• 한국수소및신에너지학회논문집
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• 제25권4호
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• pp.386-392
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• 2014

The effective water management in a polymer electrolyte membrane fuel cell (PEMFC) is one of the key strategies for improving cell performance and durability. In this work, an ex situ measurement was carried out to understand the water droplet behavior on the surface of gas diffusion layer (GDL) as a fundamental study for establishing novel water management. For that purpose, simplified cell including one rib and two flow channels was designed and fabricated. Using this ex situ device, the water droplet emergence through the GDL of the PEMFC was emulated to understand liquid water transport through the porous diffusion medium. Through the visualization experiment, the emergence and growth of water droplets at the channel/GDL interface are mainly observed with the surface characteristics of GDL (SGL 10BA, 24BA) and rib when the liquid water passes through the GDL and is expelled to the flow channel. It is expected that the results obtained from this study can contribute to the better understanding on the water droplet behavior (emergence and removal) in the flow channels of PEMFC.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 1999년도 춘계학술대회 논문집
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• pp.387-390
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• 1999

Electron swarm parameterdthe drift velocity and longitudinal diffusion coefficienthn $SiH_4-Ar$ mixtures containing 0.5% and 5% monosilane were measured using over the range of E/N from 0.01 to 300 Td at room temperature. Electron swarm parameters in argon were drastically changed by adding a small amount of monosilane. The electron drift velocity in both mixtures showed unusual behaviour against E/N. It had negative slope in the medium range of E/N, yet the slope was not smooth but contained a small hump. The longitudinal diffusion coefficient also showed a corresponding feature in its dependence on E/N. A two-tern approximation of the Boltzmann equation analysis and Monte Carlo simulation have been used to study electron transport coefficients.

• 열처리공학회지
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• 제5권4호
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• pp.215-223
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• 1992

This study has been performed to investigate into some effects of temperature, gas mixing ratio and time on the optical microstructure, hardness and wear characteristics of medium carbon alloy steel treated by plasma nitriding. The results obtained from the experiment are summarized as follows: (1) Optical micrographs of AISI 4140 steel plasma-nitrided by the double stage technique have revealed that the nitrided layer is composed of the compound layer and the diffusion layer. The variation in temperature at the first stage gives effects, on the formation of compound layer and the growth rate is shown to be relatively fast at $460^{\circ}C$. (2) The thickness of compound layer has been found to increase with increasing nitrogen percentage in the gas mixture and the holding time. It is therefore recommended that a shorter holding time and a lower nitrogen percentage are more effective to produce a tougher compound layer and a diffusion layer only. (3) X-ray diffraction analysis for AISI 4140 steel has shown that the compound layer consist of ${\gamma}^{\prime}-Fe_4N$ and ${\alpha}-Fe$ and that tough compound layer diffustion layer only can be obtained by the double stage plasmanitriding process. (4) There is also a tendency that the total hardened layer depth increases with increasing temperature, time and nitrogen percentage in the first stage during the double stage plasma nitriding. (5) The wear resistance of plasma nitrided specimens has been found thobe considerably increased compared to the untreated specimens and the amount of increment has appeared to increase further with increasing nitriding temperature, holding time and notrogen percentage of gas mixture in the first stage treatment.

• 한국가스학회지
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• 제22권5호
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• pp.89-99
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• 2018

화학물질을 취급하는 중 소업체의 경우 누출 사고 시 자동화 시스템이 갖춰진 안전장치에 의한 방재체계가 아닌 근로자에 의한 긴급 방재가 주로 이루어져 인명 환경피해 등의 발생 가능성이 높다. 본 연구는 이러한 한계점을 개선하기 위해 화학물질 취급공정 중 누출 사고 발생 빈도에 따라 누출 예상지점에 선별적으로 쉽게 탈 부착이 가능한 긴급 확산방재시스템에 대해 연구하였다. 이를 통해 사고대응이 상대적으로 취약한 중소기업의 화학사고를 시스템적으로 예방하여 화학물질 누출사고에 의한 인명, 환경피해를 방지할 수 있다.

• Journal of Microbiology and Biotechnology
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• 제23권9호
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• pp.1229-1243
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• 2013

In this paper, an air isolate (NITT6L) has been screened based on hemolytic activity, emulsification activity, drop collapsing test, and oil displacement test, as well as lipase activity. It was found that strain NITT6L was able to reduce the surface tension of the medium from 61.5 to 39.83 mN/m and could form stable emulsions with tested vegetable oils. Morphological, biochemical, 16S rRNA sequencing analyses, and fatty acid methyl ester analysis using gas chromatography confirmed that the air isolate under study was Pseudomonas aeruginosa. Characterization of the biosurfactant using agar double diffusion assay revealed that the biosurfactant was anionic in nature, and CTAB-methylene blue assay and Molisch test revealed its glycolipid nature. The FT-IR spectrum confirmed that the crude biosurfactant was a rhamnolipid. Using unoptimized medium containing sucrose as the carbon source, the isolate was found to produce 0.3 mg/ml of rhamnolipid in batch cultivation (shake flask) at $37^{\circ}C$ and pH 7. Optimization of the medium components was carried out using design of experiments and the yield of rhamnolipid has been enhanced to 4.6 mg/ml in 72 h of fermentation.

