• 제목/요약/키워드: Gas tube

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고온용 연료전지 미반응 가스를 이용한 촉매연소-개질 통합 반응기의 성능 비교 (Performance Comparison of Integrated Reactor with Steam Reforming and Catalytic Combustion using Anode Off-Gas for High Temperature Fuel Cells)

  • 강태규;성해정;이상민;안국영;김용모
    • 한국수소및신에너지학회논문집
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    • 제22권6호
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    • pp.800-809
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    • 2011
  • The reaction characteristics of an integrated reactor with steam reformer and catalytic combustor using anode offgas for high temperature fuel cells such as MCFC and SOFC have been experimentally investigated in the present study. The coupled reactor had a coaxial cylindrical shape, and the inner and the outer tube was packed with combustion catalysts and reforming catalysts, respectively. Thus, the endothermic steam reforming could proceed by absorbing heat from catalytic combustion of anode offgas. Results show that increasing inlet temperature and decreasing excess air ratio increased the reformer temperature, which led to the increase in $H_2$ yield. The reforming performance for SOFC conditions was better than that for MCFC conditions since the composition of flammable components became smaller for MCFC cases. Measured reformate composition under various test conditions correlated well with thermal equilibrium composition.

새로운 효소반응기를 이용한 요소의 연속·자동화 정량 (Continuous Automated Determination of Urea Using a New Enzyme Reactor)

  • 이흥락;양승태
    • 대한화학회지
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    • 제36권3호
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    • pp.393-404
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    • 1992
  • 새로운 효소반응기를 쓰는 요소 정량용 연속${\cdot}$자동화 장치의 감응성질을 조사하였다. 효소반응기는 지지체인 nylon-6입자(42∼48 mesh)를 teflon관(안지름 2mm, 길이 20cm)에 충전시키고, 이 지지체의 표면에 공유결합제인 glutaraldehyde로 urease를 고정화시켜서 제작하였다. 연속${\cdot}$자동화장치는 효소반응기, 기체투석기 및 지시전극인 관형 PVC-nonactin막 암모늄 이온 선택성 전극을 차례로 연결하여 만들었다. 이 장치를 써서 요소를 정량할 때 감응특성은 다음과 같다. 곧 직선감응 농도범위는 $5.5{\times}10^{-6}$~$2.4{\times}10^{-3}M$, 감응기울기는 57.8 mV/decade, 검출한계는 $1.5{\times}10^{-6}M$, 효소반응기의 전환백분율은 80.8%이었다. 효소반응기의 최적 완충용액은 0.01M Tris-HCl 완충용액(pH 7.0∼7.8)과 0.01M 인산염 완충용액(pH 6.9∼7.5)이었고, 수명은 150일 정도였다. 또한 다른 생리활성물질의 방해는 없었다.

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Improving Accident Tolerance of Nuclear Fuel with Coated Mo-alloy Cladding

  • Cheng, Bo;Kim, Young-Jin;Chou, Peter
    • Nuclear Engineering and Technology
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    • 제48권1호
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    • pp.16-25
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    • 2016
  • In severe loss of coolant accidents (LOCA), similar to those experienced at Fukushima Daiichi and Three Mile Island Unit 1, the zirconiumalloy fuel claddingmaterials are rapidlyheateddue to nuclear decay heating and rapid exothermic oxidation of zirconium with steam. This heating causes the cladding to rapidly react with steam, lose strength, burst or collapse, and generate large quantities of hydrogen gas. Although maintaining core cooling remains the highest priority in accident management, an accident tolerant fuel (ATF) design may extend coping and recovery time for operators to restore emergency power, and cooling, and achieve safe shutdown. An ATF is required to possess high resistance to steam oxidation to reduce hydrogen generation and sufficient mechanical strength to maintain fuel rod integrity and core coolability. The initiative undertaken by Electric Power Research Institute (EPRI) is to demonstrate the feasibility of developing an ATF cladding with capability to maintain its integrity in $1,200-1,500^{\circ}C$ steam for at least 24 hours. This ATF cladding utilizes thin-walled Mo-alloys coated with oxidation-resistant surface layers. The basic design consists of a thin-walled Mo alloy structural tube with a metallurgically bonded, oxidation-resistant outer layer. Two options are being investigated: a commercially available iron, chromium, and aluminum alloy with excellent high temperature oxidation resistance, and a Zr alloy with demonstratedcorrosionresistance.Asthese composite claddings will incorporate either no Zr, or thin Zr outer layers, hydrogen generation under severe LOCA conditions will be greatly reduced. Key technical challenges and uncertainties specific to Moalloy fuel cladding include: economic core design, industrial scale fabricability, radiation embrittlement, and corrosion and oxidation resistance during normal operation, transients, and severe accidents. Progress in each aspect has been made and key results are discussed in this document. In addition to assisting plants in meeting Light Water Reactor (LWR) challenges, accident-tolerant Mo-based cladding technologies are expected to be applicable for use in high-temperature helium and molten salt reactor designs, as well as nonnuclear high temperature applications.

