• The Korean Journal of Ceramics
• /
• v.5 no.2
• /
• pp.99-103
• /
• 1999

Compressive creep of dense polycrystalline $BaTiO_3$, with average grain sizes of 19.3-52.4$\mu\textrm{m}$, has been investigated at 1100-$1300^{\circ}C$ in air or under controlled atmospheres $(10^2-10^5Pa \;O_2)$. Some cavity growth occurred during deformation because of non-steady-state damage accumulation in the form of cavitation. Comparison of the creep data of polycrystalline BaTiO3 with existing diffusivity and creep data for perovskite oxides suggested that deformation of polycrystalline $BaTiO_3$ was controlled by the extrinsic lattice diffusion of barium or titanium.

• Proceedings of the Korean Powder Metallurgy Institute Conference
• /
• 2006.09a
• /
• pp.670-671
• /
• 2006

We report on the mechanical and structural properties of nanocrystalline 8% and 10% mol yttria stabilized zirconia (YSZ) obtained using mechanical alloying (MA). The as-milled powders show a body-centered cubic structure with grain sizes in the nanometer scale. After uniaxial pressing and sintering the compacts exhibit good mechanical properties. We discuss the correlation of these enhanced properties with the microstructural changes induced by heat treatment.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
• /
• 2000.07a
• /
• pp.436-439
• /
• 2000

Change of dielectric loss of use in high relative permitivity capacitor BaTiO$_3$ ceramic depends on Mn doping have been investigated. The powders used in this study were commercial BaTiO$_3$, TiO$_2$and, MnCO$_3$. Sample was fabricated by conventional ceramic process. The quantity of Mn was changed gradually from 0.lmol% to 10mo1%. The sintering densities were reduced with increasing amount of MnCO$_3$. This result is because of increase of low density second phase BaMnO$_3$. When the samples were doped by over 0.2mol% of MnCO$_3$, average grain sizes were enlarge to several tens ${\mu}{\textrm}{m}$. The dielectric losses were reduced by Mn doping to lmol% but, increased from lmol% to 10mo1% gradually.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
• /
• 2000.07a
• /
• pp.739-742
• /
• 2000

Nanostructured ZnS thin films were grown on the slide glass substrate by the chemical bath deposition using an aqueous so1ution Of ZnSO$_4$and CH$_3$CSNH$_2$at 95$^{\circ}C$. The average grain sizes of the ZnS thin film estimating from the Debye-Scherrer formula are 4.8 nm. The optical transmittance edge of the ZnS thin films (4.0 eV) was shifted to the shelter wavelength compared with that of the bulk ZnS (3.67 eV) due to the quantum size effects. The ZnS thin films showed a strong photoluminescence intensity and a sharp emission band from 410 to 480 nm 3t room temperature. The PWHM of photoluminescence peak was about 40 nm. For the viloet(410 nm) and blue(480 nm) emission of the ZnS thin films, the temperature dependence can be described by an Arrhenius equation with an activation energy of 168 and 157 meV, respectively.

• Journal of the Semiconductor & Display Technology
• /
• v.17 no.4
• /
• pp.46-50
• /
• 2018

The purpose of this study is to analyze effects of filtering system of cutting fluid which is used for machining silicon electrode. For the research, different sizes of filter clothes are applied to check grain size of sludge of cutting fluid. Surface roughness of machined workpiece, depth of damage inside of silicon electrode, and suspended solids of cutting fluid are experimented and analyzed. From these experiments, it is verified that filtering system of cutting fluid is very important factor for machining. Results of this study can affect various benefits to the semiconductor industry for better productivity and better atmospheric pollution in workplace.

• Journal of Korean Society of Coastal and Ocean Engineers
• /
• v.21 no.6
• /
• pp.444-452
• /
• 2009

Textural parameters were calculated from the surface sediments collected from Jinu-do beach in Nov. 2005 and May 2006. In Nov. 2005 and May, 2006, the grain size distribution of surface sediments shows that the mode of $3.0\phi$(i.e., 0.125 mm) dominated the west beach of Jinu-do, but in the east beach the mode of $3.0\phi$(i.e., 0.125 mm) decreased and the mode of $2.5\phi$(i.e., 0.177 mm) was apparently distinct, resulting in the more coarsening trend. Mean grain size of surface sediments also indicates little difference in the west beach between two investigations, but the increasing difference between mean grain sizes in the east beach, showing more coarsening pattern. Such seasonal pattern corresponds to the positive skewness in the east beach in May, 2006. As a result, after the winter in 2005, the surface sediments in the west beach of Jinu-do experienced a little variation, whereas the apparent coarsening of surface sediments occurred in the east beach by removal of $3.0\phi$(i.e., 0.125 mm) fine-grained sand particles. The observed seasonal change may be attributed to the different hydrographic condition and sediment delivery/removal on the surface sediments between the west beach and the east beach of Jinu-do through the increased precipitation and more freshwater discharge from the Nakdong River during the summer and the intensified wave and tide during the winter in the Nakdong River estuary.