• 천문학회지
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• 제36권3호
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• pp.111-121
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• 2003

In order to explore the cosmic ray acceleration at the cosmological shocks, we have performed numerical simulations of one-dimensional, plane-parallel, cosmic ray (CR) modified shocks with the newly developed CRASH (Cosmic Ray Amr SHock) numerical code. Based on the hypothesis that strong Alfven waves are self-generated by streaming CRs, the Bohm diffusion model for CRs is adopted. The code includes a plasma-physics-based 'injection' model that transfers a small proportion of the thermal proton flux through the shock into low energy CRs for acceleration there. We found that, for strong accretion shocks with Mach numbers greater than 10, CRs can absorb most of shock kinetic energy and the accretion shock speed is reduced up to $20\%$, compared to pure gas dynamic shocks. Although the amount of kinetic energy passed through accretion shocks is small, since they propagate into the low density intergalactic medium, they might possibly provide acceleration sites for ultra-high energy cosmic rays of $E\ll10^{18}eV$. For internal/merger shocks with Mach numbers less than 3, however, the energy transfer to CRs is only about $10-20\%$ and so nonlinear feedback due to the CR pressure is insignificant. Considering that intracluster medium (ICM) can be shocked repeatedly, however, the CRs generated by these weak shocks could be sufficient to explain the observed non-thermal signatures from clusters of galaxies.

• 에너지공학
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• 제24권2호
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• pp.84-90
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• 2015

Hydrogen has some remarkably high values of the key properties for transport processes, such as kinematic viscosity, thermal conductivity and diffusion coefficient. Hydrogen, as an energy medium, has some distinct benefits for its high efficiency and convenience in storage, transportation and conversion. Hydrogen has much wider limits of flammability in air than methane, propane or gasoline and the minimum ignition energy is about an order of magnitude lower than for other combustibles. Statistical thermodynamics provides the relationships that we need in order to bridge this gap between the macro and the micro. Our most important application will involve the calculation of the thermodynamic properties of the ideal gas.

• 천문학회지
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• 제26권1호
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• pp.1-12
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• 1993

In order to explore the time dependence of the closure parameters of the two-fluid calculations for supernova remnants and the terminal shocks of stellar winds, we have considered a simple model in which the time evolution of the cosmic-ray distribution function was followed in the test-particle limit using the Bohm diffusion model. The particles are mostly accelerated to relativistic energy either in the free expansion phase of the SNRs or in the early phase of the stellar winds, so the evolution of the closure parameters during these early stages is substantial and should be followed correctly. We have also calculated the maximum momentum which is limited by either the age or the curvature of these spherical shocks. We found that SNRs expanding into the medium where the gas density decreases with the distance from the explosion center might be necessary to explain the observed power-law distribution of the galactic cosmic rays. The energy loss due to the escaping energetic particles has been estimated for the terminal shocks of the stellar winds.

• 한국항공우주학회지
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• 제48권3호
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• pp.187-194
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• 2020

본 연구에서는 고도에 따른 간섭 유동과 공력특성을 파악하고, 측추력 제트에 사용된 기체의 종류에 따라 다화학종 가스제트의 확산을 고려한 유동해석을 수행하였다. 공기제트에 비해서 임의로 가정한 다화학종 가스 제트를 사용하는 경우 충격파의 위치와 제트의 확산 영역이 동체전방으로 이동한다. 이로 인해 표면의 고압영역이 앞으로 나가며 같은 조건에서 보다 높은 피칭 모멘트를 갖는다. 또한 고온효과의 적용에 따라 압력분포 예측에 차이를 보였다. 그리고 저고도의 측추력제트 유동 구조와 비교했을 때 중고도 유동조건에서 주변 대기의 낮은 밀도로 측추력 제트의 두께가 더 크며, 넓은 영역에 걸쳐 확산된다.

• 터널과지하공간
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• 제29권4호
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• pp.262-279
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• 2019

고준위방사성폐기물처분장의 공학적 방벽에서는 다양한 원인으로 인해 기체가 발생한다. 만약 기체 생성 속도가 기체 확산 속도보다 빠를 경우 기체의 압력이 증가하게 되고, 기체 유입 압력(gas entry pressure)을 넘어서게 되면 기체가 급격히 벤토나이트 완충재를 통과하는 기체 이동 현상(gas migration)이 발생하게 되며 이는 사람과 주변 환경을 방사능에 노출시킬 수 있기 때문에, 공학적 방벽의 장기 건전성 확보 측면에서 기체 이동 현상을 명확히 규명하는 것이 매우 중요하다. 특히 벤토나이트 완충재와 같이 점토 물질을 다량 함유한 매질에서만 나타나는 매우 중요한 기체 흐름 현상인 팽창 흐름에 대한 수리-역학적 메커니즘을 규명하고, 기체 이동 현상의 정량적 평가를 위한 새로운 수치 해석 기법 개발 및 검증이 필수적이다. 따라서 본 연구에서는 공학적 방벽에서의 기체 이동 현상을 모사하고자 역학 손상 모델 및 손상도를 고려한 2상 유동 모델을 개발하였으며, 일정 체적 경계 조건 하에서의 1차원 기체 주입 시험 모사를 통해 개발된 모델의 적용성을 검토하였다. 수치 해석 결과 공극 수압 및 응력, 기체 유출량이 팽창 흐름 발생 시 급격히 증가하는 현상을 모사할 수 있었다.