• 한국대기환경학회지
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• 제20권1호
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• pp.77-85
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• 2004

In this study, the concentrations of reduced S compounds (including hydrogen sulfide (H$_2$S); methyl mercaptan ($CH_3$SH); dimethyl sulfide (($CH_3$)$_2$S); carbon disulfide (CS$_2$); and dimethyl disulfide (($CH_3$)$_2$S$_2$) were determined from landfill gas (LFG) in three municipal landfill sites in the two cities of Gwang Ju (GJ) and Jeju (JJ), Korea. The S gas concentrations measured in these landfill sites were found to be dominated by H$_2$S with its mean concentration of 850 ppm from 10 LFG samples. Both absolute and relative dominance of H$_2$S was seen to be significant in most LFG samples, except those collected from very old and inactive landfills. Unlike the pattern of H$_2$S, other S gases were typically observed at much reduced concentration levels (a few ppm or less) as follows: DMS (3.5); $CH_3$SH (1.3); CS$_2$(1.2); and DMDS (0.02 ppm). If compared equally in mass concentration unit (mg m$^{-3}$ ), H$_2$S generally explained far above 90% of all S gas masses determined concurrently. Moreover, as its mass concentration commonly exceeds those of the major aromatic VOC components in LFG (like benzene and toluene), it appeared to be one of the most dominant gaseous components emitted as LFG in a quantitative sense.

• 한국가스학회지
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• 제1권1호
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• pp.73-80
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• 1997

본 연구는 화학장치설비중 저장탱크에서 누출된 유해독성가스인 염소의 풍하거리에 따른 10분 평균, 30분 평균 및 1시간 평균 최대 지표면 농도를 산출하여 염소가스의 법적 규제농도인 IDLH 및 ERPG-3 농도들과 비교함으로써 유해위험거리 (hazard distance) 또는 독성완충거리 (toxic buffer distance)를 정량적으로 예측하는 분산모델링 방법론을 개발하고자 수행되었다. 본 분산모델링을 위하여 누출원모델, 분산모델, 기상 및 지형자료들 이 SuperChems 모델에 입력자료로 사용되었으며, 대기의 안정도, 풍속, 표면거칠기 길이의 변화에 따른 지표면 농도의 영향이 평가되었다.

• 한국연소학회지
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• 제18권4호
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• pp.1-11
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• 2013

The oxy-fuel combustion is $CO_2$ capture technology that uses mixture of pure $O_2$ and recirculated exhaust as oxidizer. Currently some Oxy-fuel power plants demonstration project is underway in worldwide. Meanwhile research project for converting 125 MWe Young-Dong power plant to 100 MWe oxy-fuel power plants is progress. In this paper, 1 D process analytical approach was applied for conducting process design and operating parameters sensitivity analysis for oxy-fuel combustion of Young-Dong power plant. As a result, appropriate gas recirculation rates was 74.3% that in order to maintain normal rating superheater, reheater steam temperature and boiler heat transfer patterns. And boiler efficiency 85.0%, CPU inlet $CO_2$ mole concentration 71.34% was predicted for retrofitted boiler. The oxygen concentration in the secondary recycle gas is predicted as 27.1%. Meanwhile the oxygen concentration 22.4% and moisture concentration 5.3% predicted for primary recycle gas. As the primary and secondary gas recirculation increases, then heat absorption of the reheater is tends to increases whereas superheater side is decreased, and also the efficiency is tends to decrease, according to results of sensitivity analysis for operating parameters. In addition, the ambient air ingression have a tendency to lead to decline of efficiency for boiler as well as decline of $CO_2$ purity of CPU inlet.

