• Title/Summary/Keyword: Gas removal

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A Study on Effective Removal Method of Odorant Smell in Natural Gas using Sodium Hypochlorite (차아염소산나트륨을 이용한 천연가스 부취냄새 효과적 탈취방법 연구)

  • Lim, Hyung-Duk
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.19 no.6
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    • pp.154-159
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    • 2018
  • Intentional releases occur frequently during maintenance in gas supplying companies, which may result in unpleasant odors, and the possible mistaken belief of a gas accident. Therefore, this study developed a chemical process for effective odorant removal in natural gas using an active chemical that is released intentionally during maintenance and inspection. To develop an effective treatment process for removing the odorant from released natural gas, the effluent concentrations of the odorant in the released gas were measured after a chemical oxidation reaction with a sodium hypochlorite solution in a compact gas scrubbing equipment newly devised in this study. The device was based on a mixed gas vent after the solution inject odorant in the gas through the energy of the venting gas. The cascade combination of a venturi pipe and mixing chamber was developed to remove the odorant effectively from the purposely-released natural gas using an oxidative reaction between the mercaptan compounds (odorant) and the sodium hypochlorite solution. On the other hand, the developed method could be applied limitedly to a relatively small gas release from a low-pressure source. Further studies will be needed to apply the developed process to a large-scale gas release from a high-pressure source.

The syudy of reaction kinetics in the thermophilic aerobic digestion process of piggery wastewater (축산폐수의 고온호기성 소화공정에서의 반응동력학 연구)

  • Kim, Yong-Kwan;Kim, Seok-Won;Kim, Baek-Jae
    • Proceedings of KOSOMES biannual meeting
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    • 2007.11a
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    • pp.97-102
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    • 2007
  • The piggery wastewater is the major source of the water pollution problem in the rural area. The treatment alternatives for piggery wastewater are limited by the characteristics of both high organic and nitrogen(N) content. In order to investigate an efficient N removal system, the thermophilic aerobic digestion process was examined. The experiment was investigated organic and nitrogen removal efficiency at various HRTs and air supply volume. The results of semi-continuous experiment indicated that a higher removal of the soluble portion of COD was achieved with the longer HRTs. However, the inert portion of COD in piggery wastewater was not much changed by thermophilic aerobic digestion. In addition, with the higher HRT of 3 days, up to 79% of NH4-N removal efficiency was achieved. Lower the HRTs, a decrease of NH4-N removal was founds. The gas samples from the lab reactor were analyzed along with the N content in influent and effluent. The N2O formation in our system indicates a novel aerobic deammonification process occurred during the thermophilic aerobic digestion. Both N02 and N03 were not presented in the effluent of thermophilic aerobic digester. With the HRT of 3 days, 36.4% of influent N(or 57.5% removal N) was aerobically converted to N2O gas. The ammonium conversion to N2O gas significantly decrease to 4.5% at low HRT of .05 day..

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Adsorption Characteristics of Commercial Wood Charcoal in Korea (I) (국내 시판용 목탄의 흡착 특성(I))

  • Lee, Dong-Young;Kim, Byung-Ro
    • Journal of the Korean Wood Science and Technology
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    • v.38 no.1
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    • pp.27-35
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    • 2010
  • To evaluate the basic characteristics and adsorption properties of commercial wood charcoal, we investigated the proximate analysis, porosimetry analysis, methylene blue adsorption, removal ratios of formaldehyde, and removal ratio of ethylene gas. Fixed carbon contents of traditional black and white charcoal, and mechanical charcoal were 51.8~76.6%, 72.9~84.6%, and 48.5~80.3%, respectively. Refining degrees of the most traditional black charcoal were 9, and those of white charcoal and mechanical charcoals were zero. Specific surface area of traditional black charcoal was 0.1~13.7 $m^2/g$, which was quite lower than that of white charcoal (53.2~372.6 $m^2/g$) and mechanical charcoals (224.3~464.6 $m^2/g$). Also, amounts of methylene blue adsorption were quite lower in black charcoal (0.53~1.97 mg/g) compared with white charcoal (2.68~7.68 mg/g) and mechanical charcoal (11.63~26.10 mg/g). Removal ratios of formaldehyde of the black charcoal were 11.4~26.7%, which is quite similar to white charcoal (17.9~34.9%) and mechanical charcoal (5.5~25.8%). Removal ratios of ethylene gas for traditional black charcoal, traditional white charcoal, and mechanical charcoal were 2.2~43.5%, 21.7~39.1%, 21.7~39.1%, respectively. There was no significant difference in the removal ratios of formaldehyde and ethylene gas among traditional black charcoal, traditional white charcoal, and mechanical charcoal.

