• Title/Summary/Keyword: Gas methane

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Rapid Changes in CO Concentration Levels at Seven Roadside Locations in Seoul before and after 2000

  • Kim, Ki-Hyun;Shon, Zang-Ho;Park, Chan-Goo;Jeon, Eui-Chan;Kim, Jo-Chun;Choi, Kum-Chan
    • Asian Journal of Atmospheric Environment
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    • v.4 no.1
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    • pp.26-32
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    • 2010
  • Concentrations of carbon monoxide (CO) in air were analyzed from seven urban roadside (U-RS) stations in Seoul, Korea over an 11-year period (1998-2008). As noticeable changes in CO levels coincided with the Natural Gas Vehicle Supply (NGVS) program in the year 2000, its concentration data were examined between 1998-2000 (period I) and 2001-2008 (period II). The mean values of CO from all 7 stations for the whole study period were recorded as $1.19{\pm}0.22$ ppm with large drops in its mean from $1.83{\pm}0.43$ ppm in period I to $0.94{\pm}0.21$ ppm in period II. As such, CO levels between the two periods undertook the mean reduction rate of $46.9{\pm}16.2%$ (range of 18.3 to 59.9%). According to the analysis of longterm trends of CO, its concentrations in the U-RS stations decreased very rapidly with the annual mean reduction rate of 9.5% $yr^{-1}$. A line of evidence collected in this study suggests that the implementation of the NGVS program has been quite effective to induce the alterations in CO levels in all urban roadside locations throughout the city of Seoul.

Experimental Study and Setup of Its Apparatus for the Formation of Hydrate in Porous Media (다공질암에서의 하이드레이트 유동실험을 위한 실험장치 제작 및 형성 실험 연구)

  • Lee Hoseob;Kang Hyun;Sung Wonmo
    • Journal of the Korean Institute of Gas
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    • v.6 no.4 s.18
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    • pp.8-16
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    • 2002
  • Since hydrate has been discovered on the earth, many numbers of experimental studies have been conducted for characterizing the fundamental properties of hydrates, such as equilibrium conditions, thermodynamic properties, structures, kinetics, etc. It is considered naturally occurred hydrates in porous rocks have a great potential as a future of unconventional energy resources, and the investigations of formation and dissociation of hydrates in porous media are required. In this study, an experimental apparatus was designed to perform experiments of hydrates in porous core. With the apparatus developed, firstly, isochoric experiments were conducted to find hydrate equilibrium conditions in porous media, and the results were compared with reference data to verify experimental apparatus and methods in this study. Secondly, experiment of formation was examined by observing the behaviors of pressure and electrical resistance and the effects of initial water saturation on formation were analysed.

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Performance Analysis of Hybrid SOFC/GT/ST System for Marine Power Applications (선박동력용 SOFC/GT/ST 하이브리드시스템의 성능 평가에 관한 시뮬레이션)

  • Lee, Kyung-Jin;Oh, Jin-Suk;Kim, Sun-Hee;Oh, Sae-Gin;Lim, Tae-Woo;Kim, Jong-Su;Lee, Jae-Hyun;Park, Sang-Kyun;Kim, Mann-Eung;Kim, Myoung-Hwan
    • Journal of Advanced Marine Engineering and Technology
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    • v.36 no.1
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    • pp.40-50
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    • 2012
  • The electrification of the waste heat of stack is necessary to enhance the efficiency of fuel cell system. For this purpose, the hybrid SOFC/GT/ST system is suitable. The purpose of this work is to predict the performance of methane fueled SOFC/GT/ST hybrid power system and to analyze the influence of operating temperature of stack, current density of stack, and gas turbine pressure ratio. According to the analysis, it is proved that the SOFC/GT/ST hybrid system suppress the rapid decrease in efficiency and lead to the significant improvement of efficiency as compared with SOFC system.

Automatic NPK Calculation Based on Nutrients of Livestock Manure (ICT 기반 가축분뇨 중 함유 NPK 양분의 정량적 관리기법 연구)

  • Lee, Myunggyu;Kim, Sooryang;Hong, Yousik
    • The Journal of the Institute of Internet, Broadcasting and Communication
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    • v.17 no.5
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    • pp.173-179
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    • 2017
  • Advanced countries, animal wastes are produced using bioenergy and methane gas technology. In Korea, many researches are being actively carried out to develop livestock manure as a resource technology rather than a animal waste. However, the production of bio-gas using livestock manure is still in the process of development of functional livestock and compost because of low economic efficiency with livestock manure recycling technology. In this paper, in order to accurately estimate the manure output, It will calculate the manure excretion if you have finished input the number of pigs. In addition, we simulated the fertilization rate of three elements of NPK fertilizer per 100 square meters automatically.

