• Title/Summary/Keyword: Gas Transport

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Prediction of the Tritium Behavior in Very High Temperature Gas Cooled Reactor Using TRITGO (TRITGO 코드를 이용한 초고온가스로 (VHTR) 삼중 수소 거동 예측)

  • Park, Jong-Hwa;Park, Ik-Kyu;Lee, Won-Jae
    • Journal of Radiation Protection and Research
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    • v.33 no.3
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    • pp.113-120
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    • 2008
  • In this study, The TRITGO code was introduced, which can predict the amount of tritium production, it's transport, removal, distribution and the level of contamination for the produced hydrogen by the tritium on the VHTR (very high temperature gas cooled reactor). The TRITGO code was improved so that the permeation to the IS Iodine Sulfide) loop for producing the hydrogen can be simulated. The contamination level of the produced hydrogen by the tritium was predicted by the improved code for the VHTR with 600MW thermal power. The contamination level for the produced hydrogen by tritium was predicted as 0.055 Bq/$H_2-g$. This level is three order of lower than the regulation value of 56 Bq/$H_2-g$ from Japan. From this study, the following results were obtained. it is important that the fuel coating (SiC layer) should be kept intact to prevent the tritium from releasing. Also it is necessary that the level of impurity such as 3He and Li in the helium coolant and the reflector consisting of the graphite should be kept as low as possible. It was found that the capacity of the purification system for filtering the impurities directly from the coolant will be the important design parameter.

Study on Torrefaction Characteristics of Solid Biomass Fuel and Its Combustion Behavior (바이오매스 고형연료의 반탄화 특성 및 반탄화물의 연소특성에 관한 연구)

  • Lee, Weon Joon
    • Journal of the Korea Organic Resources Recycling Association
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    • v.23 no.4
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    • pp.86-94
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    • 2015
  • Torrefaction is a thermochemical process proceeded at the temperature around $250^{\circ}C$ in an inert gas condition. By torrefaction, the hemicellulose portions contained in biomass are broken down to change into the volatile gas which is removed from biomass eventually. The main purpose of biomass torrefaction is to improve the energy density of the biomass to minimize the transport energy consumption, though the flammability can be elevated for transportation. In this study two types of solid biomass fuel, waste wood and rice straw, were torrefied at various temperature range from $200^{\circ}C$ to $300^{\circ}C$ to evaluate the torrefied biomass characteristics. In addition torrefied biomass were tested to evaluate the combustion characteristics using TGA (Thermogravimetric Analysis). After the torrefaction of biomass, the C/H (carbon to hydrogen ratio) and C/O (carbon to oxygen ratio) were measured for aquisition of bio-stability as well as combustion pattern. Generally C/H ratio implies the soot formation during combustion, and the C/O ratio for bio-stability. By torrefaction temperature at $300^{\circ}C$, C/H ratio and C/O ratio were increased by two times for C/H and three times for C/O. The torrefied biomass showed similar TGA pattern to coal compared to pure biomass; that is, less mass decrease at lower temperature range for torrefied biomass than the pure biomass.

Factors influencing arterial $CO_2$ tension in cats during high frequency oscillation ventilation (고빈도 진동 환기가 동맥혈의 호흡성 가스에 미치는 영향)

  • Do, Jun-Young;Lee, Jae-Yick;Lee, Kwan-Ho;Kim, Yeung-Jo;Chung, Jae-Chun;Lee, Hyun-Woo;Lee, Suck-Kang
    • Journal of Yeungnam Medical Science
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    • v.6 no.2
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    • pp.47-55
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    • 1989
  • High frequency ventilation (HFV) is a new ventilatory technique that uses very small tidal volume(less than the anatomic dead space) and high frequency, and classified 4 distinct types according to frequency and mode of gas delivery. The mechanism of gas transport of high frequency oscillation ventilation(HFOV) is somewhat different to other types of HFV. To evaluate the determinants of $PaCO_2$ in HFOV, a study was done with a HFOV on 9 cats, and the results are : 1) $PaCO_2$ was not correlated with frequency at the constant stroke volume(6 voltage) and bias flow (6L/minutes). 2) $PaCO_2$ was correlated with stroke volume but not with bias flow under the constant frequency(15Hz/min) and bias flow(3 to 6L/min). From above results, the main determinant of $PaCO_2$ on artificial ventilation with HFOV was stroke volume, but further study between flow, the site of delivery to the airway and humidification of bias flow and $CO_2$ elimination is required in future research.

