• Title/Summary/Keyword: Gas Hazard

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Actual Condition and Realization of Important on Laboratory Safety Management in Chemical Laboratories (화학물질 사용 실험실의 안전관리 실태와 인식도)

  • Lee, Keun-Won;Choi, Yi-Rac
    • Journal of the Korean Institute of Gas
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    • v.16 no.2
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    • pp.60-66
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    • 2012
  • With diversification of research and development activity according to fusion of state-of-the-art technology, potential hazard and risk factors in new forms have been increased in the laboratories. Also, as there are many cases where the experimental condition is extremely high/low temperature and pressure, many many accidents producing loss of life and/or injuries occur due to the extreme condition. In this study, The common fact questionnaire as the survey tool for the establishment of the accident prevention countermeasure in laboratory have been developed to safety security of the laboratory workers. The current status of chemical materials and the realization of important on laboratory safety management using the questionnaire investigated by an electronic mail and visiting survey in the laboratories and universities. The collected data was analyzed with Excel program and it can be utilized as basic data for accident prevention in laboratories.

Development of the SIS Evaluation Method Based on Reliability Analysis (신뢰도 분석에 근거한 SIS 평가 방법론 개발)

  • Kim In-Won;Jin Sang-Hwa;Song Kwang Ho;Yeo Yeong-Koo
    • Journal of the Korean Institute of Gas
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    • v.6 no.1 s.17
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    • pp.66-73
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    • 2002
  • In this study a new SIS evaluation method based on the reliability analysis has been developed. It evaluates the Safety Integrity Level (SIL) using the Fault Tree Analysis (FTA), and when the SIL falls short of the systems target level, through the reliability analysis and system retrofit, this method will satisfy the aimed SIL. A hazard evaluation was carried out on the 415V Diesel BUS to verify the SIL evaluation method based on the reliability analysis. The availability of the original 415V Diesel BUS was $99.40\%$, which comes under the category of SIL 2. After exchanging the diesel generator and the isolator switch using the developed evaluation method, the availability rose to $99.94\%$, SIL 3. By applying the method presented in this study, not only will it reduce the maintenance cost due to the prevention of accidents and reduction of loss, but also maximize the reliability of the system.

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Hazard Assessment of Explosion in Suspended Dust of Wood (목재 부유분진의 폭발 위험성 평가)

  • Lee, Keun Won;Lee, Su-Hee;Han, Ou-Sup
    • Journal of the Korean Institute of Gas
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    • v.17 no.5
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    • pp.81-86
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    • 2013
  • Accidents of dust explosion has been occurred in various industries as a plastics, pharmaceuticals, timber, grain storage, solid fuels and chemicals. In this study, the silo dust, hammer mill dust and Nyusong dust in the manufacturing process of the particle board to utilize west wood, which were selected for this experiment and were evaluated the characteristics of dust explosion. The explosion characteristics such as a maximum explosion pressure, explosion index, lower explosive limit, and minimum ignition energy in suspended dust of the wood by Siwek 20 L apparatus were measured and evaluated for the experiment. The results of this study can be used the process safety measures to prevent accidents of fire and explosion in the suspended dust of wood.

A Study on Product Liability Response System of Chemical Products by Using Failure Mode and Effect Analysis (FMEA기법을 이용한 화학제품의 PL 대응체계 연구)

  • Ko J. W.;Yoo J. H.;Kim D. H
    • Journal of the Korean Institute of Gas
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    • v.7 no.4 s.21
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    • pp.30-35
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    • 2003
  • Product liability(PL) law imposes the liability on manufacturer or wholesaler when the product defects cause harm to consumers of the products or any other parties in their lives, bodies, or properties. In Korea, the law of product liability was enforced in July 2002. In this study the Product Liability Response System of chemical products was developed by using Failure Mode and Effect Analysis(FMEA). For a case study peformed for N,N-Dimethylethylamine. First, product information was gathered through Material Safety Data Sheet(MSDS)and which considered as an instruction manual of chemical product. And an effect caused by product defects is analyzed by FMEA to get Risk Priority Number(RPN) which is calculated by multiplying of severity, occurrence, and detection of the defects. Then hazard was estimated quantitatively by RPN.

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Hazards of decomposition and explosion for Tert-butylperoxymaleate (터셔리부틸퍼옥시말레이트의 분해 및 폭발 위험성)

  • Lee, Jung-Suk;Han, Ou-Sup
    • Journal of the Korean Institute of Gas
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    • v.25 no.1
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    • pp.40-47
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    • 2021
  • In this study, hazards of decomposition and explosion for tert-butylperoxymaleate(TBPM), an organic peroxide, were evaluated by using various equipment to determine the cause of a fire explosion accident. As a result of DSC analysis, the instantaneous power density of TBPM was 26,401 kW/ml, and the NFPA reactive index(Nr) was classified as 4. And the positive value of EP(explosive propagation) and SS(shock sensitivity) showed that the TBPM had a potential hazard of explosion. From the experimental results, the shock sensitivity and friction sensitivity was rated as class 4 and 5, respectively. In the pressure vessel test, TBPM was ranked USA-PVT No.4 and evaluated as a self-reactive substance. In the combustion rate test, TBPM had the combustion rate of 167 mm/sec and was evaluated as the flammable solid classification 2 in GHS.

