• Title/Summary/Keyword: Glasses

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Refractive-index Prediction for High-refractive-index Optical Glasses Based on the B2O3-La2O3-Ta2O5-SiO2 System Using Machine Learning

  • Seok Jin Hong;Jung Hee Lee;Devarajulu Gelija;Woon Jin Chung
    • Current Optics and Photonics
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    • v.8 no.3
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    • pp.230-238
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    • 2024
  • The refractive index is a key material-design parameter, especially for high-refractive-index glasses, which are used for precision optics and devices. Increased demand for high-precision optical lenses produced by the glass-mold-press (GMP) process has spurred extensive studies of proper glass materials. B2O3, SiO2, and multiple heavy-metal oxides such as Ta2O5, Nb2O5, La2O3, and Gd2O3 mostly compose the high-refractive-index glasses for GMP. However, due to many oxides including up to 10 components, it is hard to predict the refractivity solely from the composition of the glass. In this study, the refractive index of optical glasses based on the B2O3-La2O3-Ta2O5-SiO2 system is predicted using machine learning (ML) and compared to experimental data. A dataset comprising up to 271 glasses with 10 components is collected and used for training. Various ML algorithms (linear-regression, Bayesian-ridge-regression, nearest-neighbor, and random-forest models) are employed to train the data. Along with composition, the polarizability and density of the glasses are also considered independent parameters to predict the refractive index. After obtaining the best-fitting model by R2 value, the trained model is examined alongside the experimentally obtained refractive indices of B2O3-La2O3-Ta2O5-SiO2 quaternary glasses.

The Investigation of the Wearing Spectacles Rate of Middle School Students in Jeju Islands (제주도 지역 중학생의 안경착용률 조사)

  • Kang, In-San;Choi, Ji-Young;Song, Yun-Young
    • Journal of Korean Ophthalmic Optics Society
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    • v.11 no.3
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    • pp.231-240
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    • 2006
  • This study conducts a questionnaire survey of 492 middle school students in Jeju islands about the rate of using glasses/contact lens, the place and time of visual acuity test, the period of changing the glasses, the purchase price, the mason to change the glasses, the interrelationship between wearing spectacles and residential district, etc. The results are as follows: 1. 45.33% of the object of investigation use the glasses or contact lens to correct their visual acuity. Among them, the student who wears only glasses is 93.27%, the student who wears glasses and contact lens together is 5.83%, the student who wears only contact lens is 0.90%. 2. As for the period of changing his(her) glasses, below 6 month is 20.18%, from 6 month to one year is 52.02%, from one year to two years is 20.18% and more than two years is 7.62%. 3. As for the purchase price to change his(her) glasses, below 30,000won is 13.45%, from 30,000won to 50,000won is 43.50%, from 50,000won to 70,000won is 23.77%, from 70,000won to 100,000won is 15.25% and more than 100,000won is 4.03%. 4. As for the reason of changing his(her) glasses, cause of change of visual acuity is 55.16%, by broken frame and lens is 27.35%, as want to just change his(her) spectacles is 14.80% and as the others is 2.69%. 5. As for the relative importance in purchasing glasses, the student who thinks more frame is 16.59%, the student who thinks more lens is 67% and the student who thinks both frame and lens is 58.74%. 6. As for the frist time of visual acuity test, 1 grade of elementary school is 37.2%, 3 grade of elementary school is 12.56%, 4 grade of elementary school is 11.66% and 6 grade of elementary school is 11.66%. 7. As for the place of visual acuity test to determine the Dptr. of glasses which wear now, opitican's shop is 57.85% and ophthalmic clinic is 42.15%. 8. As for the frist time of wearing the glasses or contact lens for correct his(her) visual acuity, the most of answer(21.97%) is at 6 grade of elementary school. 9. As for the reason why does not wear the glasses or contact lens though his(her) naked binocular vision is below 0.8, as does not feel any difficulty in daily life is 62.5%, as know that the more wear, the more decrease his(her) visual acuity is 15.65%, by economical circumstance is 6.24% and as not good externally is 15.63%, respectively.

