• Title/Summary/Keyword: Gas analyzer

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Correlation Between Total Mercury and Methyl Mercury-In Whole Blood of South Korean

  • Jung, Seon A;Chung, Dayoung;On, Jiwon;Moon, Myeong Hee;Lee, Jeongae;Pyo, Heesoo
    • Bulletin of the Korean Chemical Society
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    • v.34 no.4
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    • pp.1101-1107
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    • 2013
  • In this study, total mercury and methyl mercury in whole blood of Korean was analyzed so as to investigate the correlation between total mercury (T-Hg) and methyl mercury (Me-Hg). 4000 whole blood samples were divided in four groups, according to T-Hg concentration in percentile: group I (p25-p50), group II (p50-p75), group III (p75-p95) and group IV (p95-p100). 100 samples were randomly selected from the each group, and Me-Hg concentration was measured. T-Hg concentration in whole blood was analyzed using a Direct Mercury Analyzer-80 and obtained limit of detection (LOD) was $0.2{\mu}gL^{-1}$. Me-Hg concentration was analyzed with ethylate derivatization using headspace-gas chromatography-mass spectrometry, and obtained LOD of methyl mercury was $0.5{\mu}gL^{-1}$. The geometric means of T-Hg and Me-Hg were $6.35{\mu}gL^{-1}$ and $4.44{\mu}gL^{-1}$, respectively, and 71.91% of T-Hg was presented as Me-Hg.

Combustion Kinetics of Pulverized Indian Coal-Char in Different CO2-O2 Mixture Isothermally (여러 CO2-O2 혼합기체에서 인도산 분말숯의 등온 연소반응)

  • Saravanan, V.;Shivakumar, R.;babu, P. Niruguna;Ramakrishna
    • Journal of the Korean Chemical Society
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    • v.53 no.6
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    • pp.635-639
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    • 2009
  • Experimental work was carried out to study the combustion kinetics of the Indian coal-char in the varying mixture of carbon dioxide-oxygen ($CO_2-O_2$). The coal sample was pulverized and sieved to less than 58 microns and charred using volatile furnace by passing the nitrogen gas. The experiments were carried out using the Thermo Gravimetric Analyzer (TGA-50) at CPRI, Bangalore, different proportions of ($CO_2-O_2$) gas was allowed in to the TGA-50 (80-20, 60-40, 40-60, 20-80) mole basis were used to study the combustion kinetics of coal Isothermally, kinetic parameters like Activation energy (E) and the pre-exponential factors (A) are calculated using the unification approach and modified Arrhenius equation.

A Study on Combustion Characteristics and Flow Analysis of a Lean Premixed Flame in Lab-Scale Gas Turbine Combustor (모형 가스터빈 연소기에서 희박 예혼합 화염의 연소 특성 및 유동 해석에 관한 연구)

  • Ryu, Hye-Yeon;Kim, Gyu-Bo;Jeon, Chung-Hwan;Chang, Young-June
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.32 no.8
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    • pp.574-581
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    • 2008
  • The characteristics of combustion and flow for a lean premixed flame in lab-scale gas turbine combustor was studied through experiment and numerical analysis. From the experiment, flame structure and heat release rate were obtained from OH emission spectroscopy. Qualitative comparisons were made line-integrated OH chemiluminescence image and abel-transformed one. NOx analyzer was implemented to get the characteristic of NOx exhaust from the combustor. From the numerical analysis, the thermal distribution and characteristic of recirculation zone with the change of fuel-air mixing degree, the characteristic of methane distribution with equivalence ratio in the combustor respectively. Total heat release rate is increased with increasing equivalence ratio. Thermal Nox is reduced with increasing fuel-air mixing degree. Increasing equivalence ratio results in the decrease of the size of reaction zone and alteration of the position of the reaction zone into the entrance of the combustor.