• Transactions on Electrical and Electronic Materials
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• 제13권6호
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• pp.305-309
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• 2012

In this study, ZnO nanorods and $SnO_2$-CuO heterogeneous oxide were grown on membrane-type gas sensor platforms and the sensing characteristics for carbon monoxide (CO) were studied. Diaphragm-type gas sensor platforms with built-in Pt micro-heaters were made using a conventional bulk micromachining method. ZnO nanorods were grown from ZnO seed layers using the hydrothermal method, and the average diameter and length of the nanorods were adjusted by changing the concentration of the precursor. Thereafter, $SnO_2$-CuO heterogeneous oxide thin films were grown from evaporated Sn and Cu thin films. The average diameters of the ZnO nanorods obtained by changing the concentration of the precursor were between 30 and 200 nm and the ZnO nanorods showed a sensitivity value of 21% at a working temperature of $350^{\circ}C$ and a carbon monoxide concentration of 100 ppm. The $SnO_2$-CuO heterogeneous oxide thin films showed a sensitivity value of 18% at a working temperature of $200^{\circ}C$ and a carbon monoxide concentration of 100 ppm.

• Bulletin of the Korean Chemical Society
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• 제25권10호
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• pp.1489-1494
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• 2004

A gas chromatography/mass spectrometric assay method was developed for the determination of persistent organochlorine pollutants (POPs) in hair. For the exact extraction study was used hair of rat exposed with POPs. Sonication of the hair matrix with 3 M HCl solution in methylene chloride of the extraction methods studied was the most efficient and rapid sample preparation method. After sonication of rat hair was achieved clean up with a solid phase extraction procedure using silica gel-florisil. Elution was performed with 8 mL of methylene chloride. The eluate was concentrated to approximately 100 ${\mu}L$ and analyzed by gas chromatography-mass spectrometry (GC-MS). Detection limits of POPs were in the concentration range of 0.6-1.2 ng/g in rat hair. Aldrin, dieldrin, p,p-DDT and mirex were dosed rat for 4 weeks at concentration of 0.01 mg/L in drinking water and detected in rat hair at concentration of 2.8, 11.3, 7.9 and 15.6 ng/g, respectively. Aldrin and p,p-DDT were metabolized to dieldrin and p,p-DDE, which were detected in concentration of 9.7 and 2.9 ng/g in rat hair, respectively. The developed method may be valuable to be used to analyze POPs in human hair.

• 한국표면공학회지
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• 제29권5호
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• pp.549-555
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• 1996

Diamond Like Carbon film is amorphous film which is considered to consist of three coordinate graphite structure and tetrahedron coordinate diamond structure. Its hardness, thermal conductivity and chemical stability are nearly to one of diamond. It is well known to become semi-conductor by doping of inpurity. In this study Diamond Like Carbon film was synthesized by Microwave Plasma CVD in the gas mixture of hydrogen-methan-nitrogen and doped of nitrogen on the single-crystal silicon or silica glass. The temperature of substrate and nitrogen concentration in the gas mixture had an effect on the bonding state, structural properties and conduction mechanism. The surface morphology was observed by Scanning Electron Microscope. The strucure was analyzed by laser Raman spectrometry. The bonding state was evaluated by electron spectroscopy. Diamond Like Carbon film synthesized was amorphous carbon containing the $sp^2$ and $sp^3$ carbon cluster. The number of $sp^2$ bonding increased as nitrogen concentration increased from 0 to 40 vol% in the feed gas at 1233K substrate temperature and at $7.4\times10^3$ Pa. Increase of nitrogen concentration made Diamond Like Carbon to be amorphous and the doze of nitragen could be controlled by nitrogen concentration of feed gas.

• 한국기후변화학회지
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• 제9권1호
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• pp.59-67
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• 2018

In this study, the $N_2O$, emitted from combustion facility, were analyzed by using simulated gas and field samples to find out how long samples can be stored in Tedlar bag. According to the results of the experiment using simulated gases (1 ppm, 5 ppm, 10 ppm) in Tedlar bag, After 144hr, $N_2O$ concentration of simulated gases changed that 1 ppm is 5.3%, 5 ppm is 12.8%, and 10ppm is 10.5%. The higher initial concentration of simulated gas was, the larger rate of $N_2O$ concentration was changed. In case of high concentration samples, it need to be careful when it was analyzed after 144 hr. Stability evaluation in Tedlar bag was carried out through field samples such as combustion facility of bituminous coal, B-C oil and LNG. The concentration rate of field samples, which is under 1 ppm of average initial concentration, was evaluated using statistical method. As a result, $N_2O$ concentrations were changed to field samples in the bag even when 96 hr had passed. And after sampling, it is necessary that sample analysis should be quickly as soon as possible.

