• Journal of Soil and Groundwater Environment
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• v.23 no.5
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• pp.26-36
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• 2018

Total petroleum hydrocarbon (TPH) is a mixture of various oil substances composed of alkane, alkene, cycloalkane, and aromatic hydrocarbons (benzene, toluene, ethylbenzene, xylene, etc.). In this study, we investigated 92 groundwater wells around 36 gas stations to evaluate distribution characteristics of petroleum hydrocarbons. Groundwater in the wells was sampled and monitored twice a year. The fraction analysis method of TPH was developed based on TNRCC 1006. The test results indicated aliphatic and aromatic fractions accounted for 28.6 and 73.8%, respectively. The detection frequencies of TPH in the monitoring wells ranged in 21.6 - 24.2%. The average concentration of TPH was 0.11 mg/L with the concentration range of 0.25~0.99 mg/L. In the result of TPH fraction analysis, in aliphatic fractions were 19% (C6-C8 : 0.2%, C8-C10 : 0.4%, C10-C12 : 0.4%, C12-C16 : 0.5%, C16-C22 : 1.0%, C22-C36 : 16.6%), and aromatic fractions were 81% (C6-C8 : 1.1%, C8-C10 : 0%, C10-C12 : 2.9%, C12-C16 : 0.3%, C16-C22 : 4%, C22-C36 : 66.8%). Fractions of C22-C36 were detected in about 83% of the monitoring wells, suggesting non-degradable characteristics of hydrocarbons with high carbon content.

• Geophysics and Geophysical Exploration
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• v.2 no.1
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• pp.33-42
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• 1999

AVO and complex trace analyses mainly used to characterize natural gas reservoir were tested in this paper for a possible application to detection of major geological discontinuities such as fracture zones. The test data used in this study were calculated by utilizing a viscoelastic numerical program which was based on the generalized Maxwell body for a horizontal fracture model. In AVO analysis of a horizontal fracture zone, p-wave reflection appears to be variant depending upon the acoustic-impedence contrast and the offset distance. The fracture zone is also effectively clarified both in gradient stack and range-limited stack in which fracture zone reflection is attenuated with the increasing offset distance. In complex attribute plots (instantaneous amplitude, frequency, and phase), the top and bottom of the fracture Tone are characterized by a zone of strong amplitudes and an event of the same phase. Low frequency characteristics appear at the fracture zone and the underneath. Amplitude attenuation and waveform dispersion are dependent on Q-contrast between the fracture zone and the surrounding media. They were properly compensated by optimum inverse Q-filtering.

• Transactions on Electrical and Electronic Materials
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• v.14 no.4
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• pp.211-215
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• 2013

Partial discharge diagnosis techniques using ultra high frequencies do not affect load movement, because there is no interruption of power. Consequently, these techniques are popular among the prevention diagnosis methods. For the first time, this measurement technique has been applied to the GIS, and has been tested by applying an extra high voltage switchboard. This particular technique makes it easy to measure in the live state, and is not affected by the noise generated by analyzing the causes of faults ? thereby making risk analysis possible. It is reported that the analysis data and the evaluation of the risk level are improved, especially for poor location, and that the measurement of Ultra high frequency (UHF) partial discharge of the real live wire in industrial switchgear is spectacular. Partial discharge diagnosis techniques by using the Ultra High Frequency sensor have been recently highlighted, and it is verified by applying them to the GIS. This has become one of the new and various power equipment techniques. Diagnosis using a UHF sensor is easy to measure, and waveform analysis is already standardized, due to numerous past case experiments. This technique is currently active in research and development, and commercialization is becoming a reality. Another aspect of this technique is that it can determine the occurrences and types of partial discharge, by the application diagnosis for live wire of ultra high voltage switchgear. Measured data by using the UHF partial discharge techniques for ultra high voltage switchgear was obtained from 200 places in Gumi, Yeosu, Taiwan and China's semiconductor plants, and also the partial discharge signals at 15 other places were found. It was confirmed that the partial discharge signal was destroyed by improving the work of junction bolt tightening check, and the cable head reinforcement insulation at 8 places with a possibility for preventing the interruption of service. Also, it was confirmed that the UHF partial discharge measurement techniques are also a prevention diagnosis method in actual industrial sites. The measured field data and the usage of the research for risk assessment techniques of the live wire status of power equipment make a valuable database for future improvements.

