• 제목/요약/키워드: Gas Transport

검색결과 863건 처리시간 0.099초

MCS-BEq 알고리즘에 의한 $SF_6-Ar$ 혼합기체의 확산계수 (Diffusion Coefficients in $SF_6-Ar$ Gas used by MCS-BE Algorithm)

  • 김상남
    • 한국조명전기설비학회:학술대회논문집
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    • 한국조명전기설비학회 2006년도 춘계학술대회 논문집
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    • pp.298-301
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    • 2006
  • This paper describes the electron energy distribution function characteristics in $SF_6-Ar$ gas calculated for range of E/N values from $50\sim700[Td]$ by the Monte Carlo simulation(MCS) and Boltzmann equation(BE) method using a set of electron collision cross sections determined by the authors and the values of electron swarm parameters are obtained by time of flight(TOF) method. In this dissertation the results of the combined experimental and theoretical studies designed to understand and predict the spatial growth and transport coefficients for electrons in $SF_6$ and $SF_6-Ar$ mixtures have described. The ionization and attachment coefficients in pure $SF_6$ and $SF_6-Ar$ mixtures have been calculated over the range of 10$SF_6$ molecule and for Ar atom proposed by other authors. The results obtained in this work will provide valuable information on the fundamental behaviors of electrons in weakly ionized gases and the role of electron attachment in the choice of better gases and unitary gas dielectrics or electro negative components in dielectric gas mixtures.

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열처리 슬러리코팅법을 이용한 연료전지 가스확산층의 제조 (Fabrication of Gas Diffusion Layer for Fuel Cells Using Heat treatment Slurry Coating Method)

  • 김성진;박성범;박용일
    • 열처리공학회지
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    • 제25권2호
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    • pp.65-73
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    • 2012
  • The Gas Diffusion Layer (GDL) of fuel cell, are required to provide both delivery of reactant gases to the catalyst layer and removal of water in either vapor or liquid form in typical PEMFCs. In this study, the fabrication of GDL containing Micro Porous Layer (MPL) made of the slurry of PVDF mixed with carbon black is investigated in detail. Physical properties of GDL containing MPL, such as electrical resistance, gas permeability and microstructure were examined, and the performance of the cell using developed GDL with MPL was evaluated. The results show that MPL with PVDF binder demonstrated uniformly distributed microstructure without large cracks and pores, which resulted in better electrical conductivity. The fuel cell performance test demonstrates that the developed GDL with MPL has a great potential due to enhanced mass transport property due to its porous structure and small pore size.

다항근사 및 2항근사 볼츠만 방정식을 이용한 $CF_4+Ar$ 혼합기체의 전자이동속도 연구 (The study of electron drift velocity in $CF_4+Ar$ molecular gas mixture by 2-term and multi-term approximation of the Boltzmann equation)

  • 송병두;하성철;전병훈
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2004년도 하계학술대회 논문집 Vol.5 No.2
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    • pp.1179-1182
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    • 2004
  • This paper describes the information for quantitative simulation of weakly ionized plasma. In previous paper, we calculated the electron transport coefficients in $CF_4+Ar$ gas mixture by using two-term approximation of Boltzmann equation. but there is difference between the result of the two-term and the multi-term approximation of the Boltzmann equation in $CF_4$ gas. Therefore, in this paper, we calculated the electron drift velocity (W) in $CF_4+Ar$ gas mixture for range of E/N values from $0.01\sim500[Td}$ at the temperature was 300[K] and pressure was 1[Torr] by multi-term approximation of the Boltzmann equation by Robson and Ness. The results of two-term and multi-term approximation of the Boltzmann equation has been compared with each other for a range of E/N.