International Rule for Environment and International Trade (국제환경규범(國際環境規範)과 무역연계(貿易連繫))

  • Shin, Han-Dong
    • THE INTERNATIONAL COMMERCE & LAW REVIEW
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    • v.12
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    • pp.587-613
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    • 1999
  • Environmental problems such as global climate change, depletion, ocean and air pollution, and resource degradation-compounded by an expanding world population-respect no border and threaten the health, prosperity and jobs of all mankind. Our efforts to promote democracy, free trade, and stability in the world will fall short unless people have a livable environment. We have an enormous stake in the management of the world's resources. By increasing demand for timber, natural gas, coal and consumer's goods have destroyed the grounds for living. Greenhouse gas emissions anywhere in the world have threatened coastal communities, and then changed the Earth's climate system. The burning of coal, oil, and other fossil fuels is increasing substantially the concentration of heat-trapping gasses such as carbon dioxide, methane, and nitrous oxide in our air. The earth's temperature and sea levels are rising as a result. Since 1972 there has been a marked growth in the number and scope of environmental treaties. In particular, after the 1992 Rio Conference, international legal instruments became more concentrated on addressing environment within the context of sustainable development and incorporated a number of new concepts and innovative approaches. A preliminary analysis of recent conventions and in particular those associated with the Rio Conference indicates various ideas, concepts and principles which have come to the fore including sustainable development, equity, common concern of humankind, common but differentiated responsibilities and global partnership. However, international trade also has an environmental impact which must be minimized or countered. Positive measures are to be preferred to achieve environmental goals, but where trade provisions are necessary, they should be appropriately used within environmental conventions to facilitate the reduction and limitation of the negative impacts of trade and to enhance the complementarity of the multilateral trade regime with the imperatives of environmental protection, in the interests of environmental protection and sustainable development generally. The international community has to recognize and endorse this need to achieve complementarity between trade and environment issues.

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Changes in Microbial Diversity, Methanogenesis and Fermentation Characteristics in the Rumen in Response to Medicinal Plant Extracts

  • Kim, Eun Tae;Moon, Yea Hwang;Min, Kwan-Sik;Kim, Chang-Hyun;Kim, Sam Churl;Ahn, Seung Kyu;Lee, Sung Sill
    • Asian-Australasian Journal of Animal Sciences
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    • v.26 no.9
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    • pp.1289-1294
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    • 2013
  • This study evaluated the in vitro effect of medicinal plant extracts on ruminal methanogenesis, four different groups of methanogens and ruminal fermentation characteristics. A fistulated Holstein cow was used as a donor of rumen fluid. Licorice and mugwort extracts (Glycyrrhiza uralensis and Artemisia capillaris, 0.5% and 1% of total substrate DM, respectively), previously used as folk remedies, were added to an in vitro fermentation incubated with buffered-rumen fluid. Total gas production in Glycyrrhiza uralensis extract treatment was not significantly different between treatments (p<0.05) while total gas production in the Artemisia capillaris extract treatment was lower than that of the control. Artemisia capillaris extract and Glycyrrhiza uralensis extract reduced $CH_4$ emission by 14% (p<0.05) and 8% (p<0.05), respectively. Ciliate-associated methanogens population decreased by 18% in the medicinal plant extracts treatments. Medicinal plant extracts also affected the order Methanobacteriales community. Methanobacteriales diversity decreased by 35% in the Glycyrrhiza uralensis extract treatment and 30% in the Artemisia capillaris extract treatment. The order Methanomicrobiales population decreased by 50% in the 0.5% of Glycyrrhiza uralensis extract treatment. These findings demonstrate that medicinal plant extracts have the potential to inhibit in vitro ruminal methanogenesis.

A Study on the Method for Measuring the live Calorific Value of LNG in storage tank using LNG Densitometer (LNG 밀도계를 이용한 저장 탱크 내 LNG 발열량 실시간 측정방법에 관한 연구)

  • Ha, Young-Cheol;Lee, Seong-Min
    • Korean Chemical Engineering Research
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    • v.49 no.1
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    • pp.35-40
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    • 2011
  • The low caloric LNG, which didn't meet the gas interchangeability of Korea, has been imported from 2005 winter season. Amount of this LNG imports has been increased from year to year. In the near future, very low caloric LNG (calorific value ${\leq}$ 9,500 kcal/$Nm^3$) such as CBM, Shale LNG will be imported large amounts. For this reason, we need a method for monitoring live calorific values(CV) of LNG in each storage tank to supply gasified LNG with interchangeable CV at LNG receiving terminal. This study was conducted to develope the method for measuring the live CVs of LNG in each storage tank using LNG densitometer. For this purpose, the accurate correlation between CV and density of LNG was derived and the uncertainty of this method was evaluated and also the measuring system for CVs was constructed at LNG receiving terminal. To verify this method, the results of measurement using this method were compared with the field data of LNG analysis and the results showed that the deviations were 0.17~0.47%.

