• Title/Summary/Keyword: Gaseous pollutants

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Developing a Method for Detecting the Asian dust event Among High $PM_{10}$ events Using Aerodynamic Particle Sizer (APS) (Aerodynamic Particle Sizer (APS)를 이용한 고농도 $PM_{10}$ 사례 중 황사 판별기법 개발)

  • Lee, Young-Gon;Cho, Chun-Ho;Kim, Myoung-Soo
    • Atmosphere
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    • v.18 no.1
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    • pp.25-32
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    • 2008
  • Log normalized volume size distribution (dV/dlog$D_p$) with 52 size ranges from 0.5 to $20.0{\mu}m$ was measured for the cases of high $PM_{10}$ mass concentration (> $200{\mu}gm^{-3}$) using the Aerodynamic Particle Sizer (APS) at the Korea Global Atmosphere Watch Center (KGAWC) from 6 April, 2006 to 5 April, 2007. Black Carbon (BC), gaseous pollutants of $NO_X$ and $SO_2$ and ${\AA}ngstr\ddot{o}m$ exponent were also measured to examine the properties of the volume size distribution. From distinct difference of the high volume concentration (> $100{\mu}m^3cm^{-3}$), the volume size distribution for each event day was clasified into four types: (1) Type 1 had the high volume concentration for supermicron particles from 2.3 to $6.0{\mu}m$ and maximum average volume concentration was $160.7{\mu}m^3cm^{-3}$ at $3.5{\mu}m$. (2) Type 2 represented the high volume concentration in the both size range of submicron ($0.7-1.0{\mu}m$) and supermicron particles ($2.1-4.1{\mu}m^3cm^{-3}$ and $136.2{\mu}m^3cm^{-3}$ were found at 0.8 and $3.3{\mu}m$ respectively. (3) Type 3 showed the high volume concentration in the size range of $0.5-3.5{\mu}m$ and highest volume concentration of $201.1{\mu}m^3cm^{-3}$ at the particle size bin of $0.8{\mu}m$. (4) Type 4 was characterized by the high volume concentration for the fine particles less than $1.2{\mu}m$ and very high concentration of $446.8{\mu}m^3cm^{-3}$. ${\AA}ngstr\ddot{o}m$ exponent, concentration of gaseous ($NO_X$ and $SO_2$), and particle (BC) pollutants suggested that Type 1 was a typical volume size distribution for the Asian dust and Type 3 provided transportation of air pollutants. The distribution in Type 2 found to have both characteristics of the Asian dust and air pollutants, and Type 4 was took place during the foggy atmosphere containing high density of local pollutants. Based on the properties of volume size distribution, we can identify the three major events contributing the increase of $PM_{10}$ mass concentration, and hope to provide a guideline for discriminating the Asian dust from high $PM_{10}$ events. More case studies and longeto advance this determination method.

A Study on the Concentration Distribution Characteristics of Air Pollutants by Yellow Sand Phenomenon (황사현상에 의한 대기오염물질의 농도분포 특성에 관한 연구)

  • 이용기;김종찬;최승석;임홍빈;최양희;이수문
    • Journal of environmental and Sanitary engineering
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    • v.17 no.2
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    • pp.71-78
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    • 2002
  • This study was conducted to evaluate the concentration distribution characteristics of air pollutants by the yellow sand from China. The concentrations and chemical properties of FPM contained in the yellow sand were compared with those of air pollutants when having no yellow sand in order to estimate the variation characteristics and the originated source of air pollutants moved by yellow sand. The concentrations of PM-2.5 and PM-10 contained in the yellow sand showed an increase of 2.3 to 2.7 times than usual, and the concentrations of NO2 and SO2 in the gaseous pollutants showed an increase of about 1.6 times by yellow sand, and thus the air contamination was much influenced by yellow sand phenomenon. The concentrations of inorganic elements contained in FPM from the yellow sand showed a higher concentration variation in the order of Al>Mg>Zn>Pb than usual. The concentration coefficient of air aerosol during the yellow sand period showed that Na, K, Ca, Mg and Fe were originated from natural source, and Pb, Cr, Cd, Cu and Zn were originated from artificial source for inorganic elements. The correlation analysis between FPM and inorganic elements showed in the descending order of Al>K>Pb>Mg, and thus the deposited amount of Pb was influenced by that of yellow sand. The average concentrations of PM-10 measured during the yellow sand period exceeded the Korea Air Environmental Standard and showed a excess rate of 3.4 times in the maximum but the average concentrations of PM-2.5 showed within the United States Air Environmental Standard.

Theoretical Study on the Characteristics of Pulverized Coal Combustor with 2 Stage Combustion (2단 연소방법에 의한 미분탄 연소기의 특성에 관한 이론적 연구)

  • Joo, Nahm-Roh;Choi, Sang-Il;Kim, Ho-Young
    • 한국연소학회:학술대회논문집
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    • 1997.06a
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    • pp.103-112
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    • 1997
  • In the combustion of the pulverized coal compared with that of liquid fuel or gaseous fuel, serious pollutants such as ash, $NO_x$ and $SO_x$ are released to surroundings. The objective of this study is the reduction of such pollutants in the combustion process. The modeling of cyclone combustor which uses the method of two stage combustion was carried out. The main burner length, scattering angle and air/fuel ratio were considered as parameters. The results show that the shorter the main burner length is, the less the amounts of coals which exit the combustor directly are, but the scattered input of coal is required anyway in order to collect all ashes. It is recommended that the shorter the main burner length is, the less the scattering angle is. And in the case of the scattered input compared with no scattering, the temperature in the combustor is more uniform and the amount of volatile is more reduced.