메조포러스 알루미나를 이용한 AlN 분말 제조 및 특성분석 (Preparation of AlN Powder Using Mesoporous Alumina and Its Characterization)

  • 김은비;이윤주;신동근;권우택;김수룡;강미숙;김영희
    • 한국세라믹학회지
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    • 제51권6호
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    • pp.544-548
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    • 2014
  • Aluminum nitride was synthesized using a carbothermal method from mesoporous alumina having a high surface area (> $1,000m^2/g$) as an aluminum source and CNTs (carbon nano tubes) as a carbon source. In this case the mesoporous alumina was used as the starting material instead of ${\alpha}-Al_2O_3$ with the expectation that the mesopores in mesoporous alumina act as channels for N2 gas and elimination of CO generated as by-product. It is also expected that the synthetic temperature should be lower compared to the use of ${\alpha}-Al_2O_3$ as a starting material due to its high surface area. The crystallinity of the produced aluminum nitride was studied by XRD and FT-IR, and the microstructure was investigated by FE-SEM. Also the purity of the aluminum nitride was analyzed through N/O determinator and ICP analysis.

세라믹 필터를 이용한 동축 서지어레스터의 잔류전압 저감 (Residual Voltage Reduction of Coaxial Surge Arrestor Using Ceramic Filler)

  • 엄주홍;조성철;이태형;이영철
    • 조명전기설비학회논문지
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    • 제21권2호
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    • pp.46-53
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    • 2007
  • 현재 급속한 발전을 거듭하고 있는 이동통신 및 무선 멀티미디어 관련 서비스(W-CDMA, DMB, WiBro 등)의 확장은 이들 시스템을 구현하기 위한 수많은 기지국과 안테나 및 다수의 신호전송선로를 필요로 한다. 기지국 또는 중계시설의 안테나는 신호전송선로를 통하여 고가의 통신 네트워크 장비들과 결합되어 있으므로 주요 통신기기 시스템은 안테나를 통해 유입하는 직격뢰 및 유도뢰에 의한 순간적인 과전압의 위험에 항시 노출되어 있다. 현재 통신용 보호기로 사용되고 있는 가스방전튜브(GDT) 또는 협대역 스터브형 어레스터는 고속 광대역의 통신설비에 대한 뇌서지 보호수단으로서는 한계점이 드러나고 있다. 따라서 본 연구에서는 안테나를 통해 입사하는 뇌서지를 효과적으로 저감시켜주는 서지어레스터의 성능향상을 위해 세라믹 필터를 적용하였으며, 잔류전압 저감에 효과적임을 성능실험을 통해 입증하였다.

X선 고전압장치의 전파 및 배전압 정류방식에 따른 X선 출력 및 선질 비교 (Comparison of Output and Radiation Quality of X-rays according to the Full-Wave Rectification Method and Dual-Voltage Rectification Method of an X-ray Generator)

  • 김태곤;천민우;박용필
    • 한국전기전자재료학회논문지
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    • 제23권7호
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    • pp.534-538
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    • 2010
  • X-ray systems for medical treatment use noninvasive procedures. Being capable of locally inspecting the inside of the body, X-ray systems are routinely used for basic diagnosis. X-ray systems to be used for medical purposes were originally made with a gas filled tube inside an induction coil in the initial stages of development but with this approach it becomes difficult to take a satisfactory picture through thick body sections, non invasively. However continued development made it possible to take non-invasive pictures of breasts, blood vessels and other body parts through thick body sections. Recently, high-voltage X-ray generators of more compact size, increased generation efficiency, and sophisticated output control have become possible. All of these features are made possible by the use of a high-frequency output from an inverter and a fast switching semiconductor device. In this paper, we describe a new X-ray generator operating with a resonant inverter in order to reduce switching loss and high frequency noise. In addition, in order to identify the differences amongst types of rectification, we have compared output and the quality of X-ray pictures obtained with full-wave rectification and dual-voltage rectification methods.

고체 로켓 노즐의 경계층 해석과 유한차분법을 이용한 탄소/페놀릭의 열반응 해석 연구 (Analysis of Boundary Layer in Solid Rocket Nozzle and Numerical Analysis of Thermal Response of Carbon/Phenolic using Finite Difference Method)

  • 서상규;함희철;강윤구
    • 한국추진공학회지
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    • 제22권1호
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    • pp.36-44
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    • 2018
  • 고체 로켓 추진기관 노즐의 내열재로 사용되는 탄소/페놀릭 복합재료의 열반응 수치해석을 수행하였다. 본 논문에서 탄소/페놀릭 재료의 열반응 해석은 (1) 로켓 노즐벽에서 대류열전달계수를 구하기 위한 연소가스의 경계층 적분방정식 수치해석과 (2) 삭마두께, 숯깊이 및 온도를 계산하기 위한 탄소/페놀릭의 열반응(열분해, 삭마)을 고려한 1차원 열전도 해석으로 구성된다. 시험결과와 해석결과를 비교 분석하였으며, 목삽입재 좌우 인접 부위를 제외하고 잘 일치하는 것을 확인 할 수 있었다.

