• 한국진공학회지
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• 제7권1호
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• pp.29-34
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• 1998

PECVD방법으로 증착된 비정질 실리콘(a-Si)박막이 고상결정화되고 x-선 회절 (XRD)방법으로 조사되었다. a-Si박막들은 기판 온도 120-$380^{\circ}C$사이에서 Si(100)웨이퍼 위에 $SiH_4$가스 혹은 수소희석된 $SiH_4$가스로 증착되고, $600^{\circ}C$로 가열되어 결정화되었다. 고상화 되었을 때(111), (220), (311)XRD피크들이 나타났고 (111) 우선방위가 두드러졌다. 고상결정 화된 다결정 실리콘(poly-Si)박막들의 XRD피크의 세기는 기판온도가 낮아짐에 따라 증가되 었고, 수소희석은 고상화 효과를 감소시켰다. XRD로 측정된(111)결정립의 평균크기는 기판 온도가 낮아짐에 따라 약 10nm로 증가하였다. 기판온도가 낮아질수록 증착속도는 증가하였 으며, 결정의 크기는 증착속도와 밀접한 관계가 있었다. Si계의 구조적 무질서도가 클수록 고상화에 의한 결정립의 크기도 커지는 것으로 생각된다.

• 전기학회논문지
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• 제57권12호
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• pp.2199-2201
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• 2008

Sulfur hexafluoride($SF_6$) is a gaseous dielectric used in high voltage electrical equipment such as an insultor or arc quenching medium in the transmission and distribution of electricity. however, $SF_6$ is one of the greenhouse gases(GHG) with a global warming potential that is 23,900 times greater than that of carbon dioxide($CO_2$). for this reason, $SF_6$ emissions in electric equipment shall be controlled to reduce GHG and improve cost-effective use of $SF_6$ for economical benefits. Until recently there has not been any investigation on $SF_6$ emission characteristics and inventory in Korea. To understand emission characteristics during the use-phase, the scope of this study was limited to the following closed pressure system equipment from 10 substations in Korea. This study highlights (1) the investigation of sampling/analysis methodology for $SF_6$ emissions in high voltage equipment, (2) the estimation of $SF_6$ emissions in the use-phase, and (3) the comparison between the emission ratio and the mass-balance applied to inventory study. According to this study, the majority of emissions were related to electric equipment nameplates and the rest of the emissions were related to the handling of $SF_6$ during operations. from this result, emission ratios estimated from this study were similar; GIS was 14% and GCB was 13%, as maintenance process conditions were the same as manual process conditions for both equipment.

• 전기학회논문지
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• 제66권12호
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• pp.1889-1894
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• 2017

Global automobile manufacturers are developing electric vehicles (EVs) to eliminate the pollutant emissions from internal combustion vehicles and to minimize fossil fuel consumptions for the future generations. However, EVs have a disadvantage of shorter traveling distance than that of conventional vehicles. To answer this shortfall, more batteries are installed in the EV to satisfy the consumer expectation for the driving range. However, as the energy capacity of the battery mounted in the EV increases, the amount of heat generated by each cell also increases. Naturally, a better battery thermal management system (BTMS) is required to control the temperature of the cells efficiently because the appropriate thermal environment of the cells greatly affects the power output from the battery pack. Typically, the BTMS is divided into an active and a passive system depending on the energy usage of the thermal management system. Heat exchange materials usually include gas and liquid, semiconductor devices and phase change material (PCM). In this study, an application of PCM for a BTMS was investigated to maintain an optimal battery operating temperature range by utilizing characteristics of a PCM, which can accumulate large amounts of latent heat. The system was modeled using Dymola from Dassault Systems, a multi-physics simulation tool. In order to compare the relative performance, the BTMS with the PCM and without the PCM were modeled and the same battery charge/discharge scenarios were simulated. Number of analysis were conducted to compare the battery cooling performance between the model with the aluminum case and PCM and the model with the aluminum case only.

• 한국기후변화학회지
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• 제5권1호
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• pp.61-70
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• 2014

최근 3년간 항공부문 온실가스 배출량은 연평균 5.7%씩 증가하고 있으며, 국민 소득수준 향상과 국제선 노선 확장 등 저비용 항공사의 성장가속화로 인해 운항 수요가 빠르게 증가하고 있어 항공부문 온실가스 배출량은 지속적으로 증가할 전망이다. 본 연구에서는 국적 A항공사의 2011년도 비행 데이터(FOQA)를 활용하여 비행단계별 연료소비 패턴과 Tier 3a급 온실가스 배출량을 산정하였으며, Tier 2 산정 방법 결과와 비교하였다. 대상 항공기는 보잉계열의 B737-600, B737-700, B737-800이었으며, 국내 노선은 김포-제주, 국제 노선은 인천-나리타를 주요 노선으로 선정하였다. 분석결과, 1회당 총 연료소비량은 김포-제주는 2,298~2,405 kg이고, 비행단계별로는 순항 78% 차지하였으며, 인천-나리타는 4,763~6,291 kg으로 순항 시 87% 차지하였다. 또한, B737-700의 경우, 1회당 평균 분당 연료소비량은 이륙단계에서 순항단계보다 2.6~3.0배 더 많이 소모되는 것으로 나타났다. 한편, Tier 3a급 배출량은 김포-제주는 1회당 평균 7톤, 인천-나리타 1회당 평균 16톤 발생되는 것으로 나타났으며, Tier 3a 방법이 Tier 2보다 2.7% 더 작게 산정된 것으로 나타났다. 이와 같은 통계는 항공기 운항절차별 감축 수단 이행 시 연료절감량과 감축량을 산출하는데 있어 중요한 기초자료로 활용되리라 판단된다.

