• Title/Summary/Keyword: Gas Transport

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Gas-Transport Properties through Various Cations Exchanged Sulfonated Poly(ether imide) Membranes

  • Rhim, Ji-Won
    • Korean Membrane Journal
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    • v.3 no.1
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    • pp.51-58
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    • 2001
  • The surface of Poly(ether imide) (PEI) membranes has been sulfonated using CIS03H. The resulting membranes were characterized through the analysis of ESCA and contact angle measurements The sulfonated PEI membranes were exposed to gases of $O_2$, $N_2$, and $CO_2$ to measure the permeation rates and ideal separation factors. In addition, the diffusivities and solubilities of individual gases were measured. The diffusivity effect is more dominant than the solubility one on gas transports.

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Effect of Oxidation Multi-Walled Carbon Nanotubes for Methane Hydrate Formation (산화탄소나노튜브를 이용한 메탄 하이드레이트 형성)

  • Park, Sung-Seek;Kim, Nam-Jin
    • Journal of the Korean Solar Energy Society
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    • v.30 no.5
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    • pp.11-16
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    • 2010
  • Methane hydrate is crystalline ice-like compounds which formed methane gas enters within water molecules composed cavity and each other from physically-bond at specially temperature and pressure condition. $1m^3$ of methane hydrate can be decomposed into the maximum of $216m^3$ of methane gas under standard condition. If these characteristics of hydrate are utilized in the opposite sense, natural gas can be fixed into water in the form of a hydrate solid. Therefore the use of hydrate is considered to be a great way to transport and store natural gas in large quantity. However, when methane hydrate is formed artificially, the amount of gas that is consumed is relatively low, due to the slow reaction rate between water and methane gas. Therefore for practical purposes in the application, the present investigation focuses on increasing the amount of gas consumed by adding chemically oxidized OMWCNTs to pure water. The results show that when 0.003 wt% of oxidation multi-walled carbon nanotubes was added to pure water, the amount of gas consumed was almost four times more than that of pure water indicating its effect in hydrate formation and the hydrate formation time decreased at alow subcooling temperature.

A Study of Mixed Refrigerant Process Control in Liquefied Natural Gas Process using Dynamic Simulation (동적 모사를 이용한 천연가스 액화 공정에서 혼합냉매 공정 제어 연구)

  • Lee, Jae Yong;Park, Chan-Cook
    • Journal of the Korean Institute of Gas
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    • v.19 no.6
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    • pp.99-104
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    • 2015
  • Today the most efficient way to transport the natural gas is carried via the liquid. In order to liquefy the natural gas to be cooled to $-160^{\circ}C$ or less. Cooling method has a number of different ways. In this paper, we studied control method for the representative liquefaction process, C3MR. Natural gas liquefaction control is a tool that can maintain the quality of natural gas is a means to ensure stable operation. Analyzing the C3MR process, and select the control parameters for the control valve. We find control structure for mixed refrigerant cycle through the step response. A control result obtained through the dynamic simulation arbitrarily given a disturbance was found to maintain a steady-state results.

Distribution and Origin of Quaternary Mass Transport Deposit in the Ulleung Basin, East Sea (동해 울릉분지 제 4기 질량류 퇴적체 분포 및 기원)

  • Yi, Young-Mi;Yoo, Dong-Geun;Kang, Nyeon-Keon;Yi, Bo-Yeon
    • Geophysics and Geophysical Exploration
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    • v.17 no.2
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    • pp.74-87
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    • 2014
  • Analysis of multi-channel seismic reflection profiles collected from the Ulleung Basin reveals that the Quaternary sequence consists of four stratigraphic units separated by erosional unconformities. Individual stratigraphic unit includes eighteen mass transport deposits which are variable in geometric characteristics and spatial distribution. Each mass transport deposit on the seismic profile is acoustically characterized by chaotic or transparent seismic facies, and shows wedge or lens-shaped external geometry. The mass transport deposits, which comprise a succession of stacked wedges, mainly occur on the southern slope, and their thickness gradually decreases toward the basin plain. The time structure map of erosional unconformities shows that a tectonic-induced structural high and troughs toward the northwest and northeast are developed at the central part of the basin. Based on the isochron map, the mass transport deposits, originated from southern part of the study area, transported to the basin plain and can be divided into two groups by the structural high. Consequently, the mass transport deposits within the Quaternary sequence in the Ulleung Basin are largely controlled by the large amounts of sediment supply, dissociation of gas hydrate during the lowstands, and central structural high.

NUMERICAL ANALYSIS OF TRANSPORT PHENOMENA IN POLYMER ELECTROLYTE FUEL CELLS (고체고분자형 연료전지 내의 이동현상에 대한 수치해석)

  • Park, C.G.
    • Journal of computational fluids engineering
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    • v.12 no.1
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    • pp.9-15
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    • 2007
  • A three dimensional numerical model to predict the flow and transport of mixtures and also the electrochemical reactions in polymer electrolyte membrane (PEM) fuel cells is developed. The numerical computation is base on vorticity- velocity method. Governing equations for the flow and transport of mixtures are coupled with the equations for electrochemical reactions and are solved simultaneously including production and condensation of vapor. Fuel cell performance predicted by this calculation is compared with the experimental results and resonable agreements are achieved.