Optimization of Gas Mixing-circulation Plasma Process using Design of Experiments (실험계획법을 이용한 가스 혼합-순환식 플라즈마 공정의 최적화)

  • Kim, Dong-Seog;Park, Young-Seek
    • Journal of Environmental Science International
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    • v.23 no.3
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    • pp.359-368
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    • 2014
  • The aim of our research was to apply experimental design methodology in the optimization of N, N-Dimethyl-4-nitrosoaniline (RNO, which is indictor of OH radical formation) degradation using gas mixing-circulation plasma process. The reaction was mathematically described as a function of four independent variables [voltage ($X_1$), gas flow rate ($X_2$), liquid flow rate ($X_3$) and time ($X_4$)] being modeled by the use of the central composite design (CCD). RNO removal efficiency was evaluated using a second-order polynomial multiple regression model. Analysis of variance (ANOVA) showed a high coefficient of determination ($R^2$) value of 0.9111, thus ensuring a satisfactory adjustment of the second-order polynomial multiple regression model with the experimental data. The application of response surface methodology (RSM) yielded the following regression equation, which is an empirical relationship between the RNO removal efficiency and independent variables in a coded unit: RNO removal efficiency (%) = $77.71+10.04X_1+10.72X_2+1.78X_3+17.66X_4+5.91X_1X_2+3.64X_2X_3-8.72X_2X_4-7.80X{_1}^2-6.49X{_2}^2-5.67X{_4}^2$. Maximum RNO removal efficiency was predicted and experimentally validated. The optimum voltage, air flow rate, liquid flow rate and time were obtained for the highest desirability at 117.99 V, 4.88 L/min, 6.27 L/min and 24.65 min, respectively. Under optimal value of process parameters, high removal(> 97 %) was obtained for RNO.

Effect of Membrane Material and Absorbent Type on $SO_2$ Removal Using Microporous Hollow-fiber Membrane G-L Contactors (다공성 중공사막 기액 접촉기틀 이용한 $SO_2$ 제거에서 막재질과 흡수제의 영향)

  • Song Hee-Ouel;Kim In-Won;Park Hyun-Hee;Lim Chun-Won;Jo Hang-Dae;Lee Hyung-Keun
    • Journal of the Korean Institute of Gas
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    • v.10 no.2 s.31
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    • pp.14-21
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    • 2006
  • An experimental apparatus for the removal of $SO_2$ gas using microporous hollow-fiber membrane G-L contactors was setup. Various performance experiments were carried out with commercial membrane modules and the membrane modules made by KIER. The $SO_2$ removal efficiency was outstanding. When the hollow-fiber membrane was used for the removal of $SO_2$, the selection of absorbers and additives, membrane material, operating conditions of membrane manufacture were significant variables to develop optimal G-L contactors. More experiment works will be done for the development of compact, cost-effective and better G-L contactors.

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A Phenomenological Review on the Damage of Hot Gas Parts caused by Explosion of Gas Turbine Cooling System (가스터빈 내부 냉각계통 발화에 의한 고온부품 손상의 현상학적 고찰)

  • Yu, Won-Ju;Lee, Seong-Hyun
    • Journal of the Korea Safety Management & Science
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    • v.12 no.2
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    • pp.75-82
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    • 2010
  • Gas turbines for power generating operate in a very high temperature condition and use natural gas for fuel. For this reason, many cases of damage happen at hot gas parts which are severely affected by high temperature gas and many cases of explosion occur by fuel gas. So a lot of efforts should be made to prevent hot gas parts damage and gas explosion accidents. Though there are many damage cases and explosion accidents, it is very difficult to find out the root causes of hot gas parts damage caused by gas explosion due to gas leakage in the heat exchanger for air cooling and gas heating. To prevent gas turbine from damage caused by gas explosion, removal of leakage gas from gas turbine is inevitably required before firing the gas turbine and installing alarm systems is also required for detecting gas leakage at stop valve to turbine while shut down.

