• Current Optics and Photonics
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• v.3 no.5
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• pp.423-428
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• 2019

Visibility of road-surface markings is one of the critical issues that should be secured for self-driving cars as well as human drivers. Glass beads are taking on the role of retroreflectors, and therefore are considered a necessity in modern pavements. In this context, retroreflectance is sensitively dependent not only on the refractive index of glass beads but also on that of the surrounding medium. This implies that the optimum refractive index of glass beads immersed in water, i.e. under wet conditions, is different from that of glass beads surrounded by air, i.e. under dry conditions. A refractive index of approximately 1.9, which is known to maximize retroreflectance under dry conditions, actually exhibits much poorer retroreflectance under wet conditions. This suggests that glass beads with optimal refractive index for wet conditions need to be installed together with those for dry conditions. We propose a facile but practical model capable of calculating retroreflectance of glass beads surrounded by an arbitrary medium, here water in particular, and experimentally verify its capability of assessing the refractive index of commercial glass beads. Changes in retroreflectance according to the mixing ratio of glass beads with different refractive indices are also discussed, in an effort to propose the proper use of glass beads produced for dry and wet conditions.

• Parasites, Hosts and Diseases
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• v.52 no.3
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• pp.317-319
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• 2014

The oocyst wall is severed by means of mechanical injury or chemical agents. This study reports the percentage of in vitro sporocyst release following mechanical shaking in the presence of varying sizes of glass beads. Glass beads measured 0.5, 1, and 3 mm in diameter and were shaken with the oocysts for different times ranging from 5 sec to 5 min. Approximately 80% of sporocysts were released with 5 min of shaking in the presence of 3 mm glass beads, as well as 30 sec with 0.5 mm beads and 1 mm glass beads. The release of sporocysts of E. tenella was most efficient using 1 mm glass beads and treatment times of 30 sec to 1 min. Therefore, the use of 1 mm glass beads with 30 sec to 1 min of agitation is recommended in order to maximize sporocyst release and recovery and to improve the yield of viable sporozoites for use in biochemical, tissue culture, and immunological applications of coccidia.

• 보존과학연구
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• s.21
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• pp.57-75
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• 2000

We performed the scientific analysis through composition analysis, micro-structure investigation, melting point and hardness test to the glass beads excavated at Naesanri in Gosung. Through this investigation, we could examine closely the characterization of raw materials and manufacture technique As a result of micro-structure investigation of glass beads, it appeared that the bubbles in glass beads have remained. Coloring agents of yellow glass bead was remained to the shape of inclusion. And on observing the transparent solid particle, we can know that these do not melt the raw materials because of low melting temperature of a crucible. The result of composition analysis of all glass beads using ICP, these were classified as $Na_2O_2$-$SiO_2$ type of glass. Also, these added to $AI_2O_3$ to improve the durability. The value of Vickers hardness of glass beads appeared the HV 490-530. The HV 1,440 of the transparent solid particle was much more than that of inner glass bead. This means that raw materials do not melt because of a low melting temperature of a crucible. The result of melting temperature analysis of glass beads using DSC/TGA, it was measured about $1,250^{\circ}C$.

• Bulletin of the Korean Chemical Society
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• v.27 no.4
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• pp.479-483
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• 2006

We developed a microfluidic immunoassay platform for the detection of various analytes such as bacterial pathogen by packing antibody-immobilized glass beads in spatially-isolated microchambers on a microfluidic device. Primary amines of antibody were covalently conjugated to carboxyl-terminated glass beads previously treated with aminosilane followed by glutaraldehyde. Through this covalent binding, up to 905 $\mu$g immunoglobulin G (IgG) per gram of glass beads was immobilized. For application, glass beads attaching antibody specific to Escherichia coli O157:H7, a foodborne pathogen, were packed into a microfluidic device and used for the detection of the serotype. This prototype immunoassay device can be used for the simultaneous detection of multiple analytes by sequentially packing different-sized glass beads attaching different antibody in discrete microchambers on a single microfluidic device.

• Current Optics and Photonics
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• v.3 no.5
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• pp.415-422
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• 2019

Retroreflection of vehicle headlights, as induced by spherical glass beads, is a key optical phenomenon that provides road-surface markings with greatly enhanced visibility, thus better securing a driver's safety in the nighttime as well as in unclear daytime. Retroreflectance of glass beads is a quite sensitive function of their refractive index, so that measurement of the refractive index of glass specifically in the shape of spherical beads needs to be performed within a reasonable uncertainty that is tolerable for road-marking applications. The Becke line method has been applied in assessing refractive index of such glass beads as e.g. an industrial standard in the Republic of Korea; however, the reference refractive-index liquids are not commercially available these days for refractive index greater than 1.80 due to the toxicity of the constituent materials. As such, high-refractive-index glass beads require an alternate method, and in this regard we propose a practically serviceable technique with uncertainty tantamount to that of the Becke line method: Based on comparison of calculated and measured retroreflectance values of commercial glass beads, we discover that their refractive index can be determined with reasonable precision via the retroreflectance measurement. Specifically, in this study the normalized retroreflectance originating from a single glass sphere is computed as a function of refractive index using the Fresnel equations, which is then validated as coinciding well with retroreflectance values measured from actual specimens, i.e. glass-bead aggregates. The uncertainties involved are delineated in connection with radius and imperfections of the glass beads.