DEVELOPMENT AND VALIDATION OF THE AEROSOL TRANSPORT MODULE GAMMA-FP FOR EVALUATING RADIOACTIVE FISSION PRODUCT SOURCE TERMS IN A VHTR

  • Yoon, Churl;Lim, Hong Sik
    • Nuclear Engineering and Technology
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    • v.46 no.6
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    • pp.825-836
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    • 2014
  • Predicting radioactive fission product (FP) behaviors in the reactor coolant system and the containment of a nuclear power plant (NPP) is one of the major concerns in the field of reactor safety, since the amount of radioactive FP released into the environment during the postulated accident sequences is one of the major regulatory issues. Radioactive FPs circulating in the primary coolant loop and released into the containment are basically in the form of gas or aerosol. In this study, a multi-component and multi-sectional analysis module for aerosol fission products has been developed based on the MAEROS model [1,2], and the aerosol transport model has been developed and verified against an analytic solution. The deposition of aerosol FPs to the surrounding structural surfaces is modeled with recent research achievements. The developed aerosol analysis model has been successfully validated against the STORM SR-11 experimental data [3], which is International Standard Problem No. 40. Future studies include the development of the resuspension, growth, and chemical reaction models of aerosol fission products.

Ionization and Attachment Coefficients in Mixtures of $SF_6$ and $N_2$ ($SF_6-N_2$ 혼합기체(混合氣體)의 전리(電離) 및 부착계수(附着係數))

  • Kim, Sang-Nam
    • The Transactions of the Korean Institute of Electrical Engineers P
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    • v.58 no.1
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    • pp.44-47
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    • 2009
  • This paper describes the information for quantitative simulation of weakly ionized plasma. We must grasp the meaning of the plasma state condition to utilize engineering application and to understand materials of plasma state. $SF_6$ gas is widely used in industrial of insulation field. In this paper, $N_2$ is mixed to improve pure $SF_6$ gas characteristics. Electron transport coefficients in $SF_6-N_2$ mixture gases are simulated in range of E/N values from 70 to 400 [Td] at 300K and 1 Torr by using Boltzmann equation method. The results of this method. which are ionization coefficient, attachment coefficient, effective ionization coefficient, and critical E/N, can be important data to present characteristic of gas for insulation. Specially critical E/N is a data to evaluate insulation strength of a gas and is presented in this paper for various mixture ratios of $SF_6-N_2$ mixture gases.

Nanoporous graphene oxide membrane and its application in molecular sieving

  • Fatemi, S. Mahmood;Arabieh, Masoud;Sepehrian, Hamid
    • Carbon letters
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    • v.16 no.3
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    • pp.183-191
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    • 2015
  • Gas transport through graphene-derived membranes has gained much interest recently due to its promising potential in filtration and separation applications. In this work, we explore Kr-85 gas radionuclide sequestration from natural air in nanoporous graphene oxide membranes in which different sizes and geometries of pores were modeled on the graphene oxide sheet. This was done using atomistic simulations considering mean-squared displacement, diffusion coefficient, number of crossed species of gases through nanoporous graphene oxide, and flow through interlayer galleries. The results showed that the gas features have the densest adsorbed zone in nanoporous graphene oxide, compared with a graphene membrane, and that graphene oxide was more favorable than graphene for Kr separation. The aim of this paper is to show that for the well-defined pore size called P-7, it is possible to separate Kr-85 from a gas mixture containing Kr-85, O2 and N2. The results would benefit the oil industry among others.

Investigation of Nonlinear Numerical Mathematical Model of a Multiple Shaft Gas Turbine Unit

  • Kim, Soo-Yong;Valeri P. Kovalevsky
    • Journal of Mechanical Science and Technology
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    • v.17 no.12
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    • pp.2087-2098
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    • 2003
  • The development of numerical mathematical model to calculate both the static and dynamic characteristics of a multi-shaft gas turbine consisting of a single combustion chamber, including advanced cycle components such as intercooler and regenerator is presented in this paper. The numerical mathematical model is based on the simplified assumptions that quasi-static characteristic of turbo-machine and injector is used, total pressure loss and heat transfer relation for static calculation neglecting fuel transport time delay can be employed. The supercharger power has a cubical relation to its rotating velocity. The accuracy of each calculation is confirmed by monitoring mass and energy balances with comparative calculations for different time steps of integration. The features of the studied gas turbine scheme are the starting device with compressed air volumes and injector's supercharging the air directly ahead of the combustion chamber.

A study of the Insulation Characteristic in $SF_6-N_2$ Mixture Gases ($SF_6-N_2$ 혼합기체의 절연특성에 관한 연구)

  • Ha, Sung-Chul;Song, Byoung-Doo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.11b
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    • pp.613-616
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    • 2001
  • This SF6 gas is widely used in industrial of insulation field. In this paper, N2 is mixed to improve pure SF6 gas characteristics. Electron transport coefficients in SF6-N2 mixture gases are simulated in range of E/N values from 70 to 400 [Td] at 300K and 1 Torr by using Boltzmann equation method. The results of this method, which are like electron drift velocity, ionization coefficient, attachment coefficient, effective ionization coefficient, and critical EIN, can be important data to present characteristic of gas for insulation. Specially critical E/N is a data to evaluate insulation strength of a gas and is presented in this paper for various mixture ratios of SF6-N2 mixture gases.?⨀␍?܀㘱〮㜳㬓M敤楣楮攠慮搠桥污瑨

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