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자동차 배기가스 측정을 위한 매연프로브 효율 개선에 관한 연구 (Improvement of Soot Probe Efficiency for Automotive Emission Measurement)

  • 채일석;김상유;김재열
    • 한국기계가공학회지
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    • 제18권8호
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    • pp.74-81
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    • 2019
  • Cars are inspected in the transport sector for their ability to achieve the greenhouse gas reduction targets. A vehicle (automobile) inspection broadly consists of regular and total checks, and both the safety level and the amount of exhaust gas are checked simultaneously during a vehicle inspection. This study deals with the efficiency of a soot probe to measure soot emissions from diesel vehicles. When the vehicle exhaust gas measurement is performed, there may be a difference between the exhaust gas temperature and the soot suction amount because of the different shape and angle of the exhaust port for each vehicle type. This may result in some incidents where the correct inspection nonconforming vehicle is not selected. Therefore, in this study, the shape of the probe was improved to increase the soot measurement efficiency under the condition of the exhaust pipe angle change.

Influence of thermo-physical properties on solutal convection by physical vapor transport of Hg2Cl2-N2 system: Part I - solutal convection

  • Kim, Geug-Tae;Kim, Young-Joo
    • 한국결정성장학회지
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    • 제20권3호
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    • pp.125-132
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    • 2010
  • For typical governing dimensionless parameters of Ar = 5, Pr = 1.16, Le = 0.14, Pe = 3.57, Cv = 1.02, $Gr_s=2.65{\times}10^6$, the effects of thermo physical properties such as a molecular weight, a binary diffusivity coefficient, a partial pressure of component B on solutally buoyancy-driven convection (solutal Grashof number $Gr_s=2.65{\times}10^6$) are theoretically investigated for further understanding and insight into an essence of solutal convection occurring in the vapor phase during the physical vapor transport of a $Hg_2Cl_2-N_2$ system. The solutally buoyancy-driven convection is significantly affected by any significant disparity in the molecular weight of the crystal components and the impurity gas of nitrogen. The solutal convection in a vertical orientation is found to be more suppressed than a tenth reduction of gravitational accelerations in a horizontal orientation. For crystal growth parameters under consideration, the greater uniformity in the growth rate is obtained for either solutal convection mode in a vertical orientation or thermal convection mode in horizontal geometry. The growth rate is also found to be first order exponentially decayed for $10{\leq}P_B{\leq}200$ Torr.

고분자 전해질 연료전지의 수소극 공급모드에 따른 성능특성 (Performance Characteristics of a Polymer Electrolyte Fuel Cell with the Anodic Supply Mode)

  • 이용택;박차식;허재혁;김용찬
    • 대한기계학회논문집B
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    • 제31권7호
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    • pp.588-595
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    • 2007
  • The water transport inside a polymer electrolyte fuel cell (PEFC) varied according to the anodic supply mode. The performance characteristics of a PEFC which can be affected by the water transport were observed with the anodic supply mode. In the flow-through and recirculation mode the performance showed no reduction with time because the flow in the anode was not stagnated. In the dead-end mode, without any discharged gas, the water remains inside of the anode, which caused the reduction of the performance with the lapse of time. However, even in the dead-end mode, little reduction of the performance with time was shown when only the anode was humidified externally. It means that the back-diffusion was the major factor to the accumulation of water in the anode rather than external humidification.

유로형상 변화에 따른 고분자 전해질 연료전지의 성능 및 전달특성에 대한 3차원 수치해석적 연구 (Three Dimensional Computational Study on Performance and Transport Characteristics of PEMFC by Flow Channel Patterns)

  • 이필형;조선아;최성훈;황상순
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2006년도 추계학술대회
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    • pp.407-410
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    • 2006
  • Selection of flow channel in the separation plate of PEMFC is very important parameter to improve its performance and reduce parasite loss. Flow patterns in the channel have great influence on the transport of hydrogen and all and water generated from electrochemical reaction in diffusion layer In this study, fluid flow in flow channel with parallel and interdigitated patterns are simulated three dimensionally on full flow domain including anode and cathode electrode together. The numerical results show that the fuel cell with interdigitated flow channel represents better performance than that with parallel flow channel due to its strong convective transport across the gas diffusion layer. But the pressure drop in parallel flow channel is much more than that in nterdigitated flow channel. The effect of temperature and stoichiometric number on performance can be calculated and analyzed as well.