• 한국산업보건학회지
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• 제16권3호
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• pp.222-232
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• 2006

Objectives: The objective of this study was to propose the total isocyanate analytical method which involves derivation of 2,4-toluene diisocyanate(2,4-TDI), 2,6-toluene diisocyanate(2,6-TDI), 4,4'-methylenediphenyl diisocyanate(4,4'-MDI) and 1,6-hexamethylene diisocyanate(1,6-HDI) using 2-chlorobenzyl alcohol(2-CBA) or 2,4-dichlorobenzyl alcohol(2,4-DCBA), and analyzing of hydrolysate of the synthesized urethane with the gas chromatography(GC)/flame ionization detector(FID), GC/pulsed discharge ionization detector-electron capture detector(PD-ECD) and GC/mass selective detector(MSD). Methods: Urethanes were synthesized by reacting 2,4-TDI, 2,6-TDI, 4,4'-MDI and 1,6-HDI to 2-CBA or 2,4-DCBA. Urethanes was verified by TLC, HPLC/UVD and GC/MSD. For field application, the most suitable condition that 2-CBA coated in glass fiber filter removed completely and urethanes were not removed was searched. 2-CBA generated from hydrolysis of urethanes according to hydrolysis conditions. Diisocyanates were collected on field air and analyzed. Results: Urethanes which were white and solid phase synthesized by reacting 2,4-TDI, 2,6-TDI, 4,4'-MDI, 1,6-HDI and 2-CBA or 2,4-DCBA. And urethanes were verified by TLC, HPLC/UVD and GC/MSD. The most suitable conditions to remove 2-CBA coated in glass fiber filter were $87^{\circ}C$ and 20 mmHg and urethanes were not removed under same condition. Hydrolysis yields of urethanes were 99 % to 111 %. 2-CBA, the hydrolysate of urethanes was analyzed by GC/FID, GC/PD-ECD and GC/MSD. Conclusions: Simultaneous analysis of 2,4-TDI, 2,6-TDI, 4,4'-MDI and 1,6-HDI deriving with 2-CBA and 2,4-DCBA, along with a total isocyanate analysis, was feasible with GC/FID, GC/PD-ECD and GC/MSD. This result will be a guide of further study on total isocyanate analysis.

• 항공우주기술
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• 제4권2호
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• pp.142-152
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• 2005

액체로켓 엔진시스템 개발에 있어서 시동부터 정상상태까지의 시동특성은 안정된 시동의 재현성을 확보하여 신뢰도를 높이는 것과 과도상태의 시간을 단축하는 두 가지 목표를 만족하는 방향으로 전개된다고 할 수 있다. 특히 우리나라와 같이 액체로켓 엔진 개발의 초기단계에서는 엔진시스템 시험의 경험이 없어, 시동에서 정상상태까지 과연 어느 정도의 시간이 필요할 것인가에 대한 예측이 힘들 수밖에 없다. 본 연구에서는 터보펌프 공급식 액체로켓 엔진의 각 구성품의 모델을 구성하여 시동 과도 해석을 수행할 수 있는 프로그램을 완성하였다. 이 프로그램을 이용하여 25톤급 가스발생기 사이클 엔진에 대한 시동 특성을 조사하여 시동에서 정상상태에 이르는 시간을 계산하였으며, 비정상 상태의 엔진시스템의 동특성을 밝힐 수 있었다.

• Journal of Advanced Marine Engineering and Technology
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• 제37권1호
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• pp.22-28
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• 2013

본 논문은 액화 천연 가스(LNG)를 주 연료로 사용하는 선박용의 LNG기화기의 특성을 조사하기 위하여 기화기 내부에서의 열전달 특성을 연구하였다. LNG를 기화하기 위한 가열열원으로서는 주 엔진에서 발생하는 워터 쟈켓의 가온수를 직접 이용하지 않고 열교환기를 통하여 간접 가열된 글리콜 워터(Glycol Water)를 사용하는 시스템을 채택하였다. LNG의 기화 과정은 상변화를 동반하기 때문에 이를 검증하기 위하여 액화질소(LN2)의 기화과정을 통하여 신뢰성을 확보하였고, LNG 기화기 내부의 최적 열적특성을 도출하기 위하여 LNG의 유입량과 가열열원인 글리콜 워터 유량변화에 대한 LNG 기화특성을 연구하였다. 해석 결과 LNG 질량유량이 0.111 kg/s과 가열원수인 부동액 질량유량이 1.805 kg/s일 경우 가스 출구 온도는 약 $6^{\circ}C$로서 LNG 선박의 최적 운전 조건임을 알 수 있었다.

