• Title/Summary/Keyword: Gas removal

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Processing and MAP(modified atmosphere packaging) Storage of Fresh-cut Apples using CA Stored Apples (CA저장 사과를 이용한 Fresh-cut Apple의 제조 및 MAP저장)

  • 정헌식;문광덕;최종욱
    • Food Science and Preservation
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    • v.6 no.4
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    • pp.351-356
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    • 1999
  • To develop and extend the shelf-life of vitamin C enriched fresh-cut apples using CA stored Fuji apples, dipping in 10% L-ascorbic acid and packaging with 0.03 mm LDPE, 0.04 mm PP and 0.08 mm Nylon/PE film(N$_2$displacement) were carried out. The changes of gas concentrations in the packaging and quality attributes of fresh-cut apples were examined during storage at 10$^{\circ}C$. The concentrations of O$_2$was maintained lower in Nylon/PE film than the other film, the level of O$_2$was in the range of 1∼3%. The increase of C$_2$H$_4$ concentrations in Nylon/PE film bag was more suppressed than the others. The vitamin C content of fresh-cut apples was enriched by dipping in L-ascorbic acid solution up to 241 mg$.$100 g-1 f.w., and the loss or that content was retarded differently by the package conditions of lower O$_2$level during storage. Browning in fresh-cut apples was shown after 6 days of storage in LDPE and PP film. but it was not shown by 14 days of storage in Nylon/PE film. Spoilage and off odor in fresh-cut apples were not detected up to 14 days of storage in Nylon/PE film. The results indicated that the vitamin C enriched fresh-cut apples can be processed from the long-term CA stored apples, and maintaining high quality of the products ill be possible in cases of the application of sealing packaging after O$_2$removal with film having low O$_2$permeability.

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Study on Characteristics of Change of Urea and Biuret Content by Temperature Variation in Urea Solution (요소수(Urea solution)의 온도변화에 따른 요소 및 뷰렛함량 변화 특성 연구)

  • Doe, Jin-woo;Park, Tae-sung;Lee, Yu-rim;Yim, Eui-soon;Lee, Joung-min;Kang, Hyung-kyu
    • Journal of the Korean Applied Science and Technology
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    • v.35 no.4
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    • pp.1307-1319
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    • 2018
  • As interests in the air pollution increases, many kinds of researches are underway on the reduction of air pollutants. The removal of nitrogen oxides from the emission gas of diesel vehicles using urea solution has shown a great effect. The quality of urea solution is strictly defined by domestic law, but the increase of impurities in urea solution reduces the effect of reducing nitrogen oxides. Therefore, in this study, the change of physical properties of urea solution was analyzed after heating the urea solution for a certain temperature and time. Also, the changes of physical properties of urea solution were analyzed according to kinds of storage container and temperature for storing the urea solution. After heating the urea solution for a certain period of time, the biuret content in urea solution increased and the content of urea decreased. As the urea content decreased, both density and refractive index decreased. In the storage stability test carried out at a constant temperature with iron and PET containers, no change in physical properties was observed.

CFD Analysis on the Internal Reaction in the SNCR System (SNCR 시스템 내부의 물질 반응에 관한 전산해석적 연구)

  • Koo, Seongmo;Yoo, Kyung-Seun;Chang, Hyuksang
    • Clean Technology
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    • v.25 no.1
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    • pp.63-73
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    • 2019
  • Numerical analysis was done to evaluate the chemical reaction and the reduction rate inside of selective non-catalytic reduction to denitrification in combustion process. The $NO_X$ reduction in selective non-catalytic reduction is converted to not only nitrogen but also nitrous oxide. Simultaneous $NO_X$ reduction and nitrous oxide generation suppressing is required in selective non-catalytic reduction because nitrous oxide influences the global warming as a greenhouse gas. The current study was performed compare the computational analysis in the same temperature and amount of NaOH, and in comparison with the previous research experiments and confirmed the reliability of the computational fluid dynamics. Additionally, controlling the addition amount of NaOH to predict the $NO_X$ reduction efficiency and nitrous oxide production. Numerical analysis was done to check the mass fraction of each material in the measurement point at the end of selective non-catalytic reduction. Experimental Value and simulation value by numerical analysis showed an error of up to 18.9% was confirmed that a generally well predicted. and it was confirmed that the widened temperature range of more than 70% $NO_X$ removal rate is increased when the addition amount of NaOH. So, large and frequent changes of the reaction temperature waste incineration facilities are expected to be effective.