Collection characteristics of wet-type multi-staged impaction system for air pollutants removal of marine diesel engines (박용디젤기관의 대기오염 저감을 위한 습식 다단 임팩션 시스템의 집진특성)

  • YOA, Seok-Jun;KWON, Jun-Hyeong
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.52 no.3
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    • pp.248-256
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    • 2016
  • The main purpose of this paper was to analyze the removal characteristics of gas/particulate phase pollutants for the present system. Experimentally, we performed to estimate the pressure drop and air pollution removal efficiency with physical variables such as stage number, tube velocity, tube diameter, water spray ($NH_4OH$), and so on. It was concluded that the pressure drop was shown below $111mmH_2O$ lower than that of the existing scrubber (centrifugal spray chamber, over 200 mmAq) at inlet velocity 3.46 m/s and 5 stage. The particular removal efficiency of this system was to be significantly higher at 99.8% in comparison with that of the existing scrubber for 5 stage, inlet velocity 3.46 m/s and $NH_4OH$ (aq) 300 mL/min. It was estimated that the removal efficiencies of $SO_2$ and $NO_2$ were 80% and 70% at system inlet velocity 2.07 m/s and $NH_4OH$ (aq) 300 mL/min respectively. Additionally, the present collection system was to be considered as an effective compact system for simultaneous removal of air pollutants (gas/particulate) due to much higher removal efficiency and appropriate pressure drop without a demister.

A Study on the Performance Improvement of the Air Washer System for Semiconductor Manufacturing Clean Rooms (반도체 클린룸용 에어와셔 시스템의 성능개선을 위한 연구)

  • Park, Sang-Tae;Yoo, Kyung-Hoon;Son, Seung-Woo
    • Proceedings of the KSME Conference
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    • 2007.05b
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    • pp.3413-3417
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    • 2007
  • In recent semiconductor manufacturing clean rooms, air washers are used to remove airborne gaseous contaminants such as $NH_3$, SOx and organic gases from the outdoor air introduced into clean room. In the present study, an experiment was carried out to examine the improvement of removal efficiency for the gaseous contaminants. In order to improve the gas removal efficiency, a hot water contact heat exchanger was installed upstream of the air washer to heat and humidify the incoming outdoor air before entering the air washer.

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A Study on the Thermal Decomposition of Carbon Tetrachloride by Pyrolytic Incineration (사염화탄소의 열분해 소각에 관한 연구)

  • 이태호;정홍기
    • Journal of environmental and Sanitary engineering
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    • v.11 no.1
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    • pp.57-61
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    • 1996
  • This study was to decompose carbon tetrachloride and CFC with pyrolytic incineration unit because of prohibition of their usage sooner or later. We have investigated heating value and temperature versus decomposing rate, removal of $Cl_2$ and dust in the flue gas, The results obtained were as follows; 1. In combustion condition to decompose $CCl_4$ heating value was 3,300Kcal/Kg, retention time was 2,0 sec. incinerator exit temperature was $950^{\circ}C$. 2.The removal of HCI and $Cl_2$ in flue gas used NaOH as reagent, then molar ratio o of $Na^+/Cl^-$ was 1.07. 3. NaCI of dust component was more than 90 %, 2 stage venturi scrubber was used to remove dust, then removal rate of dust was 99% over at L/G of $1.7Vm^3$

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NOx removal in cylinder type reactor and Packed-bed type reactor (원통형과 packed-bed형 반응기에서 NOx제거특성)

  • 박재윤;박상현;이경호;하상태;송원섭;황보국
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.07a
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    • pp.499-502
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    • 2001
  • In this experiment, an attempt to use the sludge pellets as catalyst for NO removal from simulated gas is experimentally investigated by using cylinder type reactor and packed-bed reactor. An experimental investigation has been conducted for NO concentration of 50[ppm], 100[ppm], 200[ppm] balanced with air, a gas flow rate of 5[1/min]. Ac voltage to discharge the gases was supplied. In the result, NOx removal rate in packed bed reactor is higher than that in cylinder type reactor. it is thought that plasma density in contact point of BaTiO$_3$ is significantly higher than that in cylinder reactor.

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