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A study on appropriate ship power system for pulse load combine with secondary battery (펄스부하에 적합한 이차전지 연동형 선박 전력시스템에 관한 연구)

  • Oh, Jin-Seok;Lee, Hun-Seok
    • Journal of Advanced Marine Engineering and Technology
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    • v.37 no.8
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    • pp.962-968
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    • 2013
  • Problem of greenhouse gases associated with global warming and the world rise in fuel oil prices due to the depletion of fossil fuel has attracted attention. For this reason, maritime transport business, has shown interest in green-ship technology to reduce the consumption of fuel and reduce greenhouse gas for environmental protection. Power system of the ship is one of the most important factors for safe operation. Therefore, at design of ship power system, most of existing vessel used comparative large capacity generator in order to respond peak load such as bow thruster, crane and etc. In the navigation of ship, marine generators most would be operated at low load operation. In the low load operation of the generation rate of 50% or less, the operation efficiency of the generator it deteriorated, to consume more fuel oil. It also, it means that adversely effect the life of the generator. In this paper, studied how to apply for a secondary battery in container ship that relatively frequent arrival and departure in port. As a result, in order to apply the secondary battery to increase the operating efficiency of the generator during the voyage, it was confirmed that it is possible to reduce fuel consumption.

Numerical Study of Evaporation and Ignition of in-line Array Liquid Droplets (액적 배열의 증발과 착화에 관한 수치해석적 연구)

  • 김충익;송기훈
    • Fire Science and Engineering
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    • v.13 no.1
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    • pp.37-47
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    • 1999
  • The spreading fire of very small floating particles after they are ignited is fast and t therefore dangerous. The research on this area has been limited to experiments and global simulations which treat them as dusts or gaseous fuel with certain concentration well m mixed with air. This research attempted micro-scale analysis of ignition of those particles modeling them as liquid droplets. For the beginning, the in-line array of fuel droplets is modeled by two-dimensional, unsteady conservation equations for mass, momentum, energy and species transport in the gas phase and an unsteady energy equation in the liquid phase. They are solved numerically in a generalized non-orthogonal coordinate. The single step chemical reaction with reaction rate controlled by Arrhenius’ law is assumed to a assess chemical reaction numerically. The calculated results show the variation of temperature and the concentration profile with time during evaporation and ignition process. Surrounding oxygen starts to mix with evaporating fuel vapor from the droplet. When the ignition condition is met, the exothermic reactions of the premixed gas initiate a and burn intensely. The maximum temperature position gradually approaches the droplet surface and maximum temperature increases rapidly following the ignition. The fuel and oxygen concentration distributions have minimum points near the peak temperature position. Therefore the moment of ignition seems to have a premixed-flame aspect. After this very short transient period minimum points are observed in the oxygen and fuel d distributions and the diffusion flame is established. The distance between droplets is an important parameter. Starting from far-away apart, when the distance between droplets decreases, the ignition-delay time decreases meaning faster ignition. When they are close and after the ignition, the maximum temperature moves away from the center line of the in-line array. It means that the oxygen at the center line is consumed rapidly and further supply is blocked by the flame. The study helped the understanding of the ignition of d droplet array and opened the possibility of further research.