• Journal of Conservation Science
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• v.34 no.4
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• pp.305-311
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• 2018

The yellow crystalline material present in yellow and green glass beads excavated from sites in the Baekje region of Korea was previously analyzed through scanning electron microscopy with energy dispersive spectroscopy and X-ray diffraction, revealing that the yellow crystalline material was $PbSnO_3$. This material is a pigment that is rarely seen in the Korean peninsula. Furthermore, some studies have been published on the provenance of lead in this material, which revealed no relationship to Korea, China, or Japan. In this study, we collected all accessible results of analyses on the lead isotope ratio of yellow and green glass beads excavated from the Korean peninsula, specifically from 7 sites in the Baekje region(located in the vicinity of Seoul, Wanju, Hwaseong, Osan, Gongju, Buyeo, and Iksan) and 2 sites in the Silla region(located in the vicinity of Gyeongju and Changnyeong). We subsequently investigated the lead provenance of the opacifying agents in the glass beads through comparison with the current extent of the galena data accumulated for the East Asian region, including Korea, China, and Japan, and for Thailand(Kanchanaburi Province), Southeast Asia. Our analysis determined that the lead provenance of the glass beads excavated from the Korean peninsula was Thailand(Kanchanaburi Province). Beyond our results, further studies should seek to determine the production sites of the glass beads. Obtaining and comparing the scientific analyses of glass beads from India and Southeast Asia would enable research on the glass beads trade through the maritime silk road.

• Applied Chemistry for Engineering
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• v.3 no.3
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• pp.430-439
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• 1992

To improve the adhesion of interface and dispersion of glass beads in the composite, HDPE filled with glass brads, we encapsulated the g1ass beads with polymer by phase separation method using complex coacervation in organic solvent. EMAA and EAA were used as the polymeric wall materials. The microencapsulation efficiency and morphology were observed by thermogravimetric analysis and SEM, respectively. And also we investigated the physical and dynamic mechanical properties of the composite as the function of the beads contents and microencapsulation efficiency. Compared with the composite containing non-treated glass beads, the decrease in tensile strengthe of the composites containing the encapsulated glass beads become markedly small, and about 30~40% Increase in tensile modulus was observed. From the results of the dynamic mechanical analysis, it was found that the adhesion of interface and dispersion could be improved upon encapsulation.

• Journal of Conservation Science
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• v.33 no.5
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• pp.331-344
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• 2017

In this study, glass beads from Osan Sucheong were classified according to color into 10 groups. Among these groups, reddish brown, bluish green, and purplish blue were identified as the main colors of glass beads based on their large quantities in Osan Sucheong. The glass beads of these main colors were then classified according to their chemical compositions and and looked at the changing process. Based on the results, reddish brown and bluish green glass beads can both be divided into five types, and purplish blue glass beads can be divided into four types. Furthermore, according to continuity of type, it was identified as the main attributes that the reddish brown beads belong to two types, whereas the bluish green and purplish blue each belong to one type. Based on a review of primary attributes, beads of these three colors were identified as soda glass and high-alumina glass. The results indicate that these beads came from a single, consistent route of origin into the region. However, it is possible that glass beads came through various routes into Osan Sucheong in the $4^{th}$ century, because many types of chemical compositions have been detected for beads from this time.

• Archives of Pharmacal Research
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• v.27 no.8
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• pp.873-877
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• 2004

This study was designed to determine the optimum conditions of three different factors (mixing time, mixing temperature, and tube size) in reduction of cholesterol in milk using immobilized $\beta$-CD beads. Immobilized $\beta$-CD glass beads were prepared at different conditions of silaniza-tion and $\beta$-CD immobilization reactions. In result, the glass beads (diameter 1 mm) at 20 mM 3-isocyanatopropyltriethoxysilane and 30 mM $\beta$-CD without base showed the highest choles-terol removal rate as 41%. Using above immobilized $\beta$-CD glass beads, the cholesterol removal rate was 40.2% with 6 h of mixing time in 7 mm diameter tube at $10^{\circ}C$. After choles-terol removal from milk, the glass beads were washed for cholesterol dissociation and reused. In recycling study, the cholesterol removal rate was 41%, which was mostly same as that using new glass beads. These results indicated that cholesterol removal rate was about 40% with $\beta$-CD immobilized glass beads, however, the recycling efficiency was almost 100%.

• International Journal of Highway Engineering
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• v.18 no.4
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• pp.69-75
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• 2016

PURPOSES : In this study, we evaluated changes in the retroreflectivity and luminance of phosphorescent road line markings with changes in glass beads and line marking thickness. METHODS : The color of line markings affects their retroreflectivity. Using a chromaticity test, we conducted the analysis of whether phosphorescent road line markings adhered to the "KS M 6080" standard. Then, we measured the dry retroreflectivity and wet retroreflectivity for various glass bead refractive indices. We conducted wet retroreflectivity test using the EN 1436 standard as the basis. We also conducted luminance tests for different glass bead refractive indices and line marking thicknesses. RESULTS : 1. Phosphorescent road line markings specimens satisfied the "KS M 6080" standard. 2. In dry retroreflectivity test, phosphorescent road line markings sprayed with glass beads satisfied the national police agency standard ($240mcd/(m^2{\cdot}Lux)$). Wet retroreflectivity test results showed that except for one type of No.1 glass beads, phosphorescent road line markings specimens sprayed with glass beads of one type of No.3 and two types of No.1 satisfied the national police agency standard ($100mcd/(m^2{\cdot}Lux)$). 3. Phosphorescent road line markings had higher retroreflectivity than non-phosphorescent road line markings in the dry condition. 4. Phosphorescent road line markings sprayed with glass beads demonstrated improved luminance. Luminance increased with higher glass bead refractive index and with increased line marking thickness. However, when the thickness crossed a certain threshold, phosphorescence ceased to increase; this is a characteristic of the phosphorescence phenomenon. CONCLUSIONS : Visibility across short distances can be ensured when phosphorescent road line markings are sprayed with glass beads, because of the retroreflection phenomenon. It is also possible to ensure far visibility using phosphorescent road line markings.