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Synthesis of 1, 1-Diheteroaryl Ethylenes by a Tandem Appel's Dehydration/Thermal Rearrangement Methodology

  • 이기정;허 열;전종갑
    • Bulletin of the Korean Chemical Society
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    • v.20 no.3
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    • pp.341-344
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    • 1999
  • The hydrazones of 2-acetylfuran, 2-acetylthiophene, and 2-acetylpyrrole, were allowed to react with S-methylthioacetimidate hydroiodide (8) to give azinoureas 10, and the reaction of 10 with Appel's dehydration conditions (triphenylphosphine/carbon tetrachloride/triethylamine) led to the corresponding azinocarbodiimides 11, which underwent thermal rearrangement under the reaction conditions to give 1,1-diheteroaryl ethylenes 13.

ON THE SIZES OF DUAL GROUPS

  • Song, Joungmin
    • Bulletin of the Korean Mathematical Society
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    • v.59 no.3
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    • pp.609-615
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    • 2022
  • We give a formula for the sizes of the dual groups. It is obtained by generalizing a size estimation of certain algebraic structure that lies in the heart of the proof of the celebrated primality test by Agrawal, Kayal and Saxena. In turn, by using our formula, we are able to give a streamlined survey of the AKS test.

A Probability Embedded Expert System to Detect and Resolve Network Faults Intelligently (지능적 네트워크 장애 판별 및 문제해결을 위한 확률기반 시스템)

  • Yang, Young-Moon;Chang, Byeong-Yun
    • The Journal of the Institute of Internet, Broadcasting and Communication
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    • v.11 no.2
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    • pp.135-143
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    • 2011
  • Currently network management systems(NMS) just give useful information about the criticality of the alarms and the process of the fault analysis is mainly dependent on the experts who have many years experiences in the field. Due to these reasons it takes very much time and manpower cost to localize the real root of the fault from the alarm information. Therefore, to solve these problems in this research we analyze the probability of the fault for each alarm and provide how to give the problem solving procedure with confidence level and give idea to build a system to realize the problem solving procedure. In addition, we give a case study to show how to use the proposed ideas.

An Empirical Study on Public Child Care Center for the Necessity of the Eco-Environmental Space (친환경공간의 필요성에 따른 구립 어린이집의 사례 연구)

  • Han, Hae-Ryon;Park, Young-Ki
    • Proceedings of the Korean Institute of Interior Design Conference
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    • 2007.05a
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    • pp.91-94
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    • 2007
  • The change of modern society arouse the issue of the family structure and the demand of upbringing. According to the issue, the need of the upbringing is the big interest in society. This study is on the necessity of the eco-environmental space in public child care center. The study progressed with the result of the prior study, the demand of the parents of students in eco-environmental space in child care center. The results of the study are first, the natural light source can import in sky light, side light and atrium in child care center. Second, the indoor garden and interior plants would give the natural feelings. Third, the ponds and waterways in indoor and outdoor would give the empirical experiences. And the last, the stone and clay would give the tender feelings in interior and the sand play in outdoor would give the activities. This study would be the foundation on the upcoming study of the needs of the eco-environmental spaces in child facilities.

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Synthesis of New 2-Thiouracil-5-Sulfonamide Derivatives with Biological Activity

  • Fathalla, O.A.;Zaghary, W.A.;Radwan, H.H.;Awad, S.M.;Mohamed, M.S.
    • Archives of Pharmacal Research
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    • v.25 no.3
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    • pp.258-269
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    • 2002
  • 2-Thiouracil-5-sulfonylchloride 1 reacted with a series of aromatic and heterocyclic amines to give 2a-j. The same compound 1 was reacted with a series of sulphonamides giving different sulphonamides of type 3a-e. On the other hand compound 1 was allowed to react with p-aminoacetophenone givining compound 4 which in turn was allowed to react with derivatives of alkyl thiosemicarbazides to give thiosemicarbazones of type 5a-e, also compound 4 was monobrominated to give compound 6 which in turn was reacted thiosemicarbazones of some aldehydes to give the corresponding thiazole derivatives 7a-f. In the same time compound 4 was reacted with a series of aromatic and heterocyclic aldehydes givining chalcones 8a-g (Claisen-Schemidt reaction). Also compound 4 was allowed to react with a series of aromatic and heterocyclic aldehydes, ethyl cyano acetate and/or malononitrile, and ammonium acetate giving pyridine derivatives 9a-d and 10a-e respectively. The biological effects of some of the new synthesized compounds was also investigated.

An Wireless Mobile-Fixed Station System for Remote High Quality Multimedia Emergency System (원격 응급 진료 시스템을 위한 무선 환경에서의 고정 연결 이동-고정시스템 구현)

  • 박정훈;박진배;유선국;윤태성
    • The Transactions of the Korean Institute of Electrical Engineers D
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    • v.52 no.8
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    • pp.443-451
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    • 2003
  • Many attempts have been made for the health and lives of patients at a remote site. but little attention has been given to emergency system using wireless or other intelligent networks. In this paper, shown is a remote emergency system which can be used in an ambulance. It possibly gives a great help to the patients who may lose their lives, in other words, gives pre-hospital cure to them being sent to the hospital. Doctors or specialists are able to give a quick help which may give a new life to patients. This system deal with very important patient's data-ECG, SpO$_2$, blood pressure, biomedical signal data etc. - as other emergency system. A good performance better than other system is many but shortly spoken as follows. First, this system is user friendly system activated in windows 2000 environment. Second, MPEG4 and ECG data sent to the other station for specilists can give a pre-hospital cure to patients in advance. Third, there exist effective algorithms to operate this system. Fourth, this system has been made with software mostly, so this system can be easily embedded in IBM compatible computer. In addition to this performance, for the better and reliable system, various tests were proceeded and recursively tested. Tests were made in EV-DO wireless network and Local Area Network. This mobile-fixed remote emergency system using wireless network like EV-DO network will give a great usage to needed area.