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Controlling the Properties of Graphene using CVD Method: Pristine and N-doped Graphene (화학기상증착법을 이용한 그래핀의 물성 조절: 그래핀과 질소-도핑된 그래핀)

  • Park, Sang Jun;Lee, Imbok;Bae, Dong Jae;Nam, Jungtae;Park, Byung Jun;Han, Young Hee;Kim, Keun Soo
    • KEPCO Journal on Electric Power and Energy
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    • v.1 no.1
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    • pp.169-174
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    • 2015
  • In this research, pristine graphene was synthesized using methane ($CH_4$) gas, and N-doped graphene was synthesized using pyridine ($C_5H_5N$) liquid source by chemical vapor deposition (CVD) method. Basic optical properties of both pristine and N-doped graphene were investigated by Raman spectroscopy and XPS (X-ray photoemission spectroscopy), and electrical transport characteristics were estimated by current-voltage response of graphene channel as a function of gate voltages. Results for CVD grown pristine graphene from methane gas show that G-peak, 2D-peak and C1s-peak in Raman spectra and XPS. Charge neutral point (CNP; Dirac-point) appeared at about +4 V gate bias in electrical characterization. In the case of pyridine based CVD grown N-doped graphene, D-peak, G-peak, weak 2D-peak were observed in Raman spectra and C1s-peak and slight N1s-peak in XPS. CNP appeared at -96 V gate bias in electrical characterization. These result show successful control of the property of graphene artificially synthesized by CVD method.

Development of Novel Materials for Reduction of Greenhouse Gases and Environmental Monitoring Through Interface Engineering

  • Hirano, Shin-Ichi;Gang, Seok-Jung L.;Nowotny, Janusz-Nowotny;Smart, Roger-St.C.Smart;Scrrell, Charles-C.Sorrell;Sugihara, Sunao;Taniguchi, Tomihiroi;Yamawaki, Michio;Yoo
    • Korean Journal of Materials Research
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    • v.9 no.6
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    • pp.635-653
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    • 1999
  • The present work considers work considers research strategies to address global warming. Specifically, this work considers the development of technologies of importance for the reduction of greenhouse gas emission and, especially, the materials that are critical to these technologies. It is argued that novel materials that are essential for the production of environmentally friendly energy may be developed through a special kind of engineering: interface engineering, rather than through classical bulk chemistry. Progress on the interface engineering requires to increase the present state of understanding on the local properties of materials interfaces and interfaces processes. This, consequently, requires coordinated international efforts in order to establish a strong background in the science of materials interfaces. This paper considers the impact of interfaces, such as surfaces and grain boundaries, on the functional properties of materials. This work provides evidence that interfaces exhibit outstanding properties that are not displayed by the bulk phase. It is shown that the local interface chemistry and structure and entirely different than those of the bulk phase. In consequence the transport of both charge and matter along and across interfaces, that is so important for energy conversion, is different than that in the bulk. Despite that the thickness of interfaces is of an order to a nanometer, their impact on materials properties is substantial and, in many cases, controlling. This leads to the conclusion that the development of novel materials with desired properties for specific industrial applications will be possible through controlled interface chemistry. Specifically, this will concern materials of importance for energy conversion and environmental monitoring. Therefore, there is a need to increase the present state of understanding of the local properties of materials interfaces and the relationship between interfaces and the functional properties of materials. In order to accomplish this task coordinated international efforts of specialized research centres are required. These efforts are specifically urgent regarding the development of materials of importance for the reduction of greenhouse gases. Success of research in this area depends critically on financial support that can be provided for projects on materials of importance for a sustainable environment, and these must be considered priorities for all of the global economies. The authors of the present work represent an international research group economies. The authors of the present work represent an international research group that has entered into a collaboration on the development of the materials that are critical for the reduction of greenhouse gas emissions.

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Growth of Tin Dioxide Nanostructures on Chemically Synthesized Graphene Nanosheets (화학적으로 합성된 그래핀 나노시트 위에서의 이산화주석 나노구조물의 성장)