• Economic and Environmental Geology
• /
• v.46 no.3
• /
• pp.215-220
• /
• 2013

We estimated the hydraulic conductivity of the sediments using constant-head permeability tests and electrical resistivity measurements with Jumoonjin standard sand of a uniform size and glass beads of different grain sizes. In this study, we determined the variations of the porosity, the hydraulic conductivity, and the resistivity in case 1 (changing the packing of the Jumoonjin standard sand) and in case 2 (varying the size of the glass beads). The results of case 1 showed that the hydraulic conductivity decreased with an increase in the electrical resistivity. This occurred because the sand grain while packing became rhombohedral with the a decrease of both the pore size and porosity. The results of the case 2 showed that the hydraulic conductivity increased due to the increase in the pore size as caused by the increased glass bead size. In addition, the porosity decreased and the electrical resistivity increased. Therefore, the relationship between the hydraulic conductivity and the electrical resistivity is negatively proportional as regards the grain packing with a change from cubic to rhombohedral whereas this relationship is positively proportional to the increase in the grain size.

• Nuclear Engineering and Technology
• /
• v.28 no.5
• /
• pp.458-466
• /
• 1996

The effects of dopants on the modification of microstructure of UO$_2$ and UO$_2$-4wt%CeO$_2$ sintered pellets have been studied in hydrogen and $CO_2$/CO mixture atmospheres by using $Ta_2O_5$, TiO$_2$ and $Nb_2O_5$ as sintering additives. The dopant were added as oxide powders and homogenized by attrition milling. The mixed powders were pressed, and then sintered in hydrogen at 1$700^{\circ}C$ , or in oxidizing atmosphere using Controlled $CO_2$/CO mixtures at 125$0^{\circ}C$. Both density and microstructure of UO$_2$ are modified by the addition of dopants in reducing atmosphere. The sintered density is increased with $Ta_2O_5$ addition up to 0.33wt% and subsequently decreased with higher content of the additive. The effect on the densification and the gain growth are apparent with the addition of 0.24wt% $Nb_2O_5$. With 0.lwt% titania and 0.6wt% $Ta_2O_5$, the sintered density is decreased, but the grain size is increased. In oxidizing atmosphere, the grain sizes for UO$_2$ doped with the above additives are smaller than that for pure UO$_2$. The grain size of Ta or Nb-doped UO$_2$ is decreased with increasing $CO_2$/CO ratio, but that of pure UO$_2$or T-doped UO$_2$ is increased. A large portion of second phases is observed in UO$_2$ doped with 0.lwt% TiO$_2$ sintered in hydrogen atmosphere, while, in $CO_2$/CO atmospheres, the second phases or dopant agglomerates are not observed. For UO$_2$-4wt%CeO$_2$ mixed oxide, the effect of additives on the gain growth is not so much as that for the pure UO$_2$. This is attributed to the formation of clusters by dopant cations and Ce ions, so that the additives contribute to a lesser exent to the grain growth for the mixed oxide.

• Journal of the Korean Ceramic Society
• /
• v.41 no.10 s.269
• /
• pp.728-734
• /
• 2004

The effect of microstructure of WC-Co substrates which have different WC grain sizes from submicron to 5 $\mu$m on the diamond-substrate adhesion strength was investigated. The substrates were pre-treated by two methods : chemical etching with Murakami's solution and subsequently with $H_2SO_4$, and thermal heat-treatment. The adhesion strength was estimated by degree of peeling after Rockwell indentation. Diamond films of 20 $\mu$m thickness deposited on the heat-treated substrates showed an excellent adhesion strength at the load of 100 kg, which ascribed to the large and elongated WC grains. However, the cutting edge of insert was deformed after heat treatment and the surface morphology of heat treated substrate strongly affected on the surface roughness of the deposited diamond films. On the contrary, the diamond film of 10 $\mu$m in thickness on the chemically etched substrates of average WC grain size over 2 $\mu$m showed good adhesion strength enough not to peel-off under a load of 60 kg. Especially, the substrate of average WC grain size over 5 $\mu$m exhibited much improved reliability of adhesion comparing with the substrate of average grain size under 2 $\mu$m. No substrate deformation was observed in this case after the chemical etching, which is more advantageous and more practical in terms of precious machining than the heat treatment case.

• Journal of Sensor Science and Technology
• /
• v.11 no.6
• /
• pp.327-334
• /
• 2002

Fine particles of $SnO_2$ were fabricated by the sol-gel powder processing using tine(II) chloride dihydrate($SnCl_2{\cdot}2H_2O$) and ethanol($C_2H_5OH$) as raw materials. The powders were investigated about the properties and electrical sensing. Gel powders were fabricated by drying of sol at $120^{\circ}C$ after aging 72hrs and 168hrs. The amount of $SnO_2$ phase was increased below $600^{\circ}C$ due to the elimination of volatile components, and the $SnO_2$ phase was almost completed by the heat treatment at $700^{\circ}C$ for 30min. The grain sizes were about 30nm below $700^{\circ}C$, and it showed the narrow distribution of the grain sizes. The specimens to measure electrical properties were fabricated by the thick film screen printing technique on the alumina substrates. The conductance of $SnO_2$ was showed the intrinsic behaviour of semiconducting ceramics above at $450^{\circ}C$. The constant conductance was observed in the temperature range of $200{\sim}450^{\circ}C$. The sensing properties of response time, recovery, and sensitivity of CO were improved with aging time.