• 대한전자공학회논문지SD
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• 제44권4호
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• pp.10-17
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• 2007

FTIR 분광계는 간섭계를 사용하여 표적 물질에 대한 간섭무늬를 획득하고, 이를 푸리에 변환함으로써 기체상태 물질의 적외선 영역 스펙트럼을 획득하기 위한 유용한 기법이다. 본 논문에서는 불규칙적 위치에서 간섭무늬 샘플링에 관하여 고속 스캔 간섭계의 신호처리에서의 샘플링 노이즈 영향에 대한 연구와 이에 대하여 실험적으로 검증 하였다.

• 한국마린엔지니어링학회:학술대회논문집
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• 한국마린엔지니어링학회 2000년도 추계학술대회 논문집(Proceeding of the KOSME 2000 Autumn Annual Meeting)
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• pp.30-36
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• 2000

A numerical study was conducted to investigate the effects of flow parameters in a entrained flow combustor on the flow characteristics. The computational model was based on the gas phase Eulerian equations of mass, momentum and energy. The code was formulated with RNG k-$\varepsilon$ model for turbulent flow. The calculation parameters were the magnitude of primary and secondary jet velocity and the height difference between primary and secondary jet. As the secondary jet velocity increased, the upper recirculation zone of the primary jet was strengthened. It was found that as the primary jet velocity increased, there was a critical jet velocity at which the size of upper and lower recirculation zone was changed.

• 대한기계학회논문집
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• 제17권7호
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• pp.1841-1850
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• 1993

A simplified one-dimensional analysis has been performed to predict the local pressure distributions in Y-Jet twin-fluid atomizers. Fluid compressibility was considered both in the gas(air) and two-phase(mixing) ports. The annular-mist flow model was adopted to analyze the flow in the mixing port. A series of experiments also has been performed; the results show that the air flow rate increases and the liquid flow rate decreases with the increase of the air injection pressure and/or with the decrease of the liquid injection pressure. From the measured injection pressures and flow rates, the appropriate constants for the correlations of the pressure loss coefficients and the rate of drop entrainment were decided. The local pressures inside the nozzle by prediction reasonably agree with those by the experiments.

• 대한화학회지
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• 제22권3호
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• pp.138-148
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• 1978

자연 다이아몬드의 생성에 관한 여러가지 이론적인 검토를 해보았다. 특히 강조한 것은 다이아몬드의 생성이 기체에서 생긴다는 이론이다. 영구용 질양분석기의 검체안에서 분쇠 검출된 자연 다이아몬드내에 모인 기체에서 보아 다이아몬드의 생성에 대한 그 외계의 기체조성을 검토 제의한다. $200^{\circ}C$, 109 torr의 진공내에서 분쇠된 다이아몬드로부터 생성된 물질들은, 검출된 양의 순으로 나타낸다면, 물, 수소, 질소, 이산화탄소, 메탄, 일산화탄소, 아르곤 및 에틸알코올등이다. 열의학적으로 C-H-O-N 기체상의 조성의 검토는 가능한 다이아몬드의 생성조건에 관한 정보를 제공한다. 이미주어진 실험적 결과의 비교는 다이아몬드 생성에 관한 가능한 온도-압력조건이 주어진다.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2012년도 제42회 동계 정기 학술대회 초록집
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• pp.418-418
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• 2012

We fabricated a new type of hybrid film using molecular layer deposition (MLD). The MLD is a gas phase process analogous to atomic layer deposition (ALD) and also relies on a saturated surface reaction sequentially which results in the formation of a monolayer in each sequence. In the MLD process, polydiacetylene (PDA) layers were grown by repeated sequential surface reactions of titanium tetrachloride and 2,4-hexadiyne-1,6-diol with ultraviolet (UV) polymerization under a substrate temperature of $100^{\circ}C$. Ellipsometry analysis showed a self-limiting surface reaction process and linear growth of the hybrid films. Polymerization of the hybrid films was confirmed by infrared (IR) spectroscopy and UV-Vis spectroscopy. Composition of the films was confirmed by IR spectroscopy and X-ray photoelectron (XP) spectroscopy. The titanium oxide cross-linked polydiacetylene (TiOPDA) hybrid films exhibited good thermal and mechanical stabilities.