• Journal of Conservation Science
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• v.32 no.2
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• pp.123-139
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• 2016

The excavated potteries of Goryeo Period from the Sandongri archaeological site in Seosan were studied on physicochemical analyses. Surface color of the samples are mainly grayish blue, and showed the natural glaze by melting the body soils during the burning. Partly, swelling surface are observed bloated marks because of blow out gas by burning. The potteries are some possibility of making the similar source clay on the basis of magnetic susceptibilities (about $1{\times}10^{-3}SI\;unit$) and general occurrences. Values of specific gravity, apparent porosity and absorption ratio are divided two groups as highly different cases of bloating surface samples. The source clay of the potteries used mainly microcrystalline clay, the mineral compositions are quartz and some colored minerals. Based on the analysis, the burning temperature of the potteries are assumed that they were around $1,100^{\circ}C$ because detection of quartz and mullite within hard and compact matrices. As geochemical variations of the samples, evolution trends of rare earth, compatible and incompatible elements showed very similar patterns excepting the some major elements, that means the potteries are interpreted to making by elutriation processes using the same raw clays from very similar basement rocks of genetically.

• Analytical Science and Technology
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• v.15 no.1
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• pp.80-86
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• 2002

The simultaneous analysis of the odorous compounds designated by law in Korea and Japan was examined with the thermal desorber gas chromatography-mass spectrometry using one column. The approximate concentrations of trimethyl amine, acetaldehyde, methyl mercaptan and dimethyl sulfide were estimated. Styrene, dimethyl disulfide, propionaldehyde, n-butyl aldehyde, i-butyl aldehyde, n-valeraldehyde, i-valeraldehyde, ethyl acetate, toluene, xylene, methyl i-butyl ketone and i-butanol were detected at concentrations of the detection limits of their threshold values. As a typical example of simultaneous analysis of the odorous compounds, the volatile organic compounds emitted from compost procedure of food waste were concentrated and analyzed with thermal desorber/GC/MSD, and major malodorous compounds were estimated from the concentrations and threshold values of the detected components. From the result of analysis, 34 compounds were confirmed and among them, trimethyl amine, i-valeraldehyde, methyl mercaptan, methyl allyl sulfide, dimethyl sulfide, acetaldehyde, ethanol, n-butyaldehyde were expected to attribute to the odor in order of strength.

• Analytical Science and Technology
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• v.14 no.1
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• pp.88-93
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• 2001

To measure the levels of dioxins in food selling at local markets, meat was analyzed by high resolution gas chromatography/high resolution ass spectrometry (HRGC/HRMS). The food samples were obtained from 5 large cities of Seoul, Chunchon, Daejon, Kwangju and Busan in Korea. All the samples were minced and extracted with Soxhlet extractor for 18 hours. After extraction, extracts were cleaned up by sulfuric acid impregnated silica gel, purified on a series of silica gel, alumina, carbon column chromatography and then analyzed by HRGC/HRMS. The contaminated levels were calculated as the TEQs by multiplying with the corresponding WHO-TEFs for each congeners. The overall recoveries were ranged from 80% to 153% and the limit of detection was about 0.01 ppt at S/N>3. The levels of PCDD/Fs for beef, pork and chicken were 0.018, 0.008 and <0.001 pgTEQ/g, respectively. In addition, the levels of non-ortho-co-planar PCBs for beef, pork and chicken were 0.008, 0.002 and 0.001 pgTEQ/g, respectively. Among food samples analyzed, chicken showed the lowest level of dioxin-like compounds. Regarding congener pattern, OCDD and PCB #77 were the highest contributing congeners.