SPRAY AND COMBUSTION CHARACTERISTICS OF HYDROCARBON FUEL INJECTED FROM PRESSURE-SWIRL NOZZLES

  • Laryea Gabriel Nii;No Soo-Young
    • Journal of ILASS-Korea
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    • v.9 no.4
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    • pp.31-37
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    • 2004
  • This paper presents spray and combustion characteristics of hydrocarbon fuel injected from pressure-swirl nozzles. Three commercial nozzles with orifice diameters of 0.256, 0.308 and 0.333mm and injection pressures ranging from 0.7 to 1.3 MPa were selected f9r the experiments. Spray characteristics such as breakup length. spray angle and drop size (SMD) were analyzed using photo image analyses and Malvern Panicle Size Analyzer. The drop size was measured with and without a blower at the same measuring locations. The flame length and width were measured using photo image analyses. The temperature distribution along the axial distance and the gas emission such as CO, $CO_2\;and\;NO_x$ were studied. The breakup length decreased with an increase in injection pressure for each nozzle but increased with an increase in nozzle orifice diameter. The spray angle increased and SMD decreased with an increase in injection pressure. The flame with an increased linearly with an increase in injection pressure and in nozzle orifice diameter. The flame temperature increased with an increase in injection pressure but decreased along the axial distance. The maximum temperatures occurred closer to the burner exit and flame at axial distance of 242mm from the diffuser tip. The experimental results showed that the level of CO decreased while that of $CO_2\;and\;NO_x$ increased with an increase in injection pressure and nozzle orifice diameter.

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Evaluation of Removal Efficiency of Water Contents using Inertial Impaction Separator (관성 충돌 방식의 액적 분리장치의 수분제거효율 평가)

  • Lee, Sin Young;Hong, Won Seok;Shin, Wanho;Kim, Gyujin;Song, Dong Keun
    • Particle and aerosol research
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    • v.9 no.1
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    • pp.23-29
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    • 2013
  • Inertial impaction type mist eliminators are the most effective instruments to separate mist from the gas. In this work, the effect of the horizontal chevron type mist eliminators is characterized experimentally. Droplet size distribution and evaluation of removal efficiency of the chevron type mist eliminators at different gas flows were investigated using an aerosol particle size analyzer and a portable aerosol spectrometer, respectively. The experimental investigations showed that the mist removal efficiency in these instruments is dependent in the droplet size, and the pressure drop is nil.

Magnetic Field Distribution Characteristics of Ring-Shaped Electrodeless Fluorescent Lamp (둥근형 무전극 형광램프의 자계 분포 특성)

  • Choi, Yong-Sung;Cho, Jae-Cheol;Lee, Kyung-Sup
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.12a
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    • pp.53-57
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    • 2006
  • In this paper, maxwell 3D finite element analysis program (Ansoft) was used to obtain electromagnetic properties associated with the coil and nearby structures. The electromagnetic emitting properties were presented by 3D simulation software operated at 250 kHz and some specific conditions. The electromagnetic field in the ferrite core was shown to be high and symmetric. An LS-100 luminance meter and a Darsa-2000 spectrum analyzer were used in the experiment. According to data on the lamp tested using high magnetic field ferrite, the optical and thermal wave fields were shown to be high around the ring-shaped electrodeless fluorescent lamp. The optical or light field was high at the center of the bulb rather than around the ferrite core. The light conditions of the bulb were assumed to be complex, depending on the condition of the filler gas, the volume of the bulb, and the frequency of the inverter. Our results have shown coupling between the gas plasma and the field of the light emitted to be nonlinear.

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A study for development of Barrier coupler-type UHF sensor for Partial Discharge measurement in GIS(Gas Insulated Switchgear) (Gas Insulated Switchgear(GIS) 내부 부분방전 측정을 위한 Barrier coupler-type UHF센서 개발에 관한 연구)

  • Hwang, Chul-Min;Koo, Ja-Yoon;Lee, Young-Sang;Yoon, Jin-Yul
    • Proceedings of the KIEE Conference
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    • 2003.07c
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    • pp.1897-1899
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    • 2003
  • 본 논문에서는 Barrier coupler type UHF 센서의 현장적용 및 감도개선을 위해 외부잡음의 차폐방법과 광대역 안테나를 Barrier coupler type UHF센서에 적용시켜 센서의 성능을 개선시켰다. GIS 내부에서 발생하는 부분방전 신호를 검출하기 위하여 UHF대역(0.3${\sim}$3GHz)의 전자파 신호의 검출이 가능한 광대역 Rectangular 패치 안테나를 barrier coupler type UHF 센서에 적응 설계하였으며, Rectangular patch antenna를 배열(array) 했을 때의 특성들을 비교하였다. 이론 위해 상용화된 EM Simulator를 이용하여 센서의 방향성과 감도 특성을 검토하여 설계 및 제작하였다. 개발된 센서의 실제 특성을 분석하기 위해서 network analyzer로 센서의 특성을 분석하였고, 실규모의 GIS 챔버를 사용하여 다양한 결함에 대한 센서의 감도와 특성을 평가하였다. 본 연구의 결과로서 제작된 barrier coupler type UHF센서가 가스절연기기(GIS)의 부 부방전 신호를 검출할수 있음을 입증하였고, 광대역 외장형센서의 경우 patch antenna의 구조에 크게 상관하지 않음을 알 수 있었다. 향후에는 GIS 내장형 센서와 비교 연구론 통해 barrier coupler type 센서의 성능을 개선하고자 한다.