• 설비공학논문집
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• 제19권6호
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• pp.447-456
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• 2007

Suspended particles behavior when they go through a vertical riser with heat transfer is of significant concern to system designers and operators in pneumatic transport, various processes such as in chemical, pharmaceutical and food industries. When it comes with the energy system, that knowledge is critical to the reliable design practices of related equipment as heat exchangers, especially in the phase of system scale-up. Without haying a good understanding of the related physics, many scale-up practices based on their pilot plant experience suffer from unexpected behaviors and problems of unstable fluidization typically associated with excessive pressure drop, pressure fluctuation and even unsuccessful particle circulation. In the present study, we try to explain the observed phenomena with related physics, which may help understanding of our unanswered experiences and to provide the designers with more reliable resources for their work. We selected hot exhaust gas with solid particle that goes through a heat exchanger riser as our model to be considered. The effect of temperature change on the gas velocity, thermodynamic properties, and eventually on the particles motion behavior is reviewed along with some heat transfer analyses. The present study presents an optimal riser length at full scale under given conditions, and also defines the theoretical limiting length of the riser. The field data from the numerical analysis was validated against our experimental results.

• 환경생물
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• 제36권3호
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• pp.345-351
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• 2018

An efficient, quick and low-cost extraction and clean up method for the determination of 14 polycyclic aromatic hydrocarbons (PAHs) in the agricultural water samples was optimized using gas chromatography-tandem mass spectrometry (GC-MS/MS). The extraction of the target compounds in water sample was carried out with acetonitrile, followed by partitioning promoted by the addition of salt. As a clean-up procedure, dispersive solid phase extraction was employed to purify the analytes of interest for GC-MS/MS analysis. This method was successfully applied for the quantification of PAHs in real water samples collected for the purpose of monitoring from the waterways located in Chungbuk (15 sites) and Gyeongbuk (6 sites), S. Korea. Phenanthrene (0.54 to $2.53{\mu}gL^{-1}$) was detected in all the water samples collected from both the sites. Fluoranthene was detected in the water samples collected from the two sites in Gyeongbuk province, but other PAHs were not determined in these water sampling sites. Based on these results, the determined PAHs were conducted using an environmental risk assessment. The risk characterization ratios (RCRs) for phenanthrene ranged from 0.37 to 3.21. These RCR values referred to as risk was not controlled because RCR values of some sites were greater than 1. In conclusion, it is proposed that the optimized method in combination with GC-MS/MS could be successfully employed for the determination of PAHs in any environmental samples including water samples.

• The Korean Journal of Pain
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• 제35권1호
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• pp.33-42
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• 2022

Background: Cupressus arizonica Greene is a coniferous tree with great importance in fragrance and pharmaceutical industries. Essential oils from C. arizonica (EC) have shown potential antioxidant, and anti-microbial activities. This study aimed at investigating the anti-nociceptive and anti-inflammatory effects/mechanisms of EC. Methods: The EC was evaluated for anti-nociceptive and anti-inflammatory activities on male Wistar rats using a formalin test and carrageenan-induced paw edema, respectively. Also, we pre-treated some of the animals with naloxone and flumazenil in the formalin test to find out the possible contributions of opioid and benzodiazepine receptors to EC anti-nociceptive effects. Finally, gas chromatography/mass spectrometry (GC/MS) analysis was used to identify the EC's constituents. Results: EC in intraperitoneal doses of 0.5 and 1 g/kg significantly decrease the nociceptive responses in both early and late phases of the formalin test. From a mechanistic point of view, flumazenil administration 20 minutes before the most effective dose of EC (1 g/kg) showed a meaningful reduction in the associated anti-nociceptive responses during the early and late phases of the formalin test. Naloxone also reduced the anti-nociceptive role of EC in the late phase. Furthermore, EC at the doses of 1, 0.5, and 0.25 g/kg significantly reduced paw edema from 0.5 hours after carrageenan injection to 4 hours. GC/MS analysis showed that isolated EC is a monoterpene-rich oil with the major presence of α-pinene (71.92%), myrcene (6.37%), δ-3-carene (4.68%), β-pinene (3.71%), and limonene (3.34%). Conclusions: EC showed potent anti-nociceptive and anti-inflammatory activities with the relative involvement of opioid and benzodiazepine receptors.