Evaluation of Ventilation Performance of a Residential Unit for Different Sampling Points through Actual Field Tests (실증실험을 통한 측정 위치에 따른 주거공간 환기성능 평가)

  • Kwag, Byung Chang;Lee, Soo Man;Kim, Gil Tae;Kim, Jong Yeob
    • Land and Housing Review
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    • v.13 no.3
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    • pp.93-106
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    • 2022
  • Ventilation plays an important role in controlling indoor air quality. Due to the recent spread of infectious diseases such as COVID-19 and with people spending more time indoors, there's been increased attention on the importance of ventilation performance. In many countries, ventilation is regulated by airflow rates and the number of air changes per hour (ACH). However, airflow rates and ACH alone do not provide an accurate account of actual indoor pollutant removal and ventilation uniformity in a space. This study looked into the ventilation performance of an actual residential unit using several sampling points instead of basing it off of airflow and air change rates. Literature review was used to derive relevant influencing factors and the tracer gas dilution method was used for the field test. The study measured air velocity, age of air, and ventilation efficiency at several locations and compared them to the average value at the center of the test space to determine the differences in ventilation performance at the selected measurement points. The study showed that different sampling locations resulted in different ventilation values. Findings of this study will be used to develop an experimental procedure for evaluating indoor ventilation performance of actual residential spaces.

Proposal of a Pilot Plant (2T/day) for Solid Fuel Conversion of Cambodian Mango Waste Using Hybrid Hydrothermal Carbonization Technology (하이브리드 수열탄화기술을 이용한 캄보디아 망고 폐기물 고형연료화 실증플랜트 (2T/day) 제안)

  • Han, Jong-il;Lee, Kangsoo;Kang, Inkook
    • Journal of Appropriate Technology
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    • v.7 no.1
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    • pp.59-71
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    • 2021
  • Hybrid hydrothermal carbonization (Hybrid HTC) technology is a proprietary thermochemical process for two or more organic wastes.The reaction time is less than two hours with temperature range 180~250℃ and pressure range 20~40bar. Thanks to accumulation of the carbon of the waste during Hybrid HTC process, the energy value of the solid fuel increases significantly with comparatively low energy consumption. It has also a great volume reduction with odor removal effect so that it is evaluated as the best solid fuel conversion technology for various organic wastes. In this study of the hybrid hydrothermal carbonization, the effect on the calorific value and yield of Cambodian mango waste were evaluated according to changes in temperature and reaction time. Through the study, parameter optimization has been sought with improving energy efficiency of the whole plant. It is decomposed in the Hydro-Carbonation Technology to Generate Gas. At this time, it is possible to develop manufacturing and production technologies such as hydrogen (H2) and methane (CH4). Based on the results of the study, a pilot plant (2t/day) has been proposed for future commercialization purpose along cost analysis, mass balance and energy balance calculations.

Catalytic Hydrodeoxygenation of Biomass-Derived Oxygenates: a Review (바이오매스 유래 함산소 화합물의 수첨탈산소 촉매 반응: 총설)

  • Ha, Jeong-Myeong
    • Clean Technology
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    • v.28 no.2
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    • pp.174-181
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    • 2022
  • Biomass is a sustainable alternative resource for production of liquid fuels and organic compounds that are currently produced from fossil fuels including petroleum, natural gas, and coal. Because the use of fossil fuels can increase the production of greenhouse gases, the use of carbon-neutral biomass can contribute to the reduction of global warming. Although biological and chemical processes have been proposed to produce petroleum-replacing chemicals and fuels from biomass feedstocks, it is difficult to replace completely fossil fuels because of the high oxygen content of biomass. Production of petroleum-like fuels and chemicals from biomass requires the removal of oxygen atoms or conversion of the oxygen functionalities present in biomass derivatives, which can be achieved by catalytic hydrodeoxygenation. Hydrodeoxygenation has been used to convert raw biomass-derived materials, such as biomass pyrolysis oils and lignocellulose-derived chemicals and lipids, into deoxygenated fuels and chemicals. Multifunctional catalysts composed of noble metals and transition metals supported on high surface area metal oxides and carbons, usually selected as supports of heterogeneous catalysts, have been used as efficient hydrodeoxygenation catalysts. In this review, the catalysts proposed in the literature are surveyed and hydrodeoxygenation reaction systems using these catalysts are discussed. Based on the hydrodeoxygenation methods reported in the literature, an insight for feasible hydrodeoxygenation process development is also presented.

Effect of Impregnation and Modification on Activated Carbon for Acetaldehyde Adsorption (아세트알데하이드 흡착을 위한 활성탄의 첨착 및 개질 효과)

  • Jin Chan Park;Dong Min Kim;Jong Dae Lee
    • Korean Chemical Engineering Research
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    • v.61 no.3
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    • pp.472-478
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    • 2023
  • In this study, the acetaldehyde removal characteristics of activated carbon (AC) for air purifier filters were investigated using metal catalysts-impregnation and functional group-modification method. The AC with a high specific surface area(1700 m2/g) and micropores was prepared by KOH activation of coconut charcoal and the efficiency of catalyst and functional group immobilization was examined by varying the drying conditions within the pores after immersion. The physical properties of the prepared activated carbon were analyzed by BET, ICP, EA, and FT-IR, and the acetaldehyde adsorption performances were investigated using gas chromatography (GC) at various impregnation and modified conditions. As the concentration of impregnation solution increased, the amount of impregnated metal catalysts increased, while the specific surface area showed a decreasing trend. The adsorption tests of the metal catalyst-impregnated and functional group-modified activated carbons revealed that excellent adsorption performance in compositions MgO10@AC, CaO10@AC, EU10@AC, and H-U3N1@AC, respectively. The MgO10@AC, which showed the highest adsorption performance, had a breakthrough time of 533.8 minutes and adsorption capacity of 57.4 mg/g for acetaldehyde adsorption. It was found that the nano-sized MgO catalyst on the activated carbon improved the adsorption performance by interacting with carbonyl groups of acetaldehyde.

