Journal of Korean Society for Atmospheric Environment (한국대기환경학회지)

Korean Society for Atmospheric Environment (한국대기환경학회)
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Hydrogen Peroxide Concentrations in Air in Seoul

서울시 대기 중 $H_2O_2$의 농도

  • 강충민 (건국대학교 환경공학과) ;
  • 김희강 (건국대학교 환경공학과)
  • Published : 2000.02.01
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Abstract

Gas-phase hydrogen peroxide(H2O2) concentrations were measured to investigate it's distribution in the ambient air in downtown Seoul(Kwanghwamum and Mullae-dong). These measurements were made during four season, from April 30, 1998 to January 29, 1999, using Cold Trap and HPLC. Measurements were also made of other photochemical oxidants and trace gases(O3, NO2, CO and SO2) and meteorological parameters(relative humidity, temperature, solar radiation and wind speed). The mean of all observations was 0.10 ppbv and the range measured was below the level of detection(>0.01 ppbv) to 0.47ppbv. The higher seasonal mean concentrations showed during the summer(0.21 ppbv) and concentrations of H2O2 showed a diurnal variation with maximum concentrations in the afternoon(12:30∼14:00). The results from the corrrelation analysis showed that the concentration of gaseous H2O2 is strongly dependent on the other air pollutants(NO2, CO and O3) and meteorological parameters(relative humidity, temperature and solar radiation.)

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References

  1. 건국대학교 석사학위논문 수도권지역에서 광화학반응에 의한 $H_2O_2$와 HNO₃생성에 관한 연구 강충민
  2. 도시지역 광화학반응과 2차오염물질 생성에 관한 연구(Ⅰ) 국립환경연구원
  3. Geophys. Res. Lett. v.19 Low yields of SO₂ from dimethyl sulfide oxidation in the marine boundary layer Bandy, A.R.;D.L. Scott;B.W. Bloomquist;S.M Chen;D.C. Thorton
  4. Nature v.317 Chemical mechanisms of acid generation in the troposhet Calvert, J G.;A. Lazrus;G.L. Kok;B.G. Heikes;J.G. Walegn;J Lind;C.A. Cantrell
  5. Int. J Chem. Kinet. v.9 The dependence on H₂O and on NH₃ of the kmetics of the self reactron of HO₂· in the gas phase formation of HO₂· H₂O and HO₂· NH₃ complexes Hamilton, E.J;R R Lii
  6. Atmos Environ. v.30 no.6 Hydrogen peroxide and organic hydroperoxide concentrations in air in a Eucalyptus Forest in Central Portugal Jackson, A.V.;C N. Hewitt
  7. J. of Atmos. and Ocean. Tech. v.12 Method for the collection and HPLC analysis of hydrogen peroxide and C₁ and C₂ hydroperoxides in the atmosphere Lee, M.H.;B.C. Noone;D O'sullivan;B.G. Heikes
  8. North Carolina Air & Wase Manage. Assoc. v.44 Analysis of gaseous hydrogen peroxide concentrations in Raleeigh Mita, D.;V.P. Aneja
  9. Institute of Geophysics and Planctary Physics Publication no.2803 Atmospheric H₂O₂measurement comparison of cold trap method with impinget bubbling method Sakugawa, H.;I. R. Kalpan
  10. Acid Rain Gaseous hydrogen peroxide in Los Angeles air: implication to its availability for oxidizing atmospheric SO₂ Sakugawa, H.;I R Kaplan
  11. Atmos. Environ. v.27A no.9 Comparison of H₂O₂ and O₃ content in atmospheric samples in the San Bernardino Mountains, Southern California Skugawa, H.;I.R. Kaplan
  12. Atmos. Environ. v.31 no.8 Measurements of hydrogen peroxide and individual organic peroxides in the marine troposphere Sauet, F.;S. Limbach;G.K Moortgat
  13. Atmos. Environ. v.20 A homogeneous mechanism for use in a regional acid deposition model Stockwell, W R