A Study on the Application of Criteria for the Classification of Explosive Hazardous Areas in Flammable Liquid Handling Laboratories (인화성액체 취급 연구실의 폭발위험장소 구분에 관한 기준 적용 연구)

  • Min-Ho, Kim;Jun-Seo, Lee;Eun-Hee, Kim;Byung-Chol, Ma
    • Journal of the Korean Institute of Gas
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    • v.26 no.6
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    • pp.1-8
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    • 2022
  • With the development of the chemical industry, related accidents frequently occur, and fire and explosion accidents account for a large proportion. In order to prevent fire and explosion accidents, places that handle flammable liquids are classified according to the Korean Industrial Standards (KSC IEC60079-10-1) in accordance with the relevant laws. The same applies to laboratories dealing with flammable liquids. This paper verified the applicability of the procedure for classifying explosion hazard areas according to the Korean Industrial Standards when flammable liquid release from the laboratory to form an evaporative pool, and also verified the effect of a change in ventilation speed on the release characteristics. Through this, it was found that it was difficult to apply the criteria for the classification of places at risk of explosion according to the Korean Industrial Standards, and special safety measures should be prepared.

A study on the Risks of Using Filtration Facilities at the Organic Light Emitting Diode(OLED) and Its Preventive Measures (유기발광다이오드(OLED) 소재 제조 현장 여과 설비사용 위험성 및 개선 방안 연구)

  • Jong-Ku Kwak;Chankyu Kang
    • Journal of the Korean Institute of Gas
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    • v.27 no.4
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    • pp.1-11
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    • 2023
  • The size of the OLED material market is expected to grow from $1.1 billion in 2019 to $2.3 billion in 2023, with an average annual sustainable growth of more than 19%. Among the facilities mainly used by OLED material manufacturers, accidents such as fire, explosion, and leakage frequently occur when using filtration equipment, so it is necessary to improve the risk when using filtration equipment. In this study, it was divided into four main processes, namely, assembly and disassembly process, filtration process, wet cake recovery process, and washing process in order to derive the risks associated with the use of filtration equipment. Hazard factors were derived by conducting accident case investigations, preliminary interviews, and surveys. For the analysis of questionnaire results, statistical analysis such as frequency analysis and Pearson chi-square test analysis was performed using SPSS 21, and risk improvement measures were suggested using the analyzed results. It is expected that this study will serve as a basis for dealing with safety and risk factors that may occur as the size of the OLED market expands.

Hazardous Material Process Risk Evaluation Using HAZOP and Bow-tie (HAZOP 및 BOW-TIE를 이용한 위험물질 취급공정의 위험성평가)

  • Min-Seo Nam;Byung-Tae Yoo
    • Journal of the Korean Institute of Gas
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    • v.28 no.1
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    • pp.35-43
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    • 2024
  • With continuous advancements in industry, science, and technology, there is a steady increase in the number and utilization of new chemicals. The growing societal emphasis on chemical safety management is paralleled by an increasing public demand for robust safety measures. While various ministries at the government level oversee the safety management of chemical substances, the occurrence of accidents related to chemical substances remains frequent each year due to problems such as aging facilities and careless handling. Upon analyzing domestic chemical accident cases, incidents occurred predominantly in the sequence of leakage, explosion, fire, and others. The main causes of these accidents were examined, revealing facility defects and non-compliance with safety management as the primary contributing factors. In this study, Hazard and Operability Analysis (HAZOP) was employed to identify hazardous risk factors associated with the handling of hydrofluoric acid in workplaces, and a risk assessment was performed using Bow-Tie method. Based on the results of this study, it is expected to enhance safety management plans aimed at preventing chemical accidents in workplaces dealing with similar facilities. Ultimately, these insights contribute to the development of an advanced chemical safety management system, capable of proactively preventing potential chemical accidents.

A Study on the Safety Job Procedures for Alkaline Water Electrolysis Facilities Based on Renewable Energy (재생에너지 기반 알칼라인 수전해설비의 안전작업절차 방안 연구)

  • Doo-Hyoun Seo;Tae-Hun Kim;Kwang-Won Rhie;Seong-Chul Hong;Hyun-Gi Kim
    • Journal of the Korean Institute of Gas
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    • v.28 no.1
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    • pp.27-34
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    • 2024
  • In accordance with the clean hydrogen-centered hydrogen industry development plan, technology development and demonstration operation of water electrolysis devices are being actively carried out. Risk assessments are performed on newly developed hydrogen-using facilities and supplies to identify potential hazard factors. However, in general, most industrial accidents are caused by operator's human error or incorrect work practices. Additionally, the possibility of accidents occurring during operation control, maintenance, and inspection increases. For this reason, for equipment developed for demonstration operation, the correct work methods for the main jobs of operator must be reviewed and work procedures must be prepared. Accordingly, in this study, we conducted a job safety analysis (JSA) on major jobs in the operation of water electrolysis facilities to study safe work methods and necessary measures.

Risk Evaluation of Scrubber Deposition By-Products in the Diffusion Process (Diffusion 공정 내 스크러버 퇴적 부산물의 위험성 평가)

  • Minji Kim;Jinback Lee;Seungho Jung;Keunwon Lee
    • Journal of the Korean Institute of Gas
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    • v.28 no.2
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    • pp.76-83
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    • 2024
  • In the semiconductor manufacturing process, the Diffusion process generates various reactive by-products. These by-products are deposited inside the pipes of post-processing and exhaust treatment systems, posing a potential risk of substantial dust explosions. In this study, three methods material verification, selection of analysis samples, and risk analysis were employed to address the substances produced during the Diffusion process. Among the materials handled in the Diffusion process, ZrO2, TEOD, and E-DEOS were identified as raw material capable of generating by-product dust. Test for Minimum Ignition Energy and dust explosion were conducted on the by-products collected from each processing facility. The results indicated that, in the case of MIE, none of the by-products ignited. However, the dust explosion test revealed that ZrO2 exhibited a maximum pressure of 7.6 bar and Kst value of 73.3 bar·m/s, its explosive hazard. Consequently, to mitigate such risks in semiconductor processes, it is excessive buildup.