31 alloy sheets were investigated. Two different kinds of AZ31 sheets were originally fabricated by using direct casting and strip casting methods respectively. Both sheets have similar grain sizes of about $7{\mu}m$ with a relatively equiaxed structure after rolling. A series of tensile tests were carried out to get flow behavior in terms of temperature and strain rate. Also, grain size effect was investigated by annealing as-received sheet at elevated temperatures. Elongation increased with temperature increment as well expected. However, the differences in tensile test condition did not give much difference in elongation even at the temperature range where a large elongation would be expected with such as fine grain of $7{\mu}m$. Blow forming experiments showed that forming condition did not result in higher difference in dome height. However, the interesting feature from this study was that formability of this AZ31 alloy got different with stress condition. Firstly, biaxial stress condition might result in lower temperature and strain rate dependencies compared to uniaxial tension results for both DC and SC sheets. Secondly, DC showed slower grain growth in uniaxial tension than in biaxial stress state while SC has much higher grain growth rage in uniaxial tension than in bulging.

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Study on the Kinetics and Mechanism of Grain Growth during the Thermal Decomposition of Magnesite

  • Fu, Da-Xue;Feng, Nai-Xiang;Wang, Yao-Wu
    • Bulletin of the Korean Chemical Society
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    • 제33권8호
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    • pp.2483-2488
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    • 2012
  • The X-ray line broadening technique was used to calculate the grain size of MgO at 1023, 1123, 1223 K respectively either in $CO_2$ or during the thermal decomposition of magnesites in air as well as in vacuum. By referring to the conventional grain growth equation, $D^n=kt$, the activation energy and pre-exponential factor for the process in air are gained as 125.8 kJ/mol and $1.56{\times}10^8\;nm^4/s$, respectively. Ranman spectroscopy was employed to study the surface structure of MgO obtained during calcination of magnesite, by which the mechanism of grain growth was analyzed and discussed. It is suggested that a kind of highly reactive MgO is produced during the thermal decomposition of magnesites, which is exactly the reason why the activation energy of the grain growth during the thermal decomposition of magnesite is lower than that of bulk diffusion or surface diffusion.

참나무 아속(亞屬) 주요 수종의 조직적 성질과 종압축강도와의 관계 (The Relationship between Anatomical Characteristics and Compression Strength Parallel to Grain in Major Species of Lepidobalanus)

  • 오승원
    • Journal of the Korean Wood Science and Technology
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    • 제26권1호
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    • pp.63-69
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    • 1998
  • This study was carried out to get some basic information on mechanical properties of Korea Lepidobalanus for rational utilization of wood. Five species of Quercus variabilis, Q. aliena, Q. serrata, Q. mongolica, Q. acutissima belong to Lepidobalanus were investigated in this research. Relationship of anatomical characteristics to compression strength parallel to grain was analyzed using stepwise regression technique. All possible combination of 21 independent variables were regressed on compression strength parallel to grain. The summarized results in this study were as follows: I. In the proportion of wood structural elements, the factors that had the greatest influence on compression strength parallel to grain appeared to be proportion of ray in earlywood in Q. variabilis and Q. acutissima, proportion of wood fiber in latewood in Q. aliena and Q. serrata and proportion of vessel in earlywood in Q. mongolica respectively. 2. In the size of wood element and its structure, the factors that had the greatest influence on compression strength parallel to grain were microfibril angle in Q. variabilis, Q. serrata and Q. mongolica and length of wood fiber in Q. aliena and Q. acutissima.