Characteristics of Water Level and Velocity Changes due to the Propagation of Bore (단파의 전파에 따른 수위 및 유속변화의 특성에 관한 연구)

  • Lee, Kwang Ho;Kim, Do Sam;Yeh, Harry
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.28 no.5B
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    • pp.575-589
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    • 2008
  • In the present work, we investigate the hydrodynamic behavior of a turbulent bore, such as tsunami bore and tidal bore, generated by the removal of a gate with water impounded on one side. The bore generation system is similar to that used in a general dam-break problem. In order to the numerical simulation of the formation and propagation of a bore, we consider the incompressible flows of two immiscible fluids, liquid and gas, governed by the Navier-Stokes equations. The interface tracking between two fluids is achieved by the volume-of-fluid (VOF) technique and the M-type cubic interpolated propagation (MCIP) scheme is used to solve the Navier-Stokes equations. The MCIP method is a low diffusive and stable scheme and is generally extended the original one-dimensional CIP to higher dimensions, using a fractional step technique. Further, large eddy simulation (LES) closure scheme, a cost-effective approach to turbulence simulation, is used to predict the evolution of quantities associated with turbulence. In order to verify the applicability of the developed numerical model to the bore simulation, laboratory experiments are performed in a wave tank. Comparisons are made between the numerical results by the present model and the experimental data and good agreement is achieved.

Removal of NAPL TCE using Cement/Slag contained Fe(II) (Fe(II)로 개질된 시멘트/슬래그를 이용한 NAPL TCE의 제거)

  • Lee, Seung-Hyoung;Park, Jung-Hyun;Choi, Won-Ho;Park, Joo-Yang
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.29 no.1B
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    • pp.97-103
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    • 2009
  • The decompostion characteristics of NAPL TCE in cement/slag/Fe(II) system were studied with various TCE concentration and amounts of binders (cement/slag) For analyses of the TCE degradation by cement/slag/Fe(II), TCE solution injected using gas-tight syringe after TCE solution dissolved a methanol. Initial concentrations of TCE are 0.42 mM, NAPL condition 11.7 mM and saturated condition 16.8 mM respectively. The result showed that the cases of 8.4 mM and 4.2 mM are decreased 88% of total TCE concentration within 18 days. NAPL condition 11.7 mM was decreased 84% within 50 days and saturated condition 16.8 mM was decreased 60% of total TCE concentration within 60 days respectively. This showed that degradations of TCE in various concentrations were in one kind reaction as pseudo-first-order. TCE was dissolved as aqueous solution before degraded. The reaction rate was increased $0.12day^{-1}$, $0.24day^{-1}$, $0.31day^{-1}$ when the mass of media 0.1, 0.2, 0.3 S/L rate was increased. TCE reaction speed is affected by cement/slag surface ares in this system. When HDTMA, experimental facter, was added, TCE decomposition rate was high despite the high concentration of NAPL. and The decompostion characteristics of NAPL TCE in cement/slag/Fe(II) system were studied by using modeling.

A study to find the operation conditions to minimize carbon footprint using a simulator(EQPS) (시뮬레이터(EQPS)를 이용한 탄소발자국 최소화 운전 방안에 대한 연구)

  • Jisoo Han;Jeseung Lee;Byonghi Lee
    • Journal of the Korea Organic Resources Recycling Association
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    • v.32 no.2
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    • pp.37-48
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    • 2024
  • Wastewater treatment plants (WWTPs) are obligated to reduce carbon emissions as a part of public sector greenhouse gas (GHG) emission reduction targets. However, Sewage Statistics(2022) shows that CO2 emissions per wastewater treatment volumes have decreased by only 3.03 % compared to 2020, which is far from enough to meet the Nationally Determined Contribution (NDC) targets. This study aimed to find operational conditions of biological reactors that minimize total carbon footprint (CFP). Total CFP considers both direct emissions from biological processes and indirect emissions from energy consumption. A study was conducted using a computer simulation program which is called as EQPS for a 4-stage BNR WWTP. The results showed that total CFP was reduced by 10.97% compared to the design condition when the mixed liquor recirculation (MLR) was set to 100 % of the influent flow. The N2O emission factor (EF) of the target WWTP was calculated to be 0.138-0.199 %, which is significantly lower than the IPCC default value of 1.6 %. This study proposes a method to minimize total CFP in WWTPs by optimizing biological reactor operation and emphasizes the need for further research on N2O emission reduction.