  • Kim, Jong-IL;Kim, Ki-Chul
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.20 no.5
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    • pp.81-86
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    • 2019
  • Metal oxide/graphene composites have been known as promising functional materials for advanced applications such as high sensitivity gas sensor, and high capacitive secondary battery. In this study, tin dioxide ($SnO_2$) nanostructures were grown on chemically synthesized graphene nanosheets using a two-zone horizontal furnace system. The large area graphene nanosheets were synthesized on Cu foil by thermal chemical vapor deposition system with the methane and hydrogen gas. Chemically synthesized graphene nanosheets were transferred on cleaned $SiO_2$(300 nm)/Si substrate using the PMMA. The $SnO_2$ nanostuctures were grown on graphene nanosheets at $424^{\circ}C$ under 3.1 Torr for 3 hours. Raman spectroscopy was used to estimate the quality of as-synthesized graphene nanosheets and to confirm the phase of as-grown $SnO_2$ nanostructures. The surface morphology of as-grown $SnO_2$ nanostructures on graphene nanosheets was characterized by field-emission scanning electron microscopy (FE-SEM). As the results, the synthesized graphene nanosheets are bi-layers graphene nanosheets, and as-grown tin oxide nanostructures exhibit tin dioxide phase. The morphology of $SnO_2$ nanostructures on graphene nanosheets exhibits complex nanostructures, whereas the surface morphology of $SnO_2$ nanostructures on $SiO_2$(300 nm)/Si substrate exhibits simply nano-dots. The complex nanostructures of $SnO_2$ on graphene nanosheets are attributed to functional groups on graphene surface.

Applicability Assessment of Epoxy Resin Reinforced Glass Fiber Composites Through Mechanical Properties in Cryogenic Environment for LNG CCS (에폭시 수지가 적용된 유리섬유 복합재료의 극저온 환경 기계적 특성 분석을 통한 LNG CCS 적용성 평가)

  • Yeom, Dong-Ju;Bang, Seoung-Gil;Jeong, Yeon-Jae;Kim, Hee-Tae;Park, Seong-Bo;Kim, Yong-Tai;Oh, Hoon-Gyu;Lee, Jae-Myung
    • Journal of the Society of Naval Architects of Korea
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    • v.58 no.4
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    • pp.262-270
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    • 2021
  • Consumption of Liquefied Natural Gas (LNG) has increased due to environmental pollution; therefore, the need for LNG carriers can efficiently transport large quantities of LNG, is increased. In various types of LNG Cargo Containment System (CCS), Membrane-type MARK-III composed of composite materials is generally employed in the construction of an LNG carrier. Among composite materials in a Mark-III system, glass-fiber composites act as a secondary barrier to prevent the inner hull structure from leakage of LNG when the primary barrier is damaged. Nevertheless, several cases of damage to the secondary barriers have been reported and if damage occurs, LNG can flow into the inner hull structure, causing a brittle fracture. To prevent those problems, this study conducted the applicability assessment of composite material manufactured by bonding glass-fiber and aluminum with epoxy resin and increasing layer from three-ply (triplex) to five-ply (pentaplex). Tensile tests were performed in five temperature points (25, -20, -70, -120, and -170℃) considering temperature gradient in CCS. Scanning Electron Microscopy (SEM) and Coefficient of Thermal Expansion (CTE) analyses were carried out to evaluate the microstructure and thermos-mechanical properties of the pentaplex. The results showed epoxy resin and increasing layer number contributed to improving the mechanical properties over the whole temperature range.

Development of an Economic Material Selection Model for G-SEED Certification (녹색건축(G-SEED) 인증을 위한 경제적 자재선정 모델 개발)

  • Jeon, Byung-Ju;Kim, Byung-Soo
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.40 no.6
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    • pp.613-622
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    • 2020
  • The South Korean government plans for a 37 % reduction in CO2 emissions against business as usual by 2030. Subsequently, the Ministry of Land, Infrastructure and Transport declared a 26.9 % reduction target in greenhouse gas emissions from buildings by 2020 and established the Green Standard for Energy and Environmental Design (G-SEED) to help improve the environmental performance of buildings. Construction companies often work with consulting firms to prepare for G-SEED certification. In the process, owing to inefficient data sharing and work connections, it is difficult to achieve economic efficiency and obtain certification. The objective of this study was to develop an economic model to assist contractors in achieving the required G-SEED scores for materials and resources. To do this, we automated the process for material comparison and selection on the basis of an analysis of actual consulting data, and developed a model that selects material alternatives that can meet the required scores at a minimum cost. Information on materials is input by applying a genetic algorithm to the optimization of alternatives. When the model was applied to actual data, the construction cost could be lowered by 79.3 % compared with existing methods. The economical material selection model is expected to not only reduce construction costs for owners desiring G-SEED certification but also shorten the project design time.