• 한국신재생에너지학회:학술대회논문집
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• 2010.11a
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• pp.76.1-76.1
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• 2010

Recently, many efforts to solve the durability problem of PEM fuel cell are carried on constantly. However, despite this attention, durability researches of gas diffusion layer (GDL) are not much reported yet. Generally, GDL of PEM fuel cell experiences three external attacks, which are dissolution of water, erosion of gas flow, corrosion of electric potential. In this study, among these degradation factors, carbon corrosion of electric potential was focused and investigated with accelerated carbon corrosion test. Through the test, it is confirmed that carbon corrosion occurred at GDL, and corroded GDL decreased a performance of operating fuel cell. The property changes of GDL were measured with various methods such as air permeability meter, pore distribution analyzer, thermo gravimetric analyzer, and tensile stress test to discover the effects of carbon corrosion. Carbon corrosion caused not only loss of weight and thickness, but also degradation of mechanical strength of GDL. In addition, to analysis the reason of GDL property changes, a surface and a cross section of GDL were observed with scanning electron microscope. After 100 hours test, the GDL showed serious damage in center of layer.

• Journal of The Korean Association For Science Education
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• v.15 no.4
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• pp.437-451
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• 1995

Middle and high school students' conceptual understanding about stoichiometry, gas laws, and diffusion was compared with essay type test and multiple choice test. Whereas achievement of high school students was higher in stoichiometry, that of middle school students who were expected to go to high schools was higher in gas laws and diffusion. When students' achievement was compared to that of American college students, Korean students' achievement was higher in stoichiometry and was similar in gas laws. These results indicate that algorithmic problem solving is more emphasized than conceptual understanding in high schools and that quantitative aspects focused in chemistry education are not helpful in concept understanding. Nevertheless relatively smaller difference between concept understanding and algorithmic problem solving for high school students in this study seems to be from concept learning in middle schools.

• Proceedings of the Korean Vacuum Society Conference
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• 2012.08a
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• pp.394-394
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• 2012

We fabricated organic-inorganic superlattice films using molecular layer deposition (MLD) and atomic layer deposition (ALD). The MLD is a gas phase process in the vacuum like to atomic layer deposition (ALD) and also relies on a self-terminating surface reaction of organic precursor which results in the formation of a monolayer in each sequence. In the MLD process, 'Alucone' is very famous organic thin film fabricated using MLD. Alucone layers were grown by repeated sequential surface reactions of trimethylaluminum and ethylene glycol at substrate temperature of $80^{\circ}C$. In addition, we developed UV-assisted $Al_2O_3$ with gas diffusion barrier property better than typical $Al_2O_3$. The UV light was very effective to obtain defect-free, high quality $Al_2O_3$ thin film which is determined by water vapor transmission rate (WVTR). Ellipsometry analysis showed a self-limiting surface reaction process and linear growth of each organic, inorganic film. Composition of the organic films was confirmed by infrared (IR) spectroscopy. Ultra-violet (UV) spectroscopy was employed to measure transparency of the organic-inorganic superlattice films. WVTR is calculated by Ca test. Organic-inorganic superlattice films using UV-assisted $Al_2O_3$ and alucone have possible use in gas diffusion barrier for OLED.

• Journal of the Korean Recycled Construction Resources Institute
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• v.6 no.4
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• pp.245-251
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• 2018

Recently, as the importance of structural maintenance has been increased, studies on self - healing concrete technology are being actively carried out. On the other hand, test for evaluating the self-healing performance is not standardized yet. Although visual test is used as a basic method for measuring crack widths, it is difficult to observe the crack width inside the specimen, and there is a disadvantage that only the local measurement of the surface can be measured due to the inhomogeneous cracking characteristics. Although permeability test has been widely used as an indirect method for measuring crack width, there is a problem due to the viscosity of water, and also a possibility that the internal material of the specimen may be eluted during the test. In this study, we propose a crack width evaluation method using gas diffusion characteristics. Idealized straight cracks were fabricated by acrylic and the diffusion coefficients of specimens were analyzed with respect to crack width and thickness. The experimental results show that the crack width and the diffusion coefficient are in a linear relationship and that the thickness and diffusion coefficient are inversely related.

• Journal of the Korean Recycled Construction Resources Institute
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• v.9 no.3
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• pp.375-382
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• 2021

Self-healing concrete is in the spotlight in that it can effectively extend the lifespan of concrete structures by healing cracks in the structure by themselves without additional repairing or retrofiting actions. Currently, self-healing concrete is a field that is being actively studied around the world, but since most studies focus on the improvement of healing performance, there is a lack of methods to rationally evaluate the self-healing performance of concrete. Although the gas diffusion test method has been developed for the use in the performance evaluation of self-healing concrete, it has revealed that for gas diffusion through the matrix affect the crack diffusion coefficients depending on the environmental conditions such as the saturation of the specimen, the temperature, and humidity during the experiment. Therefore, in this study, the method has been proposed to eliminate the influence of the matrix diffusion when calculating the crack diffusion coefficient. In addition, a pre-conditioning process was introduced to shorten the experimental time. As a result, the crack width could be estimated with an error level of less than 3% in the test time of about 20 minutes.