• 한국자동차공학회논문집
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• 제7권5호
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• pp.40-54
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• 1999

The flame structure and soot formation in the counterflow Ethylene-Air nonpremixed flame are numerically analyzed. The present soot reaction mechanism involves nucleation, surface growth, particle coagulation, and oxidation steps. The gas phase chemistry and the soot nucleation, surface growth reactions are coupled by assuming that the nucleation and soot mass growth has the certain relationship with the concentration of benzene and acetylene. In terms of the centerline velocity and the soot volume fraction, the predicted results are compared with the experimental data. The detailed discussion has been made for the sensitivity of model constants and the deficiencies of the present model. Numerical results indicated that the acetylene addition to the soot surface plays the dominant role in the soot mass growth for the counterflow nonpremixed flame.

• 한국자동차공학회논문집
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• 제10권6호
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• pp.80-89
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• 2002

The flame structure and soot formation in Acetylene-Air nonpremixed jet flame are numerically analyzed. We employed two variable approach to investigate the soot formation and oxidation processes. The present soot reaction mechanism involves nucleation, surface growth, particle coagulation, and oxidation steps. The gas phase chemistry and the soot nucleation, surface growth reactions are coupled by assuming that the nucleation and soot mass growth has the certain relationship with the concentration of pyrene and acetylene. We also employed laminar flamelet model to calculate the thermo-chemical properties and the proper soot source terms from the information of detailed chemical kinetic model. The numerical and physical model used in this study successfully predict the essential features of the combustion processes and soot formation characteristics in the reaction flow field.

• Food Science and Biotechnology
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• 제18권6호
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• pp.1495-1499
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• 2009

The volatiles formed from the reactions of L-ascorbic acid with L-alanine at 5 different pH (5, 6, 7, 8, or 9) and $140{\pm}2^{\circ}C$ for 2 hr was performed using solid-phase microextraction-gas chromatography-mass spectrometry (SPME-GC-MS) analysis were identified to be 25 different kinds. The reaction between L-ascorbic acid and L-alanine led mainly to the formation of pyrazines. Many of these were alkylpyrazines, such as 3-ethyl-2,5-dimethylpyrazine, 2,5-dimethylpyrazine, 2-ethyl-5-methylpyrazine, 3,5-diethyl-2-methylpyrazine, methylpyrazine, 2-ethyl-6-methylpyrazine, and 2,3-diethyl-5-methylpyrazine, other compounds identified were furans, phenols, benzoquinones, 2,4,6-trimethylpyridine, and 2-methylbenzoxazole. The studies showed that furans, such as furfural and benzofuran were formed mainly at acidic pH. In contrast, higher pH values could promote the production of pyrazines.

• Bulletin of the Korean Chemical Society
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• 제35권10호
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• pp.2911-2916
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• 2014

The gas phase structures, energetics, and interconversion pathways of five lowest energy conformers of acetylcholine were examined employing the B3LYP, MP2, and CCSD(T) methods in conjunction with diverse basis sets including the correlation consistent aug-cc-pVDZ and aug-cc-pVTZ basis sets. It is found that use of adequate basis set containing proper polarization and diffuse functions capable of describing the floppy potential energy surface of acetylcholine is important in correctly predicting the relative stability of these conformers. The interconversion pathways and barrier heights between these conformers were elucidated by examining the potential energy surface for torsional motion, which also manifested the presence of chiral conformations of acetylcholine corresponding to the original conformations. On the basis of high level electronic energy calculations and thermal contribution analysis, four lowest energy conformers appear to be populated in the energy range of less than 1 kcal/mol at room temperature.

• Macromolecular Research
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• 제16권7호
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• pp.620-625
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• 2008

A novel nitrogen-phosphorus compound, diphenyl piperazine-1,4-diylbis(methylphosphinate)(DPPMP) was synthesized via a two step reaction and its flame retarding efficiency as a single component additive was investigated. The success of synthesis was confirmed by FTIR and $^1H$ and $^{31}P$ NMR analysis. The product was mixed with polycarbonate (PC), poly(butylene terephtalate) (PBT), ethylene-vinyl-acetate copolymer (EVA), and acrylonitrile-butadiene-styrene copolymer (ABS). The flame-retarding efficiency was evaluated using the limiting oxygen index (LOI) and the UL-94 vertical test methods. The addition of DPPMP enhanced the flame retardancy of the polymers and the V-0 ratings were obtained for the polymers examined in this study at a loading of 7-30 wt%. The gas-phase flame retardancy mode of action was suggested for this material from the thermogrametry experiment results.