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Effect of Boron Content on Atomic Structure of Boron-bearing Multicomponent Oxide Glasses: A View from Solid-state NMR (비정질 소듐 보레이트와 붕소를 함유한 다성분계 규산염 용융체의 붕소의 함량에 따른 원자 구조에 대한 고상 핵자기 공명 분광분석 연구)

  • Lee, A Chim;Lee, Sung Keun
    • Journal of the Mineralogical Society of Korea
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    • v.29 no.3
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    • pp.155-165
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    • 2016
  • Understanding the effect of boron content on atomic structures of boron-bearing multicomponent silicate melts is essential to reveal the atomistic origins of diverse geochemical processes involving silica-rich magmas, such as explosive volcanic eruption. The detailed atomic environments around B and Al in boron-bearing complex aluminosilicate glasses yield atomistic insights into reactivity of nuclear waste glasses in contact with aqueous solutions. We report experimental results on the effect of boron content on the atomic structures of sodium borate glasses and boron-bearing multicomponent silicate melts [malinkoite ($NaBSiO_4$)-nepheline ($NaAlSiO_4$) pseudo-binary glasses] using the high-resolution solid-state NMR ($^{11}B$ and $^{27}Al$). The $^{11}B$ MAS NMR spectra of sodium borate glasses show that three-coodrinated boron ($^{[3]}B$) increases with increasing $B_2O_3$ content. While the spectra imply that the fraction of non-ring species decreases with decreasing boron content, peak position of the species is expected to vary with Na content. Therefore, the quantitative estimation of the fractions of the ring/non-ring species remains to be explored. The $^{11}B$ MAS NMR spectra of the glasses in the malinkoite-nepheline join show that four-coordinated boron ($^{[4]}B$) increases as $X_{Ma}$ [$=NaBSiO_4/(NaBSiO_4+NaAlSiO_4)$] increases while $^{[3]}B$ decreases. $^{27}Al$ MAS NMR spectra of the multicomponent glasses confirm that four-coordinated aluminum ($^{[4]}Al$) is dominant. It is also observed that a drastic decrease in the peak widths (full-width at half-maximum, FWHM) of $^{[4]}Al$ with an addition of boron ($X_{Ma}=0.25$) in nepheline glasses. This indicates a decrease in structural and topological disorder around $^{[4]}Al$ in the glasses with increasing boron content. The quantitative atomic environments around boron of both binary and multicomponent glasses were estimated from the simulation results of $^{11}B$ MAS NMR spectra, revealing complex-nonlinear variation of boron topology with varying composition. The current results can be potentially used to account for the structural origins of the change in macroscopic properties of boron-bearing oxide melts with varying boron content.

A Study on the Current Status of the Glasses Design Industry in Korea (국내 안경 디자인산업 현황에 관한 연구)

  • Yun, Eul-Yo
    • Journal of the Korea Fashion and Costume Design Association
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    • v.15 no.3
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    • pp.199-211
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    • 2013
  • Glasses industry has great growth potential from the future-oriented perspective in Korea. In consideration of the fact that the ratio of aging population increases in this aging society, people have more and more interest in health. Also, their recognition on the cycle to change glasses is changing, and the utility of them as fashion items is increasing day by day, it is expected that the demand for glasses will be even more extended afterwards. Of course, presently it suffers from the gap between cheaper items and expensive ones provided by overseas prominent brands due to the bi-polarization of the market. However, they are pursuing the 2nd growth as export-leading items in the past through international glass exhibitions based on knowhow accumulated for a long time. Therefore, this study aims to examine the current status of glasses design industry in Korea reflecting the actual situations we have now and also understand the problems and limitations internalized in our glass design industry through the research process. As a result, the study has drawn the following conclusions. This paper intends to point out first, the phenomenon of bi-polarization of the glass market in Korea. Second, unequal distribution by region centering around Daegu. Third, the limitations of brand identity. Fourth, the limitations of information, planning, and marketing power. Fifth, passive conduction of international events and their insufficient effects. This study concludes that all these problems can be solved through 'planning and design, and marketing power'.

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Glasses Removal from Facial Images with Recursive PCA Reconstruction (반복적인 PCA 재구성을 이용한 얼굴 영상에서의 안경 제거)

  • 오유화;안상철;김형곤;김익재;이성환
    • Journal of the Institute of Electronics Engineers of Korea SP
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    • v.41 no.3
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    • pp.35-49
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    • 2004
  • This paper proposes a new glasses removal method from color frontal facial image to generate gray glassless facial image. The proposed method is based on recursive PCA reconstruction. For the generation of glassless images, the occluded region by glasses should be found, and a good reconstructed image to compensate with should be obtained. The recursive PCA reconstruction Provides us with both of them simultaneously, and finally produces glassless facial images. This paper shows the effectiveness of the proposed method by some experimental results. We believe that this method can be applied to removing other type of occlusion than the glasses with some modification and enhancing the performance of a face recognition system.