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Methodological Approaches to Reduce Uncertainties Associated with Air Sampling : Development and Assessment of a Six-port Manifold MFC System (대기 중 오염물질의 시료채취시 관측오차 저감방법에 대한 연구 : 6구형 매니폴더를 장착한 MFC system의 개발과 평가)

  • 김기현;오상인;최여진;김민영;최규훈
    • Journal of Korean Society for Atmospheric Environment
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    • v.19 no.4
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    • pp.377-386
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    • 2003
  • In order to develop a confident sampling technique, we designed and constructed a 6-port manifold MFC sampling system for collecting gaseous pollutants in air. Using this instrumentation, we tested the performance criteria of MFC system in terms of: (1) flow rate; (2) MFC-to-MFC variability; (3) tube-to-tube variability; and (4) time. It was interesting to find that the later two factors did not show any significant variations, while the former two show substantially large variations. However, as most of those variabilities are consistent enough to form systematic patterns, we were able to explain the occurrence patterns of all those MFC biases in terms of those four major variables. The overall results of our experiment suggest that one needs to use correction factor for each MFC unit under a given flow rate to maintain optimal accuracy and precision for sampling of those pollutants.

Hydrogen Peroxide Concentrations in Air in Seoul (서울시 대기 중 $H_2O_2$의 농도)

  • 강충민;김희강
    • Journal of Korean Society for Atmospheric Environment
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    • v.16 no.1
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    • pp.61-68
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    • 2000
  • Gas-phase hydrogen peroxide(H2O2) concentrations were measured to investigate it's distribution in the ambient air in downtown Seoul(Kwanghwamum and Mullae-dong). These measurements were made during four season, from April 30, 1998 to January 29, 1999, using Cold Trap and HPLC. Measurements were also made of other photochemical oxidants and trace gases(O3, NO2, CO and SO2) and meteorological parameters(relative humidity, temperature, solar radiation and wind speed). The mean of all observations was 0.10 ppbv and the range measured was below the level of detection(>0.01 ppbv) to 0.47ppbv. The higher seasonal mean concentrations showed during the summer(0.21 ppbv) and concentrations of H2O2 showed a diurnal variation with maximum concentrations in the afternoon(12:30∼14:00). The results from the corrrelation analysis showed that the concentration of gaseous H2O2 is strongly dependent on the other air pollutants(NO2, CO and O3) and meteorological parameters(relative humidity, temperature and solar radiation.)

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Simultaneous Removal of Gaseous and Particulate Pollutants in a Room With Optimal Ventilation System (최적 환기 시스템에 의한 실내에서의 가스 및 입자상 오염물의 동시 제거에 관한 연구)

  • 조용수;여석준
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 2003.05b
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    • pp.433-434
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    • 2003
  • 급속한 산업 발전과 더불어 산업전반에 걸쳐 환경문제가 심각해지면서 생활의 질적 향상에 따른 쾌적 환경을 추구하기 위해 실내와 작업장 내에 떠 있는 먼지나 유해가스 등의 오염물질로 인한 직업성 질병에 대한 관심이 높아지고 있다 실내ㆍ외를 불문하고 환경오염이 인체 건강 및 위생에 미치는 영향은 오염물에 대한 노출시간에 관계하기 때문에 하루의 대부분의 시간을 실내에서 생활하는 현대인에게 실내 환경의 질은 아주 중요하다. 질의 물리적 특성에 따른 가스상, 입자상의 거동 및 농도분포에 대한 수치 해석적 연구는 매우 미흡한 실정이다. (중략)

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Tunable Diode Laser Absorption Spectroscopy for Environmental Monitoring (파장가변 다이오드 레이저 흡수 분광학을 사용한 대기환경분석)

  • Ju Sang-U;Kim Seong-Geun
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 2003.11a
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    • pp.247-248
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    • 2003
  • Tunable diode laser absorption spectroscopy (TDLAS) has been widely used in environmental monitoring of gaseous species in the past decade. TDLAS is a direct measurement technique for pollutants such as NOx without any interference from other species. Because of its superior spectral purity (~0.001 ­$cm^{-1}$), absorption linewidths with resolvable rotational structure can be studied in the mid infrared region where strong fundamental vibrational transitions of molecules appear. (omitted)

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Estimation of Gaseous Air Pollutants Deposition Fluxes at Yong-dam Reservoir (용담호 주변지역 가스상 대기오염물질 침적량 추정)

  • 김학민;정구회;김재분;정재호;이범진;김선태
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 2003.11a
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    • pp.364-365
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    • 2003
  • 최근 대기기인 오염물질이 환경계에 미치는 영향에 대한 관심이 높아짐에 따라 호소수질에 직ㆍ간접적으로 영향을 주는 대기오염물질에 대한 관심이 커지고 있다. 특히 호소에 유입되는 영양염류 중 질소화합물에 대한 기여수준을 평가한 최근자료에 의하면 대규모 호소 중 89%에 상당하는 호소수내의 질소성분이 자연적으로 존재하는 양을 초과하고 있는 것으로 판단하고 있으며, 초과된 질소성분 중 최고 38%가 대기오염물질과 관련된 질소성분인 것으로 보고하고 있다. (중략)

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