• 한국연소학회:학술대회논문집
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• 한국연소학회 제26회 KOSCO SYMPOSIUM 논문집
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• pp.231-239
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• 2003

In this study, the waste of landfill was treated using advanced enriched oxygen combustion system. The oxygen concentration of this study was 21%, 25%, 30% and 40% and the operating capacity was 200 g/min and the residence time was 10 minutes. As increased the oxygen concentration of combustion air. temperature of the incinerator was increased and the temperature was increased rapidly when the oxygen concentration was 30%. As increased the oxygen concentration, the NOx (ppm) of flue gas increase d for thermal NOx, however the CO (ppm) of flue gas decreased according to the increase of combustion efficiency . The optimum operation condition of incineration was obtained when the oxygen concentration is 30%${\sim}$40%. The unburned carbon of ash decreased from 10% to 4% when the oxygen concentration was increased from 21% to 30%, therefore the high combustion efficiency can be obtained if used the oxygen enriched combustion system.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2010년도 춘계학술대회 초록집
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• pp.244.1-244.1
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• 2010

Bio energy development by using Low Calorific Gas Turbine(LCGT) has been developed for New & Renewable energy source for next generation power system, low fuel and operating cost method by using the renewable energy source in landfill gas (LFG), Food Waste, water waste and Livestock biogas. Low calorific fuel purification by pretreatment system and carbon dioxide fixation by green house system are very important design target for evaluate optimum applications for bio energy. Main problems and accidents of Low Calorific Gas Turbine system was derived from bio fuel condition such as hydro sulfide concentration, siloxane level, moisture concentration and so on. Even if the quality of the bio fuel is not better than natural gas, LCGT system has the various fuel range and environmental friendly power system. The mechanical characterisitics of LCGT system is a high total efficiency (>70%), wide range of output power (30kW - 30MW class) and very clean emmission from power system (low NOx). Also, we can use co-generation system. A green house designed for four different carbon dioxide concentration from ambient air to 2000 ppm by utilizing the exhaust gas and hot water from LCGT system. We look forward to contribute the policy for Renewable Portfolio Standards(RPS) by using LCGT power system.

• 한국가스학회지
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• 제20권5호
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• pp.34-39
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• 2016

디젤자동차용 소형브라운가스 생성 장치의 개발을 위하여 전극 셀의 재료로서 SuS와 Ni 및 Ag기반 셀을 제조하고 셀의 면적과 전해질의 농도 및 전류의 세기를 변화시켜 브라운가스 생성특성을 실험적으로 분석하였다. 전기분해 반응기는 셀의 표면적 및 전극 -극과 +극 배치를 다르게 하여 SMT30, SMT50, SMT50-1, SMT70, SMT90로 제조하였다. 이 때 각 반응기의 따른 브라운가스 생성특성은 셀의 접촉 면적이 클수록 생성특성이 증가하는 경향을 보였으며 전극배치의 경우는 같은 전극면적에서도 극의 배치 따라 차이가 있는 것을 보였다. 또한 전해질의 농도에 대한 영향은 NaOH를 1~3‰로 변화시켰을 때 농도가 적을수록 생성특성이 증가하였고, 전류의 세기의 따른 생성특성은 SMT30, SMT50, SMT50-1, SMT70, SMT90에서 각각 $0.74{\ell}/10min$, $1.0{\ell}/10min$, $1.10{\ell}/10min$, $0.97{\ell}/10min$, $1.13{\ell}/10min$가 얻어졌다.