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ECAP 강가공에 의한 마그네슘 AZ31합금의 결정립 미세화 및 미세조직 불안정성 (Grain Refinement and Microstructural Instability of an AZ31 Mg Alloy by Severe Plastic Deformation Using ECA Pressing)

  • 김호경;정강;현창용
    • 열처리공학회지
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    • 제17권3호
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    • pp.139-145
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    • 2004
  • Equal channel angular pressing (ECAP) technique had been adapted to the Mg alloy (AZ31) for achieving effective grain refinement through severe deformation. The average grain size of $2.5{\mu}m$ could be obtained after 4 passes. The stability of the ECAPed structure at elevated temperatures was examined by annealing the ECAPed materials over a wide range of temperature between 473 and 748 K. The average activation energy, Q, for static grain growth of 1, 2 and 3 passes was 33.7 kJ/mole (=0.25QL, activation for lattice diffusion). The abnormally low Q value in the lower temperature range may indicate that grain growth occurs in the unrecrystallized microstructure where non-equilibrium grain boundaries containing a large number of extrinsic dislocations exist. The yield stresses of the ECAPed alloys decreased whereas the elongations increased after the ECAP process. These results should be related to the modification of texture for easier slip on basal plane.

전착법으로 제조한 나노결정질 저Ni 퍼멀로이의 미세 조직과 자기적 특성 (Microstructure and Mgnetic Properties of Electrodeposited Nanocrystalline Low-Nickel Permalloy)

  • 허영두;이흥렬;황태진;임태홍
    • 한국표면공학회지
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    • 제36권6호
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    • pp.455-460
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    • 2003
  • Microstructural and magnetic properties of nanocrystalline Fe-46 wt%Ni and Fe-36 wt%Ni alloys were investigated. Alloys were prepared by the electrodeposition process. The electrolytes were iron sulfate/nickel chloride-based and iron chloride/nickel sulfamate-based solutions. Fe-46 wt%Ni alloy was FCC structure with grain size of 10 nm, but FCC and BCC phases were found in Fe-36 wt%Ni alloy and its grain size was smaller. Effective permeability of Fe-36 wt%Ni alloy was higher than that of Fe-46 wt%Ni alloy in the high frequency range because of large electrical resistivity and small eddy current loss resulted from grain size decrease. Up to $300^{\circ}C$ of annealing temperature, grain growth of Fe-Ni alloys slowly occured. Conversely, annealing above $450^{\circ}C$ led to a drastic grain growth. In that case, effective permeability was decreased at the temperature lower than $300^{\circ}C$ but at $300^{\circ}C$ or higher effective permeability was increased. At the high frequency of 1 MHz, electrodeposited Fe-Ni alloys had higher effective permeability with an decrease in the grain size.

고청정 Alloy718 잉고트 Cogging (Cogging of premium-quality Alloy 718)

  • 박노광;염종택;임정숙;최상욱
    • 한국군사과학기술학회지
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    • 제6권4호
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    • pp.159-166
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    • 2003
  • Microstructures and mechanical properties of VIM/VAR/VAR-processed Ni-based Alloy718 ingot were investigated. Vacuum arc remelting(VAR) results in chill grain zone, columnar grain zone, and equi-axed grain zone in the ingot due to the difference in local solidification processes. Different grain structures of the remelting ingot result in the different hot workability for the given cogging conditions. Experimental results on microstructural inhomogeniety and material flow behavior under billet cogging conditions were presented, and their potential effects on the billet cogging process are discussed.

Dielectric Properties of Orthorhombic Dysprosium Manganites

  • Wang, Wei Tian
    • 한국재료학회지
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    • 제29권12호
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    • pp.753-756
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    • 2019
  • Orthorhombic dysprosium manganite DyMnO3 with single phase is synthesized using solid-state reaction technique and the crystal structure and dielectric properties as functions of temperature and frequency are investigated. Thermally activated dielectric relaxations are shown in the temperature dependence of the complex permittivity, and the respective peaks are found to be shifted to higher temperatures as the measuring frequency increases. In Arrhenius plots, activation energies of 0.32 and 0.24 eV for the high- and low-temperature relaxations are observed, respectively. Analysis of the relationship between the real and imaginary parts of the permittivity and the frequencies allows us to explain the dielectric behavior of DyMnO3 ceramics by the universal dielectric response model. A separation of the intrinsic grain and grain boundary properties is achieved using an equivalent circuit model. The dielectric responses of this circuit are discerned by impedance spectroscopy study. The determined grain and grain boundary effects in the orthorhombic DyMnO3 ceramics are responsible for the observed high- and low-temperature relaxations in the dielectric properties.