• Journal of the Korean institute of surface engineering
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• v.36 no.1
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• pp.99-107
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• 2003

The diffusion coefficient of Xe-133 was obtained from an annealing test. The specimens were made from a UO$_2$ single crystal powder with natural enrichment. Weight and grain size were 300mg and ($23\mu\textrm{m}$, respectively. Oxygen potentials were obtained from an oxygen sensor. Released fractions were obtained from both results of gamma scans and quantitative analysis with MCNP code, The annealing test was performed at three temperatures at once. Diffusion coefficients of Xe-133 were calculated using slope of Booth theory in each O/M ratios. Activation energy and the pre-exponential factor of the diffusion coefficient were obtained. The activation energy of near stoichiomeric $UO_2$ is 310 kJ/mol. The measured values of near stoichiometric $UO_2$ are very close to other data available. Diffusion coefficients increase with hyper-stoichiometry, due to higher concentration of cation vacancies.

• Journal of the Korean Electrochemical Society
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• v.5 no.1
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• pp.7-12
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• 2002

The gas diffusion electrodes as oxygen cathodes f3r the brine electrolysis process were investigated. The gas diffusion electrode consists of a reaction layer, a gas diffusion layer, and a current distributor. The reaction layer was made from hydrophilic carbon black, hydrophobic carbon black, PTFE(polyterafluoroethylene), and Ag catalyst loaded by the silver mirror reaction or impregnation method. The gas diffusion layer was made from hydrophobic carbon black and PTFE, and Ni mesh was used as the current distributor in the reaction layer. The result that the gas diffusion electrode $(10wt\%\;Ag\;catalyst\;and\;20wt\%\;binder)$ manufactured by applying impregnation method to the carbon black f3r reaction layer showed the better performance was obtained from experiments. From the half-cell test, the measured overpotential of this oxygen cathode was about 700mV, And through the electrolysis experiment under the condition of $80^{\circ}C,\;32wt\%$ NaOH, and $300mA/cm^2$, the electrolysis voltage of this electrode was about 2.2 V, The gas diffusion electrodes manufactured in the present research were capable of continuous operations for three months.

• Journal of the Korean Recycled Construction Resources Institute
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• v.8 no.1
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• pp.143-151
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• 2020

Recently, research on self-healing concrete has been actively conducted, and various methods have been attempted for use in the maintenance of structures. However, contrary to the technical development of self-healing concrete, the method for evaluating the performance is insufficient. Although surface observation and permeability experiments are widely used to observe the healing of cracks, microscopic observation of surface may be insufficient to assess the overall performance. Also, permeation experiments should consider the losses caused by the dissolution of self-healed product and viscosity of water. Although a gas diffusion experiment have been proposed to overcome the shortcomings of these two test methods, verification has not been made on specimens with actual healing. Therefore, in this study, gas diffusion experiments were performed on the mortar specimens that had healed, and the adequacy of self-healing evaluation by the gas diffusion experiment was verified.

• Journal of the Korean Society for Heat Treatment
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• v.13 no.4
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• pp.224-230
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• 2000

Garbon steel(SM35C) was gas nitrocarburized at $580^{\circ}C$ in $55%N_2-40%NH_3-5%CO_2$ mixed gas atmosphere, and then the steel was induction hardened at $850^{\circ}C$. The microstructure of gas nitrocarburized surface layer was observed by optical microscope and SEM. The phase analysis was carried out by X-ray diffraction method. The mechanical properties of gas nitrocarburized SM35C steel was evaluated by hardness, wear and fatigue test. The thickness of compound and diffusion layer were increased with increasing the gas nitrocarburizing time and the densest compound layer was obtained at 3 hours gas nitrocarburizing time. In case of 15sec induction hardening after gas nitrocarburizing, the surface hardness was decreased from 800Hv to 630Hv owing to the decomposition of compound layer, but wear resistance was increased because of increased hardness of diffusion layer. The fatigue strength of induction hardened steel after gas nitrocarburizing, $58kgf/mm^2$, was higher than $41.5kg/mm^2$ of gas nitrocarburized steel and $45kg/mm^2$ of induction hardened steel, respectively.

• Journal of Welding and Joining
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• v.15 no.6
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• pp.32-40
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• 1997

Solid state diffusion bonding is the joining process performed by creep and diffusion, which is accelerated by heating below melting temperature and proper pressing, in vacuum or shielding gas atmosphere. By this process we can obtain sufficient joint which can't be expected from the fusion welding. For Ti-6Al-4V alloy, the optimum solid state diffusion bonding condition and mechanical properties of the joint were found, and micro void morphology at bond interface was observed by SEM. The results of tensile test showed sufficient joint, whose mechanical properties are similar to that of base metal. 850$^{\circ}$C, 3MPa is considered as the optimum bonding condition. Void morphology at interface is long and flat at the initial stage. As the percentage of bonded area increases, however, small and round voids are found. Variation of void shape can be explained as follows. As for the void shrinkage mechanism, at the initial stage, power law creep is the dominant, but diffusion mechanism is dominant when the percentage of bonded area is increased.