불응축가스량이 가변전열 히트파이프의 열수송 특성에 미치는 영향 (Influence of NCG Charging Mass on the Heat Transport Capacity of Variable Conductance Heat Pipe)

  • 서정세;박영식;정경택
    • 설비공학논문집
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    • 제18권4호
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    • pp.320-327
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    • 2006
  • Numerical analysis and experimental study are performed to investigate the effect of heat load and operating temperature on the thermal performance of several variable conductance heat pipe (VCHP) with screen meshed wick. The heat pipe is designed in 200 screen meshes, 500 mm length and 12.7 mm outer diameter tube of copper, water (4.8 g) is used as working fluid and nitrogen as non-condensible gas (NCG). Heat pipe used in this study has evaporator, condenser and adiabatic section, respectively. Analysis values and experimental data of wall temperature distribution along axial length are presented for heat transport capacity, condenser cooling water temperature change, degrees of an inclination angle and operating temperature. These analysis and experiment give the follow findings: For the same charging mass of working fluid, the operating temperature of heat pipe becomes to be high with the increasing of charging mass of NCG. When the heat flux at the evaporator section increases, the vapor pressure in the pipe rises and consequently compresses the NCG to the condenser end part and increases the active length of the condenser. From previous process, it is found out we can control the operating temperature effectively and also the analysis and experimental results are relatively coincided well.

비공비 혼합냉매 R-410A를 적용한 납작한 알루미늄 마이크로 멀티 튜브에서의 마찰손실에 관한 연구 (A study on the friction head loss in flat aluminum micro multi tubes with nonazeotropic refrigerant mixtures R-410A)

  • 이정근;민경호
    • Design & Manufacturing
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    • 제13권2호
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    • pp.37-43
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    • 2019
  • This study conducted a research as to condensation heat transfer friction loss headby using three types of flat micro multi-channel tubes with different processing of micro-fin and number of channels inside the pipes and different sizes of appearances. In addition, identical studies were conducted by using smoothing circular tubes with 5mm external diameter to study heat enhancement factor and pressure drop penalty factor. 1) The friction head loss showed an increase as the vapor quality and mass flux increased. In case of saturation temperature, it shows an increase as it gets lower. These factors are the reason occurring as the lower the saturation temperature is, the higher the density of refrigerant vapor gets. The influence of heat flux is similar as the dryness is low, but as it gets higher, it lowers in heat flux, and as the high temperature of high heat flux, it is a factor that occurs as the density gets lower. 2) RMS error of the in case of friction head loss, it showed to be predicted as 0.45~0.67 by Chisholm, Friedel, Lockhart and Martinelli. 3) As forfriction head loss penalty factor, the smaller the aspect ratio is, the larger the penalty factor gets, and as for the effect of micro-fin, the penalty factor increased because it decreases to the gas fluid the way groove for the refrigerant's flow.

Components of phytoncide from a pine forest in the southern temperate zone

  • Lee, Jeong Do;Park, Choong Hee;Joung, Da Wou;Koo, Seung Mo;Park, Bum Jin
    • 농업과학연구
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    • 제46권1호
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    • pp.33-44
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    • 2019
  • This study was conducted to examine the components of phytoncide from a pine forest in the southern temperate zone. Recent studies have found that a large amount of phytoncide is released not only from cypress trees but also from pine trees. Because the amount released is the highest during summer, we selected a warm climate region in the southern temperate zone and measured the concentration in the month of August. To capture the phytoncide from the forest atmosphere, we used the adsorption tube method with a mini pump and successfully gathered 9 L of forest air at a flow rate of 150 mL/min. We performed duplicate sampling from two different tubes installed at the same location and derived the mean value. A gas chromatography/mass spectrometer detector with thermal desorption spectroscopy was utilized to perform quantitative and qualitative analyses of the captured material. The results showed that the average phytoncide particle of the pine forest in the southern temperate zone contained a number of components as follows in descending order: ${\alpha}$-Pinene (39%, $0.28ng/m^3$), followed by ${\beta}$-Pinene (16%, $0.11ng/m^3$), D-Limonene (8%, $0.06ng/m^3$), camphor (6%, $0.04ng/m^3$), camphene (6%, $0.04ng/m^3$), and p-Cymene (5%, $0.04ng/m^3$). There were also 13 additional phytoncide components in trace amounts. The results of this study are expected to provide a useful dataset for building a "Healing-forest".