A study on the Structure of (62-x)CaO·38Al2O3 ·xBaO Glasses by Molecular Dynamics Simulation (분자동력학법에 의한(62-x)CaO·38Al2O3 ·xBaO 유리의 구조 분석)

  • Lee, Seong-Joo;Kang, Eun-Tne
    • Journal of the Korean Ceramic Society
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    • v.44 no.3 s.298
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    • pp.175-181
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    • 2007
  • Molecular dynamics simulation (MD) of $(62-x)CaO{\cdot}38Al_{2}O_{3}{\cdot}xBaO$ glasses has been carried out using empirical potentials with the covalent term. The simulations closely reproduce the total neutron correlation functions of glass with 5 mol% BaO and physical properties of these glasses such as elastic constants. For these glasses, aluminum is tetrahedrally coordinated by oxygen, but there is a part of five-fold and six-fold coordination of aluminum. There are no major changes to the mid-range structure of glass, as barium is substituted for calcium. To predict the barium coordination number, we have used the bond valence (BV) theory and also compared the results of simulation with Bond valence. The coordination number for oxygen around barium atoms is close to 8 and the average distance of barium and oxygen is nearly 2.80 A. The viscosity of these glasses increases with the content of barium oxide substituted for calcium oxide.

Preparation and Characterization of Water-Soluble Phosphate Glasses Containing Cu by Sol-Gel Method (졸-겔법에 의한 Cugkadb 인산염계 수용성 유리의 제조 및 특성)

  • 오승환;최세영;김경남
    • Journal of the Korean Ceramic Society
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    • v.35 no.4
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    • pp.319-324
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    • 1998
  • Sol-gel derived phosphate water-sioluble glasses containing Cu were prepared. Powder-shape of glasses were added in D.I water used polyethylene bottle. After solution contained glass powder were submerged in water bath on 25$^{\circ}C$ their dissolution behavior/characteristics bactericidal effect and cytotoxicity test were evaluated. The maximum amount of Cu(35 mol%) via sol-gel method was more 5 mol% increased than that with melting process. The stage of total dissolution was more dominant than that of selective leaching dur-ing dissolution due to dissolved amount of glasses increased linearly with time. The ratio of Cu+ to {{{{ {Cu }^{2+ } }} was 3:7 so that the structure of glasses is more predominant 2-dimension chain structure than 3-dimenshion po-lymeric structue. The stage of total dissolution was more dominant than that of selective leaching during dissolution. Bactericidal effect against all bacteria showed that solutions which contained 40 ppm and 100 ppm of Cu killed 80 percentages of bacteria within 2 hours and 100 percentages of those within 12 hours. The results of cytotoxicity test for L929 cells showed no cytotoxicity were observed within 96 hours for dis-solved solution that contains 40 ppm and 100 ppm of Cu.

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Children Pain Using Four Pain Assessment Tools - Faces, Glasses, Chips, Colors (4개의 도구를 이용한 아동의 통증)

  • Kim, Kyeong-Uoon
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.13 no.7
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    • pp.3016-3022
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    • 2012
  • The purpose of this study is to measure and evaluate the degree of the pain using tools such as faces, glasses, chips, and colors for 96 children in three general hospitals. The children preferred faces, glasses, chips and colors in order, and they preferred orange color for pain-free and black for intense pain. The pain score was significantly high with the children who did not have experience in hospital except colors tool in the difference by means of general characteristics(faces, glasses, chips; p<0.05). Faces, glasses, chips, colors tools are pain assessment tools which are easy simple to handle by children including family and medical personnel. We expect these tools will be used in many ways to assess pain according to a child's age in a clinical setting.

Structure and Antibacterial Property of ZnO-B2O3-P2O5 Glasses

  • Bae, Jun-Hyeon;Cha, Jae-Min;Kim, Dae-Sung;Kim, Young-Seok;Ryu, Bong-Ki
    • Journal of the Korean Ceramic Society
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    • v.55 no.2
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    • pp.135-139
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    • 2018
  • The glass structure and antibacterial properties of $(65-x)ZnO-xB_2O_3-35P_2O_5$ glasses were investigated. Zinc borophosphate glasses were prepared using a conventional melt-quenching technique at $1000^{\circ}C$. Glass transition temperature and CTE were studied and the structure of zinc borophosphate glasses was evaluated by FTIR. The $Zn^{2+}$ state increase with increasing ZnO content was investigated by XPS and a single sharp Zn $2P_{3/2}$ peak was confirmed, showing that Zn $2P_{3/2}$ exists as $Zn^{2+}$. In order to to evaluate the antimicrobial activity, Escherichia coli (E. coli) was used following the Japanese Industrial Standard JIS Z 2801; the E. coli death rate was found to increase with increasing $Zn^{2+}$ content of glasses.