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A Case Study of Sediment Transport on the Seabed due to Wave and Current Velocities

  • Choi, Byoung-Yeol;Lee, Sang-Gil;Kim, Jin-Kwang;Oh, Jin-Soo
    • Journal of Advanced Research in Ocean Engineering
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    • 제2권3호
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    • pp.99-111
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    • 2016
  • Seabed affected by scouring, sedimentation, and siltation occurrences often cause exposure, which induces risks to existing structures or crude oil or gas pipeline buried subsea. In order to prevent possible risks, more economical structure installation methodology is proposed in this study by predicting and managing the risk. Also, the seabed does not only consist of sandy material, but clayey soil is also widespread, and the effect of undrained shear strength should be considered, and by cyclic environmental load, pore water pressure will occur in the seabed, which reduces shear strength and allows particles to move easily. Based on previous research regarding sedimentation or erosion, the average value of external environmental loads should be applied; for scouring, a 100-year period of environmental conditions should be applied. Also, sedimentation and erosion are mainly categorized by the bed load and suspended load; also, they are calculated as the sum of bed load and suspended load, which can be obtained from the movement of particles caused by sedimentation or erosion.

유로형상 변화에 따른 고분자 전해질 연료전지(PEMFC)의 성능 및 전달특성에 대한 3차원 수치 해석적 연구 (Three Dimensional Computational Study on Performance and Transport Characteristics of PEMFC by Flow Channel Patterns)

  • 이필형;조선아;최성훈;황상순
    • 신재생에너지
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    • 제2권4호
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    • pp.78-85
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    • 2006
  • Selection of flow channel in the separation plate of PEMFC is very important parameter to improve its performance and reduce parasite loss. Flow patterns in the channel have great influence on the transport of hydrogen and air and removal of water generated from electrochemical reaction in diffusion layer. In this study. fluid flow in flow channel with parallel and interdigitated patterns are simulated three dimensionally on full flow domain including anode and cathode channel together. The numerical results show that the fuel cell with interdigitated flow channel represents better performance than that with parallel flow channel due to its strong convective transport across the gas diffusion layer. But the pressure drop in parallel flow channel is much more than that in interdigitated flow channel. And effects of temperature and stoichiometric number on performance can be calculated and analyzed as well. Nomenclature.

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Effects of Polyamidoamine Dendrimers on the Catalytic Layers of a Membrane Electrode Assembly in Fuel Cells

  • Lee Jin Hwa;Won Jongok;Oh In Hwan;Ha Heung Yong;Cho Eun Ae;Kang Yong Soo
    • Macromolecular Research
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    • 제14권1호
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    • pp.101-106
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    • 2006
  • The transport of reactant gas, electrons and protons at the three phase interfaces in the catalytic layers of membrane electrode assemblies (MEAs) in proton exchange, membrane fuel cells (PEMFCs) must be optimized to provide efficient transport to and from the electrochemical reactions in the solid polymer electrolyte. The aim of reducing proton transport loss in the catalytic layer by increasing the volume of the conducting medium can be achieved by filling the voids in the layer with small-sized electrolytes, such as dendrimers. Generation 1.5 and 3.5 polyamidoamine (PAMAM) dendrimer electrolytes are well-controlled, nanometer-sized materials with many peripheral ionic exchange, -COOH groups and were used for this purpose in this study. The electrochemically active surface area of the deposited catalyst material was also investigated using cyclic voltammetry, and by analyzing the Pt-H oxidation peak. The performances of the fuel cells with added PAMAM dendrimers were found to be comparable to that of a fuel cell using MEA, although the Pt utilization was reduced by the adsorption of the dendrimers to the catalytic layer.