Numerical Study on Steam-Methane Reaction Process in a Single Tube Considering Porous Catalyst (다공성 촉매를 고려한 단일튜브 내의 수증기-메탄 개질에 관한 수치해석 연구)

  • Moon, Joo Hyun;Lee, Seong Hyuk;Yoon, Kee Bong;Kim, Ji Yoon
    • Journal of the Korean Institute of Gas
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    • v.18 no.4
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    • pp.56-62
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    • 2014
  • The present study investigated numerically heat and mass transfer characteristics of a fixed bed reactor by using a computational fluid dynamics (CFD) code of Fluent (ver. 13.0). The temperature and species fraction were estimated for different porosities. For modeling of the catalyst in a fixed bed tube, catalysts were regarded as the porous material, and the empirical correlation of pressure drop based on the modified Eugun equation was used for simulation. In addition, the averaged porosities were taken as 0.545, 0.409, and 0.443 and compared with non-porous state. The predicted results showed that the temperature at the tube wall became higher than that estimated along the center line of tube, leading to higher hydrogen generation by the endothermic reaction and heat transfer. As the mean porosity increases, the hydrogen yield and the outlet temperature decreased because of the pressure drop inside the reformer tube.

Gamma-Radiolysis of Carbon Dioxide (V). Radiolysis of Carbon Dioxide-Alcohol Mixtures (이산화탄소와 알코올류의 혼합물에 대한 방사선 분해반응에 관한 연구)

  • Choi Sang Up;Pyun Hyung Chick;Jin Joon Ha
    • Journal of the Korean Chemical Society
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    • v.35 no.1
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    • pp.3-15
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    • 1991
  • The gaseous mixtures of iso-propanol of 10 torr with carbon dioxide of 0∼1990 torr were irradiated with Co-60 gamma radiation up to 50 kGy, and the products such as carbon monoxide, acetone, methane, ethane, C$_3$H$_a$, C$_4$H$_b$ and tert-butanol were analyzed by gas chromatography. G(CO) value of 4 was obtained from the gas mixtures containing more than 490 torr of carbon dioxide. The production rates of the organic products and the decomposition rate of iso-propanol increased linearly with the pressure of carbon dioxide, and G(-iso-Propanol) and G(Acetone) values increased by 4 and 2, respectively, with each 10 torr increment of carbon dioxide pressure. The mechanisms of the radiolytic decomposition of iso-propanol and the production of carbon monoxide and organic materials are discussed on the basis of the experimental results of the present study.

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Hydrophobic and Mechanical Characteristics of Hydrogenated Amorphous Carbon Films Synthesized by Linear Ar/CH4 Microwave Plasma

  • Han, Moon-Ki;Kim, Taehwan;Cha, Ju-Hong;Kim, Dong-Hyun;Lee, Hae June;Lee, Ho-Jun
    • Applied Science and Convergence Technology
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    • v.26 no.2
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    • pp.34-41
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    • 2017
  • A 2.45 GHz microwave plasma with linear antenna has been prepared for hydrophobic and wear-resistible surface coating of carbon steel. Wear-resistible properties are required for the surface protection of cutting tools and achieved by depositing a hydrogenated amorphous carbon film on steel surface through linear microwave plasma source that has $TE_{10}-TEM$ waveguide. Compared to the existing RF plasma source driven by 13.56 MHz, linear microwave plasma source can easily generate high density plasma and provide faster deposition rate and wider process windows. In this study, $Ar/CH_4$ gas mixtures are used for hydrogenated amorphous carbon film deposition. When microwave power of 1000 W is applied, 40 cm long uniform $Ar/CH_4$ plasma could be obtained in gas pressure of 200~400 mTorr. The Vickers hardness measurement of hydrogenated amorphous carbon film on steel surface was evaluated. It was found the optimized deposition condition at $Ar:CH_4=25:25$ sccm, 300 mTorr with microwave power of 1000W and RF bias power of 100W. By deposition of hydrogenated amorphous carbon film, contact angle on steel surfaces increases from $43.9^{\circ}$ to $93.2^{\circ}$.