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The development of ultra-high frequency ultra-wide bandwidth sensor for Partial Discharge monitoring in Gas Insulated Switchgears (GIS 부분방전 검출용 극초단파 초광대역 센서 개발)

  • Kim, Young-Ro;Choi, Jae-Ok;Lee, Young-Sang;Kang, Chang-Won;Park, Ki-Jun;Goo, Sun-Geun;Yoon, Jin-Yul
    • Proceedings of the KIEE Conference
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    • 2004.05b
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    • pp.113-116
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    • 2004
  • We developed internal and external type sensor to measure ultra-high frequency (UHF) partial discharge (PD) in 170 kV gas-insulated switchgears (GIS). We also manufactured a PD-generator to verify and measure the detection sensitivity of those sensors. We measured the output power of the UHF PD sensors induced by PDs of 5 pC using the PD-generator. We measured UHF propagation loss of an 170 kV GIS for optimal arrangement of the sensors. We used swept UHF signal from a network analyzer into the GIS to measure the loss of various components of the GIS.

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A Study on the Emission Characteristics of Syngas(H2/CO)-Air Premixed Flame according to the H2 contents (수소 함유량에 따른 합성가스(H2/CO)-공기 예혼합 화염의 배출특성 연구)

  • Jeong, Byeong;Choi, Jongmin;Lee, Keeman
    • 한국연소학회:학술대회논문집
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    • 2013.06a
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    • pp.9-10
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    • 2013
  • This study reports the results of an experimental investigation of emission and temperatures from the syngas-air premixed flame with a various mixture composition in the region of large equivalence ratios. The effects of hydrogen contents and equivalence ratios on the flame velocity, which reported before, and emission of syngas fuel are examined. In this study, representative syngas mixture compositions ($H_2:CO$) such as $H_2:CO=10:90$, 25:75, 50:50 and 75:25 and equivalence ratios from 0.5 to 5.0 have been conducted. The emissions of syngas fuel were measured by the high precision analyzer with enclosure configuration and the adiabatic temperatures are calculated by used Chemkin basis. The NOx emission level is coincided relatively well with the adiabatic temperature distributions in lean mixture conditions, but for rich mixture conditions NOx level was also increased again even though the adiabatic temperature decreases. Such an increasing characteristics in rich mixture conditions is coincided well with the tendency that rather the flue gas temperature increases.

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Analysis of On-Line Partial Discharge in Air-Coolded Gas Turbine Generator (공랭식 가스터빈 발전기의 운전중 부분방전 분석)

  • Lee, Eun-Chun;Kong, Tae-Sik;Kim, Jae-Chul;Kim, Hee-Dong
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.28 no.7
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    • pp.41-47
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    • 2014
  • The on-line partial discharge (PD) in stator windings of air-cooled gas turbine (GT) generator (119.2MVA, 13.8kV) is measured and analyzed in this paper. This generator was designed by global vacuum pressure impregnation (VPI). The generator failed two times at top bar (16T) of phase B in the stator slot. Six epoxy-mica capacitors were installed in three phases of GT generator. On-line PD test was performed on GT generator using turbine generator analyzer (TGA). TGA showed that the normalized quantity number (NQN) and the PD magnitude($Q_m$) were high in phase B. Internal discharges were generated in phases A, B and C. The trend analysis of NQN and $Q_m$ value are obtained in order to monitor the insulation condition in GT generator stator windings. Phases A and C were in good condition. But phase B had deteriorated significantly