• Analytical Science and Technology
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• v.24 no.5
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• pp.352-359
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• 2011

An analytical method for solvent-free determination of benzene, toluene, ethylbenzene, and xylenes (BTEX) in water using repetitive membrane extractions coupled to cryofocusing and GC-MS was derived. BTEX compounds that permeated through a nonporous silicone membrane from the aqueous phase and evaporated into the acceptor phase were purged into a cryofocusing trap ($-100^{\circ}C$) with helium gas. The BTEX compounds, thus enriched in the trap, were thermally desorbed into a capillary column GC and detected using an MS. The flow rate of the donor phase (30 mL water) was set at 10 mL/min, and membrane extractions, accomplished by returning the water drained from the extraction module to the sample container, were repeated three times at $20{\pm}2^{\circ}C$. Although recoveries (%) were variable, from the highest for benzene (approximately 80%) to the lowest for ethylbenzene and xylenes (3.5-10%), the method showed satisfactory precision (RSD 2.2-10%) with good-linearity calibration curves ($r^2$ 0.9976-0.9997 in 1-100 ${\mu}g$/L range) for all of the compounds. The method detection limits (MDLs) ranged from 0.16 to 1.8 ${\mu}g$/L. The results showed the method's advantages such as short analysis time and overall simplicity without solvent compared to the conventional techniques.

• Korean Journal of Environmental Agriculture
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• v.17 no.3
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• pp.205-210
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• 1998

This study was carried out for the dietary safety based on the level of pesticide residues in 19 kinds of agricultural products consumed in Kangwon-do, Korea. From April 1995 to December 1997, eight organochlorine pesticides in 673 samples were analyzed by using GLC-ECD. According to the results, one kind of pesticides were detected in 159(23.6%) samples and two kinds were in 24(15.1%). While Chlorobenzilate, Dicofol and Tetradifon were not found. Detection ranges of pesticides were $0.001{\sim}0.117ppm$ for DDT, $0.001{\sim}0.095ppm$ for ${\gamma}-BHC$, $0.001{\sim}0.067ppm$ for ${\alpha},{\beta}-Endosulfan$, $0.003{\sim}0.250ppm$ for Chlorothalonil and 0.033ppm for Captafol. Average residues were 0.006ppm for DDT, 0.009ppm for ${\gamma}-BHC$, 0.008ppm for ${\alpha},{\beta}-Endosulfan$, 0.024ppm for Chlorothalonil and 0.033ppm for Captafol, respectively. Consequently, all of the organochlorine pesticide residues in the analyzed samples were within the maximum residue limits.

• The Korean Journal of Pesticide Science
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• v.4 no.1
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• pp.1-10
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• 2000

The purpose of this study is to establish the assessment techniques of hazardous chemicals by the development of analytical method of biological samples. In this study, we have developed an extraction method of nine pesticides used for rice paddy that resulted in high recovery from the spiked human urine by the liquid-liquid extraction with diethyl ether at pH 7.0. Calibration curve obtained from each pesticide standard using by gas chromatography/mass spectrometry/selected ion monitoring has shown good linearity and detection limits were the range of $0.4{\sim}2.0$ ng/mL in urine. As a biological monitoring, urine samples of local farmers exposed directly to nine pesticides in the field were collected and analyzed by GC/MS. Of the tested pesticides, metabolites of phenthoate assumed were identified by GC/MS analysis. No parent compound was detected.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.16 no.3
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• pp.301-308
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• 2018

Anthropogenic radioactive noble gases formed by nuclear fission are significant indicators used to monitor the nuclear activity of neighboring countries. In particular, radioactive xenon, owing to its abundant generation and short half-life, can be used to detect nuclear testing, and radioactive krypton has been used as a tracer to monitor the reprocessing of nuclear fuels. Released radioactive noble gases are in the atmosphere at infinitesimal amounts due to their dilution in the air and their short half-life decay. Therefore, to obtain reliable and significant data when performing measurement of noble gases in the atmosphere, the minimum detectable activity (MDA) for noble gases should be defined as low as possible. In this study, the MDA values for radioactive xenon and krypton were theoretically obtained based on the BfS-IAR system by collecting both noble gases simultaneously. In addition, various MDA methods, confidence level and analysis conditions were suggested to reduce and optimize MDA with an assessment of the factors affecting MDA. The current investigation indicated that maximizing the pretreatment efficiency and performance maintenance of the counter were the most important aspects for Xe. In the case of Kr, since sample activities are much higher than those of Xe, it is possible to change the